SECȚIUNEA 1: Identificarea substanței/amestecului și a societății/întreprinderii
1.1 Identificatorul produsului
Produs
Colour for candles
Număr articol / Denumire comercială
23-887
UFI
AT44-8275-X00S-T3FK
1.2 Utilizări identificate relevante ale substanței sau amestecului și utilizări contraindicate
Utilizare generală – Coloration of hydrocarbons, waxes, oils and fats
1.3 Detalii privind furnizorul fișei cu date de securitate
Company/undertaking identification
Name bekro chemie GmbH & Co. KG
Street/POB-No.: 1 Industriestrasse 104
City D-66802 Ueberherrn
Phone # +49 6836 9198 0
Telefax # +49 6836 9198 10
E-mail info@bekro.de
1.4 Număr de telefon pentru urgențe
Name Bekro Chemie GmbH (Mo - Thu 8.00 - 16.30, Fr 8.00 - 14.30)
Phone # +49 6836 9198 0
SECȚIUNEA 2: Identificarea pericolelor
2.1 Clasificarea substanței sau a amestecului
Classification according to EC regulation 1272/2008 (CLP)
Aquatic Chronic 3; H412 Harmful to aquatic life with long lasting effects.
Eye Dam. 1; H318 Causes serious eye damage.
Repr. 2; H361f Suspected of damaging fertility.
2.2 Elemente de etichetare
| Element | Conținut |
|---|---|
| Signal word | Danger |
| Nature of Hazard | GHS05 Corrosion GHS08 Health hazard |
| Hazard statements | H318 Causes serious eye damage. H361f Suspected of damaging fertility. H412 Harmful to aquatic life with long lasting effects. |
| Safety precautions |
P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container to hazardous waste. P308+P313 IF exposed or concerned: Get medical advice/attention. P273 Avoid release to the environment. |
| Hazard components for labelling | bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate |
2.3 Alte pericole
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SECȚIUNEA 3: Compoziție/informații privind ingredientele
3.1 Substanțe
Mixture of waxes, colouring agents and additives
3.2 Amestecuri
| Ingredient periculos | Concentrație | CAS-Number | EINECS / ELINCS / NLP | REACH registration No. | Clasificare conform EC regulation 1272/2008 (CLP) |
|---|---|---|---|---|---|
| bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate | 3 % - 9,99 % | 52829-07-9 | 258-207-9 | 01-2119537297-32 | Aquatic Acute 1 (M = 1); H400 / Aquatic Chronic 2; H411 / Eye Dam. 1; H318 / Repr. 2; H361f |
Full text of H- and EUH-phrases: see section 16.
SECȚIUNEA 4: Măsuri de prim ajutor
4.1 Descrierea măsurilor de prim ajutor
| Situație | Măsuri |
|---|---|
| General information | If you feel unwell, seek medical advice. |
| In case of inhalation | Move victim to fresh air. Seek medical aid in case of troubles. |
| In case of skin contact | Thoroughly wash skin with soap and water. |
| After eye contact | Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Seek medical attention if irritation persists. |
| After swallowing | Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water. Seek medical treatment in case of troubles. |
4.2 Cele mai importante simptome și efecte, atât acute, cât și întârziate
Symptoms No data available
4.3 Indicații privind orice asistență medicală imediată și tratamente speciale necesare
Information to physician No data available
SECȚIUNEA 5: Măsuri de combatere a incendiilor
5.1 Mijloace de stingere
Suitable extinguishing media Carbon dioxide , water spray jet , extinguishing powder , foam.
Extinguishing media which must not be used for safety reasons Full water jet
5.2 Pericole speciale cauzate de substanță sau amestec
Possible combustion products Nitrogen oxides (NOx), carbon monoxide and carbon dioxide
5.3 Recomandări pentru pompieri
Special protective equipment for firefighters Wear self-contained breathing apparatus.
Additional information Do not allow water used to extinguish fire to enter drains, ground or waterways. Do not allow fire water to penetrate into surface or ground water. You have to dispose of contaminated extinguishing water according to the regulations of the authorities.
SECȚIUNEA 6: Măsuri împotriva pierderilor accidentale
6.1 Precauții personale, echipament de protecție și proceduri de urgență
Avoid dust formation. Do not breathe dust. With the formation of dust, use a dust mask. Keep away from sources of ignition - No smoking. Avoid contact with skin, eyes, and clothing.
6.2 Precauții pentru mediu
Do not allow to enter into ground-water, surface water or drains. Discharge into the environment must be avoided.
6.3 Metode și materiale pentru izolare și curățare
Take up spilled product with dustpan and brush. Avoid causing any dust. Industrial vacuum cleaner recommended to avoid causing dust. Clean soiled areas with a conventional household cleaner.
