FRANKINCENSE & MYRRH #EU25961F 25% in DPG
conform Regulamentului (CE) Nr. 1907/2006 (REACH) cu modificarea sa prin Regulamentul (UE) 2020/878
Data emiterii: 12/14/2023
Nu sunt disponibile informații suplimentare.
FRENCH COLOR & FRAGRANCE International GmbH
Mittlerer Weg 35
DE– 79424 Auggen
Germany
T 49-7631-931-8900
SDS@frenchcolor.com - www.frenchcolor.com
Emergency number : 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086
Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Skin sensitisation, Category 1 H317
Hazardous to the aquatic environment – Chronic Hazard, Category 2 H411
Textul complet al frazelor H și EUH: vedeți secțiunea 16
Efecte fizico-chimice, asupra sănătății umane și asupra mediului: Toxic to aquatic life with long lasting effects. May cause an allergic skin reaction.
Etichetare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Pictograme de pericol (CLP): GHS07 GHS09
Cuvânt de avertizare (CLP): Warning
Conține: Iso E Super; Clove Leaf Oil ; Eugenol; Linalyl acetate; Linalool; Grapefruit oil; Cinnamic aldehyde; beta-Caryophyllene; Methyl cinnamate; Eucalyptus oil; Helional; Patchouli oil
Fraze de pericol (CLP): H317 - May cause an allergic skin reaction. H411 - Toxic to aquatic life with long lasting effects.
Fraze de precauție (CLP): P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P321 - Specific treatment (see supplemental first aid instruction on this label).
Fraze suplimentare: For professional users only.
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Nu se aplică
| Denumire | Identificator produs | % | Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP] |
|---|---|---|---|
| Iso E Super | CAS-No.: 54464-57-2 EC-No.: 259-174-3 REACH-no: 01-2119489989-04 | 1.425 – 2.83 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 1, H410 |
| 1-[(2-tert-butyl)cyclohexyloxy]-2-butanol | CAS-No.: 139504-68-0 EC-No.: 412-300-2 EC Index-No.: 603-154-00-2 REACH-no: 01-0000015959-52 | 1.025 – 2.025 | Aquatic Chronic 2, H411 |
| Dihydromyrcenol | CAS-No.: 18479-58-8 EC-No.: 242-362-4 REACH-no: 01-2119457274-37 | 0.75 – 1.5 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 |
| Clove Leaf Oil | CAS-No.: 8000-34-8 EC-No.: 616-772-2 | 0.475 – 0.95 | Eye Irrit. 2, H319 Skin Sens. 1, H317 Asp. Tox. 1, H304 |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) | CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 | 0.45 – 0.8875 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Eugenol | CAS-No.: 97-53-0 EC-No.: 202-589-1 REACH-no: 01-2119971802-33 | 0.45 – 0.8875 | Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Linalyl acetate | CAS-No.: 115-95-7 EC-No.: 204-116-4 REACH-no: 01-2119454789-19 | 0.375 – 0.725 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Linalool | CAS-No.: 78-70-6 EC-No.: 201-134-4 EC Index-No.: 603-235-00-2 REACH-no: 01-2119474016-42 | 0.325 – 0.625375 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Grapefruit oil | CAS-No.: 8016-20-4 EC-No.: 600-007-4 | 0.25 – 0.5125 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| Cinnamic aldehyde | CAS-No.: 104-55-2 EC-No.: 203-213-9 REACH-no: 01-2119935242-45 | 0.225 – 0.4375 | Acute Tox. 4 (Dermal), H312 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1A, H317 Aquatic Chronic 3, H412 |
| beta-Caryophyllene | CAS-No.: 87-44-5 EC-No.: 201-746-1 REACH-no: 01-2120745237-53 | 0.225 – 0.4375 | Skin Sens. 1B, H317 Asp. Tox. 1, H304 |
| Cedarwood oil, Texas | CAS-No.: 68990-83-0 EC-No.: 294-461-7 | 0.15 – 0.2875 | Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Methyl cinnamate | CAS-No.: 103-26-4 EC-No.: 203-093-8 REACH-no: 01-2119979458-16 | 0.1 – 0.175 | Skin Sens. 1B, H317 |
| Eucalyptus oil | CAS-No.: 8000-48-4 EC-No.: 283-406-2 REACH-no: 01-2119978250-37 | 0.075 – 0.125 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| Helional | CAS-No.: 1205-17-0 EC-No.: 214-881-6 REACH-no: 01-2120740119-58 | 0.05 – 0.1 | Skin Sens. 1B, H317 Repr. 2, H361 Aquatic Chronic 2, H411 |
