ECO REACH Hunter Green Dye #D23208 SDS UE
| Formă produs | Mixture |
|---|---|
| Denumire comercială | ECO REACH Hunter Green Dye #D23208 |
| UFI | NH82-K2HE-Y00R-NQ06 |
| Cod produs | D23208 |
| Tip produs | Colorant |
| Grup de produs | Trade product |
| Categoria principală de utilizare | Industrial use,Professional use |
|---|---|
| Specificație de utilizare industrială/profesională | Industrial |
| For professional use only | |
| Utilizarea substanței/amestecului | Colorant |
| Funcție sau categorie de utilizare | Colouring agents |
Restricții de utilizare: Not for: Food/feedstuff additives, Cosmetics, personal care products
FRENCH COLOR & FRAGRANCE CO., INC.
488 GRAND AVENUE
07631 ENGLEWOOD, NEW JERSEY
USA
T +001-201-567-6883 - F +001-201-567-5749
Regulatory@frenchcolor.com - www.frenchcolor.com
Emergency number: 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086
Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Textul integral al frazelor H și EUH: a se vedea secțiunea 16
Efecte fizico-chimice, asupra sănătății umane și asupra mediului:
May cause long lasting harmful effects to aquatic life. May cause an allergic skin reaction.
Etichetare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Pictograme de pericol (CLP): GHS07
Cuvânt de avertizare (CLP): Warning
Conține: 3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives
| Fraze de pericol (CLP) | H317 - May cause an allergic skin reaction. H413 - May cause long lasting harmful effects to aquatic life. |
|---|---|
| Fraze de precauție (CLP) |
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P321 - Specific treatment (see supplemental first aid instruction on this label). |
Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Not applicable
| Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
|---|---|---|---|
| Refined Soybean oil | CAS-No.: 8001-22-7 EC-No.: 232-274-4 |
15.5 – 65.5 | Not classified |
| 3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives | CAS-No.: 97660-72-5 EC-No.: 307-585-4 REACH-no: 01-2120754185-53 |
3.875 – 16.375 | Skin Sens. 1, H317 Aquatic Chronic 4, H413 |
| 9,10-Anthracenedione, 1,4-diamino-, N,N'-mixed 2-ethylhexyl and 3-[(2-ethylhexyl)oxy]propyl and 3-methoxypropyl derivatives | CAS-No.: 90170-70-0 EC-No.: 290-505-4 REACH-no: 01-2119491195-33 |
3.875 – 16.375 | Aquatic Chronic 4, H413 |
Textul integral al frazelor H și EUH: a se vedea secțiunea 16
| Măsuri generale de prim ajutor | Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). |
|---|---|
| După inhalare | Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest. |
| După contactul cu pielea | Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see Get medical advice/attention. on this label). If skin irritation occurs: Get medical advice/attention. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. |
| După contactul cu ochii | Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. Rinse eyes with water as a precaution. |
| După ingerare | Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center or a doctor if you feel unwell. |
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
Symptoms/effects after skin contact: May cause an allergic skin reaction.
Treat symptomatically.
Mijloace de stingere adecvate: Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
Produse periculoase de descompunere în caz de incendiu: Toxic fumes may be released.
Instrucțiuni pentru stingerea incendiilor: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protecție în timpul stingerii incendiului: Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.
Proceduri de urgență: Ventilate spillage area. Evacuate unnecessary personnel. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.
Echipament de protecție: Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection".
Proceduri de urgență: Ventilate area.
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Metode de curățare: Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Alte informații: Dispose of materials or solid residues at an authorized site.
See Section 8. Exposure controls and personal protection. For further information refer to section 13.
Precauții pentru manipularea în condiții de siguranță: Ensure good ventilation of the work station. Wear personal protective equipment. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.
Măsuri de igienă: Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
Condiții de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container closed when not in use. Store in a well-ventilated place. Keep cool.
Produse incompatibile: Strong bases. Strong acids.
Materiale incompatibile: Sources of ignition. Direct sunlight.
Durată maximă de depozitare: 1 year
Temperatura de depozitare: 25 °C
Zona de depozitare: Store in a well-ventilated place. Store away from heat.
Reguli speciale privind ambalajul: Store in a closed container.
Materiale de ambalare: Do not store in corrodable metal.
No additional information available
| Refined Soybean oil (8001-22-7) | |
|---|---|
| Germany - Occupational Exposure Limits (TRGS 900) | AGW (OEL TWA) [1] 5 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed-respirable fraction (Triglyceride) |
| Switzerland - Occupational Exposure Limits | MAK (OEL TWA) [1] 5 mg/m³ (inhalable dust) |
| KZGW (OEL STEL) 20 mg/m³ (inhalable dust) |
No additional information available
No additional information available
No additional information available
No additional information available
Ensure good ventilation of the work station.
Echipament individual de protecție: Avoid all unnecessary exposure.
Simbol(uri) pentru echipament individual de protecție:
Protecția ochilor: Chemical goggles or safety glasses. Safety glasses
Protecția pielii și a corpului: Wear suitable protective clothing
Protecția mâinilor: Wear protective gloves.
Protecția respiratorie: Wear appropriate mask
No additional information available
Controlul expunerii mediului: Avoid release to the environment.
