Fișă cu date de securitate
conform Regulamentului (CE) Nr. 1907/2006 (REACH) cu modificarea sa prin Regulamentul (UE) 2020/878
| Forma produsului | Amestec |
| Numele produsului | MULLED WINE #EU16611F 25% |
| Cod produs | EU16611F_25% |
| Tip de produs | Perfumes, Fragrances |
| Specificația utilizării industriale/profesionale | Industrial Numai pentru uz profesional |
| Utilizarea substanței/amestecului | Perfumes, Fragrances |
| Categorie funcție sau utilizare | Odour agents |
No additional information available
No additional information available
No additional information available
Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
| Sensibilizarea pielii, Categoria 1 | H317 |
| Periculos pentru mediul acvatic – Pericol cronic Categoria 2 | H411 |
Textul complet al frazelor H și EUH: vezi secțiunea 16
Efecte fizico-chimice, asupra sănătății umane și asupra mediului: No additional information available
Etichetare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
| Pictograme de pericol (CLP) | GHS07 GHS09 |
| Cuvânt de avertizare (CLP) | Warning |
| Conține | Aldehyde C-16 |
| Fraze de pericol (CLP) | H317 - May cause an allergic skin reaction. H411 - Toxic to aquatic life with long lasting effects. |
| Fraze de precauție (CLP) | P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P321 - Specific treatment (see supplemental first aid instruction on this label). |
Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
Not applicable
| Nume | Identificator produs | % | Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP] |
|---|---|---|---|
| Benzyl benzoate | CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33 |
5.325 – 10.6625 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Aldehyde C-16 | CAS-No.: 77-83-8 EC-No.: 201-061-8 REACH-no: 01-2119967770-28 |
1.75 – 3.5 | Skin Sens. 1B, H317 Aquatic Chronic 2, H411 |
| methyl anthranilate | CAS-No.: 134-20-3 EC-No.: 205-132-4 |
1.5 – 3 | Eye Irrit. 2, H319 |
| Dimethylbenzyl carbinyl acetate(DMBCA) | CAS-No.: 151-05-3 EC-No.: 205-781-3 |
0.625 – 1.25 | Aquatic Chronic 3, H412 |
| Hexamethylindanopyran | CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 |
0.625 – 1.25 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Benzyl acetate substance with national workplace exposure limit(s) (BE, DK, ES, IE, LT, LV, PT, RO) |
CAS-No.: 140-11-4 EC-No.: 205-399-7 REACH-no: 01-2119638272-42 |
0.325 – 0.625 | Aquatic Chronic 3, H412 |
| Benzyl alcohol substance with national workplace exposure limit(s) (BG, CZ, DE, FI, LT, LV, PL, SI, CH) |
CAS-No.: 100-51-6 EC-No.: 202-859-9 EC Index-No.: 603-057-00-5 REACH-no: 01-2119492630-38 |
0.275 – 0.55 | Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 |
| Benzaldehyde substance with national workplace exposure limit(s) (BG, FI, HU, LT, LV, PL) |
CAS-No.: 100-52-7 EC-No.: 202-860-4 EC Index-No.: 605-012-00-5 REACH-no: 01-2119455540-44 |
0.05 – 0.075 | Acute Tox. 4 (Oral), H302 |
| Ethyl acetoacetate substance with national workplace exposure limit(s) (RO) |
CAS-No.: 141-97-9 EC-No.: 205-516-1 |
0.025 – 0.05 | Not classified |
Textul complet al frazelor H și EUH: vezi secțiunea 16
| Măsuri generale de prim ajutor | Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). |
| După inhalare | Allow affected person to breathe fresh air. Allow the victim to rest. |
| După contactul cu pielea | Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. |
| După contactul cu ochii | Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. |
| După înghițire | Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. |
| Simptome/efecte | Not expected to present a significant hazard under anticipated conditions of normal use. |
No additional information available
| Mijloace de stingere adecvate | Foam. Dry powder. Carbon dioxide. Water spray. Sand. |
| Mijloace de stingere neadecvate | Do not use a heavy water stream. |
No additional information available
| Instrucțiuni de stingere a incendiilor | Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. |
| Protecție în timpul intervenției | Do not enter fire area without proper protective equipment, including respiratory protection. |
Emergency procedures: Evacuate unnecessary personnel.
| Echipament de protecție | Equip cleanup crew with proper protection. |
| Proceduri de urgență | Ventilate area. |
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Heading 8. Exposure controls and personal protection.
