| Formă produs | Mixture |
|---|---|
| Denumirea produsului | DAISY TYPE #EU29375F |
| UFI | 10CM-X24K-U00P-1YP2 |
| Cod produs | EU29375F |
| Tip produs | Parfumes, fragrances |
| Grup de produs | Trade product |
| Categorie principală de utilizare | Industrial use, Professional use |
|---|---|
| Specificare utilizare industrială/profesională | Industrial |
| Destinat numai uzului profesional | For professional use only |
| Utilizarea substanței/amestecului | Parfumes, fragrances |
| Funcție sau categorie de utilizare | Odour agents |
No additional information available
| Furnizor | FRENCH COLOR & FRAGRANCE International GmbH |
|---|---|
| Adresă | Mittlerer Weg 35, DE– 79424 Auggen, Germany |
| Telefon | T 49-7631-931-8900 |
| E-mail / web | SDS@frenchcolor.com - www.frenchcolor.com |
Emergency number: 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086
Classification according to Regulation (EC) No. 1272/2008 [CLP]
| Acute toxicity (oral), Category 4 | H302 |
|---|---|
| Skin corrosion/irritation, Category 2 | H315 |
| Skin sensitisation, Category 1 | H317 |
| Hazardous to the aquatic environment – Chronic Hazard, Category 2 | H411 |
Full text of H- and EUH-statements: see section 16
Adverse physicochemical, human health and environmental effects
Harmful if swallowed. May cause an allergic skin reaction. Toxic to aquatic life with long lasting effects. Causes skin irritation.
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Conține: Benzyl benzoate; Iso E Super; ACETYL HEXAMETHYL TETRALIN; Ethyl linalool; Linalyl acetate; Linalool; Citronellol Pure; Amberwood F; Helional; Hydroxy; Hexyl cinnamic aldehyde; Cashmeran
Hazard statements (CLP): H302 - Harmful if swallowed. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements (CLP): P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash hands, forearms and face thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
Extra phrases: For professional users only.
Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
Not applicable
| Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
|---|---|---|---|
| Benzyl benzoate | CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33 | 30.9 – 61.894 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Iso E Super | CAS-No.: 54464-57-2 EC-No.: 259-174-3 REACH-no: 01-2119489989-04 | 5.6 – 11.2 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 1, H410 |
| Hexamethylindanopyran | CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 | 1.8 – 3.6 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Dihydromyrcenol | CAS-No.: 18479-58-8 EC-No.: 242-362-4 REACH-no: 01-2119457274-37 | 1 – 1.9 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 |
| Vanillin | CAS-No.: 121-33-5 EC-No.: 204-465-2 REACH-no: 01-2119516040-60 | 0.9 – 1.85 | Eye Irrit. 2, H319 |
| ACETYL HEXAMETHYL TETRALIN | CAS-No.: 21145-77-7 EC-No.: 244-240-6 | 0.6 – 1.1 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Cedarwood oil, Texas | CAS-No.: 68990-83-0 EC-No.: 294-461-7 | 0.5 – 0.9 | Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| 3,7-Dimethyl-1,6-nonadien-3-ol | CAS-No.: 10339-55-6 EC-No.: 233-732-6 REACH-no: 01-2119969272-32 | 0.4 – 0.75 | Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Linalyl acetate | CAS-No.: 115-95-7 EC-No.: 204-116-4 REACH-no: 01-2119454789-19 | 0.3 – 0.6 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Linalool | CAS-No.: 78-70-6 EC-No.: 201-134-4 EC Index-No.: 603-235-00-2 REACH-no: 01-2119474016-42 | 0.3 – 0.5 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Citronellol Pure | CAS-No.: 106-22-9 EC-No.: 203-375-0 REACH-no: 01-2119453995-23 | 0.2 – 0.45 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Amberwood F | CAS-No.: 58567-11-6 EC-No.: 261-332-1 | 0.2 – 0.3 | Skin Irrit. 2, H315 Skin Sens. 1B, H317 Aquatic Chronic 2, H411 |
