Fișă cu date de securitate
conform Regulamentului (CE) nr. 1907/2006 (REACH) cu modificarea prin Regulamentul (UE) 2020/878
Data emiterii: 9/25/2024 · Versiunea: 1.0
Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Textul complet al declarațiilor H și EUH: vezi secțiunea 16
Impacte fizico-chimice, asupra sănătății umane și asupra mediului: No additional information available
Etichetare conform Regulamentului (CE) nr. 1272/2008 [CLP]
GHS07 Semnal: Warning
Conține: Hexyl cinnamic aldehyde; Orange oil ; benzyl alcohol; CINNAMAL; Linalyl acetate; citral; Cashmeran; Heliotropine; Isovaleraldehyde; 3(2H)-Furanone, 4-hydroxy-2,5-dimethyl-
Indicații de pericol:
Fraze de precauție:
Phrases suplimentare: Restricted to professional users.
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Not applicable
| Denumire | Identificator produs | % | Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP] |
|---|---|---|---|
| Hexyl cinnamic aldehyde | CAS-No.: 101-86-0 EC-No.: 202-983-3 REACH-no: 01-2119533092-50 | 1.525 – 3.025 | Skin Sens. 1, H317 Aquatic Chronic 2, H411 |
| Orange oil | CAS-No.: 8008-57-9 EC-No.: 232-433-8 REACH-no: 01-2119493353-35 | 1.075 – 2.125 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Ethyl vanillin | CAS-No.: 121-32-4 EC-No.: 204-464-7 REACH-no: 01-211958961-24 | 1.075 – 2.125 | Eye Irrit. 2, H319 |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB) | CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 | 0.85 – 1.6875 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| benzyl alcohol | substance with national workplace exposure limit(s) (BG, CZ, DE, FI, LT, LV, PL, SI, CH) CAS-No.: 100-51-6 EC-No.: 202-859-9 EC Index-No.: 603-057-00-5 REACH-no: 01-2119492630-38 | 0.4 – 0.775 | Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| CINNAMAL | CAS-No.: 104-55-2 EC-No.: 203-213-9 EC Index-No.: 606-155-00-6 REACH-no: 01-2119935242-45 | 0.25 – 0.5 | Acute Tox. 4 (Dermal), H312 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1A, H317 Aquatic Chronic 3, H412 |
| Linalyl acetate | CAS-No.: 115-95-7 EC-No.: 204-116-4 REACH-no: 01-2119454789-19 | 0.2 – 0.4125 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| CAS-No.: 104-21-2 EC-No.: 203-185-8 | 0.175 – 0.35 | Skin Sens. 1, H317 | |
| citral | substance with national workplace exposure limit(s) (BE, ES, IE, PL, PT) CAS-No.: 5392-40-5 EC-No.: 226-394-6 EC Index-No.: 605-019-00-3 REACH-no: 01-2119462829-23 | 0.125 – 0.25 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Cashmeran | CAS-No.: 33704-61-9 EC-No.: 251-649-3 REACH-no: 01-2119977131-40 | 0.125 – 0.25 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 STOT RE 2, H373 Aquatic Chronic 2, H411 |
| Heliotropine | CAS-No.: 120-57-0 EC-No.: 204-409-7 REACH-no: 01-2119983608-21 | 0.075 – 0.125 | Skin Sens. 1B, H317 |
| Isovaleraldehyde | substance with national workplace exposure limit(s) (AT, DE, LT, SI) CAS-No.: 590-86-3 EC-No.: 209-691-5 | 0.05 – 0.1 | Flam. Liq. 2, H225 Eye Irrit. 2, H319 Skin Sens. 1B, H317 STOT SE 3, H335 Aquatic Chronic 2, H411 |
| 1,2-Propanediol | substance with national workplace exposure limit(s) (GB, HR, IE, LT, LV, PL, NO) CAS-No.: 57-55-6 EC-No.: 200-338-0 REACH-no: 01-2119456809-23 | 0.025 – 0.04 | Not classified |
| 3(2H)-Furanone, 4-hydroxy-2,5-dimethyl- | CAS-No.: 3658-77-3 EC-No.: 222-908-8 | 0 – 0.01 | Acute Tox. 4 (Oral), H302 Skin Corr. 1B, H314 Eye Irrit. 2, H319 Skin Sens. 1A, H317 |
| Denumire | Identificator produs | Limite specifice de concentrație (%) |
|---|---|---|
| CINNAMAL | CAS-No.: 104-55-2 EC-No.: 203-213-9 EC Index-No.: 606-155-00-6 REACH-no: 01-2119935242-45 |
(0.01 ≤ C < 100) Skin Sens. 1, H317 |
Textul complet al declarațiilor H și EUH: vezi secțiunea 16
Măsuri generale: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
După inhalare: Allow affected person to breathe fresh air. Allow the victim to rest.
