Fișă cu Date de Securitate
conform Regulamentului (CE) nr. 1907/2006 (REACH) cu modificarea sa prin Regulamentul (UE) 2020/878
Data emiterii: 9/25/2024 | Versiune: 1.0
Utilizări relevante identificate
Utilizări contraindicate
No additional information available
No additional information available
No additional information available
Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Textul complet al mențiunilor H și EUH: a se vedea secțiunea 16
Efecte fizico-chimice, asupra sănătății umane și asupra mediului
No additional information available
Etichetare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Not applicable
| Denumire | Identificator produs | % | Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP] |
|---|---|---|---|
| Dipropylene glycol monomethyl ether |
CAS-No.: 34590-94-8 EC-No.: 252-104-2 |
2.99 – 5.9848 | Not classified |
| Fir Needle oil, Siberian |
CAS-No.: 8021-29-2 EC-No.: 294-351-9 REACH-no: 01-2120738835-44 |
0.16 – 0.31499 |
Flam. Liq. 3, H226 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
Textul complet al mențiunilor H și EUH: a se vedea secțiunea 16
Măsuri generale de prim ajutor: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
După inhalare: Allow affected person to breathe fresh air. Allow the victim to rest.
După contactul cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
După contactul cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
După ingestie: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Simptome/efecte: Not expected to present a significant hazard under anticipated conditions of normal use.
No additional information available
Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
No additional information available
Instrucțiuni de stingere a incendiilor: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.
Protecție în timpul stingerii incendiilor: Do not enter fire area without proper protective equipment, including respiratory protection.
Pentru personalul care nu intervine în situații de urgență: Evacuate unnecessary personnel.
Pentru echipele de intervenție
Echipament de protecție: Equip cleanup crew with proper protection.
Proceduri de urgență: Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Metode de curățare: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Heading 8. Exposure controls and personal protection.
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor.
Condiții de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Produse incompatibile: Strong bases. Strong acids.
Materiale incompatibile: Sources of ignition. Direct sunlight.
Storage class (LK): LK 10/12 - Liquids
No additional information available
8.1.1 Valori-limită naționale de expunere profesională și valori biologice limită
| Substanță | Țară / Organizație | Limită | Observații |
|---|---|---|---|
| Dipropylene glycol monomethyl ether (34590-94-8) | EU - Indicative Occupational Exposure Limit (IOEL) | IOEL TWA 308 mg/m³ IOEL TWA 50 ppm | Possibility of significant uptake through the skin |
| Austria - Occupational Exposure Limits | MAK (OEL TWA) 307 mg/m³ (mixed isomers) MAK (OEL TWA) 50 ppm (mixed isomers) MAK (OEL STEL) 614 mg/m³ (isomers mixtures) MAK (OEL STEL) 100 ppm (isomers mixtures) | skin notation | |
| Belgium - Occupational Exposure Limits | OEL TWA 308 mg/m³ OEL TWA 50 ppm | Skin, skin notation | |
| Bulgaria - Occupational Exposure Limits | OEL TWA 308 mg/m³ OEL TWA 50 ppm | ||
| Croatia - Occupational Exposure Limits | GVI (OEL TWA) 308 mg/m³ GVI (OEL TWA) 50 ppm | skin notation | |
| Cyprus - Occupational Exposure Limits | OEL TWA 308 mg/m³ OEL TWA 50 ppm | Skin-potential for cutaneous absorption | |
