PERFECTLY PUMPKIN #EU13513F 10% - Fișă cu date de securitate

SECȚIUNEA 1: Identificarea substanței/amestecului și a societății/întreprinderii

1.1. Identificatorul produsului

Formă produs: Mixture

Nume produs: PERFECTLY PUMPKIN #EU13513F 10%

Cod produs: EU13513F_10%

Tip de produs: Perfumes, fragrances

1.2. Utilizări identificate relevante ale substanței sau amestecului și utilizări contraindicate

1.2.1. Utilizări identificate relevante

Specificație utilizare industrială/profesională: Industrial

For professional use only

Utilizarea substanței/amestecului: Perfumes, fragrances

Categorie funcție sau utilizare: Odour agents

1.2.2. Utilizări contraindicate

No additional information available

1.3. Detalii privind furnizorul fișei cu date de securitate

No additional information available

1.4. Număr de telefon pentru urgențe

No additional information available

SECȚIUNEA 2: Identificarea pericolelor

2.1. Clasificarea substanței sau amestecului

Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]

Skin sensitisation, Category 1 H317

Hazardous to the aquatic environment – Chronic Hazard, Category 3 H412

Full text of H- and EUH-statements: see section 16

Efecte adverse fizico-chimice, asupra sănătății umane și asupra mediului

No additional information available

2.2. Elemente de etichetare

Etichetare conform Regulamentului (CE) nr. 1272/2008 [CLP]

Pictograme de pericol (CLP): GHS07

Cuvânt de avertizare (CLP): Warning

Conține: Eugenol; Cinnamic aldehyde; COUMARIN; Amyl cinnamic aldehyde; Heliotropine

Fraze de pericol (CLP): H317 - May cause an allergic skin reaction.
H412 - Harmful to aquatic life with long lasting effects.

Fraze de precauție (CLP):

P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P321 - Specific treatment (see supplemental first aid instruction on this label).

Fraze suplimentare: For professional users only.

2.3. Alte pericole

Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

SECȚIUNEA 3: Compoziție/informații privind ingredientele

3.1. Substanțe

Not applicable

3.2. Amestecuri

Nume	Identificator produs	%	Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Benzyl benzoate	CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33	2.75 – 5.5	Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411
Cinnamic aldehyde	CAS-No.: 104-55-2 EC-No.: 203-213-9 REACH-no: 01-2119935242-45	0.85075 – 1.70375	Acute Tox. 4 (Dermal), H312 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 Aquatic Chronic 3, H412
Eugenol	CAS-No.: 97-53-0 EC-No.: 202-589-1 REACH-no: 01-2119971802-33	0.31625 – 0.64	Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Skin Sens. 1B, H317
COUMARIN	CAS-No.: 91-64-5 EC-No.: 202-086-7 REACH-no: 01-2119943756-26	0.1900015 – 0.380003	Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Skin Sens. 1, H317 Aquatic Chronic 2, H411
Heliotropine	CAS-No.: 120-57-0 EC-No.: 204-409-7 REACH-no: 01-2119983608-21	0.0625 – 0.125	Skin Sens. 1B, H317
Amyl cinnamic aldehyde	CAS-No.: 122-40-7 EC-No.: 204-541-5	0.05 – 0.1	Skin Sens. 1B, H317 Aquatic Chronic 2, H411
acetyl propionyl	substance with national workplace exposure limit(s) (DE, SI, CH) CAS-No.: 600-14-6 EC-No.: 209-984-8	0.025 – 0.05	Flam. Liq. 2, H225 Eye Dam. 1, H318 Skin Sens. 1B, H317 STOT RE 2, H373
Benzaldehyde	substance with national workplace exposure limit(s) (BG, FI, HU, LT, LV, PL) CAS-No.: 100-52-7 EC-No.: 202-860-4 EC Index-No.: 605-012-00-5 REACH-no: 01-2119455540-44	0.025 – 0.05	Acute Tox. 4 (Oral), H302
Benzyl alcohol	substance with national workplace exposure limit(s) (BG, CZ, DE, FI, LT, LV, PL, SI, CH) CAS-No.: 100-51-6 EC-No.: 202-859-9 EC Index-No.: 603-057-00-5 REACH-no: 01-2119492630-38	0.02 – 0.04	Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319
.alpha.-Pinene	substance with national workplace exposure limit(s) (BE, EE, ES, LT, PT, SE, NO) CAS-No.: 80-56-8 EC-No.: 201-291-9	0.001 – 0.0053	Flam. Liq. 3, H226
.beta.-Pinene	substance with national workplace exposure limit(s) (BE, EE, ES, LT, PT, SE, NO) CAS-No.: 127-91-3 EC-No.: 204-872-5	0.001 – 0.0053	Flam. Liq. 3, H226
d-Limonene	substance with national workplace exposure limit(s) (DE, ES, FI, SI, NO, CH) CAS-No.: 5989-27-5 EC-No.: 205-341-0 EC Index-No.: 601-096-00-2 REACH-no: 01-2119493353-35	0.0005 – 0.0023	Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 3, H412
p-Cymene	substance with national workplace exposure limit(s) (DK, EE, LT, LV, SE) CAS-No.: 99-87-6 EC-No.: 202-796-7 EC Index-No.: 601-094-00-1	0.0001 – 0.001	Flam. Liq. 3, H226 Acute Tox. 3 (Inhalation), H331 Acute Tox. 3 (Inhalation:dust,mist), H331 Repr. 2, H361 Asp. Tox. 1, H304 Aquatic Chronic 2, H411

Full text of H- and EUH-statements: see section 16

SECȚIUNEA 4: Măsuri de prim ajutor

4.1. Descrierea măsurilor de prim ajutor

Măsuri generale de prim ajutor: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

După inhalare: Allow affected person to breathe fresh air. Allow the victim to rest.

După contactul cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.

După contactul cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.

După ingestie: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Cele mai importante simptome și efecte, atât acute, cât și întârziate

Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.

4.3. Indicații privind orice asistență medicală imediată și tratamente speciale necesare

No additional information available

SECȚIUNEA 5: Măsuri de combatere a incendiilor

5.1. Mijloace de stingere

Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Mijloace de stingere neadecvate: Do not use a heavy water stream.

5.2. Pericole speciale generate de substanță sau amestec

No additional information available

5.3. Recomandări pentru pompieri

Instrucțiuni de stingere a incendiilor: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.

Protecție în timpul intervenției: Do not enter fire area without proper protective equipment, including respiratory protection.

SECȚIUNEA 6: Măsuri în caz de eliberare accidentală

6.1. Precauții personale, echipament de protecție și proceduri de urgență

6.1.1. Pentru personalul care nu este de urgență

Proceduri de urgență: Evacuate unnecessary personnel.

6.1.2. Pentru echipele de intervenție

Echipament de protecție: Equip cleanup crew with proper protection.

Proceduri de urgență: Ventilate area.

6.2. Precauții pentru mediu

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Metode și material pentru izolare și curățare

Metode de curățare: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.

6.4. Trimitere la alte secțiuni

See Section 8. Exposure controls and personal protection.

SECȚIUNEA 7: Manipulare și depozitare

7.1. Precauții pentru manipulare în condiții de siguranță

Precauții: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.

7.2. Condiții pentru depozitare în condiții de siguranță, inclusiv incompatibilități

Condiții de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.

Produse incompatibile: Strong bases. Strong acids.

Materiale incompatibile: Sources of ignition. Direct sunlight.

7.3. Utilizare finală specifică

No additional information available

SECȚIUNEA 8: Controale ale expunerii/protecția personală

8.1. Parametri de control

8.1.1. Valori limită naționale de expunere profesională și valori biologice limită

Substanță	Țară / limită	Valoare
.alpha.-Pinene (80-56-8)	Belgium - Occupational Exposure Limits	OEL TWA [ppm] 20 ppm
.alpha.-Pinene (80-56-8)	Estonia - Occupational Exposure Limits	OEL TWA 150 mg/m³; OEL TWA [ppm] 25 ppm; OEL STEL 300 mg/m³; OEL STEL [ppm] 50 ppm
.alpha.-Pinene (80-56-8)	Lithuania - Occupational Exposure Limits	IPRV (OEL TWA) 150 mg/m³; IPRV (OEL TWA) [ppm] 25 ppm; TPRV (OEL STEL) 300 mg/m³; TPRV (OEL STEL) [ppm] 50 ppm
.alpha.-Pinene (80-56-8)	Portugal - Occupational Exposure Limits	OEL TWA [ppm] 20 ppm (Turpentine and selected Monoterpenes); OEL chemical category Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen
.alpha.-Pinene (80-56-8)	Spain - Occupational Exposure Limits	VLA-ED (OEL TWA) [1] 113 mg/m³; VLA-ED (OEL TWA) [2] 20 ppm; OEL chemical category Sensitizer
.alpha.-Pinene (80-56-8)	Sweden - Occupational Exposure Limits	NGV (OEL TWA) 150 mg/m³; NGV (OEL TWA) [ppm] 25 ppm; KTV (OEL STEL) 300 mg/m³; KTV (OEL STEL) [ppm] 50 ppm; OEL chemical category Sensitizer
.alpha.-Pinene (80-56-8)	Norway - Occupational Exposure Limits	Grenseverdi (OEL TWA) [1] 140 mg/m³; Grenseverdi (OEL TWA) [2] 25 ppm; Korttidsverdi (OEL STEL) 175 mg/m³ (value calculated); Korttidsverdi (OEL STEL) [ppm] 37.5 ppm (value calculated); OEL chemical category Skin notation
.alpha.-Pinene (80-56-8)	USA - ACGIH - Occupational Exposure Limits	ACGIH OEL TWA [ppm] 20 ppm (Turpentine and selected Monoterpenes); ACGIH chemical category Not Classifiable as a Human Carcinogen, dermal sensitizer

d-Limonene (5989-27-5)

Țară / limită	Valoare
Finland - Occupational Exposure Limits	HTP (OEL TWA) [1] 140 mg/m³; HTP (OEL TWA) [2] 25 ppm; HTP (OEL STEL) 280 mg/m³; HTP (OEL STEL) [ppm] 50 ppm
Germany - Occupational Exposure Limits (TRGS 900)	AGW (OEL TWA) [1] 28 mg/m³ ...; AGW (OEL TWA) [2] 5 ppm ...; Chemical category Skin notation, Skin sensitization
Slovenia - Occupational Exposure Limits	OEL TWA 28 mg/m³; OEL TWA [ppm] 5 ppm; OEL STEL 112 mg/m³; OEL STEL [ppm] 20 ppm; OEL chemical category Potential for cutaneous absorption
Spain - Occupational Exposure Limits	VLA-ED (OEL TWA) [1] 168 mg/m³; VLA-ED (OEL TWA) [2] 30 ppm; OEL chemical category Sensitizer, skin - potential for cutaneous absorption
Norway - Occupational Exposure Limits	Grenseverdi (OEL TWA) [1] 140 mg/m³; Grenseverdi (OEL TWA) [2] 25 ppm; Korttidsverdi (OEL STEL) 175 mg/m³ (value calculated); Korttidsverdi (OEL STEL) [ppm] 37.5 ppm (value calculated); OEL chemical category Allergenic substance
Switzerland - Occupational Exposure Limits	MAK (OEL TWA) [1] 40 mg/m³; MAK (OEL TWA) [2] 7 ppm; KZGW (OEL STEL) 80 mg/m³; KZGW (OEL STEL) [ppm] 14 ppm; OEL chemical category Sensitizer

.beta.-Pinene (127-91-3)

Țară / limită	Valoare
Belgium - Occupational Exposure Limits	OEL TWA [ppm] 20 ppm
Estonia - Occupational Exposure Limits	OEL TWA 150 mg/m³ ...; OEL TWA [ppm] 25 ppm ...; OEL STEL 300 mg/m³ ...; OEL STEL [ppm] 50 ppm ...
Lithuania - Occupational Exposure Limits	IPRV (OEL TWA) 150 mg/m³; IPRV (OEL TWA) [ppm] 25 ppm; TPRV (OEL STEL) 300 mg/m³; TPRV (OEL STEL) [ppm] 50 ppm
Portugal - Occupational Exposure Limits	OEL TWA [ppm] 20 ppm ...; OEL chemical category Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen
Spain - Occupational Exposure Limits	VLA-ED (OEL TWA) [1] 113 mg/m³; VLA-ED (OEL TWA) [2] 20 ppm; OEL chemical category Sensitizer
Sweden - Occupational Exposure Limits	NGV (OEL TWA) 150 mg/m³; NGV (OEL TWA) [ppm] 25 ppm; KTV (OEL STEL) 300 mg/m³; KTV (OEL STEL) [ppm] 50 ppm; OEL chemical category Sensitizer
Norway - Occupational Exposure Limits	Grenseverdi (OEL TWA) [1] 140 mg/m³; Grenseverdi (OEL TWA) [2] 25 ppm; Korttidsverdi (OEL STEL) 175 mg/m³ (value calculated); Korttidsverdi (OEL STEL) [ppm] 37.5 ppm (value calculated)
USA - ACGIH - Occupational Exposure Limits	ACGIH OEL TWA [ppm] 20 ppm ...; ACGIH chemical category Not Classifiable as a Human Carcinogen, dermal sensitizer

p-Cymene (99-87-6)

Țară / limită	Valoare
Denmark - Occupational Exposure Limits	OEL TWA [1] 135 mg/m³ (Methylisopropylbenzenes); OEL TWA [2] 25 ppm (Methylisopropylbenzenes); OEL STEL 270 mg/m³ (Methylisopropylbenzenes); OEL STEL [ppm] 50 ppm (Methylisopropylbenzenes)
Estonia - Occupational Exposure Limits	OEL TWA 140 mg/m³; OEL TWA [ppm] 25 ppm; OEL STEL 190 mg/m³; OEL STEL [ppm] 35 ppm
Latvia - Occupational Exposure Limits	OEL TWA 10 mg/m³ (Cymene (2, 3, 4-isomers mixture))
Lithuania - Occupational Exposure Limits	IPRV (OEL TWA) 140 mg/m³; IPRV (OEL TWA) [ppm] 25 ppm; TPRV (OEL STEL) 190 mg/m³; TPRV (OEL STEL) [ppm] 35 ppm
Sweden - Occupational Exposure Limits	NGV (OEL TWA) 140 mg/m³; NGV (OEL TWA) [ppm] 25 ppm; KTV (OEL STEL) 190 mg/m³; KTV (OEL STEL) [ppm] 35 ppm

Benzyl alcohol (100-51-6)

Țară / limită	Valoare
Bulgaria - Occupational Exposure Limits	OEL TWA 5 mg/m³
Czech Republic - Occupational Exposure Limits	PEL (OEL TWA) 40 mg/m³
Finland - Occupational Exposure Limits	HTP (OEL TWA) [1] 45 mg/m³; HTP (OEL TWA) [2] 10 ppm
Germany - Occupational Exposure Limits (TRGS 900)	AGW (OEL TWA) [1] 22 mg/m³ ...; AGW (OEL TWA) [2] 5 ppm ...; Chemical category Skin notation
Latvia - Occupational Exposure Limits	OEL TWA 5 mg/m³
Lithuania - Occupational Exposure Limits	IPRV (OEL TWA) 5 mg/m³; OEL chemical category Skin notation
Poland - Occupational Exposure Limits	NDS (OEL TWA) 240 mg/m³
Slovenia - Occupational Exposure Limits	OEL TWA 22 mg/m³; OEL TWA [ppm] 5 ppm; OEL STEL 44 mg/m³; OEL STEL [ppm] 10 ppm; OEL chemical category Potential for cutaneous absorption
Switzerland - Occupational Exposure Limits	MAK (OEL TWA) [1] 22 mg/m³ (aerosol, vapour); MAK (OEL TWA) [2] 5 ppm (aerosol, vapour); OEL chemical category Skin notation

acetyl propionyl (600-14-6)

Țară / limită	Valoare
Germany - Occupational Exposure Limits (TRGS 900)	AGW (OEL TWA) [1] 0.083 mg/m³; AGW (OEL TWA) [2] 0.02 ppm; Chemical category Skin notation, Skin sensitization
Slovenia - Occupational Exposure Limits	OEL TWA 0.083 mg/m³; OEL TWA [ppm] 0.02 ppm; OEL STEL 0.083 mg/m³; OEL STEL [ppm] 0.02 ppm; OEL chemical category Potential for cutaneous absorption
Switzerland - Occupational Exposure Limits	MAK (OEL TWA) [1] 0.08 mg/m³; MAK (OEL TWA) [2] 0.02 ppm; KZGW (OEL STEL) 0.16 mg/m³; KZGW (OEL STEL) [ppm] 0.04 ppm; OEL chemical category Sensitizer, Skin notation

Benzaldehyde (100-52-7)

Țară / limită	Valoare
Bulgaria - Occupational Exposure Limits	OEL TWA 5 mg/m³
Finland - Occupational Exposure Limits	HTP (OEL TWA) [1] 4.4 mg/m³; HTP (OEL TWA) [2] 1 ppm; HTP (OEL C) 17.4 mg/m³; HTP (OEL C) [ppm]] 4 ppm
Hungary - Occupational Exposure Limits	AK (OEL TWA) 5 mg/m³; CK (OEL STEL) 10 mg/m³
Latvia - Occupational Exposure Limits	OEL TWA 5 mg/m³
Lithuania - Occupational Exposure Limits	IPRV (OEL TWA) 5 mg/m³
Poland - Occupational Exposure Limits	NDS (OEL TWA) 10 mg/m³; NDSCh (OEL STEL) 40 mg/m³

8.1.2. Proceduri recomandate de monitorizare

No additional information available

8.1.3. Contaminanți ai aerului formați

No additional information available

8.1.4. DNEL and PNEC

No additional information available

8.1.5. Control banding

No additional information available

8.2. Controlul expunerii

8.2.1. Controale tehnice adecvate

No additional information available

8.2.2. Echipament individual de protecție

Personal protective equipment: Avoid all unnecessary exposure.

8.2.2.1. Protecția ochilor și a feței
Eye protection: Chemical goggles or safety glasses

8.2.2.2. Protecția pielii
Hand protection: Wear protective gloves.

8.2.2.3. Protecția respiratorie
Respiratory protection: Wear appropriate mask

8.2.2.4. Pericole termice

No additional information available

8.2.3. Controale ale expunerii asupra mediului

Other information: Do not eat, drink or smoke during use.

SECȚIUNEA 9: Proprietăți fizice și chimice

9.1. Informații privind proprietățile fizice și chimice de bază

Physical state: Liquid

Colour: Standard.

Odour: characteristic.

Odour threshold: No data available

pH: No data available

Relative evaporation rate (butylacetate=1): No data available

Melting point: No data available

Freezing point: No data available

Boiling point: No data available

Flash point: > 93 °C

Auto-ignition temperature: No data available

Decomposition temperature: No data available

Flammability (solid, gas): Non flammable.

Vapour pressure: No data available

Relative vapour density at 20°C: No data available

Relative density: No data available

Solubility: No data available

Partition coefficient n-octanol/water (Log Pow): No data available

Viscosity, kinematic: No data available

Viscosity, dynamic: No data available

Explosive properties: No data available

Oxidising properties: No data available

Explosive limits: No data available

9.2. Alte informații

No additional information available

SECȚIUNEA 10: Stabilitate și reactivitate

10.1. Reactivitate

No additional information available

10.2. Stabilitate chimică

Not established.

10.3. Posibilitatea de reacții periculoase

Not established.

10.4. Condiții de evitat

Direct sunlight. Extremely high or low temperatures.

10.5. Materiale incompatibile

Strong acids. Strong bases.

10.6. Produși de descompunere periculoși

fume. Carbon monoxide. Carbon dioxide.

