Fişă cu date de securitate, conform Regulamentului (CE) nr. 1907/2006 (REACH) cu modificarea prin Regulamentul (UE) 2020/878
Forma produsului: Mixture
Numele produsului: FRESH CUT PEONY #EU41821F 5%
Cod produs: EU41821F_5%
Tip de produs: Perfumes, fragrances
1.2.1. Utilizări relevante identificate
Spec. de utilizare industrială/profesională: Industrial
For professional use only
Utilizarea substanţei/amestecului: Perfumes, fragrances
Categoria funcţiei sau de utilizare: Odour agents
1.2.2. Utilizări contraindicate
No additional information available
No additional information available
No additional information available
Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Hazardous to the aquatic environment – Chronic Hazard, Category 3 H412
Full text of H- and EUH-statements: see section 16
Efecte fizico-chimice adverse, asupra sănătăţii umane şi asupra mediului
No additional information available
Etichetare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Cuvânt de avertizare (CLP): -
Fraze de pericol (CLP): H412 - Harmful to aquatic life with long lasting effects.
Fraze de precauţie (CLP): P273 - Avoid release to the environment.
P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Fraze EUH: EUH208 - Contains Hexyl cinnamic aldehyde, Linalyl acetate, Linalool, Vertenex, Geraniol, Benzyl salicylate, Iso E Super, Citronellol Pure. May produce an allergic reaction.
Fraze suplimentare: For professional users only.
Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
Not applicable
| Nume | Identificator produs | % | Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP] |
|---|---|---|---|
| Benzyl benzoate | CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33 |
0.79 – 1.584125 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Hexyl cinnamic aldehyde | CAS-No.: 101-86-0 EC-No.: 202-983-3 REACH-no: 01-2119533092-50 |
0.2 – 0.400005 | Skin Sens. 1, H317 Aquatic Chronic 2, H411 |
| Linalyl acetate | CAS-No.: 115-95-7 EC-No.: 204-116-4 REACH-no: 01-2119454789-19 |
0.135 – 0.267365 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Hexamethylindanopyran | CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 |
0.125 – 0.2525 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Linalool | CAS-No.: 78-70-6 EC-No.: 201-134-4 EC Index-No.: 603-235-00-2 REACH-no: 01-2119474016-42 |
0.1 – 0.2 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Vertenex | CAS-No.: 32210-23-4 EC-No.: 250-954-9 REACH-no: 01-2119976286-24 |
0.1 – 0.2 | Skin Sens. 1B, H317 |
| Geraniol | CAS-No.: 106-24-1 EC-No.: 203-377-1 EC Index-No.: 603-241-00-5 REACH-no: 01-2119552430-49 |
0.07 – 0.1425 | Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317 |
| Benzyl salicylate | CAS-No.: 118-58-1 EC-No.: 204-262-9 EC Index-No.: 607-754-00-5 REACH-no: 01-2119969442-31 |
0.07 – 0.135 | Eye Irrit. 2, H319 Skin Sens. 1B, H317 Aquatic Chronic 3, H412 |
| Iso E Super | CAS-No.: 54464-57-2 EC-No.: 259-174-3 REACH-no: 01-2119489989-04 |
0.07 – 0.135 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 1, H410 |
| Citronellol Pure | CAS-No.: 106-22-9 EC-No.: 203-375-0 REACH-no: 01-2119453995-23 |
0.065 – 0.13 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Ethyl acetoacetate | substance with national workplace exposure limit(s) (RO) CAS-No.: 141-97-9 EC-No.: 205-516-1 |
0.02 – 0.035 | Not classified |
| Benzyl acetate | substance with national workplace exposure limit(s) (BE, DK, ES, IE, LT, LV, PT, RO) REACH-no: 01-2119638272-42 CAS-No.: 140-11-4 EC-No.: 205-399-7 |
0.015 – 0.0275 | Aquatic Chronic 3, H412 |
| Carbitol | substance with national workplace exposure limit(s) (AT, DE, EE, SE, SI, CH) CAS-No.: 111-90-0 EC-No.: 203-919-7 REACH-no: 01-2119475105-42 |
0.007233 – 0.0108495 | Not classified |
| decyl alcohol | substance with national workplace exposure limit(s) (BG, DE, LT, LV, RO, CH) CAS-No.: 112-30-1 EC-No.: 203-956-9 |
0 – 0.00043 | Aquatic Chronic 3, H412 |
| Aldehyde C-6 | substance with national workplace exposure limit(s) (FI, PL) CAS-No.: 66-25-1 EC-No.: 200-624-5 |
0 – 0.000105 | Flam. Liq. 3, H226 |
| Caproic acid | substance with national workplace exposure limit(s) (BG, LT, LV) CAS-No.: 142-62-1 EC-No.: 205-550-7 |
0 – 0.000005 | Eye Dam. 1, H318 Skin Corr. 1C, H314 |
Full text of H- and EUH-statements: see section 16
Măsuri generale de prim ajutor: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
Măsuri de prim ajutor după inhalare: Allow affected person to breathe fresh air. Allow the victim to rest.