După contactul cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
După contactul cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
După înghițire: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
No additional information available
Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
No additional information available
Instrucțiuni de stingere: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.
Protecție în timpul stingerii incendiului: Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1. Pentru personalul care nu intervine în situații de urgență
Emergency procedures: Evacuate unnecessary personnel.
6.1.2. Pentru respondenții la urgență
Protective equipment: Equip cleanup crew with proper protection.
Emergency procedures: Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Methods for cleaning up: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Heading 8. Exposure controls and personal protection.
Precautions for safe handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor.
Storage conditions: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Incompatible products: Strong bases. Strong acids.
Incompatible materials: Sources of ignition. Direct sunlight.
Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids
Joint storage table:
Storage class (LK): LK 10/12 - Liquids
No additional information available
8.1.1 National occupational exposure and biological limit values
| Substanță | Țară | Valoare limită |
|---|---|---|
| benzyl alcohol (100-51-6) | Bulgaria | OEL TWA 5 mg/m³ |
| Czech Republic | PEL (OEL TWA) 40 mg/m³ | |
| Finland | HTP (OEL TWA) 45 mg/m³; 10 ppm | |
| Germany | AGW (OEL TWA) 22 mg/m³; 5 ppm; Chemical category: skin notation | |
| Latvia | OEL TWA 5 mg/m³ | |
| Lithuania | IPRV (OEL TWA) 5 mg/m³; OEL chemical category: skin notation | |
| Poland | NDS (OEL TWA) 240 mg/m³ | |
| Slovenia / Switzerland | OEL TWA 22 mg/m³; 5 ppm / MAK 22 mg/m³; 5 ppm; skin notation | |
| citral (5392-40-5) | Belgium | OEL TWA 32 mg/m³ (vapor and aerosol); 5 ppm (vapor and aerosol); Skin |
| Ireland | OEL TWA 5 ppm; OEL STEL 15 ppm (calculated) | |
| Poland | NDS (OEL TWA) 27 mg/m³; NDSCh (OEL STEL) 54 mg/m³ | |
| Portugal | OEL TWA 5 ppm (inhalable fraction; vapor); Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen, skin - potential for cutaneous exposure | |
| Spain / USA - ACGIH | VLA-ED 5 ppm / ACGIH OEL TWA 5 ppm; Skin - potential significant contribution to overall exposure by the cutaneous route, dermal sensitizer | |
| Isovaleraldehyde (590-86-3) | Austria | MAK (OEL TWA) 39 mg/m³; 10 ppm; OEL STEL 39 mg/m³; 10 ppm; OEL C 39 mg/m³; 10 ppm |
| Germany | AGW (OEL TWA) 39 mg/m³; 10 ppm | |
| Lithuania | IPRV (OEL TWA) 10 mg/m³ | |
| Slovenia | OEL TWA 39 mg/m³; 10 ppm; OEL STEL 39 mg/m³; 10 ppm | |
| 1,2-Propanediol (57-55-6) | Croatia | GVI (OEL TWA) 474 mg/m³ (total vapor and particles); 10 mg/m³ (particles); 150 ppm |
| Ireland | OEL TWA 10 mg/m³ (particulates); 470 mg/m³ (total vapour and particulates); 150 ppm; OEL STEL 1410 mg/m³; 30 mg/m³; 450 ppm | |
| Latvia / Lithuania | OEL TWA 7 mg/m³ / IPRV (OEL TWA) 7 mg/m³ | |
| Poland | NDS (OEL TWA) 100 mg/m³ (vapor and inhalable fraction) | |
| United Kingdom / Norway | WEL TWA 474 mg/m³; 10 mg/m³; 150 ppm / Grenseverdi 79 mg/m³; 25 ppm; Korttidsverdi 118.5 mg/m³; 37.5 ppm |
8.1.2. Recommended monitoring procedures: No additional information available
8.1.3. Air contaminants formed: No additional information available
8.1.4. DNEL and PNEC: No additional information available
8.1.5. Control banding: No additional information available
8.2.1. Engineering controls adecvate: No additional information available
Personal protective equipment: Avoid all unnecessary exposure.
