No additional information available
FRENCH COLOR & FRAGRANCE International GmbH
Mittlerer Weg 35
DE– 79424 Auggen
Germany
T 49-7631-931-8900
SDS@frenchcolor.com - www.frenchcolor.com
Emergency number: 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Adverse physicochemical, human health and environmental effects
Toxic to aquatic life with long lasting effects. Causes skin irritation. Causes serious eye irritation. Harmful to aquatic life with long lasting effects. May cause an allergic skin reaction.
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP): GHS07
Signal word (CLP): Warning
Contains: Orange oil ; Eugenol; Cinnamic aldehyde; trans-Anethole; Linalool; Geranyl acetate; Citral; Linalyl acetate; beta-Caryophyllene; Iso E Super; COUMARIN; Calamus oil; 1,2-Cyclopentanedione, 3-methyl-; Anise oil (Spanish); Ginger oil; Heliotropine
Hazard statements (CLP):
Precautionary statements (CLP):
Extra phrases: For professional users only.
Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Not applicable
| Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
|---|---|---|---|
| Orange oil | CAS-No.: 8008-57-9 EC-No.: 232-433-8 REACH-no: 01-2119493353-35 | 3.8 – 7.5 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Eugenol | CAS-No.: 97-53-0 EC-No.: 202-589-1 REACH-no: 01-2119971802-33 | 2.325 – 4.625 | Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Cinnamic aldehyde | CAS-No.: 104-55-2 EC-No.: 203-213-9 REACH-no: 01-2119935242-45 | 2.005 – 4.03125 | Acute Tox. 4 (Dermal), H312 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 Aquatic Chronic 3, H412 |
| trans-Anethole | CAS-No.: 4180-23-8 EC-No.: 224-052-0 | 1.8 – 3.5 | Skin Sens. 1B, H317 |
| Benzaldehyde | substance with national workplace exposure limit(s) (BG, FI, HU, LT, LV, PL) CAS-No.: 100-52-7 EC-No.: 202-860-4 EC Index-No.: 605-012-00-5 REACH-no: 01-2119455540-44 | 1.6 – 3.25 | Acute Tox. 4 (Oral), H302 |
| Linalool | CAS-No.: 78-70-6 EC-No.: 201-134-4 EC Index-No.: 603-235-00-2 REACH-no: 01-2119474016-42 | 1.5 – 3.0035 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Geranyl acetate | CAS-No.: 105-87-3 EC-No.: 203-341-5 REACH-no: 01-2119973480-35 | 1.1 – 2.25 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 3, H412 |
| Aldehyde C-10 | CAS-No.: 112-31-2 EC-No.: 203-957-4 | 1 – 2 | Eye Irrit. 2, H319 Aquatic Chronic 3, H412 |
| Terpineol | CAS-No.: 8000-41-7 EC-No.: 232-268-1 | 0.8 – 1.5 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 |
| Linalyl acetate | CAS-No.: 115-95-7 EC-No.: 204-116-4 REACH-no: 01-2119454789-19 | 0.5 – 1.0025 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Citral | substance with national workplace exposure limit(s) (BE, ES, IE, PL, PT) CAS-No.: 5392-40-5 EC-No.: 226-394-6 EC Index-No.: 605-019-00-3 REACH-no: 01-2119462829-23 | 0.5 – 1 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Oenanthic ether (Ethyl heptanoate) | CAS-No.: 106-30-9 EC-No.: 203-382-9 | 0.5 – 1 | Flam. Liq. 3, H226 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 |
| beta-Caryophyllene | CAS-No.: 87-44-5 EC-No.: 201-746-1 REACH-no: 01-2120745237-53 | 0.355 – 0.6875 | Skin Sens. 1B, H317 Asp. Tox. 1, H304 |
| Camphene | CAS-No.: 79-92-5 EC-No.: 201-234-8 | 0.3 – 0.5 | Flam. Sol. 2, H228 Eye Irrit. 2, H319 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Iso E Super | CAS-No.: 54464-57-2 EC-No.: 259-174-3 REACH-no: 01-2119489989-04 | 0.1 – 0.2 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 1, H410 |
| COUMARIN | CAS-No.: 91-64-5 EC-No.: 202-086-7 REACH-no: 01-2119943756-26 | 0.10001 – 0.150025 | Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Skin Sens. 1, H317 Aquatic Chronic 2, H411 |
| Ethyl benzoate | substance with national workplace exposure limit(s) (RO) CAS-No.: 93-89-0 EC-No.: 202-284-3 | 0.1 – 0.1 | Not classified |