| Musk ketone | CAS-No.: 81-14-1 EC-No.: 201-328-9 EC Index-No.: 609-069-00-7 | 0.1 – 0.2 | Carc. 2, H351 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Helional | CAS-No.: 1205-17-0 EC-No.: 214-881-6 REACH-no: 01-2120740119-58 | 0.1 – 0.15 | Skin Sens. 1B, H317 Repr. 2, H361 Aquatic Chronic 2, H411 |
| Hydroxy | CAS-No.: 107-75-5 EC-No.: 203-518-7 REACH-no: 01-2119973482-31 | 0.1 – 0.15 | Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Hexyl cinnamic aldehyde | CAS-No.: 101-86-0 EC-No.: 202-983-3 REACH-no: 01-2119533092-50 | 0.1 – 0.1 | Skin Sens. 1, H317 Aquatic Chronic 2, H411 |
| Carbitol substance with national workplace exposure limit(s) (AT, DE, EE, SE, SI, CH) | CAS-No.: 111-90-0 EC-No.: 203-919-7 REACH-no: 01-2119475105-42 | 0.1 – 0.1 | Not classified |
| Cashmeran | CAS-No.: 33704-61-9 EC-No.: 251-649-3 REACH-no: 01-2119977131-40 | 0.1 – 0.1 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 STOT RE 2, H373 Aquatic Chronic 2, H411 |
| decyl alcohol substance with national workplace exposure limit(s) (BG, DE, LT, LV, RO, CH) | CAS-No.: 112-30-1 EC-No.: 203-956-9 | 0 – 0.0028 | Aquatic Chronic 3, H412 |
| Aldehyde C-6 substance with national workplace exposure limit(s) (FI, PL) | CAS-No.: 66-25-1 EC-No.: 200-624-5 | 0 – 0.0007 | Flam. Liq. 3, H226 |
Full text of H- and EUH-statements: see section 16
| Măsuri generale de prim ajutor | If you feel unwell, seek medical advice (show the label where possible). Call a poison center or a doctor if you feel unwell. |
|---|---|
| După inhalare | Remove person to fresh air and keep comfortable for breathing. Allow the victim to rest. |
| După contactul cu pielea | If skin irritation occurs: Get medical advice/attention. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. |
| După contactul cu ochii | Obtain medical attention if pain, blinking or redness persists. Rinse eyes with water as a precaution. |
| După ingerare | Obtain emergency medical attention. Rinse mouth. Call a poison center or a doctor if you feel unwell. |
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
Symptoms/effects after skin contact: May cause an allergic skin reaction. Irritation.
Treat symptomatically.
Mijloace de stingere adecvate: Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
Hazardous decomposition products in case of fire: Toxic fumes may be released.
Firefighting instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.
Emergency procedures: Ventilate spillage area. Evacuate unnecessary personnel. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.
Protective equipment: Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection".
Emergency procedures: Ventilate area.
Avoid release to the environment. Notify authorities if liquid enters sewers or public waters.
For containment: Collect spillage.
Methods for cleaning up: Take up liquid spill into absorbent material. Store away from other materials.
Other information: Dispose of materials or solid residues at an authorized site.
Exposure controls and personal protection. For further information refer to section 13.
Precautions for safe handling: Ensure good ventilation of the work station. Provide good ventilation in process area to prevent formation of vapour. Avoid contact with skin and eyes. Wear personal protective equipment. Avoid breathing dust/fume/gas/mist/vapours/spray.
Hygiene measures: Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product.
