Fișă cu date de securitate (SDS) — conform Regulamentului (CE) nr. 1907/2006 (REACH), cu modificarea Regulamentului (UE) 2020/878
Specificația utilizării industriale/profesionale: Industrial
For professional use only
Utilizarea substanței/amestecului: Parfumuri, Fragrances
Categorie funcțională sau de utilizare: Odour agents
No additional information available
No additional information available
No additional information available
Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]: Not classified
Efecte fizico-chimice adverse, pentru sănătatea umană și pentru mediu: No additional information available
Etichetare conform Regulamentului (CE) nr. 1272/2008 [CLP]
EUH phrases:
EUH208 - Contains Citrus medica limonum (Lemon) peel oil, Orange Oil, Linalool, Lime oil distilled . May produce an allergic reaction.
EUH210 - Safety data sheet available on request.
Extra phrases: Restricted to professional users.
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Not applicable
| Nume | Identificator produs | % | Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP] |
|---|---|---|---|
| 1-Butanol, 3-methoxy-3-methyl- | CAS-No.: 56539-66-3 EC-No.: 260-252-4 REACH-no: 01-2119976333-33 |
0.54 – 1.08 | Eye Irrit. 2, H319 |
| Citrus medica limonum (Lemon) peel oil | CAS-No.: 8008-56-8 EC-No.: 284-515-8 |
0.1 – 0.2 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Repr. 2, H361 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Orange Oil | CAS-No.: 8028-48-6 EC-No.: 232-433-8 |
0.1 – 0.2 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| Linalool | CAS-No.: 78-70-6 EC-No.: 201-134-4 EC Index-No.: 603-235-00-2 REACH-no: 01-2119474016-42 |
0.075 – 0.15 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Lime oil distilled | CAS-No.: 8008-26-2 EC-No.: 290-010-3 REACH-no: 01-2120138646-51 |
0.075 – 0.15 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 Repr. 2, H361 Asp. Tox. 1, H304 Aquatic Chronic 1, H410 |
Full text of H- and EUH-statements: see section 16
Măsuri generale de prim ajutor: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
După inhalare: Allow affected person to breathe fresh air. Allow the victim to rest.
După contactul cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
După contactul cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
După înghițire: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Simptome/efecte: Not expected to present a significant hazard under anticipated conditions of normal use.
No additional information available
Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
No additional information available
Instrucțiuni de stingere a incendiilor: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.
Protecție în timpul stingerii incendiului: Do not enter fire area without proper protective equipment, including respiratory protection.
Pentru personalul care nu face parte din echipa de intervenție: Evacuate unnecessary personnel.
Pentru personalul de intervenție: Equip cleanup crew with proper protection. Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Heading 8. Exposure controls and personal protection.
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor.
Condiții de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Produse incompatibile: Strong bases. Strong acids.
Materiale incompatibile: Sources of ignition. Direct sunlight.
Clasă de depozitare (LGK, TRGS 510): LGK 12 - Non-combustible liquids
Tabel de depozitare comună:
Depozitarea comună nu este permisă pentru: LGK 1, LGK 6.2, LGK 7
Depozitarea comună permisă cu restricții pentru: LGK 4.1A, LGK 4.3, LGK 5.1C
Depozitarea comună permisă pentru: LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13
Clasă de depozitare (LK): LK 10/12 - Liquids
No additional information available
No additional information available
No additional information available
No additional information available
No additional information available
No additional information available
No additional information available
Avoid all unnecessary exposure.
Chemical goggles or safety glasses
Wear protective gloves.
