Baked Apple #EU40762F

Emergency number: 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086

Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]

Skin sensitisation, Category 1 — H317

Hazardous to the aquatic environment – Chronic Hazard, Category 3 — H412

Efecte adverse fizico-chimice, asupra sănătății umane și asupra mediului

Harmful to aquatic life with long lasting effects. May cause an allergic skin reaction.

Etichetare conform Regulamentului (CE) nr. 1272/2008 [CLP]

Pictograme de pericol (CLP): GHS07

Conține: Eugenol; Cinnamic aldehyde; Orange Oil; Allyl cyclohexylpropionate; Cinnamalva; citral; COUMARIN; Heliotropine; Davana oil

Fraze de pericol (CLP): H317 - May cause an allergic skin reaction. H412 - Harmful to aquatic life with long lasting effects.

Fraze de precauție (CLP): P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P321 - Specific treatment (see supplemental first aid instruction on this label).

Fraze suplimentare: For professional users only.

Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

Not applicable

Nume	Identificator produs	%	Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Verdox	CAS-No.: 88-41-5 EC-No.: 201-828-7 REACH-no: 01-2119970713-33	2.2 – 4.4001	Aquatic Chronic 2, H411
Eugenol	CAS-No.: 97-53-0 EC-No.: 202-589-1 REACH-no: 01-2119971802-33	1.9 – 3.8001	Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Skin Sens. 1B, H317
Cinnamic aldehyde	CAS-No.: 104-55-2 EC-No.: 203-213-9 REACH-no: 01-2119935242-45	1.4 – 2.8501	Acute Tox. 4 (Dermal), H312 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1A, H317 Aquatic Chronic 3, H412
2(3H)-Furanone, 5-heptyldihydro-	CAS-No.: 104-67-6 EC-No.: 203-225-4 REACH-no: 01-2119959333-34	1.2 – 2.4001	Aquatic Chronic 3, H412
Vanillin	CAS-No.: 121-33-5 EC-No.: 204-465-2 REACH-no: 01-2119516040-60	0.9 – 1.7501	Eye Irrit. 2, H319
Allyl heptanoate	CAS-No.: 142-19-8 EC-No.: 205-527-1 REACH-no: 01-2119488961-23	0.7 – 1.3	Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Aquatic Acute 1, H400 Aquatic Chronic 3, H412
Citronellyl acetate (mixed Isomers)	CAS-No.: 150-84-5 EC-No.: 205-775-0	0.5 – 1.0981	Aquatic Chronic 2, H411 Skin Irrit. 2, H315
Orange Oil	CAS-No.: 8028-48-6 EC-No.: 232-433-8	0.5 – 0.9	Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411
Allyl cyclohexylpropionate	CAS-No.: 2705-87-5 EC-No.: 220-292-5	0.3 – 0.65	Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Skin Sens. 1, H317 Aquatic Chronic 1, H410
Cinnamalva	CAS-No.: 1885-38-7 EC-No.: 217-552-5	0.3 – 0.65	Acute Tox. 3 (Oral), H301 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Skin Sens. 1B, H317
citral	substance with national workplace exposure limit(s) (BE, ES, IE, PL, PT) CAS-No.: 5392-40-5 EC-No.: 226-394-6 EC Index-No.: 605-019-00-3 REACH-no: 01-2119462829-23	0.3 – 0.65	Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317
COUMARIN	CAS-No.: 91-64-5 EC-No.: 202-086-7 REACH-no: 01-2119943756-26	0.2 – 0.45	Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Skin Sens. 1, H317 Aquatic Chronic 2, H411
Heliotropine	CAS-No.: 120-57-0 EC-No.: 204-409-7 REACH-no: 01-2119983608-21	0.2 – 0.45	Skin Sens. 1B, H317
Davana oil	CAS-No.: 8016-03-3 EC-No.: 295-155-6	0.1 – 0.2	Skin Sens. 1, H317
benzaldehyde	substance with national workplace exposure limit(s) (BG, FI, HU, LT, LV, PL) CAS-No.: 100-52-7 EC-No.: 202-860-4 EC Index-No.: 605-012-00-5 REACH-no: 01-2119455540-44	0.1 – 0.15	Acute Tox. 4 (Oral), H302

Full text of H- and EUH-statements: see section 16

Măsuri de prim ajutor după inhalare: Remove person to fresh air and keep comfortable for breathing.