| Ethyl acetate | substance with national workplace exposure limit(s) (AT, BE, BG, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GI, GR, HR, HU, IE, IT, LT, LU, LV, MT, NL, PL, PT, RO, SE, SI, SK, NO, CH); substance with a Community workplace exposure limit CAS-No.: 141-78-6 EC-No.: 205-500-4 EC Index-No.: 607-022-00-5 REACH-no: 01-2119475103-46 | 0.1 – 0.1 | Flam. Liq. 1, H224 Eye Irrit. 2, H319 STOT SE 3, H336 |
| Calamus oil (Acorus calamus L.) | CAS-No.: 8015-79-0 EC-No.: 283-869-0 | 0.1 – 0.1 | Acute Tox. 4 (Oral), H302 Skin Sens. 1, H317 |
| 1,2-Cyclopentanedione, 3-methyl- | CAS-No.: 765-70-8 EC-No.: 212-154-8 | 0.1 – 0.1 | Acute Tox. 4 (Oral), H302 Skin Sens. 1, H317 |
| Butyric acid | substance with national workplace exposure limit(s) (BG, LT, LV, RO) CAS-No.: 107-92-6 EC-No.: 203-532-3 EC Index-No.: 607-135-00-X | 0.1 – 0.1 | Skin Corr. 1B, H314 |
| Anise oil (Spanish) | CAS-No.: 8007-70-3 EC-No.: 616-914-3 | 0.1 – 0.1 | Skin Sens. 1, H317 Muta. 2, H341 Carc. 2, H351 Aquatic Chronic 3, H412 |
| zingiber officinale (ginger) root oil | CAS-No.: 8007-08-7 EC-No.: 283-634-2 | 0.1 – 0.1 | Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| Heliotropine | CAS-No.: 120-57-0 EC-No.: 204-409-7 REACH-no: 01-2119983608-21 | 0.1 – 0.1 | Skin Sens. 1B, H317 |
| Carbitol | substance with national workplace exposure limit(s) (AT, DE, EE, SE, SI, CH) CAS-No.: 111-90-0 EC-No.: 203-919-7 REACH-no: 01-2119475105-42 | 0.07233 – 0.07233 | Not classified |
| .beta.-Pinene | substance with national workplace exposure limit(s) (BE, EE, ES, LT, PT, SE, NO) CAS-No.: 127-91-3 EC-No.: 204-872-5 | 0.01 – 0.0275 | Flam. Liq. 3, H226 |
| .alpha.-Pinene | substance with national workplace exposure limit(s) (BE, EE, ES, LT, PT, SE, NO) CAS-No.: 80-56-8 EC-No.: 201-291-9 | 0.01 – 0.0275 | Flam. Liq. 3, H226 |
| d-Limonene | substance with national workplace exposure limit(s) (DE, ES, FI, SI, NO, CH) CAS-No.: 5989-27-5 EC-No.: 205-341-0 EC Index-No.: 601-096-00-2 REACH-no: 01-2119493353-35 | 0.005 – 0.0125 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 |
| p-Cymene | substance with national workplace exposure limit(s) (DK, EE, LT, LV, SE) CAS-No.: 99-87-6 EC-No.: 202-796-7 EC Index-No.: 601-094-00-1 | 0.001 – 0.005 | Flam. Liq. 3, H226 Acute Tox. 3 (Inhalation), H331 Acute Tox. 3 (Inhalation:dust,mist), H331 Repr. 2, H361 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
Full text of H- and EUH-statements: see section 16
First-aid measures after inhalation: Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact: Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention.
First-aid measures after eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion: Call a poison center or a doctor if you feel unwell.
Symptoms/effects after skin contact: Irritation. May cause an allergic skin reaction.
Symptoms/effects after eye contact: Eye irritation.
Treat symptomatically.
Suitable extinguishing media: Water spray. Dry powder. Foam. Carbon dioxide.
Hazardous decomposition products in case of fire: Toxic fumes may be released.
Protection during firefighting: Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.
For non-emergency personnel: Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.
For emergency responders: Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".
Avoid release to the environment.
For containment: Collect spillage.
Methods for cleaning up: Take up liquid spill into absorbent material.
Other information: Dispose of materials or solid residues at an authorized site.
For further information refer to section 13.
Precautions for safe handling: Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. Avoid breathing dust/fume/gas/mist/vapours/spray.
Hygiene measures: Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace.
Storage conditions: Store in a well-ventilated place. Keep cool.
Storage temperature: 25 °C
Storage area: Store in a well-ventilated place. Store away from heat.
Special rules on packaging: Store in a closed container.
Packaging materials: Do not store in corrodable metal.
