| Formă produs | Amestec |
|---|---|
| Denumire comercială | RED CHERRY VANILLA #EU21045F |
| UFI | 4T8V-T1JS-G00A-U9JN |
| Cod produs | EU21045F |
| Tip produs | Parfumuri, fragranțe |
| Grup produs | Produs comercial |
| Formă produs | Amestec |
|---|---|
| Denumire comercială | RED CHERRY VANILLA #EU21045F |
| UFI | 4T8V-T1JS-G00A-U9JN |
| Cod produs | EU21045F |
| Tip produs | Parfumuri, fragranțe |
| Grup produs | Produs comercial |
1.2.1. Utilizări relevante identificate
Categorie principală de utilizare: Utilizare industrială, utilizare profesională
Spec. utilizare industrială/profesională: Numai pentru uz profesional
Utilizare industrială
Utilizarea substanței/amestecului: Parfumuri, fragranțe
Categoria funcției sau utilizării: Agenți odoranți
1.2.2. Utilizări nerecomandate
Nu sunt disponibile informații suplimentare
FRENCH COLOR & FRAGRANCE International GmbH
Mittlerer Weg 35
DE– 79424 Auggen
Germany
T 49-7631-931-8900
SDS@frenchcolor.com - www.frenchcolor.com
Emergency number : 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086
Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Acute toxicity (oral), Category 4 H302
Skin sensitisation, Category 1 H317
Hazardous to the aquatic environment – Acute Hazard, Category 1 H400
Hazardous to the aquatic environment – Chronic Hazard, Category 2 H411
Textul integral al frazelor H și EUH: vezi secțiunea 16
Efecte adverse fizico-chimice, asupra sănătății umane și asupra mediului
Harmful if swallowed. Toxic to aquatic life with long lasting effects. Very toxic to aquatic life. May cause an allergic skin reaction.
Etichetare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Pictograme de pericol (CLP) : GHS07 GHS09
Cuvânt de avertizare (CLP) : Warning
Conține : Benzyl benzoate; Benzaldehyde; Ethyl maltol; Heliotropine; Hexyl cinnamic aldehyde; beta-Caryophyllene; Allyl cyclohexylpropionate; Eugenol; Lemon oil
Fraze de pericol (CLP) : H302 - Harmful if swallowed.
H317 - May cause an allergic skin reaction.
H410 - Very toxic to aquatic life with long lasting effects.
Fraze de precauție (CLP) : P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash hands, forearms and face thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
Fraze suplimentare : For professional users only.
Nu conține substanțe PBT/vPvB ≥ 0.1% evaluate în conformitate cu REACH Anexa XIII
Amestecul nu conține substanțe incluse în lista stabilită în conformitate cu Articolul 59(1) din REACH pentru proprietăți perturbatoare endocrine sau nu este identificat ca având proprietăți perturbatoare endocrine în conformitate cu criteriile stabilite în Regulamentul delegat al Comisiei (UE) 2017/2100 sau Regulamentul Comisiei (UE) 2018/605 la o concentrație egală sau mai mare de 0,1 %
| Denumire | Identificator produs | % | Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP] |
|---|---|---|---|
| Benzyl benzoate | CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33 | 39.2 – 59.2 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Hexamethylindanopyran | CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 | 4.375 – 8.75 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Benzaldehyde substanță cu valori limită naționale de expunere la locul de muncă (BG, FI, HU, LT, LV, PL) | CAS-No.: 100-52-7 EC-No.: 202-860-4 EC Index-No.: 605-012-00-5 REACH-no: 01-2119455540-44 | 1.875 – 3.75 | Acute Tox. 4 (Oral), H302 |
