C-SERIES Brown Liquid Dye #D23211

Fișă cu date de securitate
conform Regulamentului (CE) nr. 1907/2006 (REACH) cu modificarea Regulamentului (UE) 2020/878
Data emiterii: 7/11/2023
Data revizuirii: 7/1/2025
Înlocuiește versiunea din: 12/28/2022
Versiune: 2.0

SECȚIUNEA 1: Identificarea substanței/amestecului și a societății/întreprinderii

1.1. Identificatorul produsului

Forma produsului: Mixture
Denumirea produsului: C-SERIES Brown Liquid Dye #D23211
UFI: 3S82-32KM-W007-NQRD
Cod produs: D23211
Tip de produs: Colorant,Colouring agents
Grup de produs: Trade product

1.2. Utilizări relevante identificate ale substanței sau amestecului și utilizări nerecomandate

Categorii principale de utilizare: Professional use,Industrial use,Consumer use
Specificație utilizare industrială/profesională: Industrial
Utilizare: For professional use only
Utilizarea substanței/amestecului: Colorant; Colouring agents
Categorie funcție sau utilizare: Colouring agents
Utilizări nerecomandate / Restricții de utilizare: Not for: Food/feedstuff additives, Cosmetics, personal care products

1.3. Detalii privind furnizorul fișei cu date de securitate

FRENCH COLOR & FRAGRANCE INTERNATIONAL GmbH GmbH
Mittlerer Weg 35
DE 79424 Auggen
Germany
T 49-7631-931-8900
SDS@frenchcolor.com, www.frenchcolor.com

1.4. Număr de telefon pentru urgențe

Emergency number : 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086

SECȚIUNEA 2: Identificarea pericolelor

2.1. Clasificarea substanței sau a amestecului

Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]:
Skin sensitisation, Category 1 — H317
Efecte fizico-chimice, asupra sănătății umane și asupra mediului:
Potrivit cunoștințelor noastre, acest produs nu prezintă niciun risc particular, cu condiția să fie manipulat în conformitate cu bunele practici de igienă și securitate profesională.

2.2. Elemente de etichetare

Pictograme de pericol (CLP): GHS07
Cuvânt de avertizare (CLP): Warning
Conține: Reaction products of 2-Ethylaniline with heptyl naphthalen-2-ol
Fraze de pericol (CLP): H317 - May cause an allergic skin reaction.
Fraze de precauție (CLP):
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P321 - Specific treatment (see supplemental first aid instruction on this label).
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.

2.3. Alte pericole

Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

SECȚIUNEA 3: Compoziție/informații privind ingredientele

3.2. Amestecuri

Nume Identificator produs % Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Refined Soybean oil CAS-No.: 8001-22-7
EC-No.: 232-274-4 		50 Not classified
Reaction products of 2-Ethylaniline with heptyl naphthalen-2-ol CAS-No.: 1401000-07-4
EC-No.: 825-706-3
REACH-no: 01-2120775219-45 		3.52016 – 5.72026 Skin Sens. 1, H317
Aquatic Chronic 4, H413
9,10-Anthracenedione, 1,4-diamino-, N,N'-mixed 2-ethylhexyl and 3-[(2-ethylhexyl)oxy]propyl and 3-methoxypropyl derivatives CAS-No.: 90170-70-0
EC-No.: 290-505-4
REACH-no: 01-2119491195-33 		2.286 – 3.429 Aquatic Chronic 4, H413
Full text of H- and EUH-statements: see section 16

SECȚIUNEA 4: Măsuri de prim ajutor

4.1. Descrierea măsurilor de prim ajutor

Măsuri generale de prim ajutor: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
După inhalare: Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest.
După contactul cu pielea: Wash skin with plenty of water. Wash with plenty of water/…. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this label). Wash contaminated clothing before reuse. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
După contactul cu ochii: Rinse eyes with water as a precaution. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
După înghițire: Call a poison center or a doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Cele mai importante simptome și efecte, atât acute, cât și întârziate

Simptome/efecte: Not expected to present a significant hazard under anticipated conditions of normal use.
Simptome/efecte după inhalare: May cause an allergic skin reaction.

4.3. Indicații privind orice îngrijire medicală imediată și tratamente speciale necesare

Treat symptomatically.

SECȚIUNEA 5: Măsuri de combatere a incendiilor

5.1. Mijloace de stingere

Mijloace de stingere adecvate: Water spray. Dry powder. Foam. Carbon dioxide. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.

5.2. Pericole speciale cauzate de substanță sau amestec

Produse periculoase de descompunere în caz de incendiu: Toxic fumes may be released.

