GINGER COOKIE #EU24263F

Fișă cu Date de Securitate conform Regulamentului REACH (CE) 1907/2006 modificat prin Regulamentul (UE) 2020/878

Data emiterii:

7/29/2024

Versiune:

1.0

Limba:

EN (English)

Document:

EU24263F-SDS-EU-GINGER-COOKIE-EU24263F-English1.0.pdf

SECȚIUNEA 1: Identificarea substanței/amestecului și a societății/întreprinderii

1.1. Identificatorul produsului

Forma produsului:

Amestec

Denumire comercială:

GINGER COOKIE #EU24263F

UFI:

AX8U-K9NY-800F-0T5N

Cod produs:

EU24263F

Tip de produs:

Parfumuri, arome

Grup de produs:

Produs comercial

1.2. Utilizări identificate relevante ale substanței sau amestecului și utilizări contraindicate

Categorie principală de utilizare:

Utilizare profesională, utilizare industrială

Specificația de utilizare industrială/profesională:

Industrial

Utilizare numai pentru uz profesional

Utilizarea substanței/amestecului:

Parfumuri, arome

Categoria funcției sau utilizării:

Agenți de miros

1.2.2. Utilizări contraindicate

No additional information available

1.3. Detalii privind furnizorul fișei cu date de securitate

FRENCH COLOR & FRAGRANCE International GmbH

Mittlerer Weg 35, DE 79424 Auggen, Germany

49-7631-931-8900

E-mail / Web:

SDS@frenchcolor.com, www.frenchcolor.com

1.4. Număr de telefon pentru urgențe

Emergency number: 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086

SECȚIUNEA 2: Identificarea pericolelor

2.1. Clasificarea substanței sau amestecului

Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP]

Acute toxicity (oral), Category 4 — H302
Skin corrosion/irritation, Category 2 — H315
Serious eye damage/eye irritation, Category 2 — H319
Skin sensitisation, Category 1 — H317
Hazardous to the aquatic environment – Acute Hazard, Category 1 — H400
Hazardous to the aquatic environment – Chronic Hazard, Category 2 — H411

Textul complet al frazelor H și EUH: vezi secțiunea 16.

Efecte adverse fizico-chimice, asupra sănătății umane și asupra mediului: Dăunător în caz de înghițire. Provoacă iritarea pielii. Provoacă iritarea gravă a ochilor. Foarte toxic pentru mediul acvatic. Toxic pentru mediul acvatic cu efecte pe termen lung. Poate provoca o reacție alergică a pielii.

2.2. Elemente de etichetare

Etichetare conform Regulamentului (CE) Nr. 1272/2008 [CLP]

Pictograme de pericol (CLP): GHS07 GHS09

Cuvânt de avertizare (CLP): Warning

Conține: benzyl benzoate; Cinnamic aldehyde; Eugenol; COUMARIN; Citrus medica limonum (Lemon) peel oil ; beta-Caryophyllene; Phenylethyl alcohol; Acetyl Propionyl; Heliotropine; 1,2-Cyclopentanedione, 3-methyl-; Cinnamalva; Amyl cinnamic aldehyde; Methyl cinnamate

Fraze de pericol (CLP):

H302 - Harmful if swallowed.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H410 - Very toxic to aquatic life with long lasting effects.

Fraze de precauție (CLP):

P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash hands, forearms and face thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.

Fraze suplimentare: For professional users only.