Măsuri de prim ajutor după contactul cu pielea: Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention.

Măsuri de prim ajutor după contactul cu ochii: Rinse eyes with water as a precaution.

Măsuri de prim ajutor după ingerare: Call a poison center or a doctor if you feel unwell.

Simptome/efecte după contactul cu pielea: May cause an allergic skin reaction.

Treat symptomatically.

5.1. Mijloace de stingere

Mijloace de stingere adecvate: Water spray. Dry powder. Foam. Carbon dioxide.

5.2. Pericole speciale generate de substanță sau amestec

Produse periculoase de descompunere în caz de incendiu: Toxic fumes may be released.

5.3. Recomandări pentru pompieri

Protecție în timpul intervenției: Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.

6.1. Precauții personale, echipament de protecție și proceduri de urgență

6.1.1. Pentru personalul care nu face parte din serviciile de urgență

Proceduri de urgență: Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.

6.1.2. Pentru personalul de intervenție

Echipament de protecție: Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".

6.2. Precauții pentru mediu

Avoid release to the environment.

6.3. Metode și material pentru izolare și curățare

Metode de curățare: Take up liquid spill into absorbent material.

Alte informații: Dispose of materials or solid residues at an authorized site.

6.4. Trimitere la alte secțiuni

For further information refer to section 13.

7.1. Precauții pentru manipulare în condiții de siguranță

Precauții pentru manipulare în condiții de siguranță: Ensure good ventilation of the work station. Wear personal protective equipment. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.

Măsuri de igienă: Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.

7.2. Condiții pentru depozitare în siguranță, inclusiv eventuale incompatibilități

Condiții de depozitare: Store in a well-ventilated place. Keep cool.

Temperatura de depozitare: 25 °C

Zona de depozitare: Store in a well-ventilated place. Store away from heat.

Reguli speciale privind ambalarea: Store in a closed container.

Materiale de ambalare: Do not store in corrodable metal.

7.3. Utilizare finală specifică

No additional information available

8.1.1. Valori-limită de expunere profesională și biologice naționale

Substanță	Țară / limite
citral (5392-40-5)	Belgium - Occupational Exposure Limits OEL TWA 32 mg/m³ (vapor and aerosol) 5 ppm (vapor and aerosol) OEL chemical category Skin Ireland - Occupational Exposure Limits OEL TWA 5 ppm OEL STEL 15 ppm (calculated) Poland - Occupational Exposure Limits NDS (OEL TWA) 27 mg/m³ NDSCh (OEL STEL) 54 mg/m³ Portugal - Occupational Exposure Limits OEL TWA 5 ppm (inhalable fraction; vapor) OEL chemical category Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen, skin - potential for cutaneous exposure Spain - Occupational Exposure Limits VLA-ED (OEL TWA) 5 ppm (inhalable fraction and vapor) OEL chemical category Sensitizer, skin - potential for cutaneous absorption USA - ACGIH - Occupational Exposure Limits ACGIH OEL TWA 5 ppm (inhalable fraction and vapor) ACGIH chemical category Not Classifiable as a Human Carcinogen, Skin - potential significant contribution to overall exposure by the cutaneous route, dermal sensitizer
benzaldehyde (100-52-7)	Bulgaria - Occupational Exposure Limits OEL TWA 5 mg/m³ Finland - Occupational Exposure Limits HTP (OEL TWA) 4.4 mg/m³ 1 ppm HTP (OEL C) 17.4 mg/m³ 4 ppm Hungary - Occupational Exposure Limits AK (OEL TWA) 5 mg/m³ CK (OEL STEL) 10 mg/m³ Latvia - Occupational Exposure Limits OEL TWA 5 mg/m³ Lithuania - Occupational Exposure Limits IPRV (OEL TWA) 5 mg/m³
benzaldehyde (100-52-7)	Poland - Occupational Exposure Limits NDS (OEL TWA) 10 mg/m³ NDSCh (OEL STEL) 40 mg/m³