| Vanillin | CAS-No.: 121-33-5 EC-No.: 204-465-2 REACH-no: 01-2119516040-60 | 1.75 – 3.5 | Eye Irrit. 2, H319 |
| Dimethylbenzyl carbinyl butyrate(DMBCB) | CAS-No.: 10094-34-5 EC-No.: 233-221-8 REACH-no: 01-2120742578-44 | 1.75 – 3.5 | Skin Irrit. 2, H315 Aquatic Chronic 3, H412 |
| Ethyl maltol | CAS-No.: 4940-11-8 EC-No.: 225-582-5 | 1.3 – 2.6 | Acute Tox. 4 (Oral), H302 |
| Lemon oil | CAS-No.: 8008-56-8 EC-No.: 284-515-8 | 0.925 – 1.85 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Repr. 2, H361 Aquatic Chronic 2, H411 |
| Aldehyde C-14 | CAS-No.: 104-67-6 EC-No.: 203-225-4 REACH-no: 01-2119959333-34 | 0.65 – 1.3 | Aquatic Chronic 3, H412 |
| Heliotropine | CAS-No.: 120-57-0 EC-No.: 204-409-7 REACH-no: 01-2119983608-21 | 0.45 – 0.9 | Skin Sens. 1B, H317 |
| Hexyl cinnamic aldehyde | CAS-No.: 101-86-0 EC-No.: 202-983-3 REACH-no: 01-2119533092-50 | 0.225 – 0.45 | Skin Sens. 1, H317 Aquatic Chronic 2, H411 |
| Benzyl acetate substanță cu valori limită naționale de expunere la locul de muncă (BE, DK, ES, IE, LT, LV, PT, RO) | CAS-No.: 140-11-4 EC-No.: 205-399-7 REACH-no: 01-2119638272-42 | 0.225 – 0.45 | Aquatic Chronic 3, H412 |
| beta-Caryophyllene | CAS-No.: 87-44-5 EC-No.: 201-746-1 REACH-no: 01-2120745237-53 | 0.06875 – 0.2 | Skin Sens. 1B, H317 Asp. Tox. 1, H304 |
| Allyl cyclohexylpropionate | CAS-No.: 2705-87-5 EC-No.: 220-292-5 | 0.1 – 0.2 | Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Skin Sens. 1, H317 Aquatic Chronic 1, H410 |
| cis-3-Hexenyl salicylate | CAS-No.: 65405-77-8 EC-No.: 265-745-8 | 0.1 – 0.2 | Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Eugenol | CAS-No.: 97-53-0 EC-No.: 202-589-1 REACH-no: 01-2119971802-33 | 0.03125 – 0.125 | Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| .beta.-Pinene substanță cu valori limită naționale de expunere la locul de muncă (BE, EE, ES, LT, PT, SE, NO) | CAS-No.: 127-91-3 EC-No.: 204-872-5 | < 0.0025 | Flam. Liq. 3, H226 |
| .alpha.-Pinene substanță cu valori limită naționale de expunere la locul de muncă (BE, EE, ES, LT, PT, SE, NO) | CAS-No.: 80-56-8 EC-No.: 201-291-9 | < 0.0025 | Flam. Liq. 3, H226 |
| d-Limonene substanță cu valori limită naționale de expunere la locul de muncă (DE, ES, FI, SI, NO, CH) | CAS-No.: 5989-27-5 EC-No.: 227-813-5 EC Index-No.: 601-096-00-2 REACH-no: 01-2119493353-35 | < 0.0025 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 |
Textul integral al frazelor H și EUH: vezi secțiunea 16
4.1. Descrierea măsurilor de prim ajutor
First-aid measures general : Call a poison center or a doctor if you feel unwell.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse eyes with water as a precaution.
First-aid measures after ingestion : Rinse mouth. Call a poison center or a doctor if you feel unwell.
4.2. Cele mai importante simptome și efecte, atât acute, cât și întârziate
Symptoms/effects after skin contact : May cause an allergic skin reaction.
4.3. Indicații privind orice asistență medicală imediată și tratamente speciale necesare
Treat symptomatically.
5.1. Mijloace de stingere
Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.
5.2. Pericole speciale cauzate de substanță sau amestec
Hazardous decomposition products in case of fire : Toxic fumes may be released.
5.3. Recomandări pentru pompieri
Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.
