Forma produsului: Mixture
Numele produsului: FRENCH VANILLA #EU17182F 10% in DPG
Cod produs: EU17182F_10%
Tip produs: Perfumes, Fragrances
1.2.1. Utilizări relevante identificate
Specificație utilizare industrială/profesională: Industrial
For professional use only
Utilizarea substanței/amestecului: Perfumes, Fragrances
Categorie funcțională sau de utilizare: Odour agents
1.2.2. Utilizări contraindicate
No additional information available
No additional information available
No additional information available
Clasificare conform Regulamentului (EC) No. 1272/2008 [CLP]
Skin sensitization, Category 1 H317
Hazardous to the aquatic environment – Chronic Hazard Category 3 H412
Full text of H- and EUH-statements: see section 16
Efecte fizico-chimice, asupra sănătății umane și asupra mediului
No additional information available
Etichetare conform Regulamentului (EC) No. 1272/2008 [CLP]
Pictograme de pericol (CLP): GHS07
Cuvânt de avertizare (CLP): Warning
Conține: benzyl alcohol; Heliotropine
Fraze de pericol (CLP):
H317 - May cause an allergic skin reaction.
H412 - Harmful to aquatic life with long lasting effects.
Fraze de precauție (CLP):
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P321 - Specific treatment (see supplemental first aid instruction on this label).
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Not applicable
| Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
|---|---|---|---|
| benzyl benzoate | CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33 |
3.28 – 6.56 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| benzyl alcohol substance with national workplace exposure limit(s) (BG, CZ, DE, FI, LT, LV, PL, SI, CH) |
CAS-No.: 100-51-6 EC-No.: 202-859-9 EC Index-No.: 603-057-00-5 REACH-no: 01-2119492630-38 |
0.63 – 1.25 | Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Ethyl vanillin | CAS-No.: 121-32-4 EC-No.: 204-464-7 REACH-no: 01-211958961-24 |
0.5 – 1 | Eye Irrit. 2, H319 |
| Heliotropine | CAS-No.: 120-57-0 EC-No.: 204-409-7 REACH-no: 01-2119983608-21 |
0.06 – 0.125 | Skin Sens. 1B, H317 |
| Ethyl acetoacetate substance with national workplace exposure limit(s) (RO) |
CAS-No.: 141-97-9 EC-No.: 205-516-1 |
0.03 – 0.05 | Not classified |
| benzaldehyde substance with national workplace exposure limit(s) (BG, FI, HU, LT, LV, PL) |
CAS-No.: 100-52-7 EC-No.: 202-860-4 EC Index-No.: 605-012-00-5 REACH-no: 01-2119455540-44 |
0.01 – 0.01 | Acute Tox. 4 (Oral), H302 |
| butyric acid substance with national workplace exposure limit(s) (BG, LT, LV, RO) |
CAS-No.: 107-92-6 EC-No.: 203-532-3 EC Index-No.: 607-135-00-X |
0.01 – 0.01 | Skin Corr. 1B, H314 |
Full text of H- and EUH-statements: see section 16
First-aid measures general: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation: Allow affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
First-aid measures after eye contact: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
First-aid measures after ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
No additional information available
Suitable extinguishing media: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media: Do not use a heavy water stream.
No additional information available
Firefighting instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1. For non-emergency personnel
Emergency procedures: Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment: Equip cleanup crew with proper protection.
Emergency procedures: Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Methods for cleaning up: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Heading 8. Exposure controls and personal protection.
Precautions for safe handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor.
Storage conditions: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Incompatible products: Strong bases. Strong acids.
Incompatible materials: Sources of ignition. Direct sunlight.
Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids
Joint storage table:
Joint storage not permitted for : LGK 1, LGK 6.2, LGK 7
Joint storage with restrictions permitted for : LGK 4.1A, LGK 4.3, LGK 5.1C
Joint storage permitted for : LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13
Storage class (LK): LK 10/12 - Liquids
No additional information available
| Substanță | Țară / limită | Valoare |
|---|---|---|
| benzyl alcohol (100-51-6) | Bulgaria - Occupational Exposure Limits / OEL TWA | 5 mg/m³ |
| Czech Republic - Occupational Exposure Limits / PEL (OEL TWA) | 40 mg/m³ | |
| Finland - Occupational Exposure Limits / HTP (OEL TWA) | 45 mg/m³ 10 ppm | |
| Germany - Occupational Exposure Limits (TRGS 900) / AGW (OEL TWA) | 22 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 5 ppm (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Chemical category skin notation | |
| Latvia - Occupational Exposure Limits / OEL TWA | 5 mg/m³ | |
| Lithuania - Occupational Exposure Limits / IPRV (OEL TWA) | 5 mg/m³ OEL chemical category skin notation | |
| Poland - Occupational Exposure Limits / NDS (OEL TWA) | 240 mg/m³ | |
| benzyl alcohol (100-51-6) | Slovenia - Occupational Exposure Limits / OEL TWA | 22 mg/m³ 5 ppm |
| Slovenia - Occupational Exposure Limits / OEL STEL | 44 mg/m³ 10 ppm | |
| Slovenia - Occupational Exposure Limits / OEL chemical category | Potential for cutaneous absorption | |
| Switzerland - Occupational Exposure Limits / MAK (OEL TWA) | 22 mg/m³ (aerosol, vapour) 5 ppm (aerosol, vapour) skin notation | |
| Ethyl acetoacetate (141-97-9) | Romania - Occupational Exposure Limits / OEL TWA | 100 mg/m³ 19 ppm |
| Romania - Occupational Exposure Limits / OEL STEL | 200 mg/m³ 38 ppm | |
| benzaldehyde (100-52-7) | Bulgaria - Occupational Exposure Limits / OEL TWA | 5 mg/m³ |
| Finland - Occupational Exposure Limits / HTP (OEL TWA) | 4.4 mg/m³ 1 ppm | |
| Finland - Occupational Exposure Limits / HTP (OEL C) | 17.4 mg/m³ 4 ppm | |
| Hungary - Occupational Exposure Limits / AK (OEL TWA) CK (OEL STEL) | 5 mg/m³ 10 mg/m³ | |
| Latvia/Lithuania/Poland - Occupational Exposure Limits | Latvia: 5 mg/m³ Lithuania: 5 mg/m³ Poland NDS: 10 mg/m³ Poland NDSCh: 40 mg/m³ | |
| butyric acid (107-92-6) | Bulgaria - Occupational Exposure Limits / OEL TWA | 10 mg/m³ |
| Latvia - Occupational Exposure Limits / OEL TWA | 10 mg/m³ | |
| Lithuania - Occupational Exposure Limits / IPRV (OEL TWA) | 10 mg/m³ | |
| Romania - Occupational Exposure Limits / OEL TWA | 15 mg/m³ 4 ppm | |
| Romania - Occupational Exposure Limits / OEL STEL | 30 mg/m³ 8 ppm |
8.1.2. Proceduri recomandate de monitorizare
No additional information available
8.1.3. Contaminanți de aer formați
No additional information available
8.1.4. DNEL and PNEC
No additional information available
8.1.5. Control banding
No additional information available
8.2.1. Măsuri tehnice adecvate
No additional information available
8.2.2. Echipament individual de protecție
Personal protective equipment:
Avoid all unnecessary exposure.
Personal protective equipment symbol(s):
8.2.2.1. Protecția ochilor și feței
Eye protection: Chemical goggles or safety glasses
8.2.2.2. Protecția pielii
Hand protection: Wear protective gloves.
8.2.2.3. Protecția respiratorie
Respiratory protection: Wear appropriate mask
8.2.2.4. Pericole termice
No additional information available
8.2.3. Controale ale expunerii pentru mediu
Other information: Do not eat, drink or smoke during use.
Physical state: Liquid
Color: Conforms to standard.
Odor: characteristic.
Odor threshold: Not available
Melting point: Not available
Freezing point: Not available
Boiling point: Not available
Flammability: Non flammable.