2.3. Alte pericole

Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

SECȚIUNEA 3: Compoziție/informații privind componenții

3.1. Substanțe

Nu se aplică

3.2. Amestecuri

Nume	Identificator produs	%	Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
benzyl benzoate	CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33	35.5 – 71	Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411
Cinnamic aldehyde	CAS-No.: 104-55-2 EC-No.: 203-213-9 REACH-no: 01-2119935242-45	5.025 – 10.125	Acute Tox. 4 (Dermal), H312 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1A, H317 Aquatic Chronic 3, H412
Eugenol	CAS-No.: 97-53-0 EC-No.: 202-589-1 REACH-no: 01-2119971802-33	2.625 – 5.5	Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Skin Sens. 1B, H317
Ethyl vanillin	CAS-No.: 121-32-4 EC-No.: 204-464-7 REACH-no: 01-211958961-24	1 – 2	Eye Irrit. 2, H319
COUMARIN	CAS-No.: 91-64-5 EC-No.: 202-086-7 REACH-no: 01-2119943756-26	0.80005 – 1.5001	Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Skin Sens. 1, H317 Aquatic Chronic 2, H411
Vanillin	CAS-No.: 121-33-5 EC-No.: 204-465-2 REACH-no: 01-2119516040-60	0.7 – 1.3	Eye Irrit. 2, H319
Citrus medica limonum (Lemon) peel oil	CAS-No.: 8008-56-8 EC-No.: 284-515-8	0.5 – 1	Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Repr. 2, H361 Aquatic Acute 1, H400 Aquatic Chronic 2, H411
Anisic aldehyde	CAS-No.: 123-11-5 EC-No.: 204-602-6 REACH-no: 01-2119977101-43	0.5 – 1	Aquatic Chronic 3, H412
Phenylethyl alcohol	CAS-No.: 60-12-8 EC-No.: 200-456-2 REACH-no: 01-2119963921-31	0.5 – 1	Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319
beta-Caryophyllene	CAS-No.: 87-44-5 EC-No.: 201-746-1 REACH-no: 01-2120745237-53	0.275 – 0.75	Asp. Tox. 1, H304 Skin Sens. 1B, H317
Acetyl Propionyl substance with national workplace exposure limit(s) (DE, SI, CH)	CAS-No.: 600-14-6 EC-No.: 209-984-8	0.3 – 0.5	Flam. Liq. 2, H225 Eye Dam. 1, H318 Skin Sens. 1B, H317 STOT RE 2, H373
Heliotropine	CAS-No.: 120-57-0 EC-No.: 204-409-7 REACH-no: 01-2119983608-21	0.3 – 0.5	Skin Sens. 1B, H317
1,2-Cyclopentanedione, 3-methyl-	CAS-No.: 765-70-8 EC-No.: 212-154-8	0.3 – 0.5	Acute Tox. 4 (Oral), H302 Skin Sens. 1, H317
Cinnamalva	CAS-No.: 1885-38-7 EC-No.: 217-552-5	0.3 – 0.5	Acute Tox. 3 (Oral), H301 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Skin Sens. 1B, H317
Amyl cinnamic aldehyde	CAS-No.: 122-40-7 EC-No.: 204-541-5	0.3 – 0.5	Skin Sens. 1B, H317 Aquatic Chronic 2, H411
Methyl cinnamate	CAS-No.: 103-26-4 EC-No.: 203-093-8 REACH-no: 01-2119979458-16	0.1 – 0.25	Skin Sens. 1B, H317
benzaldehyde substance with national workplace exposure limit(s) (BG, FI, HU, LT, LV, PL)	CAS-No.: 100-52-7 EC-No.: 202-860-4 EC Index-No.: 605-012-00-5 REACH-no: 01-2119455540-44	0.1 – 0.25	Acute Tox. 4 (Oral), H302
(R)-p-mentha-1,8-diene; d-limonene substance with national workplace exposure limit(s) (DE, ES, FI, SI, NO, CH)	CAS-No.: 5989-27-5 EC-No.: 205-341-0 EC Index-No.: 601-096-00-2 REACH-no: 01-2119493353-35	< 0.01	Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 3, H412
.alpha.-Pinene substance with national workplace exposure limit(s) (BE, EE, ES, LT, PT, SE, NO)	CAS-No.: 80-56-8 EC-No.: 201-291-9	< 0.01	Flam. Liq. 3, H226 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410
.beta.-Pinene substance with national workplace exposure limit(s) (BE, EE, ES, LT, PT, SE, NO)	CAS-No.: 127-91-3 EC-No.: 204-872-5	< 0.01	Flam. Liq. 3, H226

SECȚIUNEA 4: Măsuri de prim ajutor

4.1. Descrierea măsurilor de prim ajutor

Măsuri generale:

Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Call a poison center or a doctor if you feel unwell.

După inhalare:

Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest.

După contactul cu pielea:

If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see Get medical advice/attention. on this label). If skin irritation occurs: Get medical advice/attention. Wash with plenty of water/…. Wash contaminated clothing before reuse. Get medical advice/attention. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention.

După contactul cu ochii:

If eye irritation persists: Get medical advice/attention. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

După înghițire:

Do NOT induce vomiting. Obtain emergency medical attention. Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. Call a poison center or a doctor if you feel unwell.

4.2. Cele mai importante simptome și efecte, atât acute, cât și întârziate

Simptome/efecte:

Not expected to present a significant hazard under anticipated conditions of normal use.

După contactul cu pielea:

Iritație. Poate provoca o reacție alergică a pielii.

După contactul cu ochii:

Iritarea ochilor.

4.3. Indicații privind orice asistență medicală imediată și tratamente speciale necesare

Tratați simptomatic.

SECȚIUNEA 5: Măsuri de combatere a incendiilor

5.1. Mijloace de stingere a incendiilor

Mijloace adecvate:

Sand. Water spray. Dry powder. Foam. Carbon dioxide.

Mijloace nepotrivite:

Do not use a heavy water stream.

5.2. Pericole speciale cauzate de substanță sau amestec

Produse periculoase de descompunere în caz de incendiu:

Toxic fumes may be released.

5.3. Recomandări pentru pompieri

Instrucțiuni de stingere a incendiilor:

Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.

Protecție în timpul stingerii:

Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.

SECȚIUNEA 6: Măsuri în caz de eliberare accidentală

6.1. Precauții personale, echipament de protecție și proceduri de urgență

Pentru personalul care nu intervine în situații de urgență:

Ventilate spillage area. Evacuate unnecessary personnel. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.

Pentru echipele de intervenție:

Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection". Emergency procedures: Ventilate area.

6.2. Precauții pentru mediu

Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Metode și materiale pentru izolare și curățare

Pentru izolare:

Collect spillage.

Metode de curățare:

Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.

Alte informații:

Dispose of materials or solid residues at an authorized site.

6.4. Trimiteri la alte secțiuni

See Section 8. Exposure controls and personal protection. For further information refer to section 13.

SECȚIUNEA 7: Manipulare și depozitare

7.1. Precauții pentru manipulare în condiții de siguranță

Precauții:

Ensure good ventilation of the work station. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid contact with skin and eyes. Wear personal protective equipment. Avoid breathing dust/fume/gas/mist/vapours/spray.

Măsuri de igienă:

Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product.

7.2. Condiții de depozitare în condiții de siguranță, inclusiv eventuale incompatibilități

Condiții de depozitare:

Keep only in the original container in a cool, well ventilated place away from : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container closed when not in use. Store in a well-ventilated place. Keep cool.

Produse incompatibile:

Strong bases. Strong acids.

Materiale incompatibile:

Sources of ignition. Direct sunlight.

Temperatura de depozitare:

25 °C

Zona de depozitare:

Store in a well-ventilated place. Store away from heat.

Reguli speciale privind ambalarea:

Store in a closed container.

Materiale de ambalare:

Do not store in corrodable metal.

Germania

Clasa de depozitare (LGK, TRGS 510):

LGK 12 - Non-combustible liquids

Tabel de depozitare comună:

Joint storage not permitted for: LGK 1, LGK 6.2, LGK 7
Joint storage with restrictions permitted for: LGK 4.1A, LGK 4.3, LGK 5.1C
Joint storage permitted for: LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13

Elveția

Clasa de depozitare (LK):

LK 10/12 - Liquids

7.3. Utilizare finală specifică

No additional information available

SECȚIUNEA 8: Controlul expunerii/protecția personală

8.1. Parametri de control

8.1.1. Valori limită naționale de expunere profesională și valori biologice limită

Substanță	Țară / limită	Valoare
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)	Finland - Occupational Exposure Limits HTP (OEL TWA)	140 mg/m³ 25 ppm
	Finland - Occupational Exposure Limits HTP (OEL STEL)	280 mg/m³ 50 ppm
	Germany - Occupational Exposure Limits (TRGS 900) AGW (OEL TWA)	28 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 5 ppm (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed)
	Germany - Occupational Exposure Limits (TRGS 900) Chemical category	Skin notation, Skin sensitization
	Slovenia - Occupational Exposure Limits OEL TWA	28 mg/m³ 5 ppm
	Slovenia - Occupational Exposure Limits OEL STEL	112 mg/m³ 20 ppm
	Slovenia - Occupational Exposure Limits OEL chemical category	Potential for cutaneous absorption
	Spain - Occupational Exposure Limits VLA-ED (OEL TWA)	168 mg/m³ 30 ppm

Notă: în documentul sursă, subsecțiunile pentru .alpha.-Pinene, .beta.-Pinene și benzaldehyde conțin liste naționale extinse ale limitelor de expunere. Acestea au fost păstrate mai jos în format tabelar și în ordinea originală.

Substanță	Țară / limită	Valoare
.alpha.-Pinene (80-56-8)	Belgium - Occupational Exposure Limits OEL TWA	20 ppm
	Estonia - Occupational Exposure Limits OEL TWA	150 mg/m³ (Turpentine produced from Nordic conifers has an irritating effect on the skin, monoterpenes, with the exception of 3-Carene, have a lesser effect) 25 ppm (Turpentine produced from Nordic conifers has an irritating effect on the skin, monoterpenes, with the exception of 3-Carene, have a lesser effect)
	Estonia - Occupational Exposure Limits OEL STEL	300 mg/m³ (Turpentine produced from Nordic conifers has an irritating effect on the skin, monoterpenes, with the exception of 3-Carene, have a lesser effect) 50 ppm (Turpentine produced from Nordic conifers has an irritating effect on the skin, monoterpenes, with the exception of 3-Carene, have a lesser effect)
	Lithuania - Occupational Exposure Limits IPRV (OEL TWA)	150 mg/m³ 25 ppm
	Lithuania - Occupational Exposure Limits TPRV (OEL STEL)	300 mg/m³ 50 ppm
	Portugal - Occupational Exposure Limits OEL TWA	20 ppm (Turpentine and selected Monoterpenes)
	Portugal - Occupational Exposure Limits OEL chemical category	Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen
.beta.-Pinene (127-91-3)	Belgium - Occupational Exposure Limits OEL TWA	20 ppm
	Estonia - Occupational Exposure Limits OEL TWA	150 mg/m³ ... 25 ppm ... 300 mg/m³ ... 50 ppm
	Lithuania - Occupational Exposure Limits IPRV (OEL TWA)	150 mg/m³ 25 ppm
	Lithuania - Occupational Exposure Limits TPRV (OEL STEL)	300 mg/m³ 50 ppm
	Portugal - Occupational Exposure Limits OEL TWA	20 ppm (Turpentine and selected Monoterpenes)
	Portugal - Occupational Exposure Limits OEL chemical category	Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen
	Sweden - Occupational Exposure Limits NGV / KGV	150 mg/m³ / 300 mg/m³; 25 ppm / 50 ppm
Acetyl Propionyl (600-14-6)	Germany - Occupational Exposure Limits (TRGS 900) AGW (OEL TWA)	0.083 mg/m³ 0.02 ppm
	Germany - Occupational Exposure Limits (TRGS 900) Chemical category	Skin notation, Skin sensitization
	Slovenia - Occupational Exposure Limits OEL TWA / OEL STEL	0.083 mg/m³ 0.02 ppm
	Switzerland - Occupational Exposure Limits MAK / KZGW	0.08 mg/m³ / 0.16 mg/m³ 0.02 ppm / 0.04 ppm Sensitizer, Skin notation
benzaldehyde (100-52-7)	Bulgaria - Occupational Exposure Limits OEL TWA	5 mg/m³
	Finland - Occupational Exposure Limits HTP (OEL TWA)	4.4 mg/m³ 1 ppm
	Finland - Occupational Exposure Limits HTP (OEL C)	17.4 mg/m³ 4 ppm
	Hungary / Latvia / Lithuania / Poland	5 mg/m³ / 10 mg/m³ / 5 mg/m³ / 10 mg/m³ (see original table for full allocation)

8.1.2. Proceduri recomandate de monitorizare

No additional information available

8.1.3. Contaminanți din aer formați

No additional information available

8.1.4. DNEL și PNEC

No additional information available

8.1.5. Control banding

No additional information available

8.2. Controale ale expunerii

8.2.1. Controale inginerești adecvate

Adecvate engineering controls: Ensure good ventilation of the work station.

8.2.2. Echipament individual de protecție

Personal protective equipment: Avoid all unnecessary exposure.

Personal protective equipment symbol(s):

8.2.2.1. Protecția ochilor și a feței

Eye protection: Chemical goggles or safety glasses. Safety glasses

8.2.2.2. Protecția pielii

Skin and body protection: Wear suitable protective clothing

Hand protection: Wear protective gloves.

8.2.2.3. Protecția respiratorie

Respiratory protection: Wear appropriate mask

8.2.2.4. Pericole termice

No additional information available

8.2.3. Controlul expunerii asupra mediului

Environmental exposure controls: Avoid release to the environment.

Other information: Do not eat, drink or smoke during use.

SECȚIUNEA 9: Proprietăți fizice și chimice

9.1. Informații privind proprietățile fizice și chimice de bază

Stare fizică:

Lichid

Culoare:

light yellow. amber. Conforms to standard.

Miros:

caracteristic

Pragul de miros:

Not available

Punct de topire:

Not applicable

Punct de înghețare:

Not available

Punct de fierbere:

Not available

Inflamabilitate:

Not applicable

Limita inferioară de explozie:

Not available

Limita superioară de explozie:

Not available

Punct de aprindere:

> 93.3 °C

Temperatura de autoaprindere:

Not available

Temperatura de descompunere:

Not available

pH:

Not available

Viscozitate, cinematică:

Not available

Solubilitate:

Not available

Coeficient de partiție n-octanol/apă (Log Kow):

Not available

Presiune de vapori:

Not available

Presiune de vapori la 50°C:

Not available

Densitate:

Not available

Densitate relativă:

Not available

Densitate relativă a vaporilor la 20°C:

Not available

Caracteristici ale particulelor:

Not applicable

9.2. Alte informații

No additional information available

SECȚIUNEA 10: Stabilitate și reactivitate

10.1. Reactivitate

The product is non-reactive under normal conditions of use, storage and transport.

10.2. Stabilitate chimică

Not established.

10.3. Posibilitatea de reacții periculoase

Not established.

10.4. Condiții de evitat

Direct sunlight. Extremely high or low temperatures.

10.5. Materiale incompatibile

Strong acids. Strong bases.

10.6. Produse periculoase de descompunere

fume. Carbon monoxide. Carbon dioxide.

SECȚIUNEA 11: Informații toxicologice

11.1. Informații privind clasele de pericol definite în Regulamentul (CE) Nr. 1272/2008

Toxicitate acută (orală):

Dăunător în caz de înghițire.

Toxicitate acută (dermală):

Nu este clasificat

Toxicitate acută (inhalare):

Nu este clasificat

GINGER COOKIE #EU24263F

ATE CLP (oral) 604.719 mg/kg bodyweight

Substanță	Date toxicologice
benzyl benzoate (120-51-4)	LD50 oral rat 500 mg/kg (Source: NLM_CIP) LD50 oral 1160 mg/kg bodyweight LD50 dermal rabbit 4000 mg/kg (Source: NLM_CIP)
Cinnamic aldehyde (104-55-2)	LD50 oral rat 2220 mg/kg (Source: NLM_CIP) LD50 oral 2220 mg/kg LD50 dermal rabbit 1260 mg/kg (Source: EPA_HPV)
Eugenol (97-53-0)	LD50 oral rat 1930 mg/kg (Source: NZ_CCID) LD50 oral 2500 mg/kg bodyweight
Ethyl vanillin (121-32-4)	LD50 oral rat 1590 mg/kg (Source: NLM_CIP) LD50 oral 3000 mg/kg bodyweight LD50 dermal rat > 2000 mg/kg (Source: ECHA_API)
COUMARIN (91-64-5)	LD50 oral rat > 5000 mg/kg (Source: JAPAN_GHS) LD50 dermal rat 293 mg/kg (Source: ECHA_API)
Vanillin (121-33-5)	LD50 dermal rabbit > 5010 mg/kg (Source: OECD_SIDS) LD50 dermal 2600 mg/kg bodyweight
Citrus medica limonum (Lemon) peel oil (8008-56-8)	LD50 oral rat 2840 mg/kg (Source: NLM_CIP)
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)	LD50 oral rat 4400 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 5 g/kg (Source: CHEMVIEW)
.alpha.-Pinene (80-56-8)	LD50 oral rat 3700 mg/kg (Source: NLM_CIP) LD50 dermal rat > 5000 mg/kg (Source: CHEMVIEW)
.beta.-Pinene (127-91-3)	LD50 oral rat > 5000 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: CHEMVIEW)
Anisic aldehyde (123-11-5)	LD50 oral rat 3210 mg/kg (Source: ECHA) LD50 oral 3210 mg/kg bodyweight LD50 dermal rabbit > 5000 mg/kg (Source: EPA_HPV) LC50 Inhalation - Rat > 0.32 mg/l (Exposure time: 7 h Source: ECHA)
Phenylethyl alcohol (60-12-8)	LD50 oral rat 1609 mg/kg (Source: EPA_HPV) LD50 oral 1610 mg/kg LD50 dermal rabbit 2535 mg/kg (Source: EPA_HPV) LC50 Inhalation - Rat > 4.