Baked Apple #EU40762F 10% in DPG · conform Regulamentului (CE) nr. 1907/2006 (REACH) cu modificarea Regulamentului (UE) 2020/878
Forma produsului: Mixture
Denumirea produsului: Baked Apple #EU40762F 10% in DPG
Cod produs: EU40762F_10%
Tip de produs: Perfumes, fragrances
1.2.1. Utilizări identificate relevante
Specificație pentru utilizare industrială/profesională: Industrial
For professional use only
Utilizarea substanței/amestecului: Perfumes, fragrances
Funcție sau categorie de utilizare: Odour agents
1.2.2. Utilizări contraindicate
No additional information available
No additional information available
No additional information available
Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Skin sensitisation, Category 1 H317
Textul complet al frazelor H și EUH: vezi secțiunea 16
Etichetare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Pictograme de pericol (CLP): GHS07
Cuvânt de avertizare (CLP): Warning
Conține: Eugenol; Cinnamic aldehyde
Fraze de pericol (CLP): H317 - May cause an allergic skin reaction.
Fraze de precauție (CLP):
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P321 - Specific treatment (see supplemental first aid instruction on this label).
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
Not applicable
| Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
|---|---|---|---|
| Eugenol | CAS-No.: 97-53-0 EC-No.: 202-589-1 REACH-no: 01-2119971802-33 |
0.19 – 0.38001 | Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Cinnamic aldehyde | CAS-No.: 104-55-2 EC-No.: 203-213-9 REACH-no: 01-2119935242-45 |
0.14 – 0.28501 | Acute Tox. 4 (Dermal), H312 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1A, H317 Aquatic Chronic 3, H412 |
| Allyl heptanoate | CAS-No.: 142-19-8 EC-No.: 205-527-1 REACH-no: 01-2119488961-23 |
0.07 – 0.13 | Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 |
| citral | substance with national workplace exposure limit(s) (BE, ES, IE, PL, PT) CAS-No.: 5392-40-5 EC-No.: 226-394-6 EC Index-No.: 605-019-00-3 REACH-no: 01-2119462829-23 |
0.03 – 0.065 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| benzaldehyde | substance with national workplace exposure limit(s) (BG, FI, HU, LT, LV, PL) CAS-No.: 100-52-7 EC-No.: 202-860-4 EC Index-No.: 605-012-00-5 REACH-no: 01-2119455540-44 |
0.01 – 0.015 | Acute Tox. 4 (Oral), H302 |
Full text of H- and EUH-statements: see section 16
First-aid measures general: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation: Allow affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
First-aid measures after eye contact: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
First-aid measures after ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
No additional information available
Suitable extinguishing media: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media: Do not use a heavy water stream.
No additional information available
Firefighting instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1. Pentru personalul care nu face parte din serviciile de urgență
Emergency procedures: Evacuate unnecessary personnel.
6.1.2. Pentru personalul de intervenție
Protective equipment: Equip cleanup crew with proper protection.
Emergency procedures: Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Methods for cleaning up: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Section 8. Exposure controls and personal protection.
Precautions for safe handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
Storage conditions: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Incompatible products: Strong bases. Strong acids.
Incompatible materials: Sources of ignition. Direct sunlight.
No additional information available
8.1.1. Valori limită naționale de expunere profesională și valori biologice limită
| Substanță | Țară | Limită |
|---|---|---|
| citral (5392-40-5) | Belgium - Occupational Exposure Limits | OEL TWA 32 mg/m³ (vapor and aerosol) |
| Belgium - Occupational Exposure Limits | OEL TWA 5 ppm (vapor and aerosol) | |
| Belgium - Occupational Exposure Limits | OEL chemical category Skin | |
| Ireland - Occupational Exposure Limits | OEL TWA [2] 5 ppm | |
| Ireland - Occupational Exposure Limits | OEL STEL 15 ppm (calculated) | |
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 27 mg/m³ | |
| Poland - Occupational Exposure Limits | NDSCh (OEL STEL) 54 mg/m³ | |
| Portugal - Occupational Exposure Limits | OEL TWA 5 ppm (inhalable fraction; vapor) | |
| Portugal - Occupational Exposure Limits | OEL chemical category Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen, skin - potential for cutaneous exposure | |
| Spain - Occupational Exposure Limits | VLA-ED (OEL TWA) [2] 5 ppm (inhalable fraction and vapor) | |
| Spain - Occupational Exposure Limits | OEL chemical category Sensitizer, skin - potential for cutaneous absorption | |
| USA - ACGIH - Occupational Exposure Limits | ACGIH OEL TWA [ppm] 5 ppm (inhalable fraction and vapor) | |
| USA - ACGIH - Occupational Exposure Limits | ACGIH chemical category Not Classifiable as a Human Carcinogen, Skin - potential significant contribution to overall exposure by the cutaneous route, dermal sensitizer | |
| benzaldehyde (100-52-7) | Bulgaria - Occupational Exposure Limits | OEL TWA 5 mg/m³ |
| Finland - Occupational Exposure Limits | HTP (OEL TWA) [1] 4.4 mg/m³ | |
| Finland - Occupational Exposure Limits | HTP (OEL TWA) [2] 1 ppm | |
| Finland - Occupational Exposure Limits | HTP (OEL C) 17.4 mg/m³ | |
| Finland - Occupational Exposure Limits | HTP (OEL C) [ppm]] 4 ppm | |
| Hungary - Occupational Exposure Limits | AK (OEL TWA) 5 mg/m³ | |
| Hungary - Occupational Exposure Limits | CK (OEL STEL) 10 mg/m³ | |
| Latvia - Occupational Exposure Limits | OEL TWA 5 mg/m³ | |
| Lithuania - Occupational Exposure Limits | IPRV (OEL TWA) 5 mg/m³ | |
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 10 mg/m³ | |
| Poland - Occupational Exposure Limits | NDSCh (OEL STEL) 40 mg/m³ |
8.1.2. Proceduri recomandate de monitorizare
No additional information available
8.1.3. Contaminanți din aer formați
No additional information available
8.1.4. DNEL și PNEC
No additional information available
8.1.5. Control banding
No additional information available
8.2.1. Controale tehnice adecvate
No additional information available
8.2.2. Echipament individual de protecție
Personal protective equipment:
Avoid all unnecessary exposure.