Personal protective equipment symbol(s):
Eye protection: Chemical goggles or safety glasses
Hand protection: Wear protective gloves.
Respiratory protection: Wear appropriate mask
No additional information available
Other information: Do not eat, drink or smoke during use.
| Proprietate | Valoare |
|---|---|
| Physical state | Liquid |
| Color | Conforms to standard. |
| Odor | characteristic. |
| Odor threshold | Not available |
| Melting point | Not available |
| Freezing point | Not available |
| Boiling point | Not available |
| Flammability | Non flammable. |
| Lower explosion limit | Not available |
| Upper explosion limit | Not available |
| Flash point | > 93 °C |
| Auto-ignition temperature | Not available |
| Decomposition temperature | Not available |
| pH | Not available |
| Viscosity, kinematic | Not available |
| Solubility | Not available |
| Partition coefficient n-octanol/water (Log Kow) | Not available |
| Vapor pressure | Not available |
| Vapor pressure at 50°C | Not available |
| Density | Not available |
| Relative density | Not available |
| Relative vapor density at 20°C | Not available |
| Particle characteristics | Not applicable |
9.2.1. Information with regard to physical hazard classes: No additional information available
9.2.2. Other safety characteristics: No additional information available
10.1. Reactivity: No additional information available
10.2. Chemical stability: Not established.
10.3. Possibility of hazardous reactions: Not established.
10.4. Conditions to avoid: Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials: Strong acids. Strong bases.
10.6. Hazardous decomposition products: fume. Carbon monoxide. Carbon dioxide.
Acute toxicity (oral): Not classified
Acute toxicity (dermal): Not classified
Acute toxicity (inhalation): Not classified
Skin corrosion/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Serious eye damage/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Respiratory or skin sensitization: May cause an allergic skin reaction.
Additional information: Based on available data, the classification criteria are not met
Germ cell mutagenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Carcinogenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Reproductive toxicity: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-single exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
Isovaleraldehyde (590-86-3): STOT-single exposure — May cause respiratory irritation.
STOT-repeated exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
Cashmeran (33704-61-9): STOT-repeated exposure — May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard: Not classified
Additional information: Based on available data, the classification criteria are not met
Orange oil (8008-57-9): Hydrocarbon — Yes
Heliotropine (120-57-0): Viscosity, kinematic — Not applicable
11.2.1. Endocrine disrupting properties: No additional information available
11.2.2. Other information: Potential Adverse human health effects and symptoms — Based on available data, the classification criteria are not met
Hazardous to the aquatic environment, short–term (acute): Not classified
Hazardous to the aquatic environment, long–term (chronic): Harmful to aquatic life with long lasting effects.
CHOCOLATE ORANGE COOKIE #EU46508F 25% in DPG: Persistence and degradability — Not established.
Toate componentele enumerate: Rapidly degradable
CHOCOLATE ORANGE COOKIE #EU46508F 25% in DPG: Bioaccumulative potential — Not established.
No additional information available
No additional information available
No additional information available
Additional information: Avoid release to the environment.
Product/Packaging disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.
Ecological information: Avoid release to the environment.
