Fișă cu Date de Securitate conform Regulation (EC) 1907/2006 amendat prin Regulation (EU) 2020/878
| Forma produsului | Mixture |
|---|---|
| Denumire comercială | C-Series Liquid Dye Purple #D23202 |
| UFI | 5082-J2D2-400S-PNGT |
| Cod produs | D23202 |
| Tip de produs | Colorant,Colouring agents |
| Grup de produs | Trade product |
1.2.1. Utilizări relevante identificate
Categoria principală de utilizare: Industrial use,Professional use
Spec. utilizare industrială/profesională: Industrial
For professional use only
Utilizarea substanței/amestecului: Colorant
Categoria funcției sau a utilizării: Colouring agents
1.2.2. Utilizări contraindicate
Restricții de utilizare: Not for: Food/feedstuff additives, Cosmetics, personal care products
FRENCH COLOR & FRAGRANCE CO., INC.
488 GRAND AVENUE
07631 ENGLEWOOD, NEW JERSEY
USA
T +001-201-567-6883 - F +001-201-567-5749
Regulatory@frenchcolor.com - www.frenchcolor.com
Emergency number: 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086
Clasificare conform Regulation (EC) No. 1272/2008 [CLP]
Skin sensitisation, Category 1 H317
Full text of H- and EUH-statements: see section 16
Efecte fizico-chimice, asupra sănătății umane și asupra mediului: To our knowledge, this product does not present any particular risk, provided it is handled in accordance with good occupational hygiene and safety practice. May cause an allergic skin reaction.
Etichetare conform Regulation (EC) No. 1272/2008 [CLP]
Pictograme de pericol (CLP): GHS07
Cuvânt de avertizare (CLP): Warning
Conține: N-(2-Ethylhexyl)-1-[[3-methyl-4-[(3-methylphenyl)azo]phenyl]azo]naphthalen-2-amine
Fraze de pericol (CLP): H317 - May cause an allergic skin reaction.
Fraze de precauție (CLP):
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P321 - Specific treatment (see supplemental first aid instruction on this label).
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Not applicable
| Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
|---|---|---|---|
| Refined Soybean oil | CAS-No.: 8001-22-7 EC-No.: 232-274-4 |
40 – 50 | Not classified |
| Isopropyl myristate | CAS-No.: 110-27-0 EC-No.: 203-751-4 REACH-no: 01-2119541806-35 |
≤ 30 | Not classified |
| 9,10-Anthracenedione, 1,4-diamino-, N,N'-mixed 2-ethylhexyl and 3-[(2-ethylhexyl)oxy]propyl and 3-methoxypropyl derivatives | CAS-No.: 90170-70-0 EC-No.: 290-505-4 REACH-no: 01-2119491195-33 |
5 – 15 | Aquatic Chronic 4, H413 |
| N-(2-Ethylhexyl)-1-[[3-methyl-4-[(3-methylphenyl)azo]phenyl]azo]naphthalen-2-amine | CAS-No.: 56358-10-2 EC-No.: 260-125-3 REACH-no: 01-2120767269-40 |
1 – 10 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 4, H413 |
| 1,3-Benzenediol, 2,4-bis[(4-dodecylphenyl)azo]- | CAS-No.: 65087-00-5 EC-No.: 265-390-9 |
1 – 5 | Not classified |
Full text of H- and EUH-statements: see section 16
First-aid measures general: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation: Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention.
First-aid measures after eye contact: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. Rinse eyes with water as a precaution.
First-aid measures after ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center or a doctor if you feel unwell.
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
Symptoms/effects after skin contact: May cause an allergic skin reaction.
Treat symptomatically.
Suitable extinguishing media: Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media: Do not use a heavy water stream.
Hazardous decomposition products in case of fire: Toxic fumes may be released.
Firefighting instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.
6.1.1. Pentru personalul care nu intervine în situații de urgență
Emergency procedures: Ventilate spillage area. Evacuate unnecessary personnel. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.
6.1.2. Pentru persoanele responsabile de intervenție
Protective equipment: Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection".
Emergency procedures: Ventilate area.
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Methods for cleaning up: Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information: Dispose of materials or solid residues at an authorized site.
