Fişă cu Date de Securitate, conform Regulamentului (CE) Nr. 1907/2006 (REACH) cu modificarea Regulamentului (UE) 2020/878
Forma produsului: Mixture
Nume produs: CHOCOLATE ORANGE COOKIE #EU46508F 5% in DPG
Cod produs: EU46508F_5%
Tip produs: Perfumes, Fragrances
Specificaţie utilizare industrială/profesională: Industrial
For professional use only
Utilizarea substanţei/amestecului: Perfumes, Fragrances
Categoria funcţiei sau a utilizării: Odour agents
Utilizări contraindicate: No additional information available
No additional information available
No additional information available
Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Full text of H- and EUH-statements: see section 16
No additional information available
Etichetare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Pictograme de pericol (CLP): GHS07
Cuvânt de avertizare (CLP): Warning
Conţine: Hexyl cinnamic aldehyde; Orange oil ; benzyl alcohol; CINNAMAL
Hazard statements (CLP):
H317 - May cause an allergic skin reaction.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP):
Extra phrases: Restricted to professional users.
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Not applicable
| Nume | Product identifier | % | Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP] |
|---|---|---|---|
| Hexyl cinnamic aldehyde | CAS-No.: 101-86-0 EC-No.: 202-983-3 REACH-no: 01-2119533092-50 |
0.305 – 0.605 | Skin Sens. 1, H317 Aquatic Chronic 2, H411 |
| Orange oil | CAS-No.: 8008-57-9 EC-No.: 232-433-8 REACH-no: 01-2119493353-35 |
0.215 – 0.425 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB) | CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 |
0.17 – 0.3375 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| benzyl alcohol | substance with national workplace exposure limit(s) (BG, CZ, DE, FI, LT, LV, PL, SI, CH) CAS-No.: 100-51-6 EC-No.: 202-859-9 EC Index-No.: 603-057-00-5 REACH-no: 01-2119492630-38 |
0.08 – 0.155 | Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| CINNAMAL | CAS-No.: 104-55-2 EC-No.: 203-213-9 EC Index-No.: 606-155-00-6 REACH-no: 01-2119935242-45 |
0.05 – 0.1 | Acute Tox. 4 (Dermal), H312 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1A, H317 Aquatic Chronic 3, H412 |
| citral | substance with national workplace exposure limit(s) (BE, ES, IE, PL, PT) CAS-No.: 5392-40-5 EC-No.: 226-394-6 EC Index-No.: 605-019-00-3 REACH-no: 01-2119462829-23 |
0.025 – 0.05 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Isovaleraldehyde | substance with national workplace exposure limit(s) (AT, DE, LT, SI) CAS-No.: 590-86-3 EC-No.: 209-691-5 |
0.01 – 0.02 | Flam. Liq. 2, H225 Eye Irrit. 2, H319 Skin Sens. 1B, H317 STOT SE 3, H335 Aquatic Chronic 2, H411 |
| 1,2-Propanediol | substance with national workplace exposure limit(s) (GB, HR, IE, LT, LV, PL, NO) CAS-No.: 57-55-6 EC-No.: 200-338-0 REACH-no: 01-2119456809-23 |
0.005 – 0.008 | Not classified |
| Nume | Product identifier | Specific concentration limits (%) |
|---|---|---|
| CINNAMAL | CAS-No.: 104-55-2 EC-No.: 203-213-9 EC Index-No.: 606-155-00-6 REACH-no: 01-2119935242-45 |
(0.01 ≤ C < 100) Skin Sens. 1, H317 |
Full text of H- and EUH-statements: see section 16
Măsuri generale: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
După inhalare: Allow affected person to breathe fresh air. Allow the victim to rest.
După contact cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
După contact cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
După înghiţire: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
No additional information available
Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
No additional information available
Instrucţiuni de stingere a incendiilor: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.
Protecţie în timpul stingerii incendiului: Do not enter fire area without proper protective equipment, including respiratory protection.
Pentru personalul care nu intervine în situaţii de urgenţă: Evacuate unnecessary personnel.
Pentru echipele de intervenţie: Equip cleanup crew with proper protection. Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Heading 8. Exposure controls and personal protection.
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor.
Condiţii de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Produse incompatibile: Strong bases. Strong acids.
Materiale incompatibile: Sources of ignition. Direct sunlight.