| Czech Republic - Occupational Exposure Limits | PEL (OEL TWA) 270 mg/m³ | Potential for cutaneous absorption | |
| Denmark - Occupational Exposure Limits | OEL TWA 309 mg/m³ OEL TWA 50 ppm OEL STEL 618 mg/m³ OEL STEL 100 ppm | Potential for cutaneous absorption | |
| Estonia - Occupational Exposure Limits | OEL TWA 308 mg/m³ OEL TWA 50 ppm | skin notation | |
| Finland - Occupational Exposure Limits | HTP (OEL TWA) 310 mg/m³ HTP (OEL TWA) 50 ppm | Potential for cutaneous absorption | |
| France - Occupational Exposure Limits | VME (OEL TWA) 308 mg/m³ (restrictive limit) VME (OEL TWA) 50 ppm (restrictive limit) | Risk of cutaneous absorption | |
| Germany - Occupational Exposure Limits (TRGS 900) | AGW (OEL TWA) 310 mg/m³ (isomer mixture) AGW (OEL TWA) 50 ppm (isomer mixture) | ||
| Gibraltar - Occupational Exposure Limits | OEL TWA 308 mg/m³ OEL TWA 50 ppm | skin notation | |
| Greece - Occupational Exposure Limits | OEL TWA 600 mg/m³ OEL TWA 100 ppm OEL STEL 900 mg/m³ OEL STEL 150 ppm | skin - potential for cutaneous absorption | |
| Hungary - Occupational Exposure Limits | AK (OEL TWA) 308 mg/m³ | ||
| Ireland - Occupational Exposure Limits | OEL TWA 308 mg/m³ ((2-Methoxymethylethoxy)propanol) OEL TWA 50 ppm ((2-Methoxymethylethoxy)propanol) OEL STEL 924 mg/m³ (calculated (2-(2-Methoxypropoxy)-1-propanol) OEL STEL 150 ppm (calculated (2-(2-Methoxypropoxy)-1-propanol) | Potential for cutaneous absorption | |
| Italy - Occupational Exposure Limits | OEL TWA 308 mg/m³ (1-(3-Methoxypropoxy)propan-1-ol) OEL TWA 50 ppm (1-(3-Methoxypropoxy)propan-1-ol) | skin - potential for cutaneous absorption | |
| Latvia - Occupational Exposure Limits | OEL TWA 308 mg/m³ OEL TWA 50 ppm | skin - potential for cutaneous exposure | |
| Lithuania - Occupational Exposure Limits | IPRV (OEL TWA) 300 mg/m³ (2-(2-Methoxypropoxy)-propanol) IPRV (OEL TWA) 50 ppm (2-(2-Methoxypropoxy)-propanol) TPRV (OEL STEL) 450 mg/m³ (2-(2-Methoxypropoxy)-propanol) TPRV (OEL STEL) 75 ppm (2-(2-Methoxypropoxy)-propanol) | skin notation | |
| Luxembourg - Occupational Exposure Limits | OEL TWA 308 mg/m³ OEL TWA 50 ppm | Possibility of significant uptake through the skin | |
| Malta - Occupational Exposure Limits | OEL TWA 308 mg/m³ OEL TWA 50 ppm | Possibility of significant uptake through the skin | |
| Netherlands - Occupational Exposure Limits | TGG-8u (OEL TWA) 300 mg/m³ TGG-8u (OEL TWA) 48.7 ppm | ||
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 240 mg/m³ (mixture of isomers: 1-(2-Methoxy-1-methylethoxy)propan-2-ol, 1-(2-Methoxy-2-methylethoxy)propan-2-ol and 2-(2-Methoxy-1-methylethoxy)propan-1-ol) NDSCh (OEL STEL) 480 mg/m³ (mixture of isomers: 1-(2-Methoxy-1-methylethoxy)propan-2-ol, 1-(2-Methoxy-2-methylethoxy)propan-2-ol, 2-(2-Methoxy-1-methylethoxy)propan-1-ol) | ||
| Portugal - Occupational Exposure Limits | OEL TWA 308 mg/m³ (indicative limit value) OEL TWA 50 ppm (indicative limit value) OEL STEL 150 ppm | skin - potential for cutaneous exposure indicative limit value | |
| Romania - Occupational Exposure Limits | OEL TWA 308 mg/m³ OEL TWA 50 ppm | skin notation | |
| Slovakia - Occupational Exposure Limits | NPHV (OEL TWA) 308 mg/m³ NPHV (OEL TWA) 50 ppm | Potential for cutaneous absorption | |
| Slovenia - Occupational Exposure Limits | OEL TWA 308 mg/m³ OEL TWA 50 ppm OEL STEL 308 mg/m³ OEL STEL 50 ppm | Potential for cutaneous absorption | |
| Spain - Occupational Exposure Limits | VLA-ED (OEL TWA) 308 mg/m³ (indicative limit value) VLA-ED (OEL TWA) 50 ppm (indicative limit value) | skin - potential for cutaneous absorption | |