Alte informații: Do not eat, drink or smoke during use.
| Stare fizică | Liquid |
|---|---|
| Culoare | Conforms to standard. |
| Miros | characteristic. |
| Prag de miros | Not available |
| Punct de topire | Not applicable |
| Punct de îngheț | Not available |
| Punct de fierbere | Not available |
| Inflamabilitate | Not applicable |
| Limite explozive | Not available |
| Limită inferioară de explozie | Not available |
| Limită superioară de explozie | Not available |
| Punct de aprindere | > 93.33 °C |
| Temperatura de autoaprindere | Not available |
| Temperatura de descompunere | Not available |
| pH | Not available |
| Vâscozitate, cinematică | Not available |
| Solubilitate | Not available |
| Coeficient de partiție n-octanol/apă (Log Kow) | Not available |
| Presiune de vapori | Not available |
| Presiune de vapori la 50°C | Not available |
| Densitate | Not available |
| Densitate relativă | Not available |
| Densitate relativă a vaporilor la 20°C | Not available |
Caracteristici ale particulelor: Not applicable
No additional information available
No additional information available
The product is non-reactive under normal conditions of use, storage and transport.
Not established.
Not established.
Direct sunlight. Extremely high or low temperatures.
Strong acids. Strong bases.
fume. Carbon monoxide. Carbon dioxide.
| Toxicitate acută (oral) | Not classified |
|---|---|
| Toxicitate acută (dermic) | Not classified |
| Toxicitate acută (inhalare) | Not classified |
| Corodarea/iritarea pielii | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| Lezare/iritare gravă a ochilor | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| Sensibilizare respiratorie sau cutanată | May cause an allergic skin reaction. |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| Mutagenitatea celulelor germinale | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| Carcinogenitate | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| Toxicitate pentru reproducere | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| STOT - expunere unică | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| STOT - expunere repetată | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| Pericol prin aspirare | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
No additional information available
Efecte potențiale adverse asupra sănătății umane și simptome: Based on available data, the classification criteria are not met
Ecology - general: May cause long lasting harmful effects to aquatic life.
Periculos pentru mediul acvatic, pe termen scurt (acut): Not classified
Periculos pentru mediul acvatic, pe termen lung (cronic): May cause long lasting harmful effects to aquatic life.
ECO REACH Hunter Green Dye #D23208
Persistence and degradability Not established.
3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives (97660-72-5)
Persistence and degradability Not established.
ECO REACH Hunter Green Dye #D23208
Bioaccumulative potential Not established.
3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives (97660-72-5)
Partition coefficient n-octanol/water (Log Pow) > 6.5 (at 30 °C (at pH 6.92)
Bioaccumulative potential Not established.
No additional information available
No additional information available
No additional information available
Informații suplimentare: Avoid release to the environment.
Metode de tratare a deșeurilor: Dispose of contents/container in accordance with licensed collector’s sorting instructions.
Recomandări pentru eliminarea produsului/ambalajului: Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials: Avoid release to the environment.
HP Code: HP13 - “Sensitising:” waste which contains one or more substances known to cause sensitising effects to the skin or the respiratory organs.
HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID | |
|---|---|---|---|---|---|
| 14.1. Numărul ONU sau numărul de identificare | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.2. Denumirea oficială de transport ONU | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.3. Clasa (clasele) de pericol pentru transport | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.4. Grupul de ambalare | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.5. Pericole pentru mediu | Dangerous for the environment: No | Dangerous for the environment: No Marine pollutant: No |
Dangerous for the environment: No | Dangerous for the environment: No | Dangerous for the environment: No |
No supplementary information available
Overland transport
No data available
Transport by sea
No data available
Air transport
No data available
Inland waterway transport
No data available
Rail transport
No data available
Not applicable
REACH Annex XVII (Restriction List)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(b) | ECO REACH Hunter Green Dye #D23208 | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | ECO REACH Hunter Green Dye #D23208 | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 |
REACH Annex XIV (Authorisation List): Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC): Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent): Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants): Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009): Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Explosives Precursors Regulation (2019/1148): Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004): Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
Germany
Water hazard class (WGK) : WGK 3, Highly hazardous to water (Classification according to AwSV, Annex 1).
Hazardous Incident Ordinance (12. BImSchV) : Is not subject of the Hazardous Incident Ordinance (12. BImSchV)
Netherlands
ABM category : A(3) - hazardous for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen : Refined Soybean oil,3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives are listed
SZW-lijst van mutagene stoffen : Refined Soybean oil,3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives are listed
SZW-lijst van reprotoxische stoffen – Borstvoeding : None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid : None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling : None of the components are listed
Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed
Danish National Regulations : Young people below the age of 18 years are not allowed to use the product
No chemical safety assessment has been carried out
Other information: None.
Full text of H- and EUH-statements:
Aquatic Chronic 4 Hazardous to the aquatic environment – Chronic Hazard, Category 4
H317 May cause an allergic skin reaction.
H413 May cause long lasting harmful effects to aquatic life.
Skin Sens. 1 Skin sensitisation, Category 1
The classification complies with : ATP 12
Safety Data Sheet (SDS), EU