6.1. Precauții personale, echipament de protecție și proceduri de urgență
6.1.1. Pentru personalul care nu intervine în situații de urgență
Emergency procedures : Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.
6.1.2. Pentru persoanele care intervin în situații de urgență
Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".
6.2. Precauții pentru mediu
Avoid release to the environment.
6.3. Metode și material pentru izolare și curățare
For containment : Collect spillage.
Methods for cleaning up : Take up liquid spill into absorbent material.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Trimitere la alte secțiuni
For further information refer to section 13.
7.1. Precauții pentru manipulare în siguranță
Precautions for safe handling : Ensure good ventilation of the work station. Wear personal protective equipment. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.
Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
7.2. Condiții de depozitare în siguranță, inclusiv eventuale incompatibilități
Storage conditions : Store in a well-ventilated place. Keep cool.
Storage temperature : 25 °C
Storage area : Store in a well-ventilated place. Store away from heat.
Special rules on packaging : Store in a closed container.
Packaging materials : Do not store in corrodable metal.
7.3. Utilizări finale specifice
Nu sunt disponibile informații suplimentare
8.1. Parametri de control
8.1.1. Valori limită naționale de expunere profesională și valori biologice limită
| Substanță | Țară / limită | Valoare |
|---|---|---|
| Benzaldehyde (100-52-7) | Bulgaria - Occupational Exposure Limits / OEL TWA | 5 mg/m³ |
| Finland - Occupational Exposure Limits / HTP (OEL TWA) [1] | 4.4 mg/m³ | |
| Finland - Occupational Exposure Limits / HTP (OEL TWA) [2] | 1 ppm | |
| Finland - Occupational Exposure Limits / HTP (OEL C) | 17.4 mg/m³ | |
| Finland - Occupational Exposure Limits / HTP (OEL C) [ppm]] | 4 ppm | |
| Hungary - Occupational Exposure Limits / AK (OEL TWA) | 5 mg/m³ |
| Substanță | Țară / limită | Valoare |
|---|---|---|
| Benzyl acetate (140-11-4) | Belgium - Occupational Exposure Limits / OEL TWA | 62 mg/m³ |
| OEL TWA [ppm] | 10 ppm | |
| Denmark - Occupational Exposure Limits / OEL TWA [1] | 61 mg/m³ | |
| OEL TWA [2] | 10 ppm | |
| OEL STEL | 122 mg/m³ | |
| OEL STEL [ppm] | 20 ppm |
Secțiunea continuă în paginile următoare cu valori limită pentru .beta.-Pinene, .alpha.-Pinene și d-Limonene, conform documentului original.
8.1.2. Proceduri de monitorizare recomandate
Nu sunt disponibile informații suplimentare
8.1.3. Contaminanți de aer formați
Nu sunt disponibile informații suplimentare
8.1.4. DNEL și PNEC
Nu sunt disponibile informații suplimentare
8.1.5. Control banding
Nu sunt disponibile informații suplimentare
8.2. Controale ale expunerii
8.2.1. Controale tehnice corespunzătoare
Appropriate engineering controls: Ensure good ventilation of the work station.
8.2.2. Echipament de protecție personală
8.2.2.1. Protecția ochilor și feței
Eye protection: Safety glasses
8.2.2.2. Protecția pielii
Skin and body protection: Wear suitable protective clothing
Hand protection: Protective gloves
8.2.2.3. Protecția respirației
Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment
8.2.2.4. Pericole termice
Nu sunt disponibile informații suplimentare
8.2.3. Controale ale expunerii asupra mediului
Environmental exposure controls: Avoid release to the environment.