8.2.2.1. Protecția ochilor și a feței
Eye protection: Chemical goggles or safety glasses
8.2.2.2. Protecția pielii
Hand protection: Wear protective gloves.
8.2.2.3. Protecția respirației
Respiratory protection: Wear appropriate mask
8.2.2.4. Pericole termice
No additional information available
8.2.3. Controale ale expunerii asupra mediului
Other information: Do not eat, drink or smoke during use.
Physical state: Liquid
Colour: Standard.
Odour: characteristic.
Odour threshold: No data available
pH: No data available
Relative evaporation rate (butylacetate=1): No data available
Melting point: No data available
Freezing point: No data available
Boiling point: No data available
Flash point: > 93 °C
Auto-ignition temperature: No data available
Decomposition temperature: No data available
Flammability (solid, gas): Non flammable.
Vapour pressure: No data available
Relative vapour density at 20°C: No data available
Relative density: No data available
Solubility: No data available
Partition coefficient n-octanol/water (Log Pow): No data available
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Explosive properties: No data available
Oxidising properties: No data available
Explosive limits: No data available
No additional information available
No additional information available
Not established.
Not established.
Direct sunlight. Extremely high or low temperatures.
Strong acids. Strong bases.
fume. Carbon monoxide. Carbon dioxide.
Acute toxicity (oral): Not classified
Acute toxicity (dermal): Not classified
Acute toxicity (inhalation): Not classified
| Substanță | Rezultat |
|---|---|
| Eugenol (97-53-0) | LD50 oral rat 1930 mg/kg (Source: NZ_CCID) LD50 oral 2500 mg/kg bodyweight |
| Cinnamic aldehyde (104-55-2) | LD50 oral rat 2220 mg/kg (Source: NLM_CIP) LD50 oral 2200 mg/kg bodyweight |
| Cinnamic aldehyde (104-55-2) | LD50 dermal rabbit 1260 mg/kg (Source: EPA_HPV) LD50 dermal 1100 mg/kg bodyweight |
| Allyl heptanoate (142-19-8) | LD50 oral rat 500 mg/kg (Source: NLM_CIP) LD50 oral 218 mg/kg bodyweight LD50 dermal rabbit 810 mg/kg (Source: ECHA_API) LD50 dermal 810 mg/kg bodyweight |
| citral (5392-40-5) | LD50 oral rat 4960 mg/kg (Source: NLM_CIP) LD50 dermal rabbit 2250 mg/kg (Source: NLM_CIP) |
| benzaldehyde (100-52-7) | LD50 oral rat 1292 mg/kg (Source: JAPAN_GHS) LD50 dermal rabbit > 1250 mg/kg (Source: JAPAN_GHS) |
Skin corrosion/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Serious eye damage/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Respiratory or skin sensitisation: May cause an allergic skin reaction.
Additional information: Based on available data, the classification criteria are not met
Germ cell mutagenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Carcinogenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Eugenol (97-53-0)
IARC group 3 - Not classifiable
Reproductive toxicity: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-single exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-repeated exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
Aspiration hazard: Not classified
Additional information: Based on available data, the classification criteria are not met
Potential adverse human health effects and symptoms
Based on available data, the classification criteria are not met
Hazardous to the aquatic environment, short-term (acute): Not classified
Hazardous to the aquatic environment, long-term (chronic): Not classified
| Substanță | Date ecologice |
|---|---|
| Eugenol (97-53-0) | LC50 - Fish [1] 13 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) |
| citral (5392-40-5) | EC50 - Crustacea [1] 7 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 72h - Algae [1] 16 mg/l (Species: Desmodesmus subspicatus) EC50 96h - Algae [1] 19 mg/l (Species: Desmodesmus subspicatus) |
| benzaldehyde (100-52-7) | LC50 - Fish [1] 10.6 – 11.8 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through] Source: EPA) LC50 - Fish [2] 12.69 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static] Source: IUCLID) |
Baked Apple #EU40762F 10% in DPG
Persistence and degradability Not established.