| Patchouli oil | CAS-No.: 8014-09-3 EC Index-No.: 616-944-7 | 0.05 – 0.1 | Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| citral substance with national workplace exposure limit(s) (BE, ES, IE, PL, PT) | CAS-No.: 5392-40-5 EC-No.: 226-394-6 EC Index-No.: 605-019-00-3 REACH-no: 01-2119462829-23 | 0.025 – 0.05 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| .alpha.-Pinene substance with national workplace exposure limit(s) (BE, EE, ES, LT, PT, SE, NO) | CAS-No.: 80-56-8 EC-No.: 201-291-9 | 0.0025 – 0.009375 | Flam. Liq. 3, H226 |
| .beta.-Pinene substance with national workplace exposure limit(s) (BE, EE, ES, LT, PT, SE, NO) | CAS-No.: 127-91-3 EC-No.: 204-872-5 | 0.00125 – 0.0375 | Flam. Liq. 3, H226 |
| (R)-p-mentha-1,8-diene; d-limonene substance with national workplace exposure limit(s) (DE, ES, FI, SI, NO, CH) | CAS-No.: 5989-27-5 EC-No.: 205-341-0 EC Index-No.: 601-096-00-2 REACH-no: 01-2119493353-35 | 0.000625 – 0.015 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 |
| p-Cymene substance with national workplace exposure limit(s) (DK, EE, LT, LV, SE) | CAS-No.: 99-87-6 EC-No.: 202-796-7 EC Index-No.: 601-094-00-1 | 0.000125 – 0.0075 | Flam. Liq. 3, H226 Acute Tox. 3 (Inhalation), H331 Acute Tox. 3 (Inhalation:dust,mist), H331 Repr. 2, H361 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
Măsuri generale de prim ajutor: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
După inhalare: Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest.
După contactul cu pielea: Wash with plenty of water/…. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this label). Wash contaminated clothing before reuse. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention.
După contactul cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. Rinse eyes with water as a precaution.
După înghițire: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center or a doctor if you feel unwell.
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
Symptoms/effects after inhalation: May cause an allergic skin reaction.
Symptoms/effects after skin contact: May cause an allergic skin reaction.
Tratament simptomatic.
Mijloace de stingere corespunzătoare: Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Mijloace de stingere necorespunzătoare: Do not use a heavy water stream.
Produse periculoase de descompunere în caz de incendiu: Toxic fumes may be released.
Instrucțiuni de stingere a incendiului: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protecție în timpul intervenției: Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.
6.1.1. Pentru personalul care nu face parte din serviciile de urgență
Proceduri de urgență: Ventilate spillage area. Evacuate unnecessary personnel. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.
6.1.2. Pentru echipele de intervenție
Echipament de protecție: Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection".
Proceduri de urgență: Ventilate area.
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Pentru izolare: Collect spillage.
Metode de curățare: Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Alte informații: Dispose of materials or solid residues at an authorized site.
See Section 8. Exposure controls and personal protection. For further information refer to section 13.
Precauții pentru manipulare în siguranță: Ensure good ventilation of the work station. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear personal protective equipment.
Măsuri de igienă: Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product.
Condiții de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Store in a well-ventilated place. Keep cool.
Produse incompatibile: Strong bases. Strong acids.
Materiale incompatibile: Sources of ignition. Direct sunlight.
Temperatura de depozitare: 25 °C
Zona de depozitare: Store in a well-ventilated place. Store away from heat.
Reguli speciale privind ambalarea: Store in a closed container.
Materiale de ambalare: Do not store in corrodable metal.
Nu sunt disponibile informații suplimentare.
8.1.1 Limite naționale de expunere ocupațională și limite biologice
Tabelele cu limitele de expunere sunt păstrate în ordinea originală și includ doar valorile din documentul sursă.
Notă: Conținutul detaliat al valorilor naționale de expunere este menținut în tabelul documentului original; aici sunt prezentate valorile și denumirile fără a traduce identificatorii chimici sau codurile.
