Forma produsului: Amestec
Denumire comercială: MULLED WINE #EU16611F
UFI: Y40G-M13K-E000-TMRK
Cod produs: EU16611F
Tip de produs: Parfumuri, fragrance-uri
Grup de produse: Produs comercial
Categoria principală de utilizare: Uz profesional, uz industrial
Specificație utilizare industrială/profesională: Industrial
Doar pentru uz profesional
Utilizarea substanței/amestecului: Parfumuri, fragrance-uri
Categorie funcție sau utilizare: Agenți de miros
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FRENCH COLOR & FRAGRANCE International GmbH
Mittlerer Weg 35
DE– 79424 Auggen
Germany
T 49-7631-931-8900
SDS@frenchcolor.com - www.frenchcolor.com
Emergency number: 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086
Clasificare conform Regulamentului (EC) No. 1272/2008 [CLP]
| Clasificare | Cod |
|---|---|
| Toxicitate acută (oral), Categoria 4 | H302 |
| Iritare gravă a ochilor/iritare oculară, Categoria 2 | H319 |
| Sensibilizare cutanată, Categoria 1 | H317 |
| Periculos pentru mediul acvatic – Pericol acut, Categoria 1 | H400 |
| Periculos pentru mediul acvatic – Pericol cronic, Categoria 2 | H411 |
Efecte adverse fizico-chimice, pentru sănătatea umană și pentru mediu: Nociv în caz de înghițire. Provoacă iritare gravă a ochilor. Foarte toxic pentru mediul acvatic. Toxic pentru mediul acvatic cu efecte pe termen lung. Poate provoca o reacție alergică a pielii.
Etichetare conform Regulamentului (EC) No. 1272/2008 [CLP]
Conține: Benzyl benzoate; Aldehyde C-16; Benzyl alcohol; Eugenol; Damascone Beta; 2-Buten-1-one, 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-, (E)-
Fraze de pericol:
H302 - Harmful if swallowed.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H410 - Very toxic to aquatic life with long lasting effects.
Fraze de precauție:
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash hands, forearms and face thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
Nu conține substanțe PBT/vPvB ≥ 0.1% evaluate în conformitate cu REACH Annex XIII
Amestecul nu conține substanță(ele) incluse în lista stabilită conform Article 59(1) din REACH pentru proprietăți de perturbare endocrină sau nu este identificat ca având proprietăți de perturbare endocrină în conformitate cu criteriile stabilite în Commission Delegated Regulation (EU) 2017/2100 sau Commission Regulation (EU) 2018/605 la o concentrație egală sau mai mare de 0,1 %
Nu se aplică
| Denumire | Identificator produs | % | Clasificare conform Regulation (EC) No. 1272/2008 [CLP] |
|---|---|---|---|
| Benzyl benzoate | CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33 | 21.3 – 42.65 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Aldehyde C-16 | CAS-No.: 77-83-8 EC-No.: 201-061-8 REACH-no: 01-2119967770-28 | 7 – 14 | Skin Sens. 1B, H317 Aquatic Chronic 2, H411 |
| methyl anthranilate | CAS-No.: 134-20-3 EC-No.: 205-132-4 | 6 – 12 | Eye Irrit. 2, H319 |
| Dimethylbenzyl carbinyl acetate(DMBCA) | CAS-No.: 151-05-3 EC-No.: 205-781-3 | 2.5 – 5 | Aquatic Chronic 3, H412 |
| Hexamethylindanopyran | CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 | 2.5 – 5 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Benzyl acetate | substance with national workplace exposure limit(s) (BE, DK, ES, IE, LT, LV, PT, RO) CAS-No.: 140-11-4 EC-No.: 205-399-7 REACH-no: 01-2119638272-42 | 1.3 – 2.5 | Aquatic Chronic 3, H412 |
| Benzyl alcohol | substance with national workplace exposure limit(s) (BG, CZ, DE, FI, LT, LV, PL, SI, CH) CAS-No.: 100-51-6 EC-No.: 202-859-9 EC Index-No.: 603-057-00-5 REACH-no: 01-2119492630-38 | 1.1 – 2.2 | Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 |