| Sweden - Occupational Exposure Limits | NGV (OEL TWA) 300 mg/m³ NGV (OEL TWA) 50 ppm KGV (OEL STEL) 450 mg/m³ KGV (OEL STEL) 75 ppm | skin notation | |
| United Kingdom - Occupational Exposure Limits | WEL TWA (OEL TWA) 308 mg/m³ WEL TWA (OEL TWA) 50 ppm WEL STEL (OEL STEL) 924 mg/m³ (calculated) WEL STEL (OEL STEL) 150 ppm (calculated) | Potential for cutaneous absorption | |
| Norway - Occupational Exposure Limits | Grenseverdi (OEL TWA) 300 mg/m³ Grenseverdi (OEL TWA) 50 ppm Korttidsverdi (OEL STEL) 375 mg/m³ (value calculated) Korttidsverdi (OEL STEL) 75 ppm (value calculated) | skin notation | |
| Switzerland - Occupational Exposure Limits | MAK (OEL TWA) 300 mg/m³ (aerosol, vapour) MAK (OEL TWA) 50 ppm (aerosol, vapour) KZGW (OEL STEL) 300 mg/m³ (aerosol, vapour) KZGW (OEL STEL) 50 ppm (aerosol, vapour) | ||
| USA - ACGIH - Occupational Exposure Limits | ACGIH OEL TWA 50 ppm (Dipropylene glycol methyl ether) |
8.1.2. Proceduri recomandate de monitorizare: No additional information available
8.1.3. Contaminanți ai aerului formați: No additional information available
8.1.4. DNEL și PNEC: No additional information available
8.1.5. Control banding: No additional information available
No additional information available
Echipament individual de protecție: Avoid all unnecessary exposure.
Simbol(uri) pentru echipamentul individual de protecție:
Protecția ochilor: Chemical goggles or safety glasses
Protecția mâinilor: Wear protective gloves.
Protecția respirației: Wear appropriate mask
No additional information available
Alte informații: Do not eat, drink or smoke during use.
9.2.1. Informații privind clasele de pericol fizic: No additional information available
9.2.2. Alte caracteristici de siguranță: No additional information available
10.1. Reactivitate: No additional information available
10.2. Stabilitate chimică: Not established.
10.3. Posibilitatea de reacții periculoase: Not established.
10.4. Condiții de evitat: Direct sunlight. Extremely high or low temperatures.
10.5. Materiale incompatibile: Strong acids. Strong bases.
10.6. Produși de descompunere periculoși: fume. Carbon monoxide. Carbon dioxide.
Toxicitate acută (orală): Not classified
Toxicitate acută (dermală): Not classified
Toxicitate acută (prin inhalare): Not classified
Dipropylene glycol monomethyl ether (34590-94-8)
LD50 oral rat 5.35 g/kg (Source: NLM_HSDB)
LD50 dermal rabbit 9500 mg/kg (Source: NLM_CIP)
Fir Needle oil, Siberian (8021-29-2)
LD50 oral rat 10200 mg/kg (Source: NLM_CIP)
Corodare/iritare cutanată: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Leziuni oculare grave/iritare oculară: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Sensibilizare respiratorie sau cutanată: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Mutagenitatea celulelor germinale: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Carcinogenitate: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Toxicitate pentru reproducere: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
STOT - expunere unică: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
STOT - expunere repetată: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Pericol prin aspirație: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
11.2.1. Proprietăți de perturbare endocrină: No additional information available
11.2.2. Alte informații
Potential Adverse human health effects and symptoms: Based on available data, the classification criteria are not met
Hazardous to the aquatic environment, short–term (acute): Not classified
Hazardous to the aquatic environment, long–term (chronic): Harmful to aquatic life with long lasting effects.