See Section 8. Exposure controls and personal protection. For further information refer to section 13.
Precautions for safe handling: Ensure good ventilation of the work station. Wear personal protective equipment. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.
Hygiene measures: Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
Storage conditions: Keep only in the original container in a cool, well ventilated place away from : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container closed when not in use. Store in a well-ventilated place. Keep cool.
Incompatible products: Strong bases. Strong acids.
Incompatible materials: Sources of ignition. Direct sunlight.
Storage temperature: 25 °C
Storage area: Store in a well-ventilated place. Store away from heat.
Special rules on packaging: Store in a closed container.
Packaging materials: Do not store in corrodable metal.
No additional information available
8.1.1. Valori limită naționale de expunere ocupațională și valori limită biologice
| Substanță | Țară / reglementare | Valoare |
|---|---|---|
| Refined Soybean oil (8001-22-7) | Germany - Occupational Exposure Limits (TRGS 900) | AGW (OEL TWA) [1] 5 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed-respirable fraction (Triglyceride) |
| Refined Soybean oil (8001-22-7) | Switzerland - Occupational Exposure Limits | MAK (OEL TWA) [1] 5 mg/m³ (inhalable dust) |
| Refined Soybean oil (8001-22-7) | Switzerland - Occupational Exposure Limits | KZGW (OEL STEL) 20 mg/m³ (inhalable dust) |
8.1.2. Proceduri recomandate de monitorizare: No additional information available
8.1.3. Contaminanți atmosferici formați: No additional information available
8.1.4. DNEL și PNEC: No additional information available
8.1.5. Control banding: No additional information available
8.2.1. Controale tehnice corespunzătoare
Ensure good ventilation of the work station.
8.2.2. Echipament individual de protecție
Personal protective equipment: Avoid all unnecessary exposure.
Personal protective equipment symbol(s):
8.2.2.1. Protecția ochilor și a feței
Eye protection: Chemical goggles or safety glasses. Safety glasses
8.2.2.2. Protecția pielii
Skin and body protection: Wear suitable protective clothing
Hand protection: Wear protective gloves.
8.2.2.3. Protecția respirației
Respiratory protection: Wear appropriate mask
8.2.2.4. Pericole termice
No additional information available
8.2.3. Controale ale expunerii asupra mediului
Environmental exposure controls: Avoid release to the environment.
Other information: Do not eat, drink or smoke during use.
| Physical state | Liquid |
|---|---|
| Colour | Conforms to standard. |
| Odour | characteristic. characteristic. |
| Odour threshold | Not available |
| Melting point | Not applicable |
| Freezing point | Not available |
| Boiling point | Not available |
| Flammability | Not applicable |
| Explosive limits | Not available |
| Lower explosion limit | Not available |
| Upper explosion limit | Not available |
| Flash point | > 93.33 °C |
| Auto-ignition temperature | Not available |
| Decomposition temperature | Not available |
| pH | Not available |
| Viscosity, kinematic | Not available |
| Solubility | Not available |
| Partition coefficient n-octanol/water (Log Kow) | Not available |
| Vapour pressure | Not available |
| Vapour pressure at 50°C | Not available |
| Density | Not available |
| Relative density | Not available |
| Relative vapour density at 20°C | Not available |
| Particle characteristics | Not applicable |
9.2.1. Informații privind clasele de pericol fizic
No additional information available
9.2.2. Alte caracteristici de siguranță
No additional information available
The product is non-reactive under normal conditions of use, storage and transport.
Not established.
Not established.
Direct sunlight. Extremely high or low temperatures.
Strong acids. Strong bases.
fume. Carbon monoxide. Carbon dioxide.
Acute toxicity (oral): Not classified
Acute toxicity (dermal): Not classified
Acute toxicity (inhalation): Not classified
Isopropyl myristate (110-27-0)
LD50 oral rat > 10000 mg/kg (Source: NLM_CIP)
LD50 dermal rabbit 5 g/kg (Source: NLM_CIP)
LC50 Inhalation - Rat > 41 mg/l (Exposure time: 1 h Source: IUCLID)
Skin corrosion/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Serious eye damage/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Respiratory or skin sensitisation: May cause an allergic skin reaction.