Germany — Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids
Joint storage table:
Joint storage not permitted for: LGK 1, LGK 6.2, LGK 7
Joint storage with restrictions permitted for: LGK 4.1A, LGK 4.3, LGK 5.1C
Joint storage permitted for: LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13
Switzerland — Storage class (LK): LK 10/12 - Liquids
No additional information available
| Substanţă | Ţară | Valoare-limită |
|---|---|---|
| benzyl alcohol (100-51-6) | Bulgaria | OEL TWA 5 mg/m³ |
| benzyl alcohol (100-51-6) | Czech Republic | PEL (OEL TWA) 40 mg/m³ |
| benzyl alcohol (100-51-6) | Finland | HTP (OEL TWA) 45 mg/m³; HTP (OEL TWA) 10 ppm |
| benzyl alcohol (100-51-6) | Germany | AGW (OEL TWA) 22 mg/m³; AGW (OEL TWA) 5 ppm; Chemical category: skin notation |
| benzyl alcohol (100-51-6) | Latvia | OEL TWA 5 mg/m³ |
| benzyl alcohol (100-51-6) | Lithuania | IPRV (OEL TWA) 5 mg/m³; OEL chemical category: skin notation |
| benzyl alcohol (100-51-6) | Poland | NDS (OEL TWA) 240 mg/m³ |
| benzyl alcohol (100-51-6) | Slovenia | OEL TWA 22 mg/m³; OEL TWA 5 ppm; OEL STEL 44 mg/m³; OEL STEL 10 ppm; OEL chemical category: Potential for cutaneous absorption |
| benzyl alcohol (100-51-6) | Switzerland | MAK (OEL TWA) 22 mg/m³ (aerosol, vapour); MAK (OEL TWA) 5 ppm (aerosol, vapour); OEL chemical category: skin notation |
| citral (5392-40-5) | Belgium | OEL TWA 32 mg/m³ (vapor and aerosol); OEL TWA 5 ppm (vapor and aerosol); OEL chemical category: Skin |
| citral (5392-40-5) | Ireland | OEL TWA 5 ppm; OEL STEL 15 ppm (calculated) |
| citral (5392-40-5) | Poland | NDS (OEL TWA) 27 mg/m³; NDSCh (OEL STEL) 54 mg/m³ |
| citral (5392-40-5) | Portugal | OEL TWA 5 ppm (inhalable fraction; vapor); OEL chemical category: Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen, skin - potential for cutaneous exposure |
| citral (5392-40-5) | Spain | VLA-ED (OEL TWA) 5 ppm (inhalable fraction and vapor); OEL chemical category: Sensitizer, skin - potential for cutaneous absorption |
| citral (5392-40-5) | USA - ACGIH | ACGIH OEL TWA 5 ppm (inhalable fraction and vapor); ACGIH chemical category: Not Classifiable as a Human Carcinogen, Skin - potential significant contribution to overall exposure by the cutaneous route, dermal sensitizer |
| Isovaleraldehyde (590-86-3) | Austria | MAK (OEL TWA) 39 mg/m³; MAK (OEL TWA) 10 ppm; MAK (OEL STEL) 39 mg/m³; MAK (OEL STEL) 10 ppm; OEL C 39 mg/m³; OEL C 10 ppm |
| Isovaleraldehyde (590-86-3) | Germany | AGW (OEL TWA) 39 mg/m³; AGW (OEL TWA) 10 ppm |
| Isovaleraldehyde (590-86-3) | Lithuania | IPRV (OEL TWA) 10 mg/m³ |
| Isovaleraldehyde (590-86-3) | Slovenia | OEL TWA 39 mg/m³; OEL TWA 10 ppm; OEL STEL 39 mg/m³; OEL STEL 10 ppm |
| 1,2-Propanediol (57-55-6) | Croatia | GVI (OEL TWA) 474 mg/m³ (total vapor and particles) 10 mg/m³ (particles); GVI (OEL TWA) 150 ppm |
| 1,2-Propanediol (57-55-6) | Ireland | OEL TWA 10 mg/m³ (particulates) 470 mg/m³ (total vapour and particulates); OEL TWA 150 ppm (total vapour and particulates); OEL STEL 1410 mg/m³ (calculated-particulates) 30 mg/m³ (calculated); OEL STEL 450 ppm (calculated-total vapour and particulates) |
| 1,2-Propanediol (57-55-6) | Latvia | OEL TWA 7 mg/m³ |
| 1,2-Propanediol (57-55-6) | Lithuania | IPRV (OEL TWA) 7 mg/m³ |
| 1,2-Propanediol (57-55-6) | Poland | NDS (OEL TWA) 100 mg/m³ (vapor and inhalable fraction) |
| 1,2-Propanediol (57-55-6) | United Kingdom | WEL TWA (OEL TWA) 474 mg/m³ (total vapour and particulates) 10 mg/m³ (particulates); WEL TWA (OEL TWA) 150 ppm (total vapour and particulates); WEL STEL (OEL STEL) 1422 mg/m³ (calculated-total vapour and particulates) 30 mg/m³ (calculated-particulate); WEL STEL (OEL STEL) 450 ppm (calculated-total vapour and particulates) |
| 1,2-Propanediol (57-55-6) | Norway | Grenseverdi (OEL TWA) 79 mg/m³; Grenseverdi (OEL TWA) 25 ppm; Korttidsverdi (OEL STEL) 118.5 mg/m³ (value calculated); Korttidsverdi (OEL STEL) 37.5 ppm (value calculated) |
No additional information available
No additional information available
No additional information available
No additional information available
No additional information available
Echipament individual de protecţie: Avoid all unnecessary exposure.