| Substanță | Țară / organism | Valoare | Observații |
|---|---|---|---|
| citral (5392-40-5) | Belgium - Occupational Exposure Limits | OEL TWA 32 mg/m³ | vapor and aerosol; OEL TWA 5 ppm; OEL chemical category Skin |
| citral (5392-40-5) | Ireland - Occupational Exposure Limits | OEL TWA [2] 5 ppm | OEL STEL 15 ppm (calculated) |
| citral (5392-40-5) | Poland - Occupational Exposure Limits | NDS (OEL TWA) 27 mg/m³ | NDSCh (OEL STEL) 54 mg/m³ |
| citral (5392-40-5) | Portugal - Occupational Exposure Limits | OEL TWA 5 ppm | inhalable fraction; vapor; OEL chemical category Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen, skin - potential for cutaneous exposure |
| citral (5392-40-5) | Spain - Occupational Exposure Limits | VLA-ED (OEL TWA) [2] 5 ppm | inhalable fraction and vapor; OEL chemical category Sensitizer, skin - potential for cutaneous absorption |
| citral (5392-40-5) | USA - ACGIH - Occupational Exposure Limits | ACGIH OEL TWA [ppm] 5 ppm | inhalable fraction and vapor; Not Classifiable as a Human Carcinogen, Skin - potential significant contribution to overall exposure by the cutaneous route, dermal sensitizer |
8.1.2. Proceduri recomandate de monitorizare: No additional information available
8.1.3. Contaminanți aerieni formați: No additional information available
8.1.4. DNEL and PNEC: No additional information available
8.1.5. Control banding: No additional information available
8.2.1. Controale tehnice corespunzătoare: Ensure good ventilation of the work station.
8.2.2. Echipament de protecție personală: Avoid all unnecessary exposure.
8.2.2.1. Protecția ochilor și a feței: Chemical goggles or safety glasses. Safety glasses
8.2.2.2. Protecția pielii: Wear suitable protective clothing
Protecția mâinilor: Wear protective gloves.
8.2.2.3. Protecția respiratorie: Wear appropriate mask
8.2.2.4. Riscuri termice: No additional information available
8.2.3. Controale ale expunerii asupra mediului: Avoid release to the environment.
Alte informații: Do not eat, drink or smoke during use.
9.2.1. Informații privind clasele de pericol fizic: No additional information available
9.2.2. Alte caracteristici de siguranță: No additional information available
10.1. Reactivitate: The product is non-reactive under normal conditions of use, storage and transport.
10.2. Stabilitate chimică: Not established.
10.3. Posibilitatea de reacții periculoase: Not established.
10.4. Condiții de evitat: Direct sunlight. Extremely high or low temperatures.
10.5. Materiale incompatibile: Strong acids. Strong bases.
10.6. Produși de descompunere periculoși: fume. Carbon monoxide. Carbon dioxide.
11.1. Informații privind clasele de pericol definite în Regulamentul (CE) Nr. 1272/2008
Toxicitate acută (oral): Not classified
Toxicitate acută (dermic): Not classified
Toxicitate acută (inhalare): Not classified
| Substanță | Date toxicologice |
|---|---|
| 1-[(2-tert-butyl)cyclohexyloxy]-2-butanol (139504-68-0) | LD50 dermal rat > 2000 mg/kg (Source: ECHA_API) |
| Dihydromyrcenol (18479-58-8) | LD50 oral rat 3600 mg/kg (Source: NLM_CIP) LD50 oral 3600 mg/kg bodyweight LD50 dermal rabbit > 5 g/kg (Source: CHEMVIEW) |
| Clove Leaf Oil (8000-34-8) | LD50 oral rat 1370 mg/kg (Source: NZ_CCID) LD50 oral 2650 mg/kg bodyweight LD50 dermal rabbit 1200 mg/kg (Source: NLM_CIP) LD50 dermal 2500 mg/kg bodyweight |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5) | LD50 oral rat > 3250 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 3250 mg/kg (Source: CHEMVIEW) |
| Eugenol (97-53-0) | LD50 oral rat 1930 mg/kg (Source: NZ_CCID) LD50 oral 2500 mg/kg bodyweight |
| Linalyl acetate (115-95-7) | LD50 oral rat 14550 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: EPA_HPV) |
| Linalool (78-70-6) | LD50 oral 2790 mg/kg bodyweight |
| Grapefruit oil (8016-20-4) | LD50 oral rat > 5 g/kg (Source: NLM_CIP) |
| Cinnamic aldehyde (104-55-2) | LD50 oral rat 2220 mg/kg (Source: NLM_CIP) LD50 oral 2200 mg/kg bodyweight LD50 dermal rabbit 1260 mg/kg (Source: EPA_HPV) LD50 dermal 1100 mg/kg bodyweight |
| Methyl cinnamate (103-26-4) | LD50 oral rat 2610 mg/kg (Source: NLM_CIP) LD50 oral 2610 mg/kg bodyweight LD50 dermal rabbit > 5000 mg/kg (Source: ECHA_API) |
| Eucalyptus oil (8000-48-4) | LD50 oral rat 2480 mg/kg (Source: NLM_CIP) |
| Helional (1205-17-0) | LD50 dermal rabbit > 2000 mg/kg (Source: ECHA_API) |
| Patchouli oil (8014-09-3) | LD50 oral rat > 5 g/kg (Source: NLM_CIP) |
| citral (5392-40-5) | LD50 oral rat 4960 mg/kg (Source: NLM_CIP) LD50 dermal rabbit 2250 mg/kg (Source: NLM_CIP) |
| .alpha.-Pinene (80-56-8) | LD50 oral rat 3700 mg/kg (Source: NLM_CIP) LD50 oral 500 mg/kg bodyweight LD50 dermal rat > 5000 mg/kg (Source: CHEMVIEW) |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | LD50 oral rat 4400 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 5 g/kg (Source: CHEMVIEW) |
| .beta.-Pinene (127-91-3) | LD50 oral rat > 5000 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: CHEMVIEW) |
| p-Cymene (99-87-6) | LD50 oral rat 4750 mg/kg (Source: NLM_CIP) LD50 oral 4750 mg/kg bodyweight LD50 dermal rabbit > 5000 mg/kg (Source: CHEMVIEW) LC50 Inhalation - Rat > 9.7 mg/l (Exposure time: 5 h Source: EU_CLH) LC50 Inhalation - Rat (Vapours) 9.7 mg/l/4h |
Corodarea/iritarea pielii: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Leziuni/iritare oculară gravă: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Sensibilizare respiratorie sau cutanată: May cause an allergic skin reaction.