Baked Apple #EU40762F 10% in DPG
Bioaccumulative potential Not established.
Eugenol (97-53-0)
Partition coefficient n-octanol/water (Log Pow) 1.83 (at 30 °C (at pH 5.5)
Cinnamic aldehyde (104-55-2)
Partition coefficient n-octanol/water (Log Pow) 2.1065 (at 25 °C)
Allyl heptanoate (142-19-8)
Partition coefficient n-octanol/water (Log Pow) 3.97 (at 20 °C (at pH 5.3)
citral (5392-40-5)
Partition coefficient n-octanol/water (Log Pow) 2.76 (at 25 °C)
benzaldehyde (100-52-7)
BCF - Fish [1] (no significant bioaccumulation)
Partition coefficient n-octanol/water (Log Pow) 1.4 (at 25 °C)
No additional information available
No additional information available
Additional information: Avoid release to the environment.
Product/Packaging disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials: Avoid release to the environment.
HP Code: HP3 - “Flammable:”
– flammable liquid waste: liquid waste having a flash point below 60 °C or waste gas oil, diesel and light heating oils having a flash point > 55 °C and ≤ 75 °C;
– flammable pyrophoric liquid and solid waste: solid or liquid waste which, even in small quantities, is liable to ignite within five minutes after coming into contact with air;
– flammable solid waste: solid waste which is readily combustible or may cause or contribute to fire through friction;
– flammable gaseous waste: gaseous waste which is flammable in air at 20 °C and a standard pressure of 101.3 kPa;
– water reactive waste: waste which, in contact with water, emits flammable gases in dangerous quantities;
– other flammable waste: flammable aerosols, flammable self-heating waste, flammable organic peroxides and flammable self-reactive waste.
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|
| Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.1. UN number: Not applicable | ||||
| 14.2. UN proper shipping name: Not applicable | ||||
| 14.3. Transport hazard class(es): Not applicable | ||||
| 14.4. Packing group: Not applicable | ||||
| 14.5. Environmental hazards: Not applicable | ||||
No supplementary information available
14.6. Special precautions for user
Overland transport
Not applicable
Transport by sea
Not applicable
Air transport
Not applicable
Inland waterway transport
Not applicable
Rail transport
Not applicable
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
15.1.1. EU-Regulations
REACH Annex XVII (Restriction List)
EU restriction list (REACH Annex XVII)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(b) | Baked Apple #EU40762F 10% in DPG ; Eugenol ; Cinnamic aldehyde ; Allyl heptanoate ; citral ; benzaldehyde | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | Cinnamic aldehyde ; Allyl heptanoate | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 |
REACH Annex XIV (Authorisation List)
Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC)
Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent)
Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants)
Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009)
Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Explosives Precursors Regulation (2019/1148)
Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004)
Contains substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
15.1.2. National regulations
France
| Code | Description |
|---|---|
| RG 84 | Conditions caused by liquid organic solvents for professional use: saturated or unsaturated aliphatic or cyclic liquid hydrocarbons and mixtures thereof; liquid halogenated hydrocarbons; nitrated derivatives of aliphatic hydrocarbons; alcohols; glycols, glycol ethers; ketones; aldehydes; aliphatic and cyclic ethers, including tetrahydrofuran; esters; dimethylformamide and dimethylacetamine; acetonitrile and propionitrile; pyridine; dimethylsulfone and dimethylsulfoxide |
Germany
Water hazard class (WGK): WGK 1, Slightly hazardous to water (Classification according to AwSV, Annex 1).
Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids.
Joint storage table:
Joint storage not permitted for : LGK 1, LGK 6.2, LGK 7.
Joint storage with restrictions permitted for : LGK 4.1A, LGK 4.3, LGK 5.1C.
Joint storage permitted for : LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13.
List of sensitizing substances (TRGS 907): Contains sensitizing substances according TRGS 907.
Hazardous Incident Ordinance (12. BImSchV): Is not subject of the Hazardous Incident Ordinance (12. BImSchV)
Netherlands
ABM category: A(4) - low hazard for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen: None of the components are listed
SZW-lijst van mutagene stoffen: None of the components are listed
SZW-lijst van reprotoxische stoffen – Borstvoeding: None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid: None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling: None of the components are listed
Denmark
Classification remarks: Emergency management guidelines for the storage of flammable liquids must be followed
Danish National Regulations: Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct contact with the product
Switzerland
Storage class (LK): LK 10/12 - Liquids
No chemical safety assessment has been carried out
Data sources: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information: None.
Full text of H- and EUH-statements:
Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3
Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard, Category 1
Aquatic Chronic 3 Hazardous to the aquatic environment – Chronic Hazard, Category 3
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
Skin Irrit. 2 Skin corrosion/irritation, Category 2
Skin Sens. 1 Skin sensitisation, Category 1
Skin Sens. 1A Skin sensitisation, category 1A
Skin Sens. 1B Skin sensitisation, category 1B
The classification complies with : ATP 12
Safety Data Sheet (SDS), EU
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.