8.1.2. Proceduri recomandate de monitorizare

No additional information available

8.1.3. Contaminanți din aer formați

No additional information available

8.1.4. DNEL și PNEC

No additional information available

8.1.5. Control banding

No additional information available

8.2.1. Controale inginerești corespunzătoare

Controale inginerești corespunzătoare: Ensure good ventilation of the work station.

8.2.2. Echipament individual de protecție

Simboluri pentru echipamentul individual de protecție:

8.2.2.1. Protecția ochilor și a feței

Protecția ochilor: Safety glasses

8.2.2.2. Protecția pielii

Protecția pielii și a corpului: Wear suitable protective clothing

Protecția mâinilor: Protective gloves

8.2.2.3. Protecția respirației

Protecția respirației: In case of insufficient ventilation, wear suitable respiratory equipment

8.2.2.4. Pericole termice

No additional information available

8.2.3. Controale ale expunerii mediului

Controale ale expunerii mediului: Avoid release to the environment.

Stare fizică	Liquid
Culoare	light yellow. amber. Conforms to standard.
Miros	characteristic.
Prag de miros	Not available
Punct de topire	Not applicable
Punct de îngheț	Not available
Punct de fierbere	Not available
Inflamabilitate	Not applicable
Limita inferioară de explozie	Not available
Limita superioară de explozie	Not available
Punct de aprindere	> 93 °C (closed cup) ASTM D7094
Temperatura de autoaprindere	Not available
Temperatura de descompunere	Not available
pH	Not available
Vâscozitate, cinematică	Not available
Solubilitate	Not available
Coeficient de partiție n-octanol/apă (Log Kow)	Not available
Presiune de vapori	Not available
Presiune de vapori la 50°C	Not available
Densitate	Not available
Densitate relativă	≈ 0.94
Densitate relativă a vaporilor la 20°C	Not available
Caracteristicile particulelor	Not applicable

9.2.1. Informații privind clasele de pericol fizic

No additional information available

9.2.2. Alte caracteristici de siguranță

No additional information available

10.1. Reactivitate

The product is non-reactive under normal conditions of use, storage and transport.

10.2. Stabilitate chimică

Stable under normal conditions.

10.3. Posibilitatea de reacții periculoase

No dangerous reactions known under normal conditions of use.

10.4. Condiții de evitat

None under recommended storage and handling conditions (see section 7).