5.3. Recomandări pentru pompieri

Instrucțiuni de stingere: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protecție în timpul stingerii incendiului: Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. Do not enter fire area without proper protective equipment, including respiratory protection.

SECȚIUNEA 6: Măsuri în caz de dispersare accidentală

6.1. Precauții personale, echipament de protecție și proceduri de urgență

Pentru personalul care nu face parte din serviciile de urgență: Emergency procedures: Ventilate spillage area. Evacuate unnecessary personnel.
Pentru echipele de intervenție: Protective equipment: Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". Equip cleanup crew with proper protection. Emergency procedures: Ventilate area.

6.2. Precauții pentru mediul înconjurător

Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Metode și material pentru izolarea incendiului și pentru curățare

Metode de curățare: Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Alte informații: Dispose of materials or solid residues at an authorized site.

6.4. Trimitere la alte secțiuni

For further information refer to section 13. See Section 8. Exposure controls and personal protection.

SECȚIUNEA 7: Manipulare și depozitare

7.1. Precauții pentru manipulare în condiții de securitate

Precauții pentru manipulare în condiții de securitate: Ensure good ventilation of the work station. Wear personal protective equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
Măsuri de igienă: Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.

7.2. Condiții de depozitare în condiții de securitate, inclusiv eventuale incompatibilități

Condiții de depozitare:Store in a well-ventilated place. Keep cool. Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Produse incompatibile:Strong bases. Strong acids.
Materiale incompatibile:Sources of ignition. Direct sunlight.
Durata maximă de depozitare:1 year
Temperatura de depozitare:25 °C
Zona de depozitare:Store in a well-ventilated place. Store away from heat.
Reguli speciale privind ambalarea:Store in a closed container.
Materiale de ambalare:Do not store in corrodable metal.

7.3. Utilizări finale specifice

No additional information available

SECȚIUNEA 8: Controale ale expunerii/protecția personală

8.1. Parametri de control

Valori limită naționale de expunere profesională și valori biologice limită
Substanță Țară / standard Limită
Refined Soybean oil (8001-22-7) Germany - Occupational Exposure Limits (TRGS 900) AGW (OEL TWA) 5 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed-respirable fraction (Triglyceride)
Refined Soybean oil (8001-22-7) Switzerland - Occupational Exposure Limits MAK (OEL TWA) 5 mg/m³ (inhalable dust (Triglycerides)
Refined Soybean oil (8001-22-7) Switzerland - Occupational Exposure Limits KZGW (OEL STEL) 20 mg/m³ (inhalable dust)

8.2. Controale ale expunerii

Controale tehnice corespunzătoare: Ensure good ventilation of the work station.
Echipament individual de protecție: Avoid all unnecessary exposure.
Pictograme pentru echipament de protecție individuală:
Protecția ochilor și a feței: Safety glasses. Chemical goggles or safety glasses
Protecția pielii: Wear suitable protective clothing
Protecția mâinilor: Protective gloves. Wear protective gloves.
Protecția respiratorie: In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate mask
Controale ale expunerii asupra mediului: Avoid release to the environment.
Alte informații: Do not eat, drink or smoke during use.

SECȚIUNEA 9: Proprietăți fizice și chimice

9.1. Informații privind proprietățile fizice și chimice de bază

Stare fizicăLiquid
Culoarebrown.
Miroscharacteristic.
Pragul de mirosNot available
Punct de topireNot applicable
Punct de înghețNot available
Punct de fierbereNot available
InflamabilitateNot applicable,Non flammable.
Limita inferioară de explozieNot available
Limita superioară de explozieNot available
Punct de aprindere> 94 °C
Temperatura de autoaprindereNot available
Temperatura de descompunereNot available
pHNot available
Viscozitate, cinematicăNot available
SolubilitateNot available
Coeficient de partiție n-octanol/apă (Log Kow)Not available
Presiunea vaporilorNot available
Presiunea vaporilor la 50°CNot available
DensitateNot available
Densitate relativăNot available
Densitatea relativă a vaporilor la 20°CNot available
Caracteristicile particulelorNot applicable

9.2. Alte informații

No additional information available

SECȚIUNEA 10: Stabilitate și reactivitate

10.1. Reactivitate

The product is non-reactive under normal conditions of use, storage and transport.

10.2. Stabilitate chimică

Stable under normal conditions. Not established.

10.3. Posibilitatea de reacții periculoase

No dangerous reactions known under normal conditions of use. Not established.

10.4. Condiții de evitat

None under recommended storage and handling conditions (see section 7). Direct sunlight. Extremely high or low temperatures.

10.5. Materiale incompatibile

Strong acids. Strong bases.