No additional information available
8.1.1 National occupational exposure and biological limit values
| Substance | Occupational Exposure Limits |
|---|---|
| Benzaldehyde (100-52-7) | |
| Bulgaria | OEL TWA 5 mg/m³ |
| Finland | HTP (OEL TWA) [1] 4.4 mg/m³ HTP (OEL TWA) [2] 1 ppm HTP (OEL C) 17.4 mg/m³ HTP (OEL C) [ppm]] 4 ppm |
| Hungary | AK (OEL TWA) 5 mg/m³ CK (OEL STEL) 10 mg/m³ |
| Latvia | OEL TWA 5 mg/m³ |
| Lithuania | IPRV (OEL TWA) 5 mg/m³ |
| Poland | NDS (OEL TWA) 10 mg/m³ NDSCh (OEL STEL) 40 mg/m³ |
| Citral (5392-40-5) | |
| Belgium | OEL TWA 32 mg/m³ (vapor and aerosol) OEL TWA [ppm] 5 ppm (vapor and aerosol) OEL chemical category Skin |
| Ireland | OEL TWA [2] 5 ppm OEL STEL [ppm] 15 ppm (calculated) |
| Poland | NDS (OEL TWA) 27 mg/m³ NDSCh (OEL STEL) 54 mg/m³ |
8.1.2. Proceduri recomandate de monitorizare: No additional information available
8.1.3. Contaminanți ai aerului formați: No additional information available
8.1.4. DNEL and PNEC: No additional information available
8.1.5. Control banding: No additional information available
8.2.1. Controale tehnice corespunzătoare: Ensure good ventilation of the work station.
8.2.2. Echipament individual de protecție
8.2.2.1. Protecția ochilor și feței: Safety glasses
8.2.2.2. Protecția pielii:
8.2.2.3. Protecția respiratorie: In case of insufficient ventilation, wear suitable respiratory equipment
8.2.2.4. Pericole termice: No additional information available
8.2.3. Controale ale expunerii mediului: Avoid release to the environment.
| Physical state | Liquid |
| Colour | light yellow. amber. Conforms to standard. |
| Odour | characteristic. |
| Odour threshold | Not available |
| Melting point | Not applicable |
| Freezing point | Not available |
| Boiling point | Not available |
| Flammability | Not applicable |
| Explosive limits | Not available |
| Lower explosion limit | Not available |
| Upper explosion limit | Not available |
| Flash point | 70 °C (closed cup) ASTM D7094 |
| Auto-ignition temperature | Not available |
| Decomposition temperature | Not available |
| pH | Not available |
| Viscosity, kinematic | Not available |
| Solubility | Not available |
| Partition coefficient n-octanol/water (Log Kow) | Not available |
| Vapour pressure | Not available |
| Vapour pressure at 50°C | Not available |
| Density | Not available |
| Relative density | ≈ 0.934 |
| Relative vapour density at 20°C | Not available |
| Particle characteristics | Not applicable |
9.2.1. Informații privind clasele de pericol fizic: No additional information available
9.2.2. Alte caracteristici de siguranță: No additional information available
10.1. Reactivity: The product is non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability: Stable under normal conditions.
10.3. Posibility of hazardous reactions: No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid: None under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials: No additional information available
10.6. Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Acute toxicity (oral): Not classified
Acute toxicity (dermal): Not classified
Acute toxicity (inhalation): Not classified
Skin corrosion/irritation: Causes skin irritation.
Serious eye damage/irritation: Causes serious eye irritation.
Respiratory or skin sensitisation: May cause an allergic skin reaction.
Germ cell mutagenicity: Not classified
Carcinogenicity: Not classified
Reproductive toxicity: Not classified
STOT-single exposure: Not classified
STOT-repeated exposure: Not classified
Aspiration hazard: Not classified
Orange oil (8008-57-9) Hydrocarbon Yes
Heliotropine (120-57-0) Viscosity, kinematic Not applicable
No additional information available
| Substanță | Date toxicologice |
|---|---|
| Orange oil (8008-57-9) | LD50 oral rat 4400 mg/kg (Source: NZ_CCID) LD50 dermal rabbit > 5000 mg/kg (Source: CHEMVIEW) |
| Eugenol (97-53-0) | LD50 oral rat 1930 mg/kg (Source: NZ_CCID) LD50 oral 2500 mg/kg bodyweight |