Lower explosion limit: Not available
Upper explosion limit: Not available
Flash point: > 93 °C
Auto-ignition temperature: Not available
Decomposition temperature: Not available
pH: Not available
Viscosity, kinematic: Not available
Solubility: Not available
Partition coefficient n-octanol/water (Log Kow): Not available
Vapor pressure: Not available
Vapor pressure at 50°C: Not available
Density: Not available
Relative density: Not available
Relative vapor density at 20°C: Not available
Particle characteristics: Not applicable
9.2.1. Informații privind clasele de pericol fizic
No additional information available
9.2.2. Alte caracteristici de siguranță
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
Not established.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide.
Acute toxicity (oral): Not classified
Acute toxicity (dermal): Not classified
Acute toxicity (inhalation): Not classified
| Substanță | Date toxicologice |
|---|---|
| benzyl benzoate (120-51-4) | LD50 oral rat > 2000 mg/kg (Source: ECHA_API) LD50 oral 1160 mg/kg body weight LD50 dermal rabbit 4000 mg/kg (Source: NLM_CIP) |
| benzyl alcohol (100-51-6) | LD50 oral rat 1230 mg/kg (Source: NLM_CIP) LD50 oral 1570 mg/kg |
| Ethyl vanillin (121-32-4) | LD50 oral rat 1590 mg/kg (Source: NLM_CIP) LD50 oral 3000 mg/kg body weight LD50 dermal rat > 2000 mg/kg (Source: ECHA_API) |
| Heliotropine (120-57-0) | LD50 oral rat 2700 mg/kg (Source: NLM_CIP) LD50 oral 2700 mg/kg body weight LD50 dermal rat > 5000 mg/kg (Source: ECHA_API) |
| Ethyl acetoacetate (141-97-9) | LD50 oral rat 3980 mg/kg (Source: NLM_CIP) LD50 dermal rabbit > 5000 mg/kg (Source: NLM_CIP) |
| benzaldehyde (100-52-7) | LD50 oral rat 1292 mg/kg (Source: JAPAN_GHS) LD50 dermal rabbit > 1250 mg/kg (Source: JAPAN_GHS) LC50 Inhalation - Rat < 5 mg/l/4h |
| butyric acid (107-92-6) | LD50 oral rat 2 g/kg (Source: NLM_CIP) LD50 oral 1630 mg/kg body weight LD50 dermal rabbit 530 mg/kg (Source: NLM_HSDB) |
Skin corrosion/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Serious eye damage/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Respiratory or skin sensitization: May cause an allergic skin reaction.
Additional information: Based on available data, the classification criteria are not met
Germ cell mutagenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Carcinogenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Reproductive toxicity: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-single exposure: Not classified
Hazardous to the aquatic environment, short–term (acute): Not classified
Hazardous to the aquatic environment, long–term (chronic): Harmful to aquatic life with long lasting effects.
| Substanță | Date ecotoxicologice |
|---|---|
| benzyl benzoate (120-51-4) | LC50 - Fish [1] 2.32 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) NOEC (chronic) 0.168 mg/l |
| benzyl alcohol (100-51-6) | LC50 - Fish [1] 460 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static] Source: EPA) LC50 - Fish [2] 10 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static] Source: EPA) EC50 - Crustacea [1] 23 mg/l (Exposure time: 48 h - Species: water flea) |
| Ethyl vanillin (121-32-4) | LC50 - Fish [1] 81.4 – 94.3 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) |
| Heliotropine (120-57-0) | LC50 - Fish [1] 2.5 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [static] Source: ECHA) |
| Ethyl acetoacetate (141-97-9) | LC50 - Fish [1] 298 mg/l (Exposure time: 96 h - Species: Pimephales promelas Source: IUCLID) LC50 - Fish [2] 290 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss Source: IUCLID) EC50 - Crustacea [1] 646 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 72h - Algae [1] > 500 mg/l (Species: Desmodesmus subspicatus) |
| benzaldehyde (100-52-7) | LC50 - Fish [1] 10.6 – 11.8 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through] Source: EPA) LC50 - Fish [2] 12.69 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static] Source: IUCLID) |
| butyric acid (107-92-6) | EC50 72h - Algae [1] 46.7 mg/l (Species: Desmodesmus subspicatus) |
FRENCH VANILLA #EU17182F 10% in DPG — Persistence and degradability Not established.