Wear appropriate mask
No additional information available
Alte informații: Do not eat, drink or smoke during use.
| Proprietate | Valoare |
|---|---|
| Physical state | Liquid |
| Color | Conforms to standard. |
| Odor | characteristic. |
| Odor threshold | Not available |
| Melting point | Not available |
| Freezing point | Not available |
| Boiling point | Not available |
| Flammability | Non flammable. |
| Lower explosion limit | Not available |
| Upper explosion limit | Not available |
| Flash point | > 93 °C |
| Auto-ignition temperature | Not available |
| Decomposition temperature | Not available |
| pH | Not available |
| Viscosity, kinematic | Not available |
| Solubility | Not available |
| Partition coefficient n-octanol/water (Log Kow) | Not available |
| Vapor pressure | Not available |
| Vapor pressure at 50°C | Not available |
| Density | Not available |
| Relative density | Not available |
| Relative vapor density at 20°C | Not available |
| Particle characteristics | Not applicable |
No additional information available
No additional information available
10.1. Reactivitate: No additional information available
10.2. Stabilitate chimică: Not established.
10.3. Posibilitatea de reacții periculoase: Not established.
10.4. Condiții de evitat: Direct sunlight. Extremely high or low temperatures.
10.5. Materiale incompatibile: Strong acids. Strong bases.
10.6. Produși de descompunere periculoși: fume. Carbon monoxide. Carbon dioxide.
Toxicitate acută (oral): Not classified
Toxicitate acută (dermal): Not classified
Toxicitate acută (inhalare): Not classified
| Substanță | Date toxice |
|---|---|
| 1-Butanol, 3-methoxy-3-methyl- (56539-66-3) | LD50 dermal rat > 2000 mg/kg (Source: ECHA_API) LC50 Inhalation - Rat > 5 mg/l/4h |
| Citrus medica limonum (Lemon) peel oil (8008-56-8) | LD50 oral rat 2840 mg/kg (Source: NLM_CIP) |
| Orange Oil (8028-48-6) | LD50 dermal rabbit > 5000 mg/kg (Source: ECHA_API) |
| Linalool (78-70-6) | LD50 oral 2790 mg/kg |
| Lime oil distilled (8008-26-2) | LD50 oral rat 5600 mg/kg LD50 dermal rabbit > 5000 mg/kg |
Corodare/iritare cutanată: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Leziuni/iritare oculară gravă: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Sensibilizare respiratorie sau cutanată: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Mutagenicitate asupra celulelor germinale: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Carcinogenitate: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Toxicitate pentru reproducere: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
STOT - expunere unică: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
STOT - expunere repetată: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Pericol prin aspirare: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
11.2.1. Proprietăți de perturbare endocrină: No additional information available
11.2.2. Alte informații:
Efecte adverse potențiale asupra sănătății umane și simptome: Based on available data, the classification criteria are not met
Periculos pentru mediul acvatic, pe termen scurt (acut): Not classified
Periculos pentru mediul acvatic, pe termen lung (cronic): Not classified
| Substanță | Date ecotoxicologice |
|---|---|
| 1-Butanol, 3-methoxy-3-methyl- (56539-66-3) | LC50 - Fish [1] > 100 mg/l (Exposure time: 96 h - Species: Oryzias latipes [semi-static] Source: ECHA) |
| Linalool (78-70-6) | EC50 96h - Algae [1] 88.3 mg/l (Species: Desmodesmus subspicatus) |
CLEMENTINE CUPCAKE #EU18123F 5% in DPG: Not established.
1-Butanol, 3-methoxy-3-methyl- (56539-66-3): Not established.
Citrus medica limonum (Lemon) peel oil (8008-56-8): Rapidly degradable
Orange Oil (8028-48-6): Rapidly degradable
Linalool (78-70-6): Rapidly degradable
Lime oil distilled (8008-26-2): Rapidly degradable
CLEMENTINE CUPCAKE #EU18123F 5% in DPG: Not established.
1-Butanol, 3-methoxy-3-methyl- (56539-66-3): Partition coefficient n-octanol/water (Log Pow) 0.18 (at 24.8 °C (at pH 6.4)
Bioaccumulative potential Not established.
No additional information available
No additional information available
No additional information available
Informații suplimentare: Avoid release to the environment.
Recomandări pentru eliminarea produsului/ambalajului: Dispose in a safe manner in accordance with local/national regulations.