10.5. Materiale incompatibile

No additional information available

10.6. Produse de descompunere periculoase

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

11.1. Informații privind clasele de pericol definite în Regulamentul (CE) nr. 1272/2008

Acute toxicity (oral) : Not classified

Acute toxicity (dermal) : Not classified

Acute toxicity (inhalation) : Not classified

Verdox (88-41-5)
LD50 oral rat	4600 mg/kg (Source: NLM_CIP)
LD50 oral	4600 mg/kg bodyweight
Eugenol (97-53-0)
LD50 oral rat	1930 mg/kg (Source: NZ_CCID)
LD50 oral	2500 mg/kg bodyweight
Cinnamic aldehyde (104-55-2)
LD50 oral rat	2220 mg/kg (Source: NLM_CIP)
LD50 oral	2200 mg/kg bodyweight
LD50 dermal rabbit	1260 mg/kg (Source: EPA_HPV)
LD50 dermal	1100 mg/kg bodyweight
2(3H)-Furanone, 5-heptyldihydro- (104-67-6)
LD50 oral rat	18500 mg/kg (Source: NLM_CIP)
LD50 dermal rat	> 2000 mg/kg (Source: ECHA)
Vanillin (121-33-5)
LD50 dermal rabbit	> 5010 mg/kg (Source: OECD_SIDS)
LD50 dermal	2600 mg/kg bodyweight
Allyl heptanoate (142-19-8)
LD50 oral rat	500 mg/kg (Source: NLM_CIP)
LD50 oral	218 mg/kg bodyweight
LD50 dermal rabbit	810 mg/kg (Source: ECHA_API)
LD50 dermal	810 mg/kg bodyweight
Citronellyl acetate (mixed Isomers) (150-84-5)
LD50 oral rat	6800 mg/kg (Source: NLM_CIP)
LD50 dermal rabbit	> 2000 mg/kg (Source: ECHA_API)
Orange Oil (8028-48-6)
LD50 dermal rabbit	> 5000 mg/kg (Source: ECHA_API)
Allyl cyclohexylpropionate (2705-87-5)
LD50 oral rat	585 mg/kg (Source: NLM_CIP)
LD50 oral	380 mg/kg bodyweight
LD50 dermal rabbit	1600 mg/kg (Source: ECHA_API)
LD50 dermal	1600 mg/kg bodyweight
Cinnamalva (1885-38-7)
LD50 oral	100 mg/kg bodyweight
LD50 dermal	1100 mg/kg bodyweight
LC50 Inhalation - Rat (Dust/Mist)	1.5 mg/l/4h
citral (5392-40-5)
LD50 oral rat	4960 mg/kg (Source: NLM_CIP)
LD50 dermal rabbit	2250 mg/kg (Source: NLM_CIP)
COUMARIN (91-64-5)
LD50 oral rat	> 5000 mg/kg (Source: JAPAN_GHS)
LD50 oral	290 mg/kg bodyweight
LD50 dermal rat	293 mg/kg (Source: ECHA_API)
Heliotropine (120-57-0)
LD50 oral rat	2700 mg/kg (Source: NLM_CIP)
LD50 oral	2700 mg/kg bodyweight
LD50 dermal rat	> 5000 mg/kg (Source: ECHA_API)
benzaldehyde (100-52-7)
LD50 oral rat	1292 mg/kg (Source: JAPAN_GHS)
LD50 dermal rabbit	> 1250 mg/kg (Source: JAPAN_GHS)

Skin corrosion/irritation : Not classified

Serious eye damage/irritation : Not classified

Respiratory or skin sensitisation : May cause an allergic skin reaction.

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Eugenol (97-53-0) — IARC group 3 - Not classifiable

COUMARIN (91-64-5) — IARC group 3 - Not classifiable

Reproductive toxicity : Not classified

STOT-single exposure : Not classified

STOT-repeated exposure : Not classified

Aspiration hazard : Not classified

Heliotropine (120-57-0) — Viscosity, kinematic Not applicable

11.2. Informații privind alte pericole

No additional information available

12.1. Toxicitate

Ecologie - general: Harmful to aquatic life with long lasting effects.

Periculos pentru mediul acvatic, pe termen scurt (acut): Not classified

Periculos pentru mediul acvatic, pe termen lung (cronic): Harmful to aquatic life with long lasting effects.