Eye and face protection: Chemical goggles or safety glasses
Skin protection: Wear protective gloves.
Respiratory protection: Wear appropriate mask
Thermal hazards: No additional information available
Other information: Do not eat, drink or smoke during use.
Stare fizică: Liquid
Culoare: Conforms to standard.
Miros: characteristic.
Pragul de miros: Not available
Punct de topire: Not available
Punct de îngheţare: Not available
Punct de fierbere: Not available
Inflamabilitate: Non flammable.
Limita inferioară de explozie: Not available
Limita superioară de explozie: Not available
Punct de aprindere: > 93 °C
Temperatura de autoaprindere: Not available
Temperatura de descompunere: Not available
pH: Not available
Vâscozitate, cinematică: Not available
Solubilitate: Not available
Coeficient de partiţie n-octanol/apă (Log Kow): Not available
Presiune de vapori: Not available
Presiune de vapori la 50°C: Not available
Densitate: Not available
Densitate relativă: Not available
Densitatea relativă a vaporilor la 20°C: Not available
Caracteristici ale particulelor: Not applicable
No additional information available
10.1. Reactivitate: No additional information available
10.2. Stabilitate chimică: Not established.
10.3. Posibilitatea de reacţii periculoase: Not established.
10.4. Condiţii de evitat: Direct sunlight. Extremely high or low temperatures.
10.5. Materiale incompatibile: Strong acids. Strong bases.
10.6. Produşi de descompunere periculoşi: fume. Carbon monoxide. Carbon dioxide.
Toxicitate acută (oral): Not classified
Toxicitate acută (dermal): Not classified
Toxicitate acută (inhalation): Not classified
Date toxicologice ale componentelor:
Skin corrosion/irritation: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Serious eye damage/irritation: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Respiratory or skin sensitization: May cause an allergic skin reaction.
Informaţii suplimentare: Based on available data, the classification criteria are not met
Germ cell mutagenicity: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Carcinogenicity: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Reproductive toxicity: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
STOT-single exposure: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Isovaleraldehyde (590-86-3) — STOT-single exposure: May cause respiratory irritation.
STOT-repeated exposure: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Aspiration hazard: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Orange oil (8008-57-9): Hydrocarbon
11.2.1. Endocrine disrupting properties: No additional information available
11.2.2. Alte informaţii: Potential Adverse human health effects and symptoms: Based on available data, the classification criteria are not met
Hazardous to the aquatic environment, short–term (acute): Not classified
Hazardous to the aquatic environment, long–term (chronic): Harmful to aquatic life with long lasting effects.
Date ecotoxicologice ale componentelor:
CHOCOLATE ORANGE COOKIE #EU46508F 5% in DPG: Not established.
Hexyl cinnamic aldehyde (101-86-0): Rapidly degradable
Orange oil (8008-57-9): Rapidly degradable
HHCB (1222-05-5): Rapidly degradable
benzyl alcohol (100-51-6): Rapidly degradable
CINNAMAL (104-55-2): Rapidly degradable
citral (5392-40-5): Rapidly degradable
Isovaleraldehyde (590-86-3): Rapidly degradable
1,2-Propanediol (57-55-6): Rapidly degradable
CHOCOLATE ORANGE COOKIE #EU46508F 5% in DPG: Not established.
HHCB (1222-05-5): BCF - Fish [1] (1618 dimensionless (whole body w.w.); Partition coefficient n-octanol/water (Log Pow) 5.3 (at 25 °C (at pH 7)
benzyl alcohol (100-51-6): Partition coefficient n-octanol/water (Log Pow) 1.05
CINNAMAL (104-55-2): Partition coefficient n-octanol/water (Log Pow) 2.1065 (at 25 °C)
citral (5392-40-5): Partition coefficient n-octanol/water (Log Pow) 2.76 (at 25 °C)
Isovaleraldehyde (590-86-3): Partition coefficient n-octanol/water (Log Pow) 1.5 (at 25 °C (at pH 7)
1,2-Propanediol (57-55-6): BCF - Fish [1] (1 dimensionless; Partition coefficient n-octanol/water (Log Pow) -1.07 (at 20.5 °C (at pH >=6.2-<=6.4)
No additional information available
No additional information available
No additional information available
Additional information: Avoid release to the environment.
13.1. Metode de tratare a deşeurilor
Recomandări pentru eliminarea produsului/ambalajului: Dispose in a safe manner in accordance with local/national regulations.
Informaţii ecologice: Avoid release to the environment.
HP code: HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID | |
|---|---|---|---|---|---|
| 14.1. UN number or ID number | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.2. UN proper shipping name | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.3. Transport hazard class(es) | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.4. Packing group | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.5. Environmental hazards | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
No supplementary information available
Overland transport: Not applicable
Transport by sea: Not applicable
Air transport: Not applicable
Inland waterway transport: Not applicable
Rail transport: Not applicable
Not applicable