Măsuri de prim ajutor după contactul cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
Măsuri de prim ajutor după contactul cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
Măsuri de prim ajutor după ingerare: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Simptome/efecte: Not expected to present a significant hazard under anticipated conditions of normal use.
No additional information available
Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
No additional information available
Instrucţiuni de stingere a incendiilor: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protecţie în timpul intervenţiei: Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1. Pentru personalul care nu face parte din serviciile de urgenţă
Proceduri de urgenţă: Evacuate unnecessary personnel.
6.1.2. Pentru echipele de intervenţie
Echipament de protecţie: Equip cleanup crew with proper protection.
Proceduri de urgenţă: Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Metode de curăţare: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Section 8. Exposure controls and personal protection.
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
Condiţii de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Produse incompatibile: Strong bases. Strong acids.
Materiale incompatibile: Sources of ignition. Direct sunlight.
No additional information available
8.1.1. Valori limită naţionale de expunere profesională şi valori biologice limită
| Substanţă | Ţară / limite | Valori |
|---|---|---|
| Ethyl acetoacetate (141-97-9) | Romania - Occupational Exposure Limits | OEL TWA 100 mg/m³ OEL TWA [ppm] 19 ppm OEL STEL 200 mg/m³ OEL STEL [ppm] 38 ppm |
| Benzyl acetate (140-11-4) | Belgium - Occupational Exposure Limits | OEL TWA 62 mg/m³ OEL TWA [ppm] 10 ppm |
The document continues with national exposure limit tables for: Denmark, Ireland, Latvia, Lithuania, Portugal, Romania, Spain, USA - ACGIH, Austria, Estonia, Germany - Occupational Exposure Limits (TRGS 900), Slovenia, Sweden, Switzerland, Bulgaria, Finland, Poland.
8.1.2. Proceduri de monitorizare recomandate
No additional information available
8.1.3. Contaminanţi ai aerului formaţi
No additional information available
8.1.4. DNEL şi PNEC
No additional information available
8.1.5. Control banding
No additional information available
8.2.1. Controale tehnice adecvate
No additional information available
8.2.2. Echipament individual de protecţie
Echipament de protecţie personală: Avoid all unnecessary exposure.
Simbol(uri) pentru echipamentul individual de protecţie:
8.2.2.1. Protecţia ochilor şi a feţei
Protecţia ochilor: Chemical goggles or safety glasses
8.2.2.2. Protecţia pielii
Protecţia mâinilor: Wear protective gloves.
8.2.2.3. Protecţia respiraţiei
Protecţia respiraţiei: Wear appropriate mask
8.2.2.4. Pericole termice
No additional information available
Alte informaţii: Do not eat, drink or smoke during use.
| Stare fizică | Liquid |
|---|---|
| Culoare | Standard. |
| Miros | characteristic. |
| Pragul de miros | No data available |
| pH | No data available |
| Rata relativă de evaporare (butylacetate=1) | No data available |
| Punct de topire | No data available |
| Punct de congelare | No data available |
| Punct de fierbere | No data available |
| Punct de inflamabilitate | > 93 °C |
| Temperatura de autoaprindere | No data available |
| Temperatura de descompunere | No data available |
| Inflamabilitate (solid, gaz) | Non flammable. |
| Presiunea vaporilor | No data available |
| Densitatea relativă a vaporilor la 20°C | No data available |
| Densitate relativă | No data available |
| Solubilitate | No data available |
| Coeficient de partiţie n-octanol/apă (Log Pow) | No data available |
| Vâscozitate, cinematică | No data available |
| Vâscozitate, dinamică | No data available |
| Proprietăţi explozive | No data available |
| Proprietăţi oxidante | No data available |
| Limite explozive | No data available |
No additional information available
No additional information available
Not established.
Not established.
Direct sunlight. Extremely high or low temperatures.
Strong acids. Strong bases.
fume. Carbon monoxide. Carbon dioxide.
Toxicitate acută (orală): Not classified
Toxicitate acută (dermică): Not classified
Toxicitate acută (prin inhalare): Not classified
Numerous component-specific LD50/LC50 values follow in the source document and are preserved numerically in the original file.