| Vanillin | CAS-No.: 121-33-5 EC-No.: 204-465-2 REACH-no: 01-2119516040-60 | 0.5 – 1 | Eye Irrit. 2, H319 |
| Eugenol | CAS-No.: 97-53-0 EC-No.: 202-589-1 REACH-no: 01-2119971802-33 | 0.2 – 0.3 | Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Benzaldehyde | substance with national workplace exposure limit(s) (BG, FI, HU, LT, LV, PL) CAS-No.: 100-52-7 EC-No.: 202-860-4 EC Index-No.: 605-012-00-5 REACH-no: 01-2119455540-44 | 0.2 – 0.3 | Acute Tox. 4 (Oral), H302 |
| Ethyl acetoacetate | substance with national workplace exposure limit(s) (RO) CAS-No.: 141-97-9 EC-No.: 205-516-1 | 0.1 – 0.2 | Not classified |
| Damascone Beta | CAS-No.: 23726-92-3 EC-No.: 245-843-7 | 0.1 – 0.2 | Skin Irrit. 2, H315 Skin Sens. 1B, H317 Aquatic Chronic 2, H411 |
| Damascone alpha- (E)-1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-2-buten-1-one (24720-09-0) | CAS-No.: 24720-09-0 EC-No.: 246-430-4 | 0.1 – 0.1 | Acute Tox. 4 (Oral), H302 Skin Sens. 1B, H317 Aquatic Chronic 2, H411 |
Full text of H- and EUH-statements: see section 16
Măsuri generale de prim ajutor: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Call a poison center or a doctor if you feel unwell.
După inhalare: Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest.
După contact cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see Get medical advice/attention. on this label). If skin irritation occurs: Get medical advice/attention. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention.
După contact cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
După înghițire: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center or a doctor if you feel unwell.
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
Symptoms/effects after skin contact: May cause an allergic skin reaction.
Symptoms/effects after eye contact: Eye irritation.
Tratament simptomatic.
Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
Hazardous decomposition products in case of fire: Toxic fumes may be released.
Instrucțiuni de stingere: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protecție în timpul combaterii incendiului: Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.
6.1.1. Pentru personalul care nu face parte din serviciile de urgență
Proceduri de urgență: Ventilate spillage area. Evacuate unnecessary personnel. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.
6.1.2. Pentru respondenții de urgență
Echipament de protecție: Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection".
Proceduri de urgență: Ventilate area.
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Pentru izolare: Collect spillage.
Metode de curățare: Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Alte informații: Dispose of materials or solid residues at an authorized site.
See Section 8. Exposure controls and personal protection. For further information refer to section 13.
Precauții pentru manipulare în siguranță: Ensure good ventilation of the work station. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid contact with skin and eyes. Wear personal protective equipment. Avoid breathing dust/fume/gas/mist/vapours/spray.
Măsuri de igienă: Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product.
Condiții de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container closed when not in use. Store in a well-ventilated place. Keep cool.
Produse incompatibile: Strong bases. Strong acids.
Materiale incompatibile: Sources of ignition. Direct sunlight.
Temperatura de depozitare: 25 °C
Zona de depozitare: Store in a well-ventilated place. Store away from heat.
Reguli speciale privind ambalarea: Store in a closed container.
Materiale de ambalare: Do not store in corrodable metal.
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| Substanță | Țară | Limită |
|---|---|---|
| Benzyl acetate (140-11-4) | Belgium - Occupational Exposure Limits | OEL TWA 62 mg/m³ OEL TWA [ppm] 10 ppm |
| Denmark - Occupational Exposure Limits | OEL TWA [1] 61 mg/m³ OEL TWA [2] 10 ppm OEL STEL 122 mg/m³ OEL STEL [ppm] 20 ppm | |
| Ireland - Occupational Exposure Limits | OEL TWA [2] 10 ppm OEL STEL [ppm] 30 ppm (calculated) | |
| Latvia - Occupational Exposure Limits | OEL TWA 5 mg/m³ | |
| Lithuania - Occupational Exposure Limits | IPRV (OEL TWA) 5 mg/m³ | |
| Portugal - Occupational Exposure Limits | OEL TWA [ppm] 10 ppm OEL chemical category A4 - Not Classifiable as a Human Carcinogen | |
| Romania - Occupational Exposure Limits | OEL TWA 50 mg/m³ OEL TWA [ppm] 8 ppm OEL STEL 80 mg/m³ OEL STEL [ppm] 13 ppm | |
| Spain - Occupational Exposure Limits | VLA-ED (OEL TWA) [1] 62 mg/m³ VLA-ED (OEL TWA) [2] 10 ppm | |
| USA - ACGIH - Occupational Exposure Limits | ACGIH OEL TWA [ppm] 10 ppm ACGIH chemical category Not Classifiable as a Human Carcinogen | |
| Observație | Restul valorilor continuă conform SDS. | |
| Substanță | Țară | Limită |
|---|---|---|
| Benzyl alcohol (100-51-6) | Bulgaria - Occupational Exposure Limits | OEL TWA 5 mg/m³ |
| Czech Republic - Occupational Exposure Limits | PEL (OEL TWA) 40 mg/m³ | |
| Finland - Occupational Exposure Limits | HTP (OEL TWA) [1] 45 mg/m³ HTP (OEL TWA) [2] 10 ppm | |
| Germany - Occupational Exposure Limits (TRGS 900) | AGW (OEL TWA) [1] 22 mg/m³ AGW (OEL TWA) [2] 5 ppm Chemical category Skin notation | |
| Latvia - Occupational Exposure Limits | OEL TWA 5 mg/m³ | |
| Lithuania - Occupational Exposure Limits | IPRV (OEL TWA) 5 mg/m³ OEL chemical category Skin notation | |
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 240 mg/m³ | |
| Switzerland - Occupational Exposure Limits | MAK (OEL TWA) [1] 22 mg/m³ (aerosol, vapour) MAK (OEL TWA) [2] 5 ppm (aerosol, vapour) OEL chemical category Skin notation |
| Substanță | Țară | Limită |
|---|---|---|
| Benzaldehyde (100-52-7) | Bulgaria - Occupational Exposure Limits | OEL TWA 5 mg/m³ |
| Finland - Occupational Exposure Limits | HTP (OEL TWA) [1] 4.4 mg/m³ HTP (OEL TWA) [2] 1 ppm HTP (OEL C) 17.4 mg/m³ HTP (OEL C) [ppm]] 4 ppm | |
| Hungary - Occupational Exposure Limits | AK (OEL TWA) 5 mg/m³ CK (OEL STEL) 10 mg/m³ | |
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 10 mg/m³ NDSCh (OEL STEL) 40 mg/m³ |
| Substanță | Țară | Limită |
|---|---|---|
| Ethyl acetoacetate (141-97-9) | Romania - Occupational Exposure Limits | OEL TWA 100 mg/m³ OEL TWA [ppm] 19 ppm OEL STEL 200 mg/m³ OEL STEL [ppm] 38 ppm |
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Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Controale tehnice adecvate: Ensure good ventilation of the work station.
Echipament individual de protecție: Avoid all unnecessary exposure.
8.2.2.1. Protecția ochilor și feței: Chemical goggles or safety glasses. Safety glasses
8.2.2.2. Protecția pielii: Wear suitable protective clothing
Protecția mâinilor: Wear protective gloves.
8.2.2.3. Protecția respiratorie: Wear appropriate mask
8.2.2.4. Pericole termice: No additional information available
Environmental exposure controls: Avoid release to the environment.
Other information: Do not eat, drink or smoke during use.
Stare fizică: Liquid
Culoare: light yellow. amber. Conforms to standard.
Miros: characteristic.