benzyl benzoate (120-51-4) — Persistence and degradability May cause long-term adverse effects in the environment.
benzyl alcohol (100-51-6) — Rapidly degradable
Ethyl vanillin (121-32-4) — Rapidly degradable
Heliotropine (120-57-0) — Rapidly degradable
Ethyl acetoacetate (141-97-9) — Rapidly degradable
benzaldehyde (100-52-7) — Rapidly degradable
butyric acid (107-92-6) — Rapidly degradable
FRENCH VANILLA #EU17182F 10% in DPG — Bioaccumulative potential Not established.
benzyl benzoate (120-51-4) — Partition coefficient n-octanol/water (Log Pow) 3.97 (at 25 °C)
benzyl benzoate (120-51-4) — Bioaccumulative potential Not established.
benzyl alcohol (100-51-6) — Partition coefficient n-octanol/water (Log Pow) 1.05
Ethyl vanillin (121-32-4) — Partition coefficient n-octanol/water (Log Pow) 1.61 (at 25 °C)
Heliotropine (120-57-0) — Partition coefficient n-octanol/water (Log Pow) 1.2 (at 35 °C)
Ethyl acetoacetate (141-97-9) — Partition coefficient n-octanol/water (Log Pow) 0.8 (at 20 °C)
benzaldehyde (100-52-7) — BCF - Fish [1] (no significant bioaccumulation)
benzaldehyde (100-52-7) — Partition coefficient n-octanol/water (Log Pow) 1.4 (at 25 °C)
butyric acid (107-92-6) — Partition coefficient n-octanol/water (Log Pow) 1.1 (at 25 °C (at pH 3)
No additional information available
No additional information available
No additional information available
Additional information: Avoid release to the environment.
Product/Packaging disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.
Ecological information: Avoid release to the environment.
HP code: HP4 - “Irritant – skin irritation and eye damage:” waste which on application can cause skin irritation or damage to the eye.
HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|
| Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
No supplementary information available
Overland transport
Not applicable
Transport by sea
Not applicable
Air transport
Not applicable
Inland waterway transport
Not applicable
Rail transport
Not applicable
Not applicable
REACH Annex XVII (Restriction List)
EU restriction list (REACH Annex XVII)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(b) | FRENCH VANILLA #EU17182F 10% in DPG ; benzyl benzoate ; benzyl alcohol ; benzaldehyde ; butyric acid | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | FRENCH VANILLA #EU17182F 10% in DPG ; benzyl benzoate | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 |
REACH Annex XIV (Authorisation List)
Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC)
Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent)
Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants)
Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009)
Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Council Regulation (EC) for the control of dual-use items
Contains substance subject to the COUNCIL REGULATION (EC) for the control of dual-use items
Explosives Precursors Regulation (2019/1148)
Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004)
Contains substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
Professional diseases
| Code | Description |
|---|---|
| RG 84 | Conditions caused by liquid organic solvents for professional use: saturated or unsaturated aliphatic or cyclic liquid hydrocarbons and mixtures thereof; liquid halogenated hydrocarbons; nitrated derivatives of aliphatic hydrocarbons; alcohols; glycols, glycol ethers; ketones; aldehydes; aliphatic and cyclic ethers, including tetrahydrofuran; esters; dimethylformamide and dimethylacetamine; acetonitrile and propionitrile; pyridine; dimethylsulfone and dimethylsulfoxide |
Water hazard class (WGK): WGK 2, significant hazardous to water (Classification according to AwSV, Annex 1).
Hazardous Incident Ordinance (12. BImSchV): Is not subject to the Hazardous Incident Ordinance (12. BImSchV)
ABM category: A(2) - toxic for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen: None of the components are listed
SZW-lijst van mutagene stoffen: None of the components are listed
SZW-lijst van reprotoxische stoffen – Borstvoeding: None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid: None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling: None of the components are listed
Classification remarks: Emergency management guidelines for the storage of flammable liquids must be followed
Danish National Regulations: Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct contact with the product
No chemical safety assessment has been carried out</