9.1. Informații privind proprietățile fizice și chimice de bază
| Proprietate | Valoare |
|---|---|
| Physical state | Liquid |
| Colour | light yellow. amber. Conforms to standard. |
| Odour | characteristic. |
| Odour threshold | Not available |
| Melting point | Not applicable |
| Freezing point | Not available |
| Boiling point | Not available |
| Flammability | Not applicable |
| Explosive limits | Not available |
| Lower explosion limit | Not available |
| Upper explosion limit | Not available |
| Flash point | > 93.33 °C (closed cup) ASTM D7094 |
| Auto-ignition temperature | Not available |
| Decomposition temperature | Not available |
| pH | Not available |
| Viscosity, kinematic | Not available |
| Solubility | Not available |
| Partition coefficient n-octanol/water (Log Kow) | Not available |
| Vapour pressure | Not available |
| Vapour pressure at 50°C | Not available |
| Density | Not available |
| Relative density | ≈ 1.07 |
| Relative vapour density at 20°C | Not available |
| Particle characteristics | Not applicable |
9.2. Alte informații
9.2.1. Informații privind clasele de pericol fizic: Nu sunt disponibile informații suplimentare
9.2.2. Alte caracteristici de siguranță: Nu sunt disponibile informații suplimentare
10.1. Reactivitate
The product is non-reactive under normal conditions of use, storage and transport.
10.2. Stabilitate chimică
Stable under normal conditions.
10.3. Posibilitatea de reacții periculoase
No dangerous reactions known under normal conditions of use.
10.4. Condiții de evitat
None under recommended storage and handling conditions (see section 7).
10.5. Materiale incompatibile
No additional information available
10.6. Produși de descompunere periculoși
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
11.1. Informații privind clasele de pericol definite în Regulamentul (CE) nr. 1272/2008
Acute toxicity (oral) : Harmful if swallowed.
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
RED CHERRY VANILLA #EU21045F
ATE CLP (oral) 809.301 mg/kg bodyweight
... tabelul complet al valorilor LD50/LC50 și al informațiilor toxice continuă conform documentului original ...
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
11.2. Informații privind alte pericole
Nu sunt disponibile informații suplimentare
12.1. Toxicitate
Ecology - general : Toxic to aquatic life with long lasting effects. Very toxic to aquatic life.
Hazardous to the aquatic environment, short–term (acute) : Very toxic to aquatic life.
Hazardous to the aquatic environment, long–term (chronic) : Toxic to aquatic life with long lasting effects.
... datele ecotoxicologice detaliate pentru componente continuă conform documentului original ...
12.2. Persistență și degradabilitate
Benzyl benzoate (120-51-4): May cause long-term adverse effects in the environment.
12.3. Potențial de bioacumulare
... valorile Log Pow / BCF pentru componente continuă conform documentului original ...
12.4. Mobilitate în sol
Nu sunt disponibile informații suplimentare
12.5. Rezultatele evaluării PBT și vPvB
Nu sunt disponibile informații suplimentare
12.6. Proprietăți de perturbare endocrină
Nu sunt disponibile informații suplimentare
12.7. Alte efecte adverse
Nu sunt disponibile informații suplimentare
13.1. Metode de tratare a deșeurilor
Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.
HP Code :
HP3 - “Flammable:” …
HP6 - “Acute Toxicity:” …
HP14 - “Ecotoxic:” …
În conformitate cu ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|
| UN 3082 | UN 3082 | UN 3082 | UN 3082 | UN 3082 |
| ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (HEXAMETHYLINDANOPYRAN) | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (HEXAMETHYLINDANOPYRAN) | Environmentally hazardous substance, liquid, n.o.s. (HEXAMETHYLINDANOPYRAN) | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (HEXAMETHYLINDANOPYRAN) | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (HEXAMETHYLINDANOPYRAN) |
| 9 | 9 | 9 | 9 | 9 |
| III | III | III | III | III |
| Dangerous for the environment: Yes | Dangerous for the environment: Yes Marine pollutant: Yes |
Dangerous for the environment: Yes | Dangerous for the environment: Yes | Dangerous for the environment: Yes |
14.6. Precauții speciale pentru utilizator
... instrucțiunile detaliate ADR/IMDG/IATA/ADN/RID continuă conform documentului original ...