| Storage conditions | Keep container closed when not in use. Store in a well-ventilated place. Keep cool. |
|---|---|
| Incompatible products | Strong bases. Strong acids. |
| Incompatible materials | Sources of ignition. Direct sunlight. |
| Storage temperature | 25 °C |
| Storage area | Store in a well-ventilated place. Store away from heat. |
| Special rules on packaging | Store in a closed container. |
| Packaging materials | Do not store in corrodable metal. |
No additional information available
| Musk ketone (81-14-1) | Austria - Occupational Exposure Limits OEL chemical category Group B Carcinogen |
|---|---|
| Carbitol (111-90-0) | Austria - Occupational Exposure Limits MAK (OEL TWA) 35 mg/m³ MAK (OEL TWA) [ppm] 6 ppm MAK (OEL STEL) 140 mg/m³ MAK (OEL STEL) [ppm] 24 ppm Estonia - Occupational Exposure Limits OEL TWA 50.1 mg/m³ OEL TWA [ppm] 10 ppm OEL chemical category Skin notation Germany - Occupational Exposure Limits (TRGS 900) AGW (OEL TWA) [1] 35 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) AGW (OEL TWA) [2] 6 ppm (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Slovenia - Occupational Exposure Limits OEL TWA 35 mg/m³ OEL TWA [ppm] 6 ppm OEL STEL 70 mg/m³ OEL STEL [ppm] 12 ppm Sweden - Occupational Exposure Limits NGV (OEL TWA) 80 mg/m³ NGV (OEL TWA) [ppm] 15 ppm KTV (OEL STEL) 170 mg/m³ KTV (OEL STEL) [ppm] 30 ppm OEL chemical category Skin notation Switzerland - Occupational Exposure Limits MAK (OEL TWA) [1] 50 mg/m³ (aerosol, inhalable dust, vapour) KZGW (OEL STEL) 100 mg/m³ (aerosol, inhalable dust, vapour) |
| decyl alcohol (112-30-1) | Bulgaria - Occupational Exposure Limits OEL TWA 10 mg/m³ Germany - Occupational Exposure Limits (TRGS 900) AGW (OEL TWA) [1] 66 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) AGW (OEL TWA) [2] 10 ppm (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Latvia - Occupational Exposure Limits OEL TWA 10 mg/m³ Lithuania - Occupational Exposure Limits IPRV (OEL TWA) 10 mg/m³ Romania - Occupational Exposure Limits OEL TWA 100 mg/m³ OEL TWA [ppm] 15 ppm OEL STEL 200 mg/m³ OEL STEL [ppm] 30 ppm Switzerland - Occupational Exposure Limits MAK (OEL TWA) [1] 66 mg/m³ (aerosol, vapour) MAK (OEL TWA) [2] 10 ppm (aerosol, vapour) KZGW (OEL STEL) 66 mg/m³ (aerosol, vapour) KZGW (OEL STEL) [ppm] 10 ppm (aerosol, vapour) |
| Aldehyde C-6 (66-25-1) | Finland - Occupational Exposure Limits HTP (OEL STEL) 42 mg/m³ HTP (OEL STEL) [ppm] 10 ppm Poland - Occupational Exposure Limits NDS (OEL TWA) 40 mg/m³ NDSCh (OEL STEL) 80 mg/m³ |
8.1.2. Recommended monitoring procedures: No additional information available
8.1.3. Air contaminants formed: No additional information available
8.1.4. DNEL and PNEC: No additional information available
8.1.5. Control banding: No additional information available
Ensure good ventilation of the work station.
Personal protective equipment: Avoid all unnecessary exposure.
Personal protective equipment symbol(s):
Eye protection: Chemical goggles or safety glasses. Safety glasses
Skin and body protection: Wear suitable protective clothing
Hand protection: Wear protective gloves.
Respiratory protection: Wear appropriate mask
No additional information available
Environmental exposure controls: Avoid release to the environment.
Other information: Do not eat, drink or smoke during use.
