| Forma produsului | Amestec |
| Denumire comercială | Zanzibar Type #EU39083F |
| UFI | 7F7G-G3UF-9001-S2SD |
| Cod produs | EU39083F |
| Tipul produsului | Perfumes, fragrances |
| Grup de produs | Trade product |
| Categorie principală de utilizare | Industrial use,Professional use |
| Specificație utilizare industrială/profesională | For professional use only |
| Utilizare industrială | Perfumes, fragrances |
| Categorie funcțională sau de utilizare | Odour agents |
| Utilizări nerecomandate | Nu sunt disponibile informații suplimentare |
FRENCH COLOR & FRAGRANCE International GmbH
Mittlerer Weg 35
DE– 79424 Auggen
Germany
T 49-7631-931-8900
SDS@frenchcolor.com - www.frenchcolor.com
1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086
Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Efecte fizico-chimice, asupra sănătății umane și asupra mediului
Toxic to aquatic life with long lasting effects. Causes skin irritation. Very toxic to aquatic life with long lasting effects. May cause an allergic skin reaction.
| Pictograme de pericol (CLP) | GHS07 GHS09 |
| Cuvânt de avertizare (CLP) | Warning |
| Conține | Iso E Super; Linalyl acetate; Geraniol; COUMARIN; Hexyl salicylate; Linalool; Citronellol Pure; 4,7-Methano-1H-indene-2-carboxaldehyde, octahydro-5-methoxy-; Citral; delta-Damascone; Lemon oil ; Rosemary Oil; Orange oil |
| Fraze de pericol (CLP) | H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H410 - Very toxic to aquatic life with long lasting effects. |
| Fraze de precauție (CLP) | P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash hands, forearms and face thoroughly after handling. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P302+P352 - IF ON SKIN: Wash with plenty of water. |
| Fraze suplimentare | For professional users only. |
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Not applicable
| Denumire | Identificator produs | % | Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP] |
|---|---|---|---|
| Bis(2-ethylhexyl) adipate | CAS-No.: 103-23-1 EC-No.: 203-090-1 REACH-no: 01-2119439699-19 | 21.975 – 43.95 | Not classified |
| Iso E Super | CAS-No.: 54464-57-2 EC-No.: 259-174-3 REACH-no: 01-2119489989-04 | 12.6 – 25.2 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 1, H410 |
| Dihydromyrcenol | CAS-No.: 18479-58-8 EC-No.: 242-362-4 REACH-no: 01-2119457274-37 | 3.225 – 6.45 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 |
| Linalyl acetate | CAS-No.: 115-95-7 EC-No.: 204-116-4 REACH-no: 01-2119454789-19 | 0.7 – 1.4 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| 1-[(2-tert-butyl)cyclohexyloxy]-2-butanol | CAS-No.: 139504-68-0 EC-No.: 412-300-2 EC Index-No.: 603-154-00-2 REACH-no: 01-0000015959-52 | 0.675 – 1.35 | Aquatic Chronic 2, H411 |
| Geraniol | CAS-No.: 106-24-1 EC-No.: 203-377-1 EC Index-No.: 603-241-00-5 REACH-no: 01-2119552430-49 | 0.425 – 0.85 | Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317 |
| COUMARIN | CAS-No.: 91-64-5 EC-No.: 202-086-7 REACH-no: 01-2119943756-26 | 0.275 – 0.55 | Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Skin Sens. 1, H317 Aquatic Chronic 2, H411 |
| Hexyl salicylate | CAS-No.: 6259-76-3 EC-No.: 228-408-6 | 0.175 – 0.35 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Linalool | CAS-No.: 78-70-6 EC-No.: 201-134-4 EC Index-No.: 603-235-00-2 REACH-no: 01-2119474016-42 | 0.175 – 0.35 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Citronellol Pure | CAS-No.: 106-22-9 EC-No.: 203-375-0 REACH-no: 01-2119453995-23 | 0.15 – 0.3 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| reaction mass of: (1RS, 2RS,3SR, 6RS, 9SR)-9-methoxytricyclo[5.2.1.0(2,6)]decane-3-carbaldehyde; (1RS, 2RS, 3RS, 6RS, 8SR)-8-methoxytricyclo[5.2.1.0(2,6)]decane-3-carbaldehyde; (1RS, 2RS, 4SR, 6RS, 8SR)-8-methoxytricyclo[5.2.1.0(2,6)]decane-4-carbaldehyde | CAS-No.: 86803-90-9 EC-No.: 429-860-9;617-923-5 EC Index-No.: 605-034-00-5 | 0.075 – 0.15 | Skin Sens. 1, H317 Aquatic Chronic 2, H411 |
