Forma produsului: Mixture
Numele produsului: SIBERIAN FIR RD #EU44107F 25% in DPG
Codul produsului: EU44107F_25%
Tipul produsului: Perfumes, Fragrances
Utilizări relevante identificate
Industrial/Professional use spec: Industrial
For professional use only
Use of the substance/mixture: Perfumes, Fragrances
Function or use category: Odour agents
No additional information available
No additional information available
No additional information available
Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Hazardous to the aquatic environment – Chronic Hazard Category 3
H412
Full text of H- and EUH-statements: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
Etichetare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Cuvânt de avertizare (CLP): -
Fraze de pericol (CLP): H412 - Harmful to aquatic life with long lasting effects.
Fraze de precauție (CLP): P273 - Avoid release to the environment.
P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Fraze EUH: EUH208 - Contains Fir Needle oil, Siberian, Vertenex, Linalyl acetate. May produce an allergic reaction.
Fraze suplimentare: Restricted to professional users.
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Not applicable
| Nume | Identificator produs | % | Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP] |
|---|---|---|---|
| Dipropylene glycol monomethyl ether | CAS-No.: 34590-94-8 EC-No.: 252-104-2 |
7.475 – 14.962 | Not classified |
| Fir Needle oil, Siberian | CAS-No.: 8021-29-2 EC-No.: 294-351-9 REACH-no: 01-2120738835-44 |
0.4 – 0.787475 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Vertenex | CAS-No.: 32210-23-4 EC-No.: 250-954-9 REACH-no: 01-2119976286-24 |
0.075 – 0.15 | Skin Sens. 1B, H317 |
| Linalyl acetate | CAS-No.: 115-95-7 EC-No.: 204-116-4 REACH-no: 01-2119454789-19 |
0.075 – 0.125 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB) | CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 |
0.075 – 0.125 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
Full text of H- and EUH-statements: see section 16
First-aid measures general: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation: Allow affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
First-aid measures after eye contact: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
First-aid measures after ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
No additional information available
Suitable extinguishing media: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media: Do not use a heavy water stream.
No additional information available
Firefighting instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
For non-emergency personnel: Evacuate unnecessary personnel.
For emergency responders: Equip cleanup crew with proper protection. Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Heading 8. Exposure controls and personal protection.
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor.
Storage conditions: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Incompatible products: Strong bases. Strong acids.
Incompatible materials: Sources of ignition. Direct sunlight.
Germany
Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids
| Joint storage not permitted for | LGK 1, LGK 6.2, LGK 7 |
| Joint storage with restrictions permitted for | LGK 4.1A, LGK 4.3, LGK 5.1C |
| Joint storage permitted for | LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13 |
Switzerland
Storage class (LK): LK 10/12 - Liquids
No additional information available
Dipropylene glycol monomethyl ether (34590-94-8)
| EU - Indicative Occupational Exposure Limit (IOEL) | IOEL TWA 308 mg/m³ 50 ppm Remark: Possibility of significant uptake through the skin |
| Austria - Occupational Exposure Limits | MAK (OEL TWA) 307 mg/m³ (mixed isomers) 50 ppm (mixed isomers) MAK (OEL STEL) 614 mg/m³ (isomers mixtures) 100 ppm (isomers mixtures) OEL chemical category skin notation |
| Belgium - Occupational Exposure Limits | OEL TWA 308 mg/m³ 50 ppm OEL chemical category Skin, skin notation |
| Bulgaria - Occupational Exposure Limits | OEL TWA 308 mg/m³ 50 ppm |
| Croatia - Occupational Exposure Limits | GVI (OEL TWA) 308 mg/m³ 50 ppm OEL chemical category skin notation |
| Cyprus - Occupational Exposure Limits | OEL TWA 308 mg/m³ 50 ppm OEL chemical category Skin-potential for cutaneous absorption |
| Czech Republic - Occupational Exposure Limits | PEL (OEL TWA) 270 mg/m³ |
| Denmark - Occupational Exposure Limits | OEL TWA 309 mg/m³ 50 ppm OEL STEL 618 mg/m³ 100 ppm OEL chemical category Potential for cutaneous absorption |
| Estonia - Occupational Exposure Limits | OEL TWA 308 mg/m³ 50 ppm OEL chemical category skin notation |
| Finland - Occupational Exposure Limits | HTP (OEL TWA) 310 mg/m³ 50 ppm OEL chemical category Potential for cutaneous absorption |
| France - Occupational Exposure Limits | VME (OEL TWA) 308 mg/m³ (restrictive limit) 50 ppm (restrictive limit) OEL chemical category Risk of cutaneous absorption |
| Germany - Occupational Exposure Limits (TRGS 900) | AGW (OEL TWA) 310 mg/m³ (isomer mixture) 50 ppm (isomer mixture) |
| Gibraltar - Occupational Exposure Limits | OEL TWA 308 mg/m³ 50 ppm OEL chemical category skin notation |
| Greece - Occupational Exposure Limits | OEL TWA 600 mg/m³ 100 ppm OEL STEL 900 mg/m³ 150 ppm OEL chemical category skin - potential for cutaneous absorption |
| Hungary - Occupational Exposure Limits | AK (OEL TWA) 308 mg/m³ |
| Ireland - Occupational Exposure Limits | OEL TWA 308 mg/m³ ((2-Methoxymethylethoxy)propanol) 50 ppm ((2-Methoxymethylethoxy)propanol) OEL STEL 924 mg/m³ (calculated (2-(2-Methoxypropoxy)-1-propanol) 150 ppm (calculated (2-(2-Methoxypropoxy)-1-propanol) |
| Italy - Occupational Exposure Limits | OEL TWA 308 mg/m³ (1-(3-Methoxypropoxy)propan-1-ol) 50 ppm (1-(3-Methoxypropoxy)propan-1-ol) OEL chemical category skin - potential for cutaneous absorption |
| Latvia - Occupational Exposure Limits | OEL TWA 308 mg/m³ 50 ppm OEL chemical category skin - potential for cutaneous exposure |
| Lithuania - Occupational Exposure Limits | IPRV (OEL TWA) 300 mg/m³ (2-(2-Methoxypropoxy)-propanol) 50 ppm (2-(2-Methoxypropoxy)-propanol) TPRV (OEL STEL) 450 mg/m³ (2-(2-Methoxypropoxy)-propanol) 75 ppm (2-(2-Methoxypropoxy)-propanol) OEL chemical category skin notation |
| Luxembourg - Occupational Exposure Limits | OEL TWA 308 mg/m³ 50 ppm OEL chemical category Possibility of significant uptake through the skin |
| Malta - Occupational Exposure Limits | OEL TWA 308 mg/m³ 50 ppm OEL chemical category Possibility of significant uptake through the skin |
| Netherlands - Occupational Exposure Limits | TGG-8u (OEL TWA) 300 mg/m³ 48.7 ppm |
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 240 mg/m³ (mixture of isomers: 1-(2-Methoxy-1-methylethoxy)propan-2-ol, 1-(2-Methoxy-2-methylethoxy)propan-2-ol and 2-(2-Methoxy-1-methylethoxy)propan-1-ol) NDSCh (OEL STEL) 480 mg/m³ (mixture of isomers: 1-(2-Methoxy-1-methylethoxy)propan-2-ol, 1-(2-Methoxy-2-methylethoxy)propan-2-ol, 2-(2-Methoxy-1-methylethoxy)propan-1-ol) |