6.4 Trimitere la alte secțiuni
Personal protection equipment: see section 8, Disposal: see section 13
SECȚIUNEA 7: Manipulare și depozitare
7.1 Precauții pentru manipularea în condiții de securitate
Advices on safe handling Avoid contact with eyes and skin. When using do not eat, drink, smoke, sniff. Make sure there is sufficient air exchange and / or that working rooms are air suctioned. Avoid dust formation.
7.2 Condiții de depozitare în condiții de securitate, inclusiv eventuale incompatibilități
Requirements for storerooms and containers Keep away from sources of ignition and heat. Store in a cool dry place. Store in a well-ventilated place. Keep container tightly closed. Protect from direct sunlight.
Storage class 11
7.3 Utilizare(e) finală(e) specifică(e)
General use Coloration of hydrocarbons, waxes, oils and fats
SECȚIUNEA 8: Controale ale expunerii/protecția personală
8.1 Parametri de control
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8.2 Controale ale expunerii
| Măsură | Recomandare |
|---|---|
| Respiratory protection | With correct and proper use, and under normal conditions, breathing protection is not required. Provide good ventilation and/or an exhaust system in the work area. Wear a dust mask, in case of excessive dust. |
| Hand protection | Wear suitable gloves.- according to DIN-/EN-Norms EN 420, EN 388 and EN 374 Part 1,3 |
| Eye protection | Goggles according to EN 166. |
| Body protection | Wear suitable protective clothing and shoes. |
| General protection and hygiene measures | Keep away from food and drinks. When using do not eat, drink or smoke. Wash hands before breaks and after work. Wash contaminated clothing prior to re-use. |
SECȚIUNEA 9: Proprietăți fizice și chimice
9.1 Informații privind proprietățile fizice și chimice de bază
| Parametru | Min | Max | Observații |
|---|---|---|---|
| Form | solid | ||
| Colour | yellow-orange | ||
| Odour | characteristic | ||
| Melting point/freezing point | > 60 °C | --- | |
| Initial boiling point and boiling range | > 130 °C | 130 °C | |
| Flammability | --- | --- | |
| Explosion limits | --- | --- | |
| Flash point/flash point range | > 150 °C | 150 °C | |
| Ignition temperature | --- | --- | |
| PH | --- | --- | --- |
| Viscosity | 0 mPa.s | 0 mPa.s | --- |
| Solubility | --- | --- | --- |
| Partition coefficient: n-octanol/water | --- | --- | --- |
| Vapour pressure | --- | --- | --- |
| Density and/or relative density | --- | --- | --- |
| Relative vapour density | --- | --- | --- |
| Bulk density | --- | --- | --- |
| Flow time 4mm (DIN) | --- | --- | |
| Water solubility | Product is difficult to dissolve in water. | ||
9.2 Alte informații
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SECȚIUNEA 10: Stabilitate și reactivitate
| Subsecțiune | Informații |
|---|---|
| 10.1 Reactivity | Non-reactive |
| 10.2 Chemical stability | Product is stable under normal storage conditions. |
| 10.3 Possibility of hazardous reactions | No data available |
| 10.4 Conditions to avoid | Avoid dust formation. Avoid dust deposits. Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges. |
| 10.5 Incompatible materials | strong acids and bases, strong oxidizing agents |
| 10.6 Hazardous decomposition products | Hazardous vapours may form during fires. In case of fire may be liberated: Nitrogen oxides (NOx), carbon monoxide and carbon dioxide |
SECȚIUNEA 11: Informații toxicologice
11.1 Informații privind efectele toxicologice
General remarks No toxicological tests were conducted with the mixture.
Toxicological tests: components
| Component | Test | Valoare | Specie / Observații | Referință |
|---|---|---|---|---|
| bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate | oral LD50 | 3700.0 mg/kg | Rat | - |
| bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate | inhalative LC50 | --- | Rat | - |
| bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate | Eye irritation: | irreversible damage | Rabbit | OECD 405 |
| bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate | Mutagenicity: | not a mutagen | OECD 471 (Ames | |
| bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate | dermal LD50 | 3170.0 mg/kg | Rat | - |
| bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate | Reproductive toxicity | Suspected of damaging fertility. | Rat | OECD 443 |
| bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate | Skin sensitisation | not sensitising | guinea pig | OECD 406 |
11.2 Informații privind alte pericole
Endocrine disrupting properties No data available
Further details No data available
SECȚIUNEA 12: Informații ecologice
12.1 Toxicitate
Aquatic toxicity No data available
Ecotoxicological effects: components
| Component | Parametru | Valoare | Specie |
|---|---|---|---|
| bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate | acute Daphnia toxicity NOEC (48h) | 4.0 mg/L | Daphnia magna (Big water flea) |
| bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate | acute Daphnia toxicity EC50 (48h) | 8.58 mg/L | Daphnia magna (Big water flea) |
| bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate | acute fish toxicity LC50 (96h) | 4.4 mg/L | Lepomis macrochirus (Bluegill) |
| bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate | Bacteria toxicity IC50 (72h) | 0.705 mg/L | Pseudokirchneriella subcapitata |
12.2 Persistență și degradabilitate
Evaluation text No data available
Degree of elimination No data available
Analytical method No data available
12.3 Potențial de bioacumulare
No data available
12.4 Mobilitate în sol
No data available
12.5 Rezultatele evaluării PBT și vPvB
No data available
12.6 Proprietăți de perturbare endocrină
No data available
12.7 Alte efecte adverse
The ecotoxicological properties of this mixture are determined by the ecotoxicological properties of the single components (see section 3).