| citral | CAS-No.: 5392-40-5 EC-No.: 226-394-6 EC Index-No.: 605-019-00-3 REACH-no: 01-2119462829-23 | 0.075 – 0.15 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| delta-Damascone | CAS-No.: 57378-68-4 EC-No.: 260-709-8 | 0.075 – 0.15 | Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 1, H410 |
| Citrus medica limonum (Lemon) peel oil | CAS-No.: 8008-56-8 EC-No.: 284-515-8 | 0.075 – 0.15 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Repr. 2, H361 Aquatic Chronic 2, H411 |
| Rosemary Oil | CAS-No.: 8000-25-7 EC-No.: 283-291-9 | 0.075 – 0.15 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1B, H317 STOT SE 2, H371 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Orange oil | CAS-No.: 8008-57-9 EC-No.: 232-433-8 REACH-no: 01-2119493353-35 | 0.075 – 0.15 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
Full text of H- and EUH-statements: see section 16
| 4.1. Descrierea măsurilor de prim ajutor | |
| După inhalare | Remove person to fresh air and keep comfortable for breathing. |
| După contactul cu pielea | Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. |
| După contactul cu ochii | Rinse eyes with water as a precaution. |
| După ingestie | Call a poison center or a doctor if you feel unwell. |
| 4.2. Cele mai importante simptome și efecte, acute și întârziate | May cause an allergic skin reaction. Irritation. |
| 4.3. Indicații privind orice asistență medicală imediată și tratamente speciale necesare | Treat symptomatically. |
| 5.1. Mijloace de stingere | Water spray. Dry powder. Foam. Carbon dioxide. |
| 5.2. Pericole speciale rezultate din substanță sau amestec | Toxic fumes may be released. |
| 5.3. Recomandări pentru pompieri | Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. |
| 6.1. Precauții personale, echipament de protecție și proceduri de urgență | |
| Pentru personalul care nu intervine în situații de urgență | Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. |
| Pentru echipele de intervenție | Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". |
| 6.2. Precauții pentru mediu | Avoid release to the environment. |
| 6.3. Metode și material pentru izolare și curățare | For containment: Collect spillage. Methods for cleaning up: Take up liquid spill into absorbent material. Other information: Dispose of materials or solid residues at an authorized site. |
| 6.4. Trimitere la alte secțiuni | For further information refer to section 13. |
| 7.1. Precauții pentru manipulare în condiții de siguranță | Ensure good ventilation of the work station. Wear personal protective equipment. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. |
| Igienă | Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. |
| 7.2. Condiții de depozitare în siguranță, inclusiv incompatibilități | Store in a well-ventilated place. Keep cool. |
| Temperatura de depozitare | 25 °C |
| Zona de depozitare | Store in a well-ventilated place. Store away from heat. |
| Reguli speciale privind ambalajul | Store in a closed container. |
| Materiale de ambalare | Do not store in corrodable metal. |
| 7.3. Utilizare(e) finală(e) specifică(e) | Nu sunt disponibile informații suplimentare |
8.1.1. Valori limită naționale de expunere profesională și valori limită biologice
| Substanță | Țară / referință | Limită |
|---|---|---|
| Bis(2-ethylhexyl) adipate (103-23-1) | Poland - Occupational Exposure Limits | NDS (OEL TWA) 400 mg/m³ |
| citral (5392-40-5) | Belgium - Occupational Exposure Limits | OEL TWA 32 mg/m³ (vapor and aerosol) |
| Belgium - Occupational Exposure Limits | OEL TWA 5 ppm (vapor and aerosol) | |
| Belgium - Occupational Exposure Limits | OEL chemical category Skin | |
| Ireland - Occupational Exposure Limits | OEL TWA [2] 5 ppm | |
| Ireland - Occupational Exposure Limits | OEL STEL 15 ppm (calculated) | |