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor.
| Condiții de depozitare | Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. |
| Produse incompatibile | Strong bases. Strong acids. |
| Materiale incompatibile | Sources of ignition. Direct sunlight. |
No additional information available
| Substanță | Valori limită |
|---|---|
| Benzyl acetate (140-11-4) | |
| Belgium - Occupational Exposure Limits | OEL TWA 62 mg/m³ OEL TWA [ppm] 10 ppm |
| Denmark - Occupational Exposure Limits | OEL TWA [1] 61 mg/m³ OEL TWA [2] 10 ppm OEL STEL 122 mg/m³ OEL STEL [ppm] 20 ppm |
| Ireland - Occupational Exposure Limits | OEL TWA [2] 10 ppm OEL STEL [ppm] 30 ppm (calculated) |
| Latvia - Occupational Exposure Limits | OEL TWA 5 mg/m³ |
| Lithuania - Occupational Exposure Limits | IPRV (OEL TWA) 5 mg/m³ |
| Portugal - Occupational Exposure Limits | OEL TWA [ppm] 10 ppm OEL chemical category A4 - Not Classifiable as a Human Carcinogen |
| Romania - Occupational Exposure Limits | OEL TWA 50 mg/m³ OEL TWA [ppm] 8 ppm OEL STEL 80 mg/m³ OEL STEL [ppm] 13 ppm |
| Spain - Occupational Exposure Limits | VLA-ED (OEL TWA) [1] 62 mg/m³ VLA-ED (OEL TWA) [2] 10 ppm |
| USA - ACGIH - Occupational Exposure Limits | ACGIH OEL TWA [ppm] 10 ppm ACGIH chemical category Not Classifiable as a Human Carcinogen |
| Benzyl alcohol (100-51-6) | |
| Bulgaria - Occupational Exposure Limits | OEL TWA 5 mg/m³ |
| Czech Republic - Occupational Exposure Limits | PEL (OEL TWA) 40 mg/m³ |
| Finland - Occupational Exposure Limits | HTP (OEL TWA) [1] 45 mg/m³ HTP (OEL TWA) [2] 10 ppm |
| Germany - Occupational Exposure Limits (TRGS 900) | AGW (OEL TWA) [1] 22 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) AGW (OEL TWA) [2] 5 ppm (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Chemical category skin notation |
| Latvia - Occupational Exposure Limits | OEL TWA 5 mg/m³ |
| Lithuania - Occupational Exposure Limits | IPRV (OEL TWA) 5 mg/m³ OEL chemical category skin notation |
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 240 mg/m³ |
| Slovenia - Occupational Exposure Limits | OEL TWA 22 mg/m³ OEL TWA [ppm] 5 ppm OEL STEL 44 mg/m³ OEL STEL [ppm] 10 ppm OEL chemical category Potential for cutaneous absorption |
| Switzerland - Occupational Exposure Limits | MAK (OEL TWA) [1] 22 mg/m³ (aerosol, vapour) MAK (OEL TWA) [2] 5 ppm (aerosol, vapour) OEL chemical category skin notation |
| Benzaldehyde (100-52-7) | |
| Bulgaria - Occupational Exposure Limits | OEL TWA 5 mg/m³ |
| Finland - Occupational Exposure Limits | HTP (OEL TWA) [1] 4.4 mg/m³ HTP (OEL TWA) [2] 1 ppm HTP (OEL C) 17.4 mg/m³ HTP (OEL C) [ppm] 4 ppm |
| Hungary - Occupational Exposure Limits | AK (OEL TWA) 5 mg/m³ CK (OEL STEL) 10 mg/m³ |
| Latvia - Occupational Exposure Limits | OEL TWA 5 mg/m³ |
| Lithuania - Occupational Exposure Limits | IPRV (OEL TWA) 5 mg/m³ |
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 10 mg/m³ NDSCh (OEL STEL) 40 mg/m³ |
| Ethyl acetoacetate (141-97-9) | |
| Romania - Occupational Exposure Limits | OEL TWA 100 mg/m³ OEL TWA [ppm] 19 ppm OEL STEL 200 mg/m³ OEL STEL [ppm] 38 ppm |
No additional information available
No additional information available
No additional information available
No additional information available
No additional information available
Personal protective equipment:
Avoid all unnecessary exposure.