SECȚIUNEA 13: Considerații privind eliminarea
13.1 Metode de tratare a deșeurilor
| Produs / Ambalaj | Recomandare |
|---|---|
| Product | Dispose of waste according to applicable legislation. Discharge into the environment must be avoided. |
| Package | Dispose of waste according to applicable legislation. Non-contaminated packages may be recycled. Handle contaminated packages in the same way as the substance itself. |
SECȚIUNEA 14: Informații privind transportul
| Subsecțiune | Informații |
|---|---|
| 14.1 UN number | ADR, IATA, IMDG not regulated |
| 14.2 UN proper shipping name | Product designation: ADR/RID --- Proper shipping name: IATA-DGR --- Proper shipping name: IMDG --- |
| 14.3 Transport hazard class(es) | Class ADR/RID --- Classification code --- ADR/RID Class IATA-DGR --- Subrisk IATA-DGR --- Class IMDG --- Subrisk IMDG --- |
| 14.4 Packing group | ADR, IATA, IMDG No packaging for dangerous goods required |
| 14.5 Environmental hazards | Marine Pollutant - IMDG --- EmS --- Stowage and segregation --- |
| 14.6 Special precautions for user | --- |
| 14.7 Maritime transport in bulk according to IMO instruments | --- |
| Additional information | EQ --- Limited quantities --- Special Provisions --- Tunnel restriction --- Transport category --- Kemmler-number --- No dangerous good in sense of these transport regulations. |
SECȚIUNEA 15: Informații de reglementare
15.1 Reglementări/legislație privind securitatea, sănătatea și mediul specifice pentru substanță sau amestec
National regulations
Europe
---
Germany
Storage class 11
Water Hazard Class 2
Incident regulation ---
Information on working limitations Observe employment restrictions for young people. Observe employment restrictions for expectant or nursing mothers.
15.2 Evaluarea securității chimice
Chemical Safety Assessment No substance safety evaluation was conducted with the mixture/ substance.
SECȚIUNEA 16: Alte informații
Hazard statements (CLP)
H318 Causes serious eye damage.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
H361f Suspected of damaging fertility.
Reason of change General revision
Abrevieri
| Abreviere | Semnificație |
|---|---|
| --- | no data, not determined or not applicable |
| REACH | Registration, Evaluation, Authorisation and Restriction of Chemicals (Regulation (EC) No. 1907/2006) |
| OECD | Organisation for Economic Co-operation and Development |
| LD50 | Median lethal dose |
| LC50 | Median lethal concentration |
| EC50 | Median effective dose |
| IC50 | Median inhibitory concentration |
| VCI | Verband der chemischen Industrie |
| CAS | Chemical Abstract Service |
| EINECS | European Inventory of Existing Commercial Chemical Substances |
| ELINCS | European List of Notified Chemical Substances |
| NLP | No Longer Polymers |
| CLP | Regulation (EC) No 1272/2008 on Classification, Labelling and Packaging |
| EG | European Union |
| WGK | water hazard class (according to AwSV, Appendix 1 (5.2)) |
| AGW | Occupational Exposure Limit |
| ADR | Accord Européen relatif au transport international des marchandises dangereuses par route (European Agreement concerning the International Carriage of Dangerous Goods by Road) |
| RID | Règlement concernant le transport international ferroviaire des machandises dangereuses (Regulation on the international carriage of dangerous goods by rail) |
| IATA | International Air Transport Association |
| IMDG | International Martime Dangerous Goods |
| MARPOL | International Convention for the Prevention of Pollution From Ships (MARine POLlution) |
| EmS | Emergency Schedules |
| PBT | persistent, bioaccumulative and toxic |
| vPvB | very persistent and very bioaccumulative |