| Cinnamic aldehyde (104-55-2) | LD50 oral rat 2220 mg/kg (Source: NLM_CIP) LD50 oral 2200 mg/kg bodyweight LD50 dermal rabbit 1260 mg/kg (Source: EPA_HPV) LD50 dermal 1100 mg/kg bodyweight |
| trans-Anethole (4180-23-8) | LD50 oral rat 2090 mg/kg (Source: NLM_CIP) LD50 dermal rabbit > 4900 mg/kg (Source: ECHA_API) LC50 Inhalation - Rat > 5.1 mg/l/4h |
| Benzaldehyde (100-52-7) | LD50 oral rat 1292 mg/kg (Source: JAPAN_GHS) LD50 dermal rabbit > 1250 mg/kg (Source: JAPAN_GHS) |
| Linalool (78-70-6) | LD50 oral 2790 mg/kg bodyweight |
| Geranyl acetate (105-87-3) | LD50 oral rat 6330 mg/kg (Source: NLM_CIP) |
| Aldehyde C-10 (112-31-2) | LD50 oral rat 3730 mg/kg (Source: NLM_HSDB) LD50 dermal rabbit 5040 mg/kg (Source: NLM_HSDB) |
| Terpineol (8000-41-7) | LD50 oral rat 2900 mg/kg (Source: IUCLID) LD50 oral 4300 mg/kg bodyweight LD50 dermal rabbit > 3000 mg/kg (Source: IUCLID) |
| Citral (5392-40-5) | LD50 oral rat 4960 mg/kg (Source: NLM_CIP) LD50 dermal rabbit 2250 mg/kg (Source: NLM_CIP) |
| Oenanthic ether (Ethyl heptanoate) (106-30-9) | LD50 oral rat > 34640 mg/kg (Source: NLM_CIP) |
| Linalyl acetate (115-95-7) | LD50 oral rat 14550 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: EPA_HPV) |
| Camphene (79-92-5) | LD50 oral rat 5600 mg/kg LD50 dermal rabbit > 5000 mg/kg |
| d-Limonene (5989-27-5) | LD50 oral rat 4400 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 5 g/kg (Source: CHEMVIEW) |
| .beta.-Pinene (127-91-3) | LD50 oral rat > 5000 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: CHEMVIEW) |
| .alpha.-Pinene (80-56-8) | LD50 oral rat 3700 mg/kg (Source: NLM_CIP) LD50 oral 500 mg/kg bodyweight LD50 dermal rat > 5000 mg/kg (Source: CHEMVIEW) |
| COUMARIN (91-64-5) | LD50 oral rat > 5000 mg/kg (Source: JAPAN_GHS) LD50 oral 290 mg/kg bodyweight LD50 dermal rat 293 mg/kg (Source: ECHA_API) |
| Ethyl benzoate (93-89-0) | LD50 oral rat 2100 mg/kg (Source: NLM_CIP) LD50 oral 2500 mg/kg bodyweight |
| Ethyl acetate (141-78-6) | LD50 oral rat 5620 mg/kg (Source: NLM_CIP) LD50 dermal rabbit > 18000 mg/kg (Source: JAPAN_GHS) LC50 Inhalation - Rat [ppm] 4000 ppm/4h |
| p-Cymene (99-87-6) | LD50 oral rat 4750 mg/kg (Source: NLM_CIP) LD50 oral 4750 mg/kg bodyweight LD50 dermal rabbit > 5000 mg/kg (Source: CHEMVIEW) LC50 Inhalation - Rat > 9.7 mg/l (Exposure time: 5 h Source: EU_CLH) LC50 Inhalation - Rat (Vapours) 9.7 mg/l/4h |
| Calamus oil (Acorus calamus L.) (8015-79-0) | LD50 oral rat 777 mg/kg (Source: NLM_CIP) LD50 oral 780 mg/kg bodyweight |
| 1,2-Cyclopentanedione, 3-methyl- (765-70-8) | LD50 oral 1067 mg/kg bodyweight |
| Butyric acid (107-92-6) | LD50 oral rat 2 g/kg (Source: NLM_CIP) LD50 oral 1630 mg/kg bodyweight LD50 dermal rabbit 530 mg/kg (Source: NLM_HSDB) |
| Anise oil (Spanish) (8007-70-3) | LD50 oral rat 2250 mg/kg (Source: NLM_CIP) LD50 oral 2200 mg/kg bodyweight |
| Carbitol (111-90-0) | LD50 oral rat 10502 mg/kg (Source: OECD_SIDS) LD50 dermal rabbit 9143 mg/kg (Source: OECD_SIDS) LC50 Inhalation - Rat > 5240 mg/m³ (Exposure time: 4 h Source: NLM_CIP) |
| zingiber officinale (ginger) root oil (8007-08-7) | LD50 oral rat > 5 g/kg (Source: NLM_CIP) |
| Heliotropine (120-57-0) | LD50 oral rat 2700 mg/kg (Source: NLM_CIP) LD50 oral 2700 mg/kg bodyweight LD50 dermal rat > 5000 mg/kg (Source: ECHA_API) |
Ecology - general: Toxic to aquatic life with long lasting effects. Harmful to aquatic life with long lasting effects.
Hazardous to the aquatic environment, short-term (acute): Not classified
Hazardous to the aquatic environment, long-term (chronic): Harmful to aquatic life with long lasting effects.
| Eugenol (97-53-0) | |
| LC50 - Fish [1] | 13 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) |
| Benzaldehyde (100-52-7) | |
| LC50 - Fish [1] | 10.6 – 11.8 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through] Source: EPA) |
| LC50 - Fish [2] | 12.69 mg/l (Exposure time: 96 h - Species |