Personal protective equipment symbol(s):
Eye protection: Chemical goggles or safety glasses
Hand protection: Wear protective gloves.
Respiratory protection: Wear appropriate mask
No additional information available
Other information: Do not eat, drink or smoke during use.
| Stare fizică | Liquid |
| Culoare | Standard. |
| Miros | characteristic. |
| Prag de miros | No data available |
| pH | No data available |
| Rata relativă de evaporare (butyl acetate=1) | No data available |
| Punct de topire | No data available |
| Punct de îngheț | No data available |
| Punct de fierbere | No data available |
| Punct de aprindere | > 93 °C |
| Temperatura de autoaprindere | No data available |
| Temperatura de descompunere | No data available |
| Inflamabilitate (solid, gaz) | Non flammable. |
| Presiune de vapori | No data available |
| Densitate relativă a vaporilor la 20°C | No data available |
| Densitate relativă | No data available |
| Solubilitate | No data available |
| Coeficient de partiție n-octanol/apă (Log Pow) | No data available |
| Vâscozitate, cinematică | No data available |
| Vâscozitate, dinamică | No data available |
| Proprietăți explozive | No data available |
| Proprietăți oxidante | No data available |
| Limite de explozie | No data available |
No additional information available
| 10.1. Reactivitate | No additional information available |
| 10.2. Stabilitate chimică | Not established. |
| 10.3. Posibilitatea de reacții periculoase | Not established. |
| 10.4. Condiții de evitat | Direct sunlight. Extremely high or low temperatures. |
| 10.5. Materiale incompatibile | Strong acids. Strong bases. |
| 10.6. Produși de descompunere periculoși | fume. Carbon monoxide. Carbon dioxide. |
| Toxicitate acută (orală) | Not classified |
| Toxicitate acută (cutanată) | Not classified |
| Toxicitate acută (inhalare) | Not classified |
| Substanță | Date toxicologice |
|---|---|
| Benzyl benzoate (120-51-4) | |
| LD50 oral rat | 500 mg/kg (Source: NLM_CIP) |
| LD50 oral | 1160 mg/kg body weight |
| LD50 dermal rabbit | 4000 mg/kg (Source: NLM_CIP) |
| Aldehyde C-16 (77-83-8) | |
| LD50 oral rat | 5470 mg/kg (Source: NLM_CIP) |
| LD50 dermal rat | > 2000 mg/kg (Source: ECHA_API) |
| methyl anthranilate (134-20-3) | |
| LD50 oral rat | 2910 mg/kg (Source: NLM_CIP) |
| LD50 oral | 2780 mg/kg body weight |
| LD50 dermal rabbit | 5000 mg/kg (Source: NLM_HSDB) |
| Dimethylbenzyl carbinyl acetate(DMBCA) (151-05-3) | |
| LD50 oral rat | 3300 mg/kg (Source: NLM_CIP) |
| LD50 oral | 3300 mg/kg body weight |
| Hexamethylindanopyran (1222-05-5) | |
| LD50 oral rat | > 3250 mg/kg (Source: CHEMVIEW) |
| LD50 dermal rabbit | > 3250 mg/kg (Source: CHEMVIEW) |
| Benzyl acetate (140-11-4) | |
| LD50 oral rat | 2490 mg/kg (Source: JAPAN_GHS) |
| LD50 oral | 2490 mg/kg body weight |
| LD50 dermal rabbit | > 5000 mg/kg (Source: JAPAN_GHS) |
| Benzyl alcohol (100-51-6) | |
| LD50 oral rat | 1230 mg/kg (Source: NLM_CIP) |
| LD50 oral | 1620 mg/kg body weight |
| LD50 dermal | 2500 mg/kg body weight |
| Benzaldehyde (100-52-7) | |
| LD50 oral rat | 1292 mg/kg (Source: JAPAN_GHS) |
| LD50 dermal rabbit | > 1250 mg/kg (Source: JAPAN_GHS) |
| Ethyl acetoacetate (141-97-9) | |
| LD50 oral rat | 3980 mg/kg (Source: NLM_CIP) |
| LD50 dermal rabbit | > 5000 mg/kg (Source: NLM_CIP) |
| Corodarea/iritarea pielii | Not classified Additional information: Based on available data, the classification criteria are not met |