Eugenol (97-53-0)
LC50 - Fish [1]	13 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA)
2(3H)-Furanone, 5-heptyldihydro- (104-67-6)
LC50 - Fish [1]	569 mg/l 96 h
EC50 - Crustacea [1]	5.85 mg/l 48 h
EC50 - Other aquatic organisms [1]	5.94 mg/l 72 h
Vanillin (121-33-5)
LC50 - Fish [1]	53 – 61.3 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA)
LC50 - Fish [2]	88 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static] Source: EPA)
NOEC (acute)	10000 mg/kg (Exposure time: 42 Days - Species: Eisenia foetida [soil dry weight])
Citronellyl acetate (mixed Isomers) (150-84-5)
LC50 - Fish [1]	6.1 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA)
Allyl cyclohexylpropionate (2705-87-5)
LC50 - Fish [1]	0.13 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: ECHA)
citral (5392-40-5)
EC50 - Crustacea [1]	7 mg/l (Exposure time: 48 h - Species: Daphnia magna)
EC50 72h - Algae [1]	16 mg/l (Species: Desmodesmus subspicatus)
EC50 96h - Algae [1]	19 mg/l (Species: Desmodesmus subspicatus)
Heliotropine (120-57-0)
LC50 - Fish [1]	2.5 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [static] Source: ECHA)
benzaldehyde (100-52-7)
LC50 - Fish [1]	10.6 – 11.8 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through] Source: EPA)
LC50 - Fish [2]	12.69 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static] Source: IUCLID)

12.2. Persistență și degradabilitate

Baked Apple #EU40762F	Rapidly degradable
Verdox (88-41-5)	Rapidly degradable
Eugenol (97-53-0)	Rapidly degradable
Cinnamic aldehyde (104-55-2)	Rapidly degradable
2(3H)-Furanone, 5-heptyldihydro- (104-67-6)	Rapidly degradable
Vanillin (121-33-5)	Rapidly degradable
Allyl heptanoate (142-19-8)	Rapidly degradable
Citronellyl acetate (mixed Isomers) (150-84-5)	Rapidly degradable
Orange Oil (8028-48-6)	Rapidly degradable
Allyl cyclohexylpropionate (2705-87-5)	Rapidly degradable
Cinnamalva (1885-38-7)	Rapidly degradable
citral (5392-40-5)	Rapidly degradable
COUMARIN (91-64-5)	Rapidly degradable
Heliotropine (120-57-0)	Rapidly degradable
Davana oil (8016-03-3)	Rapidly degradable
benzaldehyde (100-52-7)	Rapidly degradable

12.3. Potențial de bioacumulare

Eugenol (97-53-0)	Partition coefficient n-octanol/water (Log Pow) 1.83 (at 30 °C (at pH 5.5)
Cinnamic aldehyde (104-55-2)	Partition coefficient n-octanol/water (Log Pow) 2.1065 (at 25 °C)
2(3H)-Furanone, 5-heptyldihydro- (104-67-6)	Partition coefficient n-octanol/water (Log Pow) 3.6 (at 25 °C)
Vanillin (121-33-5)	Partition coefficient n-octanol/water (Log Pow) 1.23 (at 22 °C)
Allyl heptanoate (142-19-8)	Partition coefficient n-octanol/water (Log Pow) 3.97 (at 20 °C (at pH 5.3)
Citronellyl acetate (mixed Isomers) (150-84-5)	Partition coefficient n-octanol/water (Log Pow) 4.9 (at 25 °C (at pH 4.23)
Allyl cyclohexylpropionate (2705-87-5)	Partition coefficient n-octanol/water (Log Pow) 4.28 (at 20 °C (at pH 5.3)
Cinnamalva (1885-38-7)	Partition coefficient n-octanol/water (Log Pow) 1.96
citral (5392-40-5)	Partition coefficient n-octanol/water (Log Pow) 2.76 (at 25 °C)
Heliotropine (120-57-0)	Partition coefficient n-octanol/water (Log Pow) 1.2 (at 35 °C)
benzaldehyde (100-52-7)	BCF - Fish [1] (no significant bioaccumulation) Partition coefficient n-octanol/water (Log Pow) 1.4 (at 25 °C)

12.4. Mobilitate în sol

No additional information available

12.5. Rezultatele evaluării PBT și vPvB

No additional information available

12.6. Proprietăți de perturbare endocrină

No additional information available

12.7. Alte efecte adverse

No additional information available

13.1. Metode de tratare a deșeurilor

Metode de tratare a deșeurilor: Dispose of contents/container in accordance with licensed collector’s sorting instructions.

Cod HP: