| Forma produsului | Amestec |
|---|---|
| Numele produsului | MULLED WINE #EU16611F 10% |
| Cod produs | EU16611F_10% |
| Tipul produsului | Perfumes, fragrances |
| Specificație utilizare industrială/profesională | Industrial For professional use only |
|---|---|
| Utilizarea substanței/amestecului | Perfumes, fragrances |
| Categoria funcției sau utilizării | Odour agents |
No additional information available
No additional information available
No additional information available
Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
| Skin sensitisation, Category 1 | H317 |
|---|---|
| Hazardous to the aquatic environment – Chronic Hazard, Category 3 | H412 |
Textul integral al declarațiilor H și EUH: vezi secțiunea 16
Efecte fizico-chimice, asupra sănătății umane și asupra mediului: No additional information available
Etichetare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
| Cuvânt de avertizare (CLP) | Warning |
|---|---|
| Conține | Aldehyde C-16 |
| Declarații de pericol (CLP) | H317 - May cause an allergic skin reaction. H412 - Harmful to aquatic life with long lasting effects. |
| Declarații de precauție (CLP) | P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P321 - Specific treatment (see supplemental first aid instruction on this label). |
Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
Not applicable
| Nume | Identificator produs | % | Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP] |
|---|---|---|---|
| Benzyl benzoate | CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33 |
2.13 – 4.265 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Aldehyde C-16 | CAS-No.: 77-83-8 EC-No.: 201-061-8 REACH-no: 01-2119967770-28 |
0.7 – 1.4 | Skin Sens. 1B, H317 Aquatic Chronic 2, H411 |
| methyl anthranilate | CAS-No.: 134-20-3 EC-No.: 205-132-4 |
0.6 – 1.2 | Eye Irrit. 2, H319 |
| Hexamethylindanopyran | CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 |
0.25 – 0.5 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Benzyl acetate | substance with national workplace exposure limit(s) (BE, DK, ES, IE, LT, LV, PT, RO) CAS-No.: 140-11-4 EC-No.: 205-399-7 REACH-no: 01-2119638272-42 |
0.13 – 0.25 | Aquatic Chronic 3, H412 |
| Benzyl alcohol | substance with national workplace exposure limit(s) (BG, CZ, DE, FI, LT, LV, PL, SI, CH) CAS-No.: 100-51-6 EC-No.: 202-859-9 EC Index-No.: 603-057-00-5 REACH-no: 01-2119492630-38 |
0.11 – 0.22 | Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 |
| Benzaldehyde | substance with national workplace exposure limit(s) (BG, FI, HU, LT, LV, PL) CAS-No.: 100-52-7 EC-No.: 202-860-4 EC Index-No.: 605-012-00-5 REACH-no: 01-2119455540-44 |
0.02 – 0.03 | Acute Tox. 4 (Oral), H302 |
| Ethyl acetoacetate | substance with national workplace exposure limit(s) (RO) CAS-No.: 141-97-9 EC-No.: 205-516-1 |
0.01 – 0.02 | Not classified |
Textul integral al declarațiilor H și EUH: vezi secțiunea 16
| Măsuri generale de prim ajutor | Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). |
|---|---|
| După inhalare | Allow affected person to breathe fresh air. Allow the victim to rest. |
| După contactul cu pielea | Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. |
| După contactul cu ochii | Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. |
| După ingerare | Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. |
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
No additional information available
Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
No additional information available
Instrucțiuni de stingere a incendiilor: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protecție în timpul stingerii incendiilor: Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1. Pentru personalul care nu este implicat în situații de urgență
Proceduri de urgență: Evacuate unnecessary personnel.
6.1.2. Pentru personalul care intervine în situații de urgență
Echipament de protecție: Equip cleanup crew with proper protection.
Proceduri de urgență: Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Metode de curățare: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Section 8. Exposure controls and personal protection.