Prag de miros: Not available
Punct de topire: Not applicable
Punct de congelare: Not available
Punct de fierbere: Not available
Inflamabilitate: Not applicable
Limite explozive: Not available
Limita inferioară de explozie: Not available
Limita superioară de explozie: Not available
Punct de aprindere: > 93 °C
Temperatura de autoaprindere: Not available
Temperatura de descompunere: Not available
pH: Not available
Vâscozitate, cinematică: Not available
Solubilitate: Not available
Coeficient de partiție n-octanol/apă (Log Kow): Not available
Presiune de vapori: Not available
Presiune de vapori la 50°C: Not available
Densitate: Not available
Densitate relativă: Not available
Densitate relativă a vaporilor la 20°C: Not available
Caracteristici ale particulelor: Not applicable
9.2.1. Informații privind clasele de pericol fizic: No additional information available
9.2.2. Alte caracteristici de siguranță: No additional information available
10.1. Reactivitate
The product is non-reactive under normal conditions of use, storage and transport.
10.2. Stabilitate chimică
Not established.
10.3. Posibilitatea unor reacții periculoase
Not established.
10.4. Condiții de evitat
Direct sunlight. Extremely high or low temperatures.
10.5. Materiale incompatibile
Strong acids. Strong bases.
10.6. Produse de descompunere periculoase
fume. Carbon monoxide. Carbon dioxide.
Toxicitate acută (oral): Harmful if swallowed.
Toxicitate acută (dermică): Not classified
Toxicitate acută (inhalare): Not classified
MULLED WINE #EU16611F ATE CLP (oral) 1114.827 mg/kg bodyweight
Skin corrosion/irritation: Not classified
Serious eye damage/irritation: Causes serious eye irritation.
Respiratory or skin sensitisation: May cause an allergic skin reaction.
Germ cell mutagenicity: Not classified
Carcinogenicity: Not classified
Reproductive toxicity: Not classified
STOT-single exposure: Not classified
STOT-repeated exposure: Not classified
Aspiration hazard: Not classified
Benzyl benzoate (120-51-4)
LD50 oral rat 500 mg/kg (Source: NLM_CIP)
LD50 oral 1160 mg/kg bodyweight
LD50 dermal rabbit 4000 mg/kg (Source: NLM_CIP)
Aldehyde C-16 (77-83-8)
LD50 oral rat 5470 mg/kg (Source: NLM_CIP)
LD50 dermal rat > 2000 mg/kg (Source: ECHA_API)
methyl anthranilate (134-20-3)
LD50 oral rat 2910 mg/kg (Source: NLM_CIP)
LD50 oral 2780 mg/kg bodyweight
LD50 dermal rabbit 5000 mg/kg (Source: NLM_HSDB)
Dimethylbenzyl carbinyl acetate(DMBCA) (151-05-3)
LD50 oral rat 3300 mg/kg (Source: NLM_CIP)
LD50 oral 3300 mg/kg bodyweight
Vanillin (121-33-5)
LD50 dermal rabbit > 5010 mg/kg (Source: OECD_SIDS)
LD50 dermal 2600 mg/kg bodyweight
Benzyl acetate (140-11-4)
LD50 oral rat 2490 mg/kg (Source: JAPAN_GHS)
LD50 oral 2490 mg/kg bodyweight
LD50 dermal rabbit > 5000 mg/kg (Source: JAPAN_GHS)
Benzyl alcohol (100-51-6)
LD50 oral rat 1230 mg/kg (Source: NLM_CIP)
LD50 oral 1620 mg/kg bodyweight
LD50 dermal 2500 mg/kg bodyweight
Eugenol (97-53-0)
LD50 oral rat 1930 mg/kg (Source: NZ_CCID)
LD50 oral 2500 mg/kg bodyweight
Hexamethylindanopyran (1222-05-5)
LD50 oral rat > 3250 mg/kg (Source: CHEMVIEW)
LD50 dermal rabbit > 3250 mg/kg (Source: CHEMVIEW)
Benzaldehyde (100-52-7)
LD50 oral rat 1292 mg/kg (Source: JAPAN_GHS)
LD50 dermal rabbit > 1250 mg/kg (Source: JAPAN_GHS)
Ethyl acetoacetate (141-97-9)
LD50 oral rat 3980 mg/kg (Source: NLM_CIP)
LD50 dermal rabbit > 5000 mg/kg (Source: NLM_CIP)
Damascone Beta (23726-92-3)
LD50 oral 2920 mg/kg bodyweight
Damascone alpha- (E)-1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-2-buten-1-one (24720-09-0) (24720-09-0)
LD50 oral 1670 mg/kg bodyweight
LD50 dermal rat 2150 – 2780 mg/kg (Source: ECHA_API)
LD50 dermal 2900 mg/kg bodyweight
Benzyl benzoate (120-51-4)
Viscosity, kinematic 7.456 mm²/s
11.2.1. Proprietăți de perturbare endocrină
No additional information available
11.2.2. Alte informații
Potential adverse human health effects and symptoms: Based on available data, the classification criteria are not met
Ecology - general: Very toxic to aquatic life. Toxic to aquatic life with long lasting effects.