| Leziuni oculare grave/iritare oculară | Not classified Additional information: Based on available data, the classification criteria are not met |
| Sensibilizare respiratorie sau cutanată | May cause an allergic skin reaction. Additional information: Based on available data, the classification criteria are not met |
| Mutagenitatea celulelor germinale | Not classified Additional information: Based on available data, the classification criteria are not met |
| Carcinogenicitate | Not classified Additional information: Based on available data, the classification criteria are not met |
| Benzyl acetate (140-11-4) | IARC group 3 - Not classifiable |
| Toxicitate pentru reproducere | Not classified Additional information: Based on available data, the classification criteria are not met |
| STOT - expunere unică | Not classified Additional information: Based on available data, the classification criteria are not met |
| STOT - expunere repetată | Not classified Additional information: Based on available data, the classification criteria are not met |
| Pericol prin aspirare | Not classified Additional information: Based on available data, the classification criteria are not met |
| Benzyl benzoate (120-51-4) | Viscosity, kinematic 7.456 mm²/s Potential Adverse human health effects and symptoms: Based on available data, the classification criteria are not met |
| Periculos pentru mediul acvatic, pe termen scurt (acut) | Not classified |
| Periculos pentru mediul acvatic, pe termen lung (cronic) | Toxic to aquatic life with long lasting effects. |
| Substanță | Date ecologice |
|---|---|
| Benzyl benzoate (120-51-4) | |
| LC50 - Fish [1] | 2.32 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) |
| NOEC (chronic) | 0.168 mg/l |
| Aldehyde C-16 (77-83-8) | |
| LC50 - Fish [1] | 4.2 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [semi-static] Source: ECHA) |
| Hexamethylindanopyran (1222-05-5) | |
| LC50 - Fish [1] | 0.452 mg/l Wolf, 1996d-27682 |
| LC50 - Other aquatic organisms [1] | > 0.14 mg/l REACH DOSSIER Pimephales promelas |
| EC50 - Crustacea [2] | 260 μg/l REACH Dossier |
| EC50 - Other aquatic organisms [1] | 0.131 mg/l REACH Dossier |
| Benzyl alcohol (100-51-6) | |
| LC50 - Fish [1] | 460 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static] Source: EPA) |
| LC50 - Fish [2] | 10 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static] Source: EPA) |
| EC50 - Crustacea [1] | 23 mg/l (Exposure time: 48 h - Species: water flea) |
| Benzaldehyde (100-52-7) | |
| LC50 - Fish [1] | 10.6 – 11.8 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through] Source: EPA) |
| LC50 - Fish [2] | 12.69 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static] Source: IUCLID) |
| Ethyl acetoacetate (141-97-9) | |
| LC50 - Fish [1] | 298 mg/l (Exposure time: 96 h - Species: Pimephales promelas Source: IUCLID) |
| LC50 - Fish [2] | 290 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss Source: IUCLID) |
| EC50 - Crustacea [1] | 646 mg/l (Exposure time: 48 h - Species: Daphnia magna) |
| EC50 72h - Algae [1] | > 500 mg/l (Species: Desmodesmus subspicatus) |
| MULLED WINE #EU16611F 25% | Persistence and degradability Not established. |
| Benzyl benzoate (120-51-4) | Persistence and degradability May cause long-term adverse effects in the environment. |
| MULLED WINE #EU16611F 25% | Bioaccumulative potential Not established. |