HP code: HP4 - “Irritant – skin irritation and eye damage:” waste which on application can cause skin irritation or damage to the eye.
HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
In accordance with ADR / IMDG / IATA / ADN / RID
ADR / IMDG / IATA / ADN / RID: Not applicable
14.1. UN number or ID number: Not applicable
14.2. UN proper shipping name: Not applicable
14.3. Transport hazard class(es): Not applicable
14.4. Packing group: Not applicable
14.5. Environmental hazards: Not applicable
No supplementary information available
14.6. Special precautions for user: Not applicable
14.7. Maritime transport in bulk according to IMO instruments: Not applicable
15.1.1. EU-Regulations
REACH Annex XVII (Restriction List): Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(a) | Orange oil ; Isovaleraldehyde | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F |
| 3(b) | CHOCOLATE ORANGE COOKIE #EU46508F 25% in DPG ; Hexyl cinnamic aldehyde ; Orange oil ; benzyl alcohol ; CINNAMAL ; Linalyl acetate ; ; citral ; Cashmeran ; Isovaleraldehyde ; 3(2H)-Furanone, 4-hydroxy-2,5-dimethyl- | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | CHOCOLATE ORANGE COOKIE #EU46508F 25% in DPG ; Hexyl cinnamic aldehyde ; Orange oil ; 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB) ; CINNAMAL ; Cashmeran ; Isovaleraldehyde | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 |
| 40. | Orange oil ; Isovaleraldehyde | Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. |
REACH Annex XIV (Authorisation List): Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC): Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent): Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants): Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009): Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Council Regulation (EC) for the control of dual-use items: Contains substance subject to the COUNCIL REGULATION (EC) for the control of dual-use items
Explosives Precursors Regulation (2019/1148): Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004): Contains substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
| Name | CN designation | CAS-No. | CN code | Category, Subcategory | Threshold | Annex |
|---|---|---|---|---|---|---|
| Piperonal | 120-57-0 | 2932 93 00 | Category 1 | Annex I |
France
Professional diseases
Code: RG 84
Description: Conditions caused by liquid organic solvents for professional use: saturated or unsaturated aliphatic or cyclic liquid hydrocarbons and mixtures thereof; liquid halogenated hydrocarbons; nitrated derivatives of aliphatic hydrocarbons; alcohols; glycols, glycol ethers; ketones; aldehydes; aliphatic and cyclic ethers, including tetrahydrofuran; esters; dimethylformamide and dimethylacetamine; acetonitrile and propionitrile; pyridine; dimethylsulfone and dimethylsulfoxide
Germany
Water hazard class (WGK): WGK 2, significant hazardous to water (Classification according to AwSV, Annex 1).
List of sensitizing substances (TRGS 907): Contains sensitizing substances according TRGS 907.
Hazardous Incident Ordinance (12. BImSchV): Is not subject to the Hazardous Incident Ordinance (12. BImSchV)
Netherlands
ABM category: A(2) - toxic for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen: Orange oil is listed
SZW-lijst van mutagene stoffen: Orange oil is listed
SZW-lijst van reprotoxische stoffen – Borstvoeding: None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid: None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling: None of the components are listed
Denmark
Classification remarks: Emergency management guidelines for the storage of flammable liquids must be followed
Danish National Regulations: Young people below the age of 18 years are not allowed to use the product; Pregnant/breastfeeding women working with the product must not be in direct contact with the product
No chemical safety assessment has been carried out
Data sources: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information: None.
| Cod | Text |
|---|---|
| Acute Tox. 4 (Dermal) | Acute toxicity (dermal), Category 4 |
| Acute Tox. 4 (Inhalation) | Acute toxicity (inhalation) Category 4 |
| Acute Tox. 4 (Oral) | Acute toxicity (oral) Category 4 |
| Aquatic Acute 1 | Hazardous to the aquatic environment – Acute Hazard Category 1 |
| Aquatic Chronic 1 | Hazardous to the aquatic environment – Chronic Hazard Category 1 |
| Aqu |