Corodarea/iritarea pielii: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Lezarea gravă/iritarea ochilor: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Sensibilizarea respiratorie sau cutanată: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Mutagenitatea celulelor germinale: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Carcinogenicitate: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Benzyl acetate (140-11-4)
IARC group 3 - Not classifiable
Toxicitate reproductivă: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
STOT - expunere unică: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
STOT - expunere repetată: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Pericol prin aspirare: Not classified
Informaţii suplimentare: Based on available data, the classification criteria are not met
Benzyl benzoate (120-51-4)
Viscosity, kinematic 7.456 mm²/s
Efecte adverse potenţiale asupra sănătăţii umane şi simptome
Based on available data, the classification criteria are not met
Periculos pentru mediul acvatic, termen scurt (acut): Not classified
Periculos pentru mediul acvatic, termen lung (cronic): Harmful to aquatic life with long lasting effects.
| Substanţă | Date ecotoxicologice |
|---|---|
| Benzyl benzoate (120-51-4) | LC50 - Fish [1] 2.32 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) NOEC (chronic) 0.168 mg/l |
| Linalyl acetate (115-95-7) | LC50 - Fish [1] 11 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [flow-through] Source: ECHA) |
| Hexamethylindanopyran (1222-05-5) | LC50 - Fish [1] 0.452 mg/l Wolf, 1996d-27682 LC50 - Other aquatic organisms [1] > 0.14 mg/l REACH DOSSIER Pimephales promelas EC50 - Crustacea [2] 260 μg/l REACH Dossier EC50 - Other aquatic organisms [1] 0.131 mg/l REACH Dossier |
| Linalool (78-70-6) | EC50 96h - Algae [1] 88.3 mg/l (Species: Desmodesmus subspicatus) |
| Vertenex (32210-23-4) | LC50 - Fish [1] 8.6 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [semi-static] Source: ECHA) |
| Geraniol (106-24-1) | LC50 - Fish [1] 22 mg/l (Exposure time: 96 h - Species: Danio rerio [static] Source: ECHA) |
| Benzyl salicylate (118-58-1) | LC50 - Fish [1] 1.03 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) |
| Ethyl acetoacetate (141-97-9) | LC50 - Fish [1] 298 mg/l (Exposure time: 96 h - Species: Pimephales promelas Source: IUCLID) LC50 - Fish [2] 290 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss Source: IUCLID) EC50 - Crustacea [1] 646 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 72h - Algae [1] > 500 mg/l (Species: Desmodesmus subspicatus) |
| Carbitol (111-90-0) | LC50 - Fish [1] 10000 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static] Source: EPA) LC50 - Fish [2] 19100 – 23900 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [flow-through] Source: EPA) EC50 - Crustacea [1] 3940 – 4670 mg/l (Exposure time: 48 h - Species: Daphnia magna) |
| decyl alcohol (112-30-1) | LC50 - Fish [1] 2.2 – 2.5 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) LC50 - Fish [2] 4.12 – 6.2 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static] Source: EPA) EC50 - Crustacea [1] 3 mg/l (Exposure time: 48 h - Species: Daphnia magna) |
| Aldehyde C-6 (66-25-1) | LC50 - Fish [1] 12 – 16.5 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) |
| Caproic acid (142-62-1) | LC50 - Fish [1] 306 – 334 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) LC50 - Fish [2] 88 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static] Source: EPA) |
FRESH CUT PEONY #EU41821F 5%
Persistenţă şi degradabilitate: Not established.
Benzyl benzoate (120-51-4)
Persistenţă şi degradabilitate: May cause long-term adverse effects in the environment.
FRESH CUT PEONY #EU41821F 5%
Potenţial de bioacumulare: Not established.
Component Log Pow / BCF values are preserved numerically in the source document.
No additional information available
No additional information available
Informaţii suplimentare: Avoid release to the environment.
Recomandări pentru eliminarea produsului/ambalajului: Dispose in a safe manner in accordance with local/national regulations.
Ecologie - materiale reziduale: Avoid release to the environment.
Cod HP: HP3 - “Flammable:”
HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|
| Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
14.1. Numărul ONU
Not applicable
14.2. Denumirea corectă ONU pentru expediţie
Not applicable
14.3. Clasa (clasele) de pericol pentru transport
Not applicable
14.4. Grupul de ambalare
Not applicable
14.5. Pericole pentru mediu
Not applicable
No supplementary information available
Transport terestru: Not applicable
Transport maritim: Not applicable
Transport aerian: Not applicable
Transport pe căi navigabile interioare: Not applicable
Transport feroviar: Not applicable
Not applicable
15.1.1. Regulamente UE
REACH Annex XVII (Restriction List)
EU restriction list (REACH Annex XVII)
The detailed restriction entries are preserved as in the source, including reference codes and substance associations.
REACH Annex XIV (Authorisation List)
Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC)
Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent)
Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants)
Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009)
Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Explosives Precursors Regulation (2019/1148)
Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004)
Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
Germany
Water hazard class (WGK): WGK 1, Slightly hazardous to water (Classification according to AwSV, Annex 1).
Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids.
Joint storage table: Joint storage not permitted for : LGK 1, LGK 6.2, LGK 7.
Joint storage with restrictions permitted for : LGK 4.1A, LGK 4.3, LGK 5