| Benzyl benzoate (120-51-4) | Partition coefficient n-octanol/water (Log Pow) 3.97 (at 25 °C) Bioaccumulative potential Not established. |
| Aldehyde C-16 (77-83-8) | Partition coefficient n-octanol/water (Log Pow) 2.4 (at 25 °C (cis isomer) |
| methyl anthranilate (134-20-3) | Partition coefficient n-octanol/water (Log Pow) 2.17 (at 22 °C) |
| Dimethylbenzyl carbinyl acetate(DMBCA) (151-05-3) | Partition coefficient n-octanol/water (Log Pow) 3.64 (at 25 °C (at pH >6-<7) |
| Hexamethylindanopyran (1222-05-5) | BCF - Fish [1] (1618 dimensionless (whole body w.w.) Partition coefficient n-octanol/water (Log Pow) 5.3 (at 25 °C (at pH 7) |
| Benzyl acetate (140-11-4) | Partition coefficient n-octanol/water (Log Pow) 1.96 (at 25 °C (at pH 7) |
| Benzyl alcohol (100-51-6) | Partition coefficient n-octanol/water (Log Pow) 1.05 |
| Benzaldehyde (100-52-7) | BCF - Fish [1] (no significant bioaccumulation) Partition coefficient n-octanol/water (Log Pow) 1.4 (at 25 °C) |
| Ethyl acetoacetate (141-97-9) | Partition coefficient n-octanol/water (Log Pow) 0.8 (at 20 °C) |
No additional information available
No additional information available
Additional information: Avoid release to the environment.
| Recomandări privind eliminarea produsului/ambalajului | Dispose in a safe manner in accordance with local/national regulations. |
| Ecologie - materiale reziduale | Avoid release to the environment. |
| Cod HP | HP3 - “Flammable:” – flammable liquid waste: liquid waste having a flash point below 60 °C or waste gas oil, diesel and light heating oils having a flash point > 55 °C and ≤ 75 °C; – flammable pyrophoric liquid and solid waste: solid or liquid waste which, even in small quantities, is liable to ignite within five minutes after coming into contact with air; – flammable solid waste: solid waste which is readily combustible or may cause or contribute to fire through friction; – flammable gaseous waste: gaseous waste which is flammable in air at 20 °C and a standard pressure of 101.3 kPa; – water reactive waste: waste which, in contact with water, emits flammable gases in dangerous quantities; – other flammable waste: flammable aerosols, flammable self-heating waste, flammable organic peroxides and flammable self-reactive waste. HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment |
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|
| 14.1. UN number UN 3082 | UN 3082 | UN 3082 | UN 3082 | UN 3082 |
| 14.2. UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Hexamethylindanopyran) |
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Hexamethylindanopyran) | Environmentally hazardous substance, liquid, n.o.s. (Hexamethylindanopyran) | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Hexamethylindanopyran) | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Hexamethylindanopyran) |
| Transport document description UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Hexamethylindanopyran), 9, III, (-) | UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Hexamethylindanopyran), 9, III, MARINE POLLUTANT | UN 3082 Environmentally hazardous substance, liquid, n.o.s. (Hexamethylindanopyran), 9, III | UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Hexamethylindanopyran), 9, III | UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Hexamethylindanopyran), 9, III |
| 14.3. Transport hazard class(es) 9 | 9 | 9 | 9 | 9 |
| 14.4. Packing group III |