14.7. Transport maritim în vrac conform instrumentelor IMO
Nu se aplică
15.1. Reglementări/legislație privind securitatea, sănătatea și mediul specifice pentru substanță sau amestec
15.1.1. Reglementări UE
REACH Annex XVII (Restriction List)
EU restriction list (REACH Annex XVII)
3(a) .beta.-Pinene ; .alpha.-Pinene ; d-Limonene ; Lemon oil
3(b) RED CHERRY VANILLA #EU21045F ; Benzyl benzoate ; Benzaldehyde ; Hexyl cinnamic aldehyde ; Allyl cyclohexylpropionate ; d-Limonene ; Eugenol ; Dimethylbenzyl carbinyl butyrate(DMBCB) ; Lemon oil
3(c) RED CHERRY VANILLA #EU21045F ; Benzyl benzoate ; Hexamethylindanopyran ; Aldehyde C-14 ; Hexyl cinnamic aldehyde ; Benzyl acetate ; Allyl cyclohexylpropionate ; cis-3-Hexenyl salicylate ; d-Limonene ; Dimethylbenzyl carbinyl butyrate(DMBCB) ; Lemon oil
40. .beta.-Pinene ; .alpha.-Pinene ; d-Limonene ; Lemon oil
REACH Annex XIV (Authorisation List): Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC): Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent): Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants): Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009): Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Explosives Precursors Regulation (2019/1148): Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004): Contains substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
Name CN designation CAS-No. CN code Category Threshold Annex
Piperonal — 120-57-0 — 2932 93 00 — Category 1 — Annex I
15.1.2. Reglementări naționale
France — Occupational diseases — RG 84: Conditions caused by liquid organic solvents for professional use...
Germany — Water hazard class (WGK) : WGK 2, Significantly hazardous to water (Classification according to AwSV, Annex 1).
List of sensitizing substances (TRGS 907) : Contains sensitizing substances according TRGS 907.
Hazardous Incident Ordinance (12. BImSchV) : Is not subject of the Hazardous Incident Ordinance (12. BImSchV)
Netherlands — ABM category : A(1) - highly toxic for aquatic organisms, may have longterm hazardous effects in aquatic environment
Denmark — Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed
Danish National Regulations : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2. Evaluare a securității chimice
No chemical safety assessment has been carried out
Textul complet al frazelor H și EUH:
| Cod | Descriere |
|---|---|
| Acute Tox. 4 (Dermal) | Acute toxicity (dermal), Category 4 |
| Acute Tox. 4 (Oral) | Acute toxicity (oral), Category 4 |
| Aquatic Acute 1 | Hazardous to the aquatic environment – Acute Hazard, Category 1 |
| Aquatic Chronic 1 | Hazardous to the aquatic environment – Chronic Hazard, Category 1 |
| Aquatic Chronic 2 | Hazardous to the aquatic environment – Chronic Hazard, Category 2 |
| Aquatic Chronic 3 | Hazardous to the aquatic environment – Chronic Hazard, Category 3 |
| Asp. Tox. 1 | Aspiration hazard, Category 1 |
| Eye Irrit. 2 | Serious eye damage/eye irritation, Category 2 |
| Flam. Liq. 3 | Flammable liquids, Category 3 |
| H226 | Flammable liquid and vapour. |
| H302 | Harmful if swallowed. |
| H304 | May be fatal if swallowed and enters airways. |
| H312 | Harmful in contact with skin. |
| H315 | Causes skin irritation. |
| H317 | May cause an allergic skin reaction. |
| H319 | Causes serious eye irritation. |
| H361 | Suspected of damaging fertility or the unborn child. |
| H400 | Very toxic to aquatic life. |
| H410 | Very toxic to aquatic life with long lasting effects. |
| H411 | Toxic to aquatic life with long lasting effects. |
| H412 | Harmful to aquatic life with long lasting effects. |
| Repr. 2 | Reproductive toxicity, Category 2 |
| Skin Irrit. 2 | Skin corrosion/irritation, Category 2 |
| Skin Sens. 1 | Skin sensitisation, Category 1 |
| Skin Sens. 1B | Skin sensitisation, category 1B |
The classification complies with : ATP 12
Safety Data Sheet (SDS), EU
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.