| Portugal - Occupational Exposure Limits | OEL TWA 308 mg/m³ (indicative limit value) 50 ppm (indicative limit value) OEL STEL 150 ppm OEL chemical category skin - potential for cutaneous exposure indicative limit value |
| Romania - Occupational Exposure Limits | OEL TWA 308 mg/m³ 50 ppm OEL chemical category skin notation |
| Slovakia - Occupational Exposure Limits | NPHV (OEL TWA) 308 mg/m³ 50 ppm OEL chemical category Potential for cutaneous absorption |
| Slovenia - Occupational Exposure Limits | OEL TWA 308 mg/m³ 50 ppm OEL STEL 308 mg/m³ 50 ppm OEL chemical category Potential for cutaneous absorption |
| Spain - Occupational Exposure Limits | VLA-ED (OEL TWA) 308 mg/m³ (indicative limit value) 50 ppm (indicative limit value) OEL chemical category skin - potential for cutaneous absorption |
| Sweden - Occupational Exposure Limits | NGV (OEL TWA) 300 mg/m³ 50 ppm KGV (OEL STEL) 450 mg/m³ 75 ppm OEL chemical category skin notation |
| United Kingdom - Occupational Exposure Limits | WEL TWA (OEL TWA) 308 mg/m³ 50 ppm WEL STEL (OEL STEL) 924 mg/m³ (calculated) 150 ppm (calculated) WEL chemical category Potential for cutaneous absorption |
| Norway - Occupational Exposure Limits | Grenseverdi (OEL TWA) 300 mg/m³ 50 ppm Korttidsverdi (OEL STEL) 375 mg/m³ (value calculated) 75 ppm (value calculated) OEL chemical category skin notation |
| Switzerland - Occupational Exposure Limits | MAK (OEL TWA) 300 mg/m³ (aerosol, vapour) 50 ppm (aerosol, vapour) KZGW (OEL STEL) 300 mg/m³ (aerosol, vapour) 50 ppm (aerosol, vapour) |
| USA - ACGIH - Occupational Exposure Limits | ACGIH OEL TWA 50 ppm (Dipropylene glycol methyl ether) |
No additional information available
No additional information available
No additional information available
No additional information available
No additional information available
Personal protective equipment: Avoid all unnecessary exposure.
Personal protective equipment symbol(s):
Eye protection: Chemical goggles or safety glasses
Hand protection: Wear protective gloves.
Respiratory protection: Wear appropriate mask
No additional information available
Other information: Do not eat, drink or smoke during use.
| Physical state | Liquid |
| Color | Conforms to standard. |
| Odor | characteristic. |
| Odor threshold | Not available |
| Melting point | Not available |
| Freezing point | Not available |
| Boiling point | Not available |
| Flammability | Non flammable. |
| Lower explosion limit | Not available |
| Upper explosion limit | Not available |
| Flash point | > 93 °C |
| Auto-ignition temperature | Not available |
| Decomposition temperature | Not available |
| pH | Not available |
| Viscosity, kinematic | Not available |
| Solubility | Not available |
| Partition coefficient n-octanol/water (Log Kow) | Not available |
| Vapor pressure | Not available |
| Vapor pressure at 50°C | Not available |
| Density | Not available |
| Relative density | Not available |
| Relative vapor density at 20°C | Not available |
| Particle characteristics | Not applicable |
No additional information available
No additional information available
No additional information available
Not established.
Not established.
Direct sunlight. Extremely high or low temperatures.
Strong acids. Strong bases.
fume. Carbon monoxide. Carbon dioxide.