| Physical state | Liquid |
|---|---|
| Colour | light yellow. amber. Conforms to standard. |
| Odour | characteristic. |
| Odour threshold | No data available |
| pH | No data available |
| Relative evaporation rate (butylacetate=1) | No data available |
| Melting point | Not applicable |
| Freezing point | No data available |
| Boiling point | No data available |
| Flash point | > 93.3 °C |
| Auto-ignition temperature | No data available |
| Decomposition temperature | No data available |
| Flammability (solid, gas) | Not applicable |
| Vapour pressure | No data available |
| Relative vapour density at 20°C | No data available |
| Relative density | 1.06 |
| Solubility | No data available |
| Partition coefficient n-octanol/water (Log Pow) | No data available |
| Viscosity, kinematic | No data available |
| Viscosity, dynamic | No data available |
| Explosive properties | No data available |
| Oxidising properties | No data available |
| Explosive limits | No data available |
No additional information available
| 10.1. Reactivity | The product is non-reactive under normal conditions of use, storage and transport. |
|---|---|
| 10.2. Chemical stability | Not established. |
| 10.3. Possibility of hazardous reactions | Not established. |
| 10.4. Conditions to avoid | Extremely high or low temperatures. |
| 10.5. Incompatible materials | Strong acids. Strong bases. |
| 10.6. Hazardous decomposition products | Carbon dioxide. |
| Acute toxicity (oral) | Harmful if swallowed. |
|---|---|
| Acute toxicity (dermal) | Not classified |
| Acute toxicity (inhalation) | Not classified |
| DAISY TYPE #EU29375F | ATE CLP (oral) 795.432 mg/kg bodyweight |
|---|---|
| Benzyl benzoate (120-51-4) | LD50 oral rat 500 mg/kg LD50 oral 1160 mg/kg bodyweight LD50 dermal rabbit 4000 mg/kg |
| Hexamethylindanopyran (1222-05-5) | LD50 oral rat > 3250 mg/kg LD50 dermal rabbit > 3250 mg/kg |
| Dihydromyrcenol (18479-58-8) | LD50 oral rat 3600 mg/kg LD50 oral 3600 mg/kg bodyweight LD50 dermal rabbit > 5 g/kg |
| Vanillin (121-33-5) | LD50 dermal rabbit > 5010 mg/kg LD50 dermal 2600 mg/kg bodyweight |
| ACETYL HEXAMETHYL TETRALIN (21145-77-7) | LD50 oral rat 570 mg/kg LD50 oral 1000 mg/kg bodyweight LD50 dermal rabbit > 5 g/kg |
| 3,7-Dimethyl-1,6-nonadien-3-ol (10339-55-6) | LD50 oral 5000 mg/kg bodyweight LD50 dermal rabbit > 5000 mg/kg |
| Linalyl acetate (115-95-7) | LD50 oral rat 14550 mg/kg LD50 dermal rabbit > 5000 mg/kg |
| Linalool (78-70-6) | LD50 oral 2790 mg/kg bodyweight |
| Citronellol Pure (106-22-9) | LD50 oral rat 3450 mg/kg LD50 oral 3450 mg/kg bodyweight LD50 dermal rabbit 2650 mg/kg LD50 dermal 2650 mg/kg bodyweight |
| Amberwood F (58567-11-6) | LD50 oral rat > 5 g/kg LD50 dermal rabbit > 5000 mg/kg |
| Musk ketone (81-14-1) | LD50 oral rat 10 g/kg LD50 dermal rabbit > 10 g/kg LC50 Inhalation - Rat > 2.99 mg/l/4h |
| Helional (1205-17-0) | LD50 dermal rabbit > 2000 mg/kg |
| Hydroxy (107-75-5) | LD50 oral rat > 5 g/kg LD50 dermal rabbit > 2000 mg/kg |
| Hexyl cinnamic aldehyde (101-86-0) | LD50 oral rat 3100 mg/kg LD50 oral 3100 mg/kg bodyweight LD50 dermal rabbit > 3000 mg/kg LC50 Inhalation - Rat > 5 mg/l/4h |
| Carbitol (111-90-0) | LD50 oral rat 10502 mg/kg LD50 dermal rabbit 9143 mg/kg LC50 Inhalation - Rat > 5240 mg/m³ (Exposure time: 4 h) |
| Cashmeran (33704-61-9) | LD50 oral 2900 mg/kg bodyweight |
| decyl alcohol (112-30-1) | LD50 oral rat 4720 mg/kg LD50 dermal rabbit 3560 mg/kg |
| Aldehyde C-6 (66-25-1) | LD50 oral rat 4890 mg/kg LD50 dermal rabbit > 8100 mg/kg |
| Skin corrosion/irritation | Causes skin irritation. |
|---|---|
| Serious eye damage/irritation | Not classified |
| Respiratory or skin sensitisation | May cause an allergic skin reaction. |
| Germ cell mutagenicity | Not classified |
| Carcinogenicity | Not classified |
| Reproductive toxicity | Not classified |
| STOT-single exposure | Not classified |
| STOT-repeated exposure | Not classified |
| Cashmeran (33704-61-9) | STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure. |
| Aspiration hazard | Not classified |
| Benzyl benzoate (120-51-4) | Viscosity, kinematic 7.456 mm²/s |
| Potential adverse human health effects and symptoms | Based on available data, the classification criteria are not met |
Ecology - general: Toxic to aquatic life with long lasting effects.