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 27 mg/m³ | |
| Poland - Occupational Exposure Limits | NDSCh (OEL STEL) 54 mg/m³ | |
| Portugal - Occupational Exposure Limits | OEL TWA 5 ppm (inhalable fraction; vapor) | |
| Spain - Occupational Exposure Limits | VLA-ED (OEL TWA) [2] 5 ppm (inhalable fraction and vapor) | |
| citral (5392-40-5) | Spain - Occupational Exposure Limits | OEL chemical category Sensitizer, skin - potential for cutaneous absorption |
| citral (5392-40-5) | USA - ACGIH - Occupational Exposure Limits | ACGIH OEL TWA [ppm] 5 ppm (inhalable fraction and vapor) |
| citral (5392-40-5) | USA - ACGIH - Occupational Exposure Limits | ACGIH chemical category Not Classifiable as a Human Carcinogen, Skin - potential significant contribution to overall exposure by the cutaneous route, dermal sensitizer |
8.1.2. Proceduri recomandate de monitorizare — Nu sunt disponibile informații suplimentare
8.1.3. Contaminanți de aer formați — Nu sunt disponibile informații suplimentare
8.1.4. DNEL și PNEC — Nu sunt disponibile informații suplimentare
8.1.5. Control banding — Nu sunt disponibile informații suplimentare
8.2.1. Controale tehnice adecvate
Ensure good ventilation of the work station.
8.2.2. Echipament individual de protecție
Protecția ochilor și feței
Safety glasses
Protecția pielii
Wear suitable protective clothing
Protecția mâinilor
Protective gloves
Protecția respirației
In case of insufficient ventilation, wear suitable respiratory equipment
8.2.4. Pericole termice — Nu sunt disponibile informații suplimentare
8.2.3. Controale ale expunerii mediului
Avoid release to the environment.
| 9.1. Informații privind proprietățile fizice și chimice de bază | |
| Stare fizică | Liquid |
| Culoare | light yellow. amber. Conforms to standard. |
| Miros | characteristic. characteristic. |
| Prag de miros | Not available |
| Punct de topire | Not applicable |
| Punct de îngheț | Not available |
| Punct de fierbere | Not available |
| Inflamabilitate | Not applicable |
| Limite explozive | Not available |
| Limită inferioară de explozie | Not available |
| Limită superioară de explozie | Not available |
| Punct de aprindere | > 93.3 °C (closed cup) ASTM D7094 |
| Temperatură de autoaprindere | Not available |
| Temperatură de descompunere | Not available |
| pH | Not available |
| Vâscozitate, cinematică | Not available |
| Solubilitate | Not available |
| Coeficient de partiție n-octanol/apă (Log Kow) | Not available |
| Presiunea vaporilor | Not available |
| Presiunea vaporilor la 50°C | Not available |
| Densitate | Not available |
| Densitate relativă | ≈ 0.95 |
| Densitatea relativă a vaporilor la 20°C | Not available |
| Caracteristici ale particulelor | Not applicable |
| 9.2. Alte informații | |
| 9.2.1. Informații privind clasele de pericol fizic | Nu sunt disponibile informații suplimentare |
| 9.2.2. Alte caracteristici de siguranță | Nu sunt disponibile informații suplimentare |
| 10.1. Reactivitate | The product is non-reactive under normal conditions of use, storage and transport. |
| 10.2. Stabilitate chimică | Stable under normal conditions. |
| 10.3. Posibilitatea reacțiilor periculoase | No dangerous reactions known under normal conditions of use. |
| 10.4. Condiții de evitat | None under recommended storage and handling conditions (see section 7). |
| 10.5. Materiale incompatibile | No additional information available |
| 10.6. Produse de descompunere periculoase | Under normal conditions of storage and use, hazardous decomposition products should not be produced. |
| 11.1. Informații privind clasele de pericol definite în Regulamentul (CE) nr. 1272/2008 | |
| Toxicitate acută (orală) | Not classified |
| Toxicitate acută (dermică) | Not classified |
| Toxicitate acută (inhalare) | Not classified |
Datele toxicologice detaliate pentru componente rămân prezentate în ordinea originală mai jos.