Acute toxicity (oral): Not classified
Acute toxicity (dermal): Not classified
Acute toxicity (inhalation): Not classified
| Dipropylene glycol monomethyl ether (34590-94-8) | LD50 oral rat 5.35 g/kg (Source: NLM_HSDB) LD50 dermal rabbit 9500 mg/kg (Source: NLM_CIP) |
| Fir Needle oil, Siberian (8021-29-2) | LD50 oral rat 10200 mg/kg (Source: NLM_CIP) |
| Vertenex (32210-23-4) | LD50 oral rat 5 g/kg (Source: NLM_CIP) |
| Vertenex (32210-23-4) | LD50 oral 3370 mg/kg body weight LD50 dermal rabbit > 5000 mg/kg (Source: CHEMVIEW) |
| Linalyl acetate (115-95-7) | LD50 oral rat 14550 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: ECHA) LC50 Inhalation - Rat > 18.94 mg/l (Exposure time: 8 h Source: ECHA) |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB) (1222-05-5) | LD50 oral rat > 3250 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 3250 mg/kg (Source: CHEMVIEW) LC50 Inhalation - Rat > 5.04 mg/l/4h |
Skin corrosion/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Serious eye damage/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Respiratory or skin sensitization: Not classified
Additional information: Based on available data, the classification criteria are not met
Germ cell mutagenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Carcinogenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Reproductive toxicity: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-single exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-repeated exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
Aspiration hazard: Not classified
Additional information: Based on available data, the classification criteria are not met
No additional information available
Potential Adverse human health effects and symptoms: Based on available data, the classification criteria are not met
Hazardous to the aquatic environment, short-term (acute): Not classified
Hazardous to the aquatic environment, long-term (chronic): Harmful to aquatic life with long lasting effects.
| Dipropylene glycol monomethyl ether (34590-94-8) | LC50 - Fish [1] > 10000 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) EC50 - Crustacea [1] 1919 mg/l (Exposure time: 48 h - Species: Daphnia magna) |
| Vertenex (32210-23-4) | LC50 - Fish [1] 8.6 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [semi-static] Source: ECHA) |
| Linalyl acetate (115-95-7) | LC50 - Fish [1] 11 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [flow-through] Source: ECHA) |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB) (1222-05-5) | LC50 - Fish [1] 0.452 mg/l Wolf, 1996d-27682 LC50 - Other aquatic organisms [1] > 0.14 mg/l REACH DOSSIER Pimephales promelas EC50 - Crustacea [2] 260 μg/l REACH Dossier EC50 - Other aquatic organisms [1] 0.131 mg/l REACH Dossier |
SIBERIAN FIR RD #EU44107F 25% in DPG
Persistence and degradability Not established.
Dipropylene glycol monomethyl ether (34590-94-8)
Persistence and degradability Rapidly degradable
Fir Needle oil, Siberian (8021-29-2)
Persistence and degradability Rapidly degradable
Vertenex (32210-23-4)
Persistence and degradability Rapidly degradable
Linalyl acetate (115-95-7)
Persistence and degradability Rapidly degradable
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB) (1222-05-5)
Persistence and degradability Rapidly degradable
SIBERIAN FIR RD #EU44107F 25% in DPG
Bioaccumulative potential Not established.
Dipropylene glycol monomethyl ether (34590-94-8)
Partition coefficient n-octanol/water (Log Pow) 0.35 (at 25 °C (at pH 7)
Vertenex (32210-23-4)
Partition coefficient n-octanol/water (Log Pow) 4.8 (at 25 °C)
Linalyl acetate (115-95-7)
Partition coefficient n-octanol/water (Log Pow) 3.9 (at 25 °C)
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB) (1222-05-5)
BCF - Fish [1] (1618 dimensionless (whole body w.w.)
Partition coefficient n-octanol/water (Log Pow) 5.3 (at 25 °C (at pH 7)
No additional information available
No additional information available
No additional information available
Additional information: Avoid release to the environment.
Product/Packaging disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.
Ecological information: Avoid release to the environment.
HP code: HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|
| Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
No supplementary information available
Overland transport
Not applicable
Transport by sea
Not applicable
Air transport
Not applicable
Inland waterway transport
Not applicable
Rail transport
Not applicable
Not applicable
REACH Annex XVII (Restriction List)
EU restriction list (REACH Annex XVII)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(a) | Fir Needle oil, Siberian | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F |
| 3(b) | Fir Needle oil, Siberian ; Vertenex ; Linalyl acetate | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | SIBERIAN FIR RD #EU44107F 25% in DPG ; Fir Needle oil, Siberian ; 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB) | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 |
| 40. | Fir Needle oil, Siberian | Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. |
REACH Annex XIV (Authorisation List)
Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC)
Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent)
Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)</