Hazardous to the aquatic environment, short–term (acute): Not classified
Hazardous to the aquatic environment, long–term (chronic): Toxic to aquatic life with long lasting effects.
| Benzyl benzoate (120-51-4) | LC50 - Fish [1] 2.32 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static]) NOEC (chronic) 0.168 mg/l |
|---|---|
| Hexamethylindanopyran (1222-05-5) | LC50 - Fish [1] 0.452 mg/l Wolf, 1996d-27682 LC50 - Other aquatic organisms [1] > 0.14 mg/l REACH DOSSIER Pimephales promelas EC50 - Crustacea [2] 260 μg/l REACH Dossier EC50 - Other aquatic organisms [1] 0.131 mg/l REACH Dossier |
| Vanillin (121-33-5) | LC50 - Fish [1] 53 – 61.3 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) LC50 - Fish [2] 88 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) NOEC (acute) 10000 mg/kg (Exposure time: 42 Days - Species: Eisenia foetida [soil dry weight]) |
| 3,7-Dimethyl-1,6-nonadien-3-ol (10339-55-6) | LC50 - Fish [1] 24 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static]) |
| Linalyl acetate (115-95-7) | LC50 - Fish [1] 11 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [flow-through]) |
| Linalool (78-70-6) | EC50 96h - Algae [1] 88.3 mg/l (Species: Desmodesmus subspicatus) |
| Carbitol (111-90-0) | LC50 - Fish [1] 10000 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) LC50 - Fish [2] 19100 – 23900 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [flow-through]) EC50 - Crustacea [1] 3940 – 4670 mg/l (Exposure time: 48 h - Species: Daphnia magna) |
| Cashmeran (33704-61-9) | LC50 - Fish [1] 10.3 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static]) |
| decyl alcohol (112-30-1) | LC50 - Fish [1] 2.2 – 2.5 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) LC50 - Fish [2] 4.12 – 6.2 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) EC50 - Crustacea [1] 3 mg/l (Exposure time: 48 h - Species: Daphnia magna) |
| Aldehyde C-6 (66-25-1) | LC50 - Fish [1] 12 – 16.5 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) |
DAISY TYPE #EU29375F: Persistence and degradability Not established.
Benzyl benzoate (120-51-4): Persistence and degradability May cause long-term adverse effects in the environment.
Cedarwood oil, Texas (68990-83-0): Persistence and degradability Not established.
Amberwood F (58567-11-6): Persistence and degradability May cause long-term adverse effects in the environment.
DAISY TYPE #EU29375F: Bioaccumulative potential Not established.
Benzyl benzoate (120-51-4): Partition coefficient n-octanol/water (Log Pow) 3.97 (at 25 °C); Bioaccumulative potential Not established.
Hexamethylindanopyran (1222-05-5): BCF - Fish [1] (1618 dimensionless (whole body w.w.); Partition coefficient n-octanol/water (Log Pow) 5.3 (at 25 °C (at pH 7)
Dihydromyrcenol (18479-58-8): Partition coefficient n-octanol/water (Log Pow) 3.25 (at 40 °C (at pH 7)
Vanillin (121-33-5): Partition coefficient n-octanol/water (Log Pow) 1.23 (at 22 °C)
ACETYL HEXAMETHYL TETRALIN (21145-77-7): Partition coefficient n-octanol/water (Log Pow) 5.7 (at 24 °C)
Cedarwood oil, Texas (68990-83-0): Bioaccumulative potential Not established.
3,7-Dimethyl-1,6-nonadien-3-ol (10339-55-6): Partition coefficient