| Substanță | Date |
|---|---|
| Bis(2-ethylhexyl) adipate (103-23-1) | LD50 oral rat 5600 mg/kg (Source: NLM_CIP) LD50 dermal rabbit 8410 mg/kg (Source: NLM_CIP) LC50 Inhalation - Rat > 5.7 mg/l/4h |
| Dihydromyrcenol (18479-58-8) | LD50 oral rat 3600 mg/kg (Source: NLM_CIP) LD50 oral 3600 mg/kg bodyweight LD50 dermal rabbit > 5 g/kg (Source: CHEMVIEW) |
| Linalyl acetate (115-95-7) | LD50 oral rat 14550 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: EPA_HPV) |
| 1-[(2-tert-butyl)cyclohexyloxy]-2-butanol (139504-68-0) | LD50 dermal rat > 2000 mg/kg (Source: ECHA_API) |
| Geraniol (106-24-1) | LD50 oral rat 3600 mg/kg (Source: NLM_CIP) LD50 oral 3600 mg/kg bodyweight LD50 dermal rabbit > 5 g/kg (Source: NLM_CIP) |
| COUMARIN (91-64-5) | LD50 oral rat > 5000 mg/kg (Source: JAPAN_GHS) LD50 oral 290 mg/kg bodyweight LD50 dermal rat 293 mg/kg (Source: ECHA_API) |
| Hexyl salicylate (6259-76-3) | LD50 oral rat > 5 g/kg (Source: NLM_CIP) LD50 dermal rabbit > 5000 mg/kg (Source: ECHA_API) |
| Linalool (78-70-6) | LD50 oral 2790 mg/kg bodyweight |
| Citronellol Pure (106-22-9) | LD50 oral rat 3450 mg/kg (Source: NLM_CIP) LD50 oral 3450 mg/kg bodyweight LD50 dermal rabbit 2650 mg/kg (Source: EPA_HPV) LD50 dermal 2650 mg/kg bodyweight |
| reaction mass of: (1RS, 2RS,3SR, 6RS, 9SR)-9-methoxytricyclo[5.2.1.0(2,6)]decane-3-carbaldehyde; (1RS, 2RS, 3RS, 6RS, 8SR)-8-methoxytricyclo[5.2.1.0(2,6)]decane-3-carbaldehyde; (1RS, 2RS, 4SR, 6RS, 8SR)-8-methoxytricyclo[5.2.1.0(2,6)]decane-4-carbaldehyde (86803-90-9) | LD50 oral rat 2800 mg/kg (Source: NLM_CIP) LD50 oral 2800 mg/kg bodyweight |
| citral (5392-40-5) | LD50 oral rat 4960 mg/kg (Source: NLM_CIP) LD50 dermal rabbit 2250 mg/kg (Source: NLM_CIP) |
| delta-Damascone (57378-68-4) | LD50 oral 1400 mg/kg bodyweight |
| Citrus medica limonum (Lemon) peel oil (8008-56-8) | LD50 oral rat 2840 mg/kg (Source: NLM_CIP) |
| Rosemary Oil (8000-25-7) | LD50 oral rat 5 g/kg (Source: NLM_CIP) |
| Orange oil (8008-57-9) | LD50 oral rat 4400 mg/kg (Source: NZ_CCID) LD50 dermal rabbit > 5000 mg/kg (Source: CHEMVIEW) |
| Corodarea/iritarea pielii | Causes skin irritation. |
| Leziuni/iritare oculară gravă | Not classified |
| Sensibilizare respiratorie sau cutanată | May cause an allergic skin reaction. |
| Mutagenicitate asupra celulelor germinale | Not classified |
| Carcinogenitate | Not classified |
| Bis(2-ethylhexyl) adipate (103-23-1) | IARC group 3 - Not classifiable |
| COUMARIN (91-64-5) | IARC group 3 - Not classifiable |
| Toxicitate pentru reproducere | Not classified |
| STOT-single exposure | Not classified |
| Rosemary Oil (8000-25-7) | STOT-single exposure May cause damage to organs. |
| STOT-repeated exposure | Not classified |
| Pericol prin aspirare | Not classified |
| Orange oil (8008-57-9) | Hydrocarbon Yes |
| 11.2. Informații privind alte pericole | Nu sunt disponibile informații suplimentare |
| 12.1. Toxicitate | Ecology - general: Toxic to aquatic life with long lasting effects. Very toxic to aquatic life with long lasting effects. |
| Periculos pentru mediul acvatic, pe termen scurt (acut) | Not classified |