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
| Condiții de depozitare | Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. |
|---|---|
| Produse incompatibile | Strong bases. Strong acids. |
| Materiale incompatibile | Sources of ignition. Direct sunlight. |
No additional information available
| Substanță | Țară / limită | Valoare |
|---|---|---|
| Benzyl acetate (140-11-4) | Belgium - Occupational Exposure Limits OEL TWA OEL TWA [ppm] | 62 mg/m³ 10 ppm |
| Denmark - Occupational Exposure Limits OEL TWA [1] OEL TWA [2] OEL STEL OEL STEL [ppm] | 61 mg/m³ 10 ppm 122 mg/m³ 20 ppm | |
| Ireland - Occupational Exposure Limits OEL TWA [2] OEL STEL [ppm] | 10 ppm 30 ppm (calculated) | |
| Latvia - Occupational Exposure Limits OEL TWA | 5 mg/m³ | |
| Lithuania - Occupational Exposure Limits IPRV (OEL TWA) | 5 mg/m³ | |
| Portugal - Occupational Exposure Limits OEL TWA [ppm] OEL chemical category | 10 ppm A4 - Not Classifiable as a Human Carcinogen | |
| Romania - Occupational Exposure Limits OEL TWA OEL TWA [ppm] OEL STEL OEL STEL [ppm] | 50 mg/m³ 8 ppm 80 mg/m³ 13 ppm | |
| Spain - Occupational Exposure Limits VLA-ED (OEL TWA) [1] VLA-ED (OEL TWA) [2] | 62 mg/m³ 10 ppm | |
| USA - ACGIH - Occupational Exposure Limits ACGIH OEL TWA [ppm] | 10 ppm | |
| Benzyl acetate (140-11-4) ACGIH chemical category | Not Classifiable as a Human Carcinogen | |
| Benzyl alcohol (100-51-6) | Bulgaria - Occupational Exposure Limits OEL TWA | 5 mg/m³ |
| Czech Republic - Occupational Exposure Limits PEL (OEL TWA) | 40 mg/m³ | |
| Finland - Occupational Exposure Limits HTP (OEL TWA) [1] HTP (OEL TWA) [2] | 45 mg/m³ 10 ppm | |
| Germany - Occupational Exposure Limits (TRGS 900) AGW (OEL TWA) [1] AGW (OEL TWA) [2] Chemical category | 22 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 5 ppm (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Skin notation | |
| Latvia - Occupational Exposure Limits OEL TWA | 5 mg/m³ | |
| Lithuania - Occupational Exposure Limits IPRV (OEL TWA) OEL chemical category | 5 mg/m³ Skin notation | |
| Poland - Occupational Exposure Limits NDS (OEL TWA) | 240 mg/m³ | |
| Slovenia - Occupational Exposure Limits OEL TWA OEL TWA [ppm] OEL STEL OEL STEL [ppm] OEL chemical category | 22 mg/m³ 5 ppm 44 mg/m³ 10 ppm Potential for cutaneous absorption | |
| Switzerland - Occupational Exposure Limits MAK (OEL TWA) [1] MAK (OEL TWA) [2] OEL chemical category | 22 mg/m³ (aerosol, vapour) 5 ppm (aerosol, vapour) Skin notation | |
| Benzaldehyde (100-52-7) | Bulgaria - Occupational Exposure Limits OEL TWA | 5 mg/m³ |
| Finland - Occupational Exposure Limits HTP (OEL TWA) [1] HTP (OEL TWA) [2] HTP (OEL C) HTP (OEL C) [ppm]] | 4.4 mg/m³ 1 ppm 17.4 mg/m³ 4 ppm | |
| Hungary - Occupational Exposure Limits AK (OEL TWA) CK (OEL STEL) | 5 mg/m³ 10 mg/m³ | |
| Latvia - Occupational Exposure Limits OEL TWA | 5 mg/m³ | |
| Lithuania - Occupational Exposure Limits IPRV (OEL TWA) | 5 mg/m³ | |
| Poland - Occupational Exposure Limits NDS (OEL TWA) NDSCh (OEL STEL) | 10 mg/m³ 40 mg/m³ | |
| Ethyl acetoacetate (141-97-9) | Romania - Occupational Exposure Limits OEL TWA OEL TWA [ppm] OEL STEL OEL STEL [ppm] | 100 mg/m³ 19 ppm 200 mg/m³ 38 ppm |
No additional information available
No additional information available
No additional information available
No additional information available
No additional information available
Personal protective equipment: Avoid all unnecessary exposure.
Personal protective equipment symbol(s):
Eye protection: Chemical goggles or safety glasses
Hand protection: Wear protective gloves.
Respiratory protection: Wear appropriate mask
No additional information available
Other information: Do not eat, drink or smoke during use.
| Stare fizică | Liquid |
|---|---|
| Culoare | Standard. |
| Miros | characteristic. |
| Pragul de miros | No data available |
| pH | No data available |
| Rata de evaporare relativă (acetat de butil=1) | No data available |
| Punct de topire | No data available |
| Punct de îngheț | No data available |
| Punct de fierbere | No data available |
| Punct de aprindere | > 93 °C |
| Temperatura de autoaprindere | No data available |
| Temperatura de descompunere | No data available |
| Inflamabilitate (solid, gaz) | Non flammable. |
| Presiunea vaporilor | No data available |
| Densitatea relativă a vaporilor la 20°C | No data available |
| Densitatea relativă | No data available |
| Solubilitate | No data available |
| Coeficient de partiție n-octanol/apă (Log Pow) | No data available |
| Viscozitate, cinematică | No data available |
| Viscozitate, dinamică | No data available |
| Proprietăți explozive | No data available |
| Proprietăți oxidante | No data available |
| Limite de explozie | No data available |
No additional information available
No additional information available
Not established.
Not established.
Direct sunlight. Extremely high or low temperatures.
Strong acids. Strong bases.
fume. Carbon monoxide. Carbon dioxide.
| Toxicitate acută (oral) | Not classified |
|---|---|
| Toxicitate acută (dermal) | Not classified |
| Toxicitate acută (inhalare) | Not classified |
| Substanță | Date toxicologice |
|---|---|
| Benzyl benzoate (120-51-4) | LD50 oral rat 500 mg/kg (Source: NLM_CIP) LD50 oral 1160 mg/kg bodyweight LD50 dermal rabbit 4000 mg/kg (Source: NLM_CIP) |
| Aldehyde C-16 (77-83-8) | LD50 oral rat 5470 mg/kg (Source: NLM_CIP) LD50 dermal rat > 2000 mg/kg (Source: ECHA_API) |
| methyl anthranilate (134-20-3) | LD50 oral rat 2910 mg/kg (Source: NLM_CIP) LD50 oral 2780 mg/kg bodyweight LD50 dermal rabbit 5000 mg/kg (Source: NLM_HSDB) |
| Hexamethylindanopyran (1222-05-5) | LD50 oral rat > 3250 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 3250 mg/kg (Source: CHEMVIEW) |
| Benzyl acetate (140-11-4) | LD50 oral rat 2490 mg/kg (Source: JAPAN_GHS) LD50 oral 2490 mg/kg bodyweight LD50 dermal rabbit > 5000 mg/kg (Source: JAPAN_GHS) |
| Benzyl alcohol (100-51-6) | LD50 oral rat 1230 mg/kg (Source: NLM_CIP) LD50 oral 1620 mg/kg bodyweight LD50 dermal 2500 mg/kg bodyweight |
| Benzaldehyde (100-52-7) | LD50 oral rat 1292 mg/kg (Source: JAPAN_GHS) LD50 dermal rabbit > 1250 mg/kg (Source: JAPAN_GHS) |
| Ethyl acetoacetate (141-97-9) | LD50 oral rat 3980 mg/kg (Source: NLM_CIP) LD50 dermal rabbit > 5000 mg/kg (Source: NLM_CIP) |
| Skin corrosion/irritation | Not classified |
|---|---|
| Informații suplimentare | Based on available data, the classification criteria are not met |
| Serious eye damage/irritation | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| Respiratory or skin sensitisation | May cause an allergic skin reaction. |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| Germ cell mutagenicity | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| Carcinogenicity | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| Benzyl acetate (140-11-4) | IARC group 3 - Not classifiable |
| Reproductive toxicity | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| STOT-single exposure | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| STOT-repeated exposure | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| Aspiration hazard | Not classified |
| Informații suplimentare | Based on available data, the classification criteria are not met |
| Benzyl benzoate (120-51-4) | Viscosity, kinematic 7.456 mm²/s |
| Efecte adverse potențiale asupra sănătății umane și simptome | Based on available data, the classification criteria are not met |
| Hazardous to the aquatic environment, short–term (acute) | Not classified |
|---|---|
| Hazardous to the aquatic environment, long–term (chronic) | Harmful to aquatic life with long lasting effects. |
| Substanță | Date ecotoxice |
|---|---|
| Benzyl benzoate (120-51-4) | LC50 - Fish [1] 2.32 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) NOEC (chronic) 0.168 mg/l |
| Aldehyde C-16 (77-83-8) | LC50 - Fish [1] 4.2 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [semi-static] Source: ECHA) |
| Hexamethylindanopyran (1222-05-5) | LC50 - Fish [1] 0.452 mg/l Wolf, 1996d-27682 LC50 - Other aquatic organisms [1] > 0.14 mg/l REACH DOSSIER Pimephales promelas EC50 - Crustacea [2] 260 μg/l REACH Dossier EC50 - Other aquatic organisms [1] 0.131 mg/l REACH Dossier |
| Benzyl alcohol (100-51-6) | LC50 - Fish [1] 460 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static] Source: EPA) LC50 - Fish [2] 10 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static] Source: EPA) EC50 - Crustacea [1] 23 mg/l (Exposure time: 48 h - Species: water flea) |
| Benzaldehyde (100-52-7) | LC50 - Fish [1] 10.6 – 11.8 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through] Source: EPA) LC50 - Fish [2] 12.69 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static] Source: IUCLID) |
| Ethyl acetoacetate (141-97-9) | LC50 - Fish [1] 298 mg/l (Exposure time: 96 h - Species: Pimephales promelas Source: IUCLID) LC50 - Fish [2] 290 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss Source: IUCLID) EC50 - Crustacea [1] 646 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 72h - Algae [1] > 500 mg/l (Species: Desmodesmus subspicatus) |
| MULLED WINE #EU16611F 10% | Persistence and degradability Not established. |
|---|---|
| Benzyl benzoate (120-51-4) | Persistence and degradability May cause long-term adverse effects in the environment. |
| MULLED WINE #EU16611F 10% | Bioaccumulative potential Not established. |
|---|---|
| Benzyl benzoate (120-51-4) | Partition coefficient n-octanol/water (Log Pow) 3.97 (at 25 °C) Bioaccumulative potential Not established. |
| Aldehyde C-16 (77-83-8) | Partition coefficient n-octanol/water (Log Pow) 2.4 (at 25 °C (cis isomer) |
| methyl anthranilate (134-20-3) | Partition coefficient n-octanol/water (Log Pow) 2.17 (at 22 °C) |
| Hexamethylindanopyran (1222-05-5) | BCF - Fish [1] (1618 dimensionless (whole body w.w.) Partition coefficient n-octanol/water (Log Pow) 5.3 (at 25 °C (at pH 7) |
| Benzyl acetate (140-11-4) | Partition coefficient n-octanol/water (Log Pow) 1.96 (at 25 °C (at pH 7) |
| Benzyl alcohol (100-51-6) | Partition coefficient n-octanol/water (Log Pow) 1.05 |
| Benzaldehyde (100-52-7) | BCF - Fish [1] (no significant bioaccumulation) Partition coefficient n-octanol/water (Log Pow) 1.4 (at 25 °C) |
| Ethyl acetoacetate (141-97-9) | Partition coefficient n-octanol/water (Log Pow) 0.8 (at 20 °C) |
No additional information available
No additional information available
Additional information: Avoid release to the environment.
| Recomandări pentru eliminarea produsului/ambalajului | Dispose in a safe manner in accordance with local/national regulations. |
|---|---|
| Ecologie - materiale reziduale | Avoid release to the environment. |
HP Code: HP3 - “Flammable:”
– flammable liquid waste: liquid waste having a flash point below 60 °C or waste gas oil, diesel and light heating oils having a flash point > 55 °C and ≤ 75 °C;
– flammable pyrophoric liquid and solid waste: solid or liquid waste which, even in small quantities, is liable to ignite within five minutes after coming into contact with air;
– flammable solid waste: solid waste which is readily combustible or may cause or contribute to fire through friction;
– flammable gaseous waste: gaseous waste which is flammable in air at 20 °C and a standard pressure of 101.3 kPa;
– water reactive waste: waste which, in contact with water, emits flammable gases in dangerous quantities;
– other flammable waste: flammable aerosols, flammable self-heating waste, flammable organic peroxides and flammable self-reactive waste.
HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
În conformitate cu ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID | |
|---|---|---|---|---|---|
| 14.1. Numărul ONU | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.2. Denumirea corectă ONU pentru expediție | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.3. Clasa (clasele) de pericol pentru transport | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.4. Grupul de ambalare | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.5. Pericole pentru mediu | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
No supplementary information available
Overland transport
Not applicable
Transport by sea
Not applicable
Air transport
Not applicable
Inland waterway transport
Not applicable
Rail transport
Not applicable
Not applicable
REACH Annex XVII (Restriction List)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(b) | MULLED WINE #EU16611F 10% ; Benzyl benzoate ; Aldehyde C-16 ; methyl anthranilate ; Benzyl alcohol ; Benzaldehyde | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | MULLED WINE #EU16611F 10% ; Benzyl benzoate ; Aldehyde C-16 ; Hexamethylindanopyran ; Benzyl acetate | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 |
REACH Annex XIV (Authorisation List)
Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC)
Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent)
Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants)
Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009)
Contains no substance(s)