Additional information: Based on available data, the classification criteria are not met
Germ cell mutagenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Carcinogenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Reproductive toxicity: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-single exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-repeated exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
Aspiration hazard: Not classified
Additional information: Based on available data, the classification criteria are not met
11.2.1. Proprietăți perturbatoare endocrine
No additional information available
11.2.2. Alte informații
Potential adverse human health effects and symptoms : Based on available data, the classification criteria are not met
Ecology - general: The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment.
Hazardous to the aquatic environment, short–term (acute): Not classified
Hazardous to the aquatic environment, long–term (chronic): Not classified
Isopropyl myristate (110-27-0)
LC50 - Fish [1] 8400 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [semi-static] Source: IUCLID)
LC50 - Fish [2] 8400 mg/l (Exposure time: 96 h - Species: Brachydanio rerio Source: IUCLID)
EC50 - Crustacea [1] 100 mg/l (Exposure time: 48 h - Species: Daphnia magna)
EC50 72h - Algae [1] > 100 mg/l (Species: Desmodesmus subspicatus)
C-Series Liquid Dye Purple #D23202
Persistence and degradability Not established.
C-Series Liquid Dye Purple #D23202
Bioaccumulative potential Not established.
Isopropyl myristate (110-27-0)
Partition coefficient n-octanol/water (Log Pow) 7.71
No additional information available
No additional information available
No additional information available
Additional information: Avoid release to the environment.
Waste treatment methods: Dispose of contents/container in accordance with licensed collector’s sorting instructions.
Product/Packaging disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials: Avoid release to the environment.
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID | |
|---|---|---|---|---|---|
| 14.1. UN number or ID number | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.2. UN proper shipping name | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.3. Transport hazard class(es) | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.4. Packing group | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.5. Environmental hazards | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
No supplementary information available
Overland transport
Not applicable
Transport by sea
Not applicable
Air transport
Not applicable
Inland waterway transport
Not applicable
Rail transport
Not applicable
Not applicable
15.1.1. EU-Regulations
REACH Annex XVII (Restriction List)
EU restriction list (REACH Annex XVII)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(b) | C-Series Liquid Dye Purple #D23202 | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
REACH Annex XIV (Authorisation List)
Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC)
Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent)
Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants)
Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009)
Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Explosives Precursors Regulation (2019/1148)
Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004)
Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
15.1.2. National regulations
Germany
Water hazard class (WGK): WGK 2, Significantly hazardous to water (Classification according to AwSV, Annex 1).
Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids.
Joint storage table:
Joint storage not permitted for: LGK 1, LGK 6.2, LGK 7.
Joint storage with restrictions permitted for: LGK 4.1A, LGK 4.3, LGK 5.1C.
Joint storage permitted for: LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13.
Hazardous Incident Ordinance (12. BImSchV): Is not subject of the Hazardous Incident Ordinance (12. BImSchV)
Netherlands
ABM category: A(3) - hazardous for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen: Refined Soybean oil,1,3-Benzenediol, 2,4-bis[(4-dodecylphenyl)azo]- are listed
SZW-lijst van mutagene stoffen: Refined Soybean oil,1,3-Benzenediol, 2,4-bis[(4-dodecylphenyl)azo]- are listed
SZW-lijst van reprotoxische stoffen – Borstvoeding: None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid: None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling: None of the components are listed
Denmark
Classification remarks: Emergency management guidelines for the storage of flammable liquids must be followed
Danish National Regulations: Young people below the age of 18 years are not allowed to use the product
Switzerland
Storage class (LK): LK 10/12 - Liquids
No chemical safety assessment has been carried out
Other information: None.
Full text of H- and EUH-statements:
Aquatic Chronic 4 Hazardous to the aquatic environment – Chronic Hazard, Category 4
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H413 May cause long lasting harmful effects to aquatic life.
Skin Irrit. 2 Skin corrosion/irritation, Category 2
Skin Sens. 1 Skin sensitisation, Category 1
The classification complies with : ATP 12
Safety Data Sheet (SDS), EU