SECȚIUNEA 11: Informații toxicologice

11.1. Informații privind efectele toxicologice

Acute toxicity (oral): Not classified

Acute toxicity (dermal): Not classified

Acute toxicity (inhalation): Not classified

Substanță	Date toxicologice
.alpha.-Pinene (80-56-8)	LD50 oral rat 3700 mg/kg (Source: NLM_CIP) LD50 oral 500 mg/kg bodyweight LD50 dermal rat > 5000 mg/kg (Source: CHEMVIEW)
d-Limonene (5989-27-5)	LD50 oral rat 4400 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 5 g/kg (Source: CHEMVIEW)
.beta.-Pinene (127-91-3)	LD50 oral rat > 5000 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: CHEMVIEW)
p-Cymene (99-87-6)	LD50 oral rat 4750 mg/kg (Source: NLM_CIP) LD50 oral 4750 mg/kg bodyweight LD50 dermal rabbit > 5000 mg/kg (Source: CHEMVIEW) LC50 Inhalation - Rat > 9.7 mg/l (Exposure time: 5 h Source: EU_CLH) LC50 Inhalation - Rat (Vapours) 9.7 mg/l/4h
Eugenol (97-53-0)	LD50 oral rat 1930 mg/kg (Source: NZ_CCID) LD50 oral 2500 mg/kg bodyweight
Cinnamic aldehyde (104-55-2)	LD50 oral rat 2220 mg/kg (Source: NLM_CIP) LD50 oral 2200 mg/kg bodyweight LD50 dermal rabbit 1260 mg/kg (Source: EPA_HPV) LD50 dermal 1100 mg/kg bodyweight
COUMARIN (91-64-5)	LD50 oral rat > 5000 mg/kg (Source: JAPAN_GHS) LD50 oral 290 mg/kg bodyweight LD50 dermal rat 293 mg/kg (Source: ECHA_API)
Benzyl alcohol (100-51-6)	LD50 oral rat 1230 mg/kg (Source: NLM_CIP) LD50 oral 1620 mg/kg bodyweight LD50 dermal 2500 mg/kg bodyweight
acetyl propionyl (600-14-6)	LD50 oral rat 3 g/kg (Source: NLM_CIP) LD50 oral 3000 mg/kg bodyweight LD50 dermal rabbit > 2000 mg/kg (Source: NIOSH) LD50 dermal 2500 mg/kg bodyweight
Benzaldehyde (100-52-7)	LD50 oral rat 1292 mg/kg (Source: JAPAN_GHS) LD50 dermal rabbit > 1250 mg/kg (Source: JAPAN_GHS)
Amyl cinnamic aldehyde (122-40-7)	LD50 oral rat 3730 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 2000 mg/kg (Source: CHEMVIEW)
Heliotropine (120-57-0)	LD50 oral rat 2700 mg/kg (Source: NLM_CIP) LD50 oral 2700 mg/kg bodyweight LD50 dermal rat > 5000 mg/kg (Source: ECHA_API)
Benzyl benzoate (120-51-4)	LD50 oral rat 500 mg/kg (Source: NLM_CIP) LD50 oral 1160 mg/kg bodyweight LD50 dermal rabbit 4000 mg/kg (Source: NLM_CIP)

Skin corrosion/irritation: Not classified

Serious eye damage/irritation: Not classified

Respiratory or skin sensitisation: May cause an allergic skin reaction.

Germ cell mutagenicity: Not classified

Carcinogenicity: Not classified

d-Limonene (5989-27-5) / Eugenol (97-53-0) / COUMARIN (91-64-5): IARC group 3 - Not classifiable

Reproductive toxicity: Not classified

STOT-single exposure: Not classified

STOT-repeated exposure: Not classified

acetyl propionyl (600-14-6): STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard: Not classified

Potential adverse human health effects and symptoms: Based on available data, the classification criteria are not met

SECȚIUNEA 12: Informații ecologice

12.1. Toxicitate

Hazardous to the aquatic environment, short-term (acute): Not classified

Hazardous to the aquatic environment, long-term (chronic): Harmful to aquatic life with long lasting effects.

Substanță	Ecotoxicitate
.alpha.-Pinene (80-56-8)	LC50 - Fish [1] 0.28 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static] Source: IUCLID) EC50 - Crustacea [1] 41 mg/l (Exposure time: 48 h - Species: Daphnia magna)
d-Limonene (5989-27-5)	LC50 - Fish [1] 0.619 – 0.796 mg/l ... LC50 - Fish [2] 35 mg/l ...
Eugenol (97-53-0)	LC50 - Fish [1] 13 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA)
Benzyl alcohol (100-51-6)	LC50 - Fish [1] 460 mg/l ... LC50 - Fish [2] 10 mg/l ... EC50 - Crustacea [1] 23 mg/l ...
Benzaldehyde (100-52-7)	LC50 - Fish [1] 10.6 – 11.8 mg/l ... LC50 - Fish [2] 12.69 mg/l ...
Heliotropine (120-57-0)	LC50 - Fish [1] 2.5 mg/l ...
Benzyl benzoate (120-51-4)	LC50 - Fish [1] 2.32 mg/l ... NOEC (chronic) 0.168 mg/l

12.2. Persistență și degradabilitate

PERFECTLY PUMPKIN #EU13513F 10%: Persistence and degradability Not established.

Benz