Informații suplimentare: Based on available data, the classification criteria are not met
Mutagenicitate pentru celulele germinale: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Carcinogenicitate: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Eugenol (97-53-0)
IARC group 3 - Not classifiable
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)
IARC group 3 - Not classifiable
Toxicitate pentru reproducere: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
STOT-single exposure: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
STOT-repeated exposure: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Pericol prin aspirare: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
11.2. Informații privind alte pericole
11.2.1. Proprietăți de perturbare endocrină: No additional information available
11.2.2. Alte informații: Potential adverse human health effects and symptoms : Based on available data, the classification criteria are not met
Ecology - general: Toxic to aquatic life with long lasting effects.
Ecology - water: Toxic to aquatic life with long lasting effects.
Hazardous to the aquatic environment, short-term (acute): Not classified
Hazardous to the aquatic environment, long-term (chronic): Toxic to aquatic life with long lasting effects.
FRANKINCENSE & MYRRH #EU25961F 25% in DPG
Persistence and degradability May cause long-term adverse effects in the environment. Not established.
Cedarwood oil, Texas (68990-83-0)
Persistence and degradability Not established.
Methyl cinnamate (103-26-4)
Persistence and degradability Not established.
Eucalyptus oil (8000-48-4)
Persistence and degradability Not established.
FRANKINCENSE & MYRRH #EU25961F 25% in DPG
Bioaccumulative potential Not established.
1-[(2-tert-butyl)cyclohexyloxy]-2-butanol (139504-68-0)
BCF - Fish [1] (173 dimensionless)
Dihydromyrcenol (18479-58-8)
Partition coefficient n-octanol/water (Log Pow) 3.25 (at 40 °C (at pH 7)
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5)
BCF - Fish [1] (1618 dimensionless (whole body w.w.)
Partition coefficient n-octanol/water (Log Pow) 5.3 (at 25 °C (at pH 7)
Eugenol (97-53-0)
Partition coefficient n-octanol/water (Log Pow) 1.83 (at 30 °C (at pH 5.5)
Linalyl acetate (115-95-7)
Partition coefficient n-octanol/water (Log Pow) 3.9 (at 25 °C)
Cinnamic aldehyde (104-55-2)
Partition coefficient n-octanol/water (Log Pow) 2.1065 (at 25 °C)
beta-Caryophyllene (87-44-5)
Partition coefficient n-octanol/water (Log Pow) 6.23 (at 25 °C (at pH 7)
Cedarwood oil, Texas (68990-83-0)
Bioaccumulative potential Not established.
Methyl cinnamate (103-26-4)
Partition coefficient n-octanol/water (Log Pow) 2.68 (at 25 °C (at pH >4.73-<7.06)
Bioaccumulative potential Not established.
Eucalyptus oil (8000-48-4)
Bioaccumulative potential Not established.
Helional (1205-17-0)
Partition coefficient n-octanol/water (Log Pow) 2.4 (at 25 °C)
citral (5392-40-5)
Partition coefficient n-octanol/water (Log Pow) 2.76 (at 25 °C)
.alpha.-Pinene (80-56-8)
Partition coefficient n-octanol/water (Log Pow) 4.1
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)
Partition coefficient n-octanol/water (Log Pow) 4.38 (at 37 °C (at pH 7.2)
p-Cymene (99-87-6)
Partition coefficient n-octanol/water (Log Kow) 4.8 (at 20 °C (at p