10.6. Produse periculoase de descompunere

Under normal conditions of storage and use, hazardous decomposition products should not be produced. fume. Carbon monoxide. Carbon dioxide.

SECȚIUNEA 11: Informații toxicologice

11.1. Informații privind clasele de pericol definite în Regulamentul (CE) nr. 1272/2008

Toxicitate acută (orală)Not classified
Toxicitate acută (dermală)Not classified
Toxicitate acută (inhalare)Not classified
Corodarea/iritarea pieliiNot classified
Informații suplimentareBased on available data, the classification criteria are not met
Lezarea gravă/iritarea ochilorNot classified
Informații suplimentareBased on available data, the classification criteria are not met
Sensibilizare respiratorie sau cutanatăMay cause an allergic skin reaction.
Informații suplimentareBased on available data, the classification criteria are not met
Mutagenicitate asupra celulelor germinaleNot classified
Informații suplimentareBased on available data, the classification criteria are not met
CarcinogenicitateNot classified
Informații suplimentareBased on available data, the classification criteria are not met
Toxicitate pentru reproducereNot classified
Informații suplimentareBased on available data, the classification criteria are not met
STOT - expunere unicăNot classified
Informații suplimentareBased on available data, the classification criteria are not met
STOT - expunere repetatăNot classified
Informații suplimentareBased on available data, the classification criteria are not met
Pericol prin aspirareNot classified
Informații suplimentareBased on available data, the classification criteria are not met

11.2. Informații privind alte pericole

Alte informații
Potential adverse human health effects and symptoms: Based on available data, the classification criteria are not met

SECȚIUNEA 12: Informații ecologice

12.1. Toxicitate

Ecologie - general: The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment.
Periculos pentru mediul acvatic, pe termen scurt (acut): Not classified
Periculos pentru mediul acvatic, pe termen lung (cronic): Not classified

12.2. Persistență și degradabilitate

C-SERIES Brown Liquid Dye #D23211Persistență și degradabilitate Not established.
Refined Soybean oil (8001-22-7)Persistență și degradabilitate Rapidly degradable
9,10-Anthracenedione, 1,4-diamino-, N,N'-mixed 2-ethylhexyl and 3-[(2-ethylhexyl)oxy]propyl and 3-methoxypropyl derivatives (90170-70-0)Persistență și degradabilitate Rapidly degradable
Reaction products of 2-Ethylaniline with heptyl naphthalen-2-ol (1401000-07-4)Persistență și degradabilitate Rapidly degradable

12.3. Potențial de bioacumulare

C-SERIES Brown Liquid Dye #D23211: Bioaccumulative potential Not established.

12.4. Mobilitate în sol

No additional information available

12.5. Rezultatele evaluării PBT și vPvB

No additional information available

12.6. Proprietăți de perturbare endocrină

No additional information available

12.7. Alte efecte adverse

Alte informații: Avoid release to the environment.

SECȚIUNEA 13: Considerații privind eliminarea

13.1. Metode de tratare a deșeurilor

Metode de tratare a deșeurilor: Dispose of contents/container in accordance with licensed collector’s sorting instructions.
Recomandări privind eliminarea produsului/ambalajului: Dispose of contents/container in accordance with local/national laws and regulations. Dispose in a safe manner in accordance with local/national regulations.
Informații ecologice privind deșeurile: Avoid release to the environment.

SECȚIUNEA 14: Informații privind transportul

In accordance with ADR / IMDG / IATA / ADN / RID
ADR IMDG IATA ADN RID
14.1. Numărul ONU sau numărul de identificare:
Not regulated for transport		 14.1. Numărul ONU sau numărul de identificare:
Not regulated for transport		 14.1. Numărul ONU sau numărul de identificare:
Not regulated for transport		 14.1. Numărul ONU sau numărul de identificare:
Not regulated for transport		 14.1. Numărul ONU sau numărul de identificare:
Not regulated for transport
14.2. Denumirea corectă ONU pentru expediție:
Not applicable		 14.2. Denumirea corectă ONU pentru expediție:
Not applicable		 14.2. Denumirea corectă ONU pentru expediție:
Not applicable		 14.2. Denumirea corectă ONU pentru expediție:
Not applicable		 14.2. Denumirea corectă ONU pentru expediție:
Not applicable
14.3. Clasa(clasele) de pericol pentru transport:
Not applicable		 14.3. Clasa(clasele) de pericol pentru transport:
Not applicable		 14.3. Clasa(clasele) de pericol pentru transport:
Not applicable		 14.3. Clasa(clasele) de pericol pentru transport:
Not applicable		 14.3. Clasa(clasele) de pericol pentru transport:
Not applicable
14.4. Grupul de ambalare:
Not applicable		 14.4. Grupul de ambalare:
Not applicable		 14.4. Grupul de ambalare:
Not applicable		 14.4. Grupul de ambalare:
Not applicable		 14.4. Grupul de ambalare:
Not applicable
14.5. Pericole pentru mediu:
Dangerous for the environment: No		 14.5. Pericole pentru mediu:
Dangerous for the environment: No
Marine pollutant: No		 14.5. Pericole pentru mediu:
Dangerous for the environment: No		 14.5. Pericole pentru mediu:
Dangerous for the environment: No		 14.5. Pericole pentru mediu:
Dangerous for the environment: No
No supplementary information available