Hazardous to the aquatic environment, short-term (acute): Very toxic to aquatic life.
Hazardous to the aquatic environment, long-term (chronic): Toxic to aquatic life with long lasting effects.
| Substanță | Date ecologice |
|---|---|
| Benzyl benzoate (120-51-4) | LC50 - Fish [1] 2.32 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) NOEC (chronic) 0.168 mg/l |
| Aldehyde C-16 (77-83-8) | LC50 - Fish [1] 4.2 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [semi-static] Source: ECHA) |
| Vanillin (121-33-5) | LC50 - Fish [1] 53 – 61.3 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) LC50 - Fish [2] 88 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static] Source: EPA) NOEC (acute) 10000 mg/kg (Exposure time: 42 Days - Species: Eisenia foetida [soil dry weight]) |
| Benzyl alcohol (100-51-6) | LC50 - Fish [1] 460 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static] Source: EPA) LC50 - Fish [2] 10 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static] Source: EPA) EC50 - Crustacea [1] 23 mg/l (Exposure time: 48 h - Species: water flea) |
| Eugenol (97-53-0) | LC50 - Fish [1] 13 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) |
| Hexamethylindanopyran (1222-05-5) | LC50 - Fish [1] 0.452 mg/l Wolf, 1996d-27682 LC50 - Other aquatic organisms [1] > 0.14 mg/l REACH DOSSIER Pimephales promelas EC50 - Crustacea [2] 260 μg/l REACH Dossier EC50 - Other aquatic organisms [1] 0.131 mg/l REACH Dossier |
| Benzaldehyde (100-52-7) | LC50 - Fish [1] 10.6 – 11.8 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through] Source: EPA) LC50 - Fish [2] 12.69 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static] Source: IUCLID) |
| Ethyl acetoacetate (141-97-9) | LC50 - Fish [1] 298 mg/l (Exposure time: 96 h - Species: Pimephales promelas Source: IUCLID) LC50 - Fish [2] 290 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss Source: IUCLID) EC50 - Crustacea [1] 646 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 72h - Algae [1] > 500 mg/l (Species: Desmodesmus subspicatus) |
MULLED WINE #EU16611F
Persistence and degradability Not established.
Benzyl benzoate (120-51-4)
Persistence and degradability May cause long-term adverse effects in the environment.
MULLED WINE #EU16611F
Bioaccumulative potential Not established.
Benzyl benzoate (120-51-4)
Partition coefficient n-octanol/water (Log Pow) 3.97 (at 25 °C)
Bioaccumulative potential Not established.
Aldehyde C-16 (77-83-8)
Partition coefficient n-octanol/water (Log Pow) 2.4 (at 25 °C (cis isomer)
methyl anthranilate (134-20-3)
Partition coefficient n-octanol/water (Log Pow) 2.17 (at 22 °C)
Dimethylbenzyl carbinyl acetate(DMBCA) (151-05-3)
Partition coefficient n-octanol/water (Log Pow) 3.64 (at 25 °C (at pH >6-<7)
Vanillin (121-33-5)
Partition coefficient n-octanol/water (Log Pow) 1.23 (at 22 °C)
Benzyl acetate (140-11-4)
Partition coefficient n-octanol/water (Log Pow) 1.96 (at 25 °C (at pH 7)
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