Dipropylene glycol monomethyl ether (34590-94-8)
LC50 - Fish [1] > 10000 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
EC50 - Crustacea [1] 1919 mg/l (Exposure time: 48 h - Species: Daphnia magna)
SIBERIAN FIR RD #EU44107F 10% in DPG: Persistence and degradability - Not established.
Dipropylene glycol monomethyl ether (34590-94-8): Persistence and degradability - Rapidly degradable
Fir Needle oil, Siberian (8021-29-2): Persistence and degradability - Rapidly degradable
SIBERIAN FIR RD #EU44107F 10% in DPG: Bioaccumulative potential - Not established.
Dipropylene glycol monomethyl ether (34590-94-8): Partition coefficient n-octanol/water (Log Pow) 0.35 (at 25 °C (at pH 7)
No additional information available
No additional information available
No additional information available
Informații suplimentare: Avoid release to the environment.
Recomandări pentru eliminarea produsului/ambalajului: Dispose in a safe manner in accordance with local/national regulations.
Informații ecologice: Avoid release to the environment.
Cod HP: HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
În conformitate cu ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID | |
|---|---|---|---|---|---|
| 14.1. Numărul ONU sau numărul de identificare | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.2. Denumirea corectă ONU pentru expediție | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.3. Clasa(clasele) de pericol pentru transport | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.4. Grupul de ambalare | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.5. Pericole pentru mediu | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
No supplementary information available
Transport rutier: Not applicable
Transport maritim: Not applicable
Transport aerian: Not applicable
Transport pe căi navigabile interioare: Not applicable
Transport feroviar: Not applicable
Not applicable
15.1.1. Regulamente UE
REACH Annex XVII (Restriction List)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(a) | Fir Needle oil, Siberian | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F |
| 3(b) | Fir Needle oil, Siberian | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | SIBERIAN FIR RD #EU44107F 10% in DPG ; Fir Needle oil, Siberian | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 |
| 40. | Fir Needle oil, Siberian | Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. |
REACH Annex XIV (Authorisation List): Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC): Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent): Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants): Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009): Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Council Regulation (EC) for the control of dual-use items: Contains substance subject to the COUNCIL REGULATION (EC) for the control of dual-use items
Explosives Precursors Regulation (2019/1148): Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004): Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
Franța
Professional diseases
Code: RG 84
Description: Conditions caused by liquid organic solvents for professional use: saturated or unsaturated aliphatic or cyclic liquid hydrocarbons and mixtures thereof; liquid halogenated hydrocarbons; nitrated derivatives of aliphatic hydrocarbons; alcohols; glycols, glycol ethers; ketones; aldehydes; aliphatic and cyclic ethers, including tetrahydrofuran; esters; dimethylformamide and dimethylacetamine; acetonitrile and propionitrile; pyridine; dimethylsulfone and dimethylsulfoxide
Germania
Water hazard class (WGK): WGK 2, significant hazardous to water (Classification according to AwSV, Annex 1).
Hazardous Incident Ordinance (12. BImSchV): Is not subject to the Hazardous Incident Ordinance (12. BImSchV)
Țările de Jos
ABM category: A(3) - hazardous for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen: Fir Needle oil, Siberian is listed
SZW-lijst van mutagene stoffen: None of the components are listed
SZW-lijst van reprotoxische stoffen – Borstvoeding: None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid: None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling: None of the components are listed
Danemarca
Classification remarks: Emergency management guidelines for the storage of flammable liquids must be followed
No chemical safety assessment has been carried out
Surse de date: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Alte informații: None.
Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment – Chronic Hazard Category 1
Asp. Tox. 1 Aspiration hazard Category 1
EUH208 Contains Fir Needle oil, Siberian. May produce an allergic reaction.
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Flam. Liq. 3