14.6. Precauții speciale pentru utilizator

Overland transport: No data available
Transport by sea: No data available
Air transport: No data available
Inland waterway transport: No data available
Rail transport: No data available

14.7. Transport maritim în vrac în conformitate cu instrumentele OMI

Not applicable

SECȚIUNEA 15: Informații de reglementare

15.1. Reglementări/legislație specifică de securitate, sănătate și mediu pentru substanță sau amestec

EU-Regulations

REACH Annex XVII (Restriction List): Contains no substance(s) listed on REACH Annex XVII (Restriction Conditions)
REACH Annex XIV (Authorisation List): Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC): Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent): Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants): Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (2024/590): Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 2024/590 on substances that deplete the ozone layer)
Council Regulation (EC) for the control of dual-use items: Contains no substance subject to the COUNCIL REGULATION (EC) for the control of dual-use items
Explosives Precursors Regulation (EU 2019/1148): Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (EC 273/2004): Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
National regulations

Germany
VOC ordinance (ChemVOCFarbV) :
Water hazard class (WGK) : WGK 3, Highly hazardous to water (Classification according to AwSV, Annex 1).
Major Accidents Ordinance (12. BImSchV) : Is not subject to the Major Accidents Ordinance (12. BImSchV)

Netherlands
ABM category : A(3) - hazardous for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen : Refined Soybean oil is listed
SZW-lijst van mutagene stoffen : Refined Soybean oil is listed
SZW-lijst van reprotoxische stoffen – Borstvoeding : None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid : None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling : None of the components are listed

Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed
Danish National Regulations : Young people below the age of 18 years are not allowed to use the product

Poland
Polish National Regulations : Act of 25 February 2011 on chemical substances and their mixtures (J. o L. No. 63, item 322 as amended; consolidated text J. o L. 2019, item 1225).
Act of 14 December 2012 on waste (J. o L. 2013, item 322 as amended; consolidated text J. o L. 2020, item 797).
The announcement of Marshal of the Sejm of the Republic of Poland dated 19 October 2016 concerning the consolidated text announcement of the decree on the management of packaging and packaging waste (J. o L. 2016, item 1863 as amended).
Decree of the Minister of Environment of 14 December 2014 on the catalogue of waste (J. o L. 2014, item 1923).
Act of 19 August 2011 on the Carriage of Dangerous Goods (J. o L. 2011 No. 227, item 1367 as amended; consolidated text J. o L. 2020, item 154).
Regulation of the Minister of Family, Labour and Social Policy of 12 June 2018 on the highest permissible concentration and intensity of noxious agents for health at work environment (J. o L. item 1286 as amended).
The announcement of Minister of Health dated 9 September 2016 concerning the consolidated text announcement of the decree of the Minister of Health of 30 December 2004 on health and safety at work related to exposure to chemical agents at work (J. o L. of 16 September 2016, item 1488)
Regulation of the Minister of Health of 2 February 2011 on tests and measurements of the noxious agents for health at work environment (J. o L. No. 33, item 166 as amended).
Regulation of the Minister of Environment of 9 December 2003 on particularly hazardous substances to the environment (J. o L. No. 217, item 2141).
ADR Agreement: Government Statement of 13 March 2023 on the entry into force of amendments to Annexes A and B to the Agreement concerning the International Carriage of Dangerous Goods by Road (ADR), signed in Geneva on 30 September 1957 (J. o. L. 2023, item 891)

15.2. Evaluarea securității chimice

No chemical safety assessment has been carried out

SECȚIUNEA 16: Alte informații

Data sources: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.

Other information: None.

Text complet pentru frazele H și EUH

Aquatic Chronic 4Hazardous to the aquatic environment – Chronic Hazard, Category 4
Skin Sens. 1Skin sensitisation, Category 1
H317May cause an allergic skin reaction.
H413May cause long lasting harmful effects to aquatic life.
Clasificarea este conformă cu: ATP 12
Safety Data Sheet (SDS), EU
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.