Informații ecologice: Avoid release to the environment.
Cod HP: HP4 - “Irritant – skin irritation and eye damage:” waste which on application can cause skin irritation or damage to the eye.
In accordance with ADR / IMDG / IATA / ADN / RID
| Informație | ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|---|
| 14.1. UN number or ID number | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.2. UN proper shipping name | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.3. Transport hazard class(es) | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.4. Packing group | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.5. Environmental hazards | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
No supplementary information available
Overland transport: Not applicable
Transport by sea: Not applicable
Air transport: Not applicable
Inland waterway transport: Not applicable
Rail transport: Not applicable
Not applicable
REACH Annex XVII (Restriction List)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(a) | Citrus medica limonum (Lemon) peel oil ; Orange Oil ; Lime oil distilled | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F |
| 3(b) | 1-Butanol, 3-methoxy-3-methyl- ; Citrus medica limonum (Lemon) peel oil ; Orange Oil ; Linalool ; Lime oil distilled | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | Citrus medica limonum (Lemon) peel oil ; Orange Oil ; Lime oil distilled | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 |
| 40. | Citrus medica limonum (Lemon) peel oil ; Orange Oil ; Lime oil distilled | Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. |
REACH Annex XIV (Authorisation List): Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC): Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent): Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants): Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009): Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Council Regulation (EC) for the control of dual-use items: Contains substance subject to the COUNCIL REGULATION (EC) for the control of dual-use items
Explosives Precursors Regulation (2019/1148): Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004): Contains substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
Clasă de pericol pentru apă (WGK): WGK 2, significant hazardous to water (Classification according to AwSV, Annex 1).
Hazardous Incident Ordinance (12. BImSchV): Is not subject to the Hazardous Incident Ordinance (12. BImSchV)
ABM category: A(3) - hazardous for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen: Lemon oil ,Orange Oil are listed
SZW-lijst van mutagene stoffen: Lemon oil ,Orange Oil are listed
SZW-lijst van reprotoxische stoffen – Borstvoeding: None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid: None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling: None of the components are listed
Classification remarks: Emergency management guidelines for the storage of flammable liquids must be followed
No chemical safety assessment has been carried out
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
None.
| Cod | Text |
|---|---|
| Aquatic Acute 1 | Hazardous to the aquatic environment – Acute Hazard Category 1 |
| Aquatic Chronic 1 | Hazardous to the aquatic environment – Chronic Hazard Category 1 |
| Aquatic Chronic 2 | Hazardous to the aquatic environment – Chronic Hazard Category 2 |
| Asp. Tox. 1 | Aspiration hazard Category 1 |
| EUH208 | Contains Citrus medica limonum (Lemon) peel oil, Orange Oil, Linalool, Lime oil distilled . May produce an allergic reaction. |
| EUH210 | Safety data sheet available on request. |
| Eye Irrit. 2 | Serious eye damage/eye irritation, Category 2 |
| Flam. Liq. 3 | Flammable liquids Category 3 |
| H226 | Flammable liquid and vapor. |
| H304 | May be fatal if swallowed and enters airways. |
| H315 | Causes skin irritation. |
| H317 | May cause an allergic skin reaction. |
| H319 | Causes serious eye irritation. |
| H361 | Suspected of damaging fertility or the unborn child. |
| H400 | Very toxic to aquatic life. |
| H410 | Very toxic to aquatic life with long lasting effects. |
| H411 | Toxic to aquatic life with long lasting effects. |
| Repr. 2 | Reproductive toxicity Category 2 |
| Skin Irrit. 2 | Skin corrosion/irritation Category 2 |
| Skin Sens. 1 | Skin sensitization, Category 1 |
| Skin Sens. 1B | Skin sensitization, Category 1B |
The classification complies with: ATP 12
Safety Data Sheet (SDS), EU
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
9/25/2024 (Issue date) — EN (English US) — 1/11
9/25/2024 (Issue date) — EN (English US) — 11/11