Restricții de utilizare: Not for: Food/feedstuff additives, Cosmetics, personal care products
FRENCH COLOR & FRAGRANCE International GmbH
Mittlerer Weg 35
DE– 79424 Auggen
Germany
T 49-7631-931-8900
SDS@frenchcolor.com - www.frenchcolor.com
Emergency number: 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin sensitisation, Category 1 H317
Hazardous to the aquatic environment – Chronic Hazard, Category 4 H413
Full text of H- and EUH-statements: see section 16
Adverse physicochemical, human health and environmental effects
May cause long lasting harmful effects to aquatic life. May cause an allergic skin reaction.
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP): GHS07
Signal word (CLP): Warning
Contains: 3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives
Hazard statements (CLP):
Precautionary statements (CLP):
Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Not applicable
| Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
|---|---|---|---|
| 3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives | CAS-No.: 97660-72-5 EC-No.: 307-585-4 REACH-no: 01-2120754185-53 |
18 – 32.5 | Skin Sens. 1, H317 Aquatic Chronic 4, H413 |
Full text of H- and EUH-statements: see section 16
First-aid measures after inhalation: Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact: Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention.
First-aid measures after eye contact: Rinse eyes with water as a precaution.
First-aid measures after ingestion: Call a poison center or a doctor if you feel unwell.
Symptoms/effects after skin contact: May cause an allergic skin reaction.
Treat symptomatically.
Suitable extinguishing media: Water spray. Dry powder. Foam. Carbon dioxide.
Hazardous decomposition products in case of fire: Toxic fumes may be released.
Protection during firefighting: Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.
6.1.1. For non-emergency personnel
Emergency procedures: Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.
6.1.2. For emergency responders
Protective equipment: Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".
Avoid release to the environment.
Methods for cleaning up: Take up liquid spill into absorbent material.
Other information: Dispose of materials or solid residues at an authorized site.
For further information refer to section 13.
Precautions for safe handling: Ensure good ventilation of the work station. Wear personal protective equipment. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.
Hygiene measures: Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
No additional information available
8.1.1 National occupational exposure and biological limit values
No additional information available
8.1.2. Recommended monitoring procedures
No additional information available
8.1.3. Air contaminants formed
No additional information available
8.1.4. DNEL and PNEC
No additional information available
8.1.5. Control banding
No additional information available
8.2.1. Appropriate engineering controls: Ensure good ventilation of the work station.
Eye protection: Safety glasses
Skin and body protection: Wear suitable protective clothing
Hand protection: Protective gloves
Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment
Thermal hazards: No additional information available
Environmental exposure controls: Avoid release to the environment.
| Physical state | Liquid |
|---|---|
| Colour | Conforms to standard. |
| Odour | characteristic. |
| Odour threshold | Not available |
| Melting point | Not applicable |
| Freezing point | Not available |
| Boiling point | Not available |
| Flammability | Not applicable |
| Explosive limits | Not available |
| Lower explosion limit | Not available |
| Upper explosion limit | Not available |
Flash point: > 93 °C
Auto-ignition temperature: Not available
Decomposition temperature: Not available
pH: Not available
Viscosity, kinematic: Not available
Solubility: Not available
Partition coefficient n-octanol/water (Log Kow): Not available
Vapour pressure: Not available
Vapour pressure at 50°C: Not available
Density: Not available
Relative density: Not available
Relative vapour density at 20°C: Not available
Particle characteristics: Not applicable
9.2.1. Information with regard to physical hazard classes
No additional information available
9.2.2. Other safety characteristics
No additional information available
10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
None under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
| Acute toxicity (oral) | Not classified |
|---|---|
| Acute toxicity (dermal) | Not classified |
| Acute toxicity (inhalation) | Not classified |
| Skin corrosion/irritation | Not classified |
| Serious eye damage/irritation | Not classified |
| Respiratory or skin sensitisation | May cause an allergic skin reaction. |
| Germ cell mutagenicity | Not classified |
| Carcinogenicity | Not classified |
| Reproductive toxicity | Not classified |
| STOT-single exposure | Not classified |
| STOT-repeated exposure | Not classified |
| Aspiration hazard | Not classified |
11.2. Information on other hazards
No additional information available
Ecology - general: May cause long lasting harmful effects to aquatic life.
Hazardous to the aquatic environment, short–term (acute): Not classified
Hazardous to the aquatic environment, long–term (chronic): May cause long lasting harmful effects to aquatic life.
3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives (97660-72-5)
Persistence and degradability Not established.
3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives (97660-72-5)
Partition coefficient n-octanol/water (Log Pow) > 6.5 (at 30 °C (at pH 6.92)
Bioaccumulative potential Not established.
No additional information available
No additional information available
No additional information available
No additional information available
Waste treatment methods: Dispose of contents/container in accordance with licensed collector’s sorting instructions.
HP Code: HP13 - “Sensitising:” waste which contains one or more substances known to cause sensitising effects to the skin or the respiratory organs.
HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|
| Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.1. UN number or ID number | 14.2. UN proper shipping name | 14.3. Transport hazard class(es) | 14.4. Packing group |
|---|---|---|---|
| Not applicable | Not applicable | Not applicable | Not applicable |
14.5. Environmental hazards
| Dangerous for the environment | No | Marine pollutant | No |
|---|
No supplementary information available
Overland transport
No data available
Transport by sea
No data available
Air transport
No data available
Inland waterway transport
No data available
Rail transport
No data available
Not applicable
15.1.1. EU-Regulations
REACH Annex XVII (Restriction List)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(b) | C-SERIES PRIMARY YELLOW DYE #D23195 | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | C-SERIES PRIMARY YELLOW DYE #D23195 | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 |
REACH Annex XIV (Authorisation List)
Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC)
Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent)
Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants)
Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009)
Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Explosives Precursors Regulation (2019/1148)
Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004)
Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
15.1.2. National regulations
Germany
Water hazard class (WGK): WGK 3, Highly hazardous to water (Classification according to AwSV, Annex 1).
Hazardous Incident Ordinance (12. BImSchV): Is not subject of the Hazardous Incident Ordinance (12. BImSchV)
Netherlands
ABM category: A(3) - hazardous for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen: 3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives is listed
SZW-lijst van mutagene stoffen: 3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives is listed
SZW-lijst van reprotoxische stoffen – Borstvoeding: None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid: None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling: None of the components are listed
Denmark
Classification remarks: Emergency management guidelines for the storage of flammable liquids must be followed
Danish National Regulations: Young people below the age of 18 years are not allowed to use the product
No chemical safety assessment has been carried out
Full text of H- and EUH-statements:
Aquatic Chronic 4 Hazardous to the aquatic environment – Chronic Hazard, Category 4
H317 May cause an allergic skin reaction.
H413 May cause long lasting harmful effects to aquatic life.
Skin Sens. 1 Skin sensitisation, Category 1
The classification complies with : ATP 12
Safety Data Sheet (SDS), EU
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.