| Periculos pentru mediul acvatic, pe termen lung (cronic) | Very toxic to aquatic life with long lasting effects. |
| Substanță | Ecotoxicitate / potențial de bioacumulare |
|---|---|
| Bis(2-ethylhexyl) adipate (103-23-1) | LC50 - Fish [1] 0.48 – 0.85 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static] Source: EPA) LC50 - Fish [2] 0.48 – 0.85 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static] Source: EPA) EC50 - Crustacea [1] > 1.6 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 72h - Algae [1] > 500 mg/l (Species: Desmodesmus subspicatus) BCF - Fish [1] (27 dimensionless) Log Pow 8.94 (at 25 °C) |
| Linalyl acetate (115-95-7) | LC50 - Fish [1] 11 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [flow-through] Source: ECHA) Log Pow 3.9 (at 25 °C) |
| Geraniol (106-24-1) | LC50 - Fish [1] 22 mg/l (Exposure time: 96 h - Species: Danio rerio [static] Source: ECHA) Log Pow 2.6 (at 25 °C) |
| Linalool (78-70-6) | EC50 96h - Algae [1] 88.3 mg/l (Species: Desmodesmus subspicatus) Log Pow 3.41 (at 25 °C) |
| citral (5392-40-5) | EC50 - Crustacea [1] 7 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 72h - Algae [1] 16 mg/l (Species: Desmodesmus subspicatus) EC50 96h - Algae [1] 19 mg/l (Species: Desmodesmus subspicatus) Log Pow 2.76 (at 25 °C) |
| 12.2. Persistență și degradabilitate | Nu sunt disponibile informații suplimentare |
| 12.3. Potențial de bioacumulare | prezentat mai sus |
| 12.4. Mobilitate în sol | Nu sunt disponibile informații suplimentare |
| 12.5. Rezultatele evaluării PBT și vPvB | Nu sunt disponibile informații suplimentare |
| 12.6. Proprietăți de perturbare endocrină | Nu sunt disponibile informații suplimentare |
| 12.7. Alte efecte adverse | Nu sunt disponibile informații suplimentare |
| 13.1. Metode de tratare a deșeurilor | Dispose of contents/container in accordance with licensed collector’s sorting instructions. |
| Cod HP | HP3 - “Flammable:” HP4 - “Irritant – skin irritation and eye damage:” HP13 - “Sensitising:” HP14 - “Ecotoxic:” |
În conformitate cu ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|
| UN 3082 | UN 3082 | UN 3082 | UN 3082 | UN 3082 |
| ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iso E Super) | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iso E Super) | Environmentally hazardous substance, liquid, n.o.s. (Iso E Super) | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iso E Super) | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iso E Super) |
| Transport document description UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iso E Super), 9, III, (-) | Transport document description UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iso E Super), 9, III, MARINE POLLUTANT | Transport document description UN 3082 Environmentally hazardous substance, liquid, n.o.s. (Iso E Super), 9, III | Transport document description UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iso E Super), 9, III | Transport document description UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iso E Super), 9, III |
| 9 | 9 | 9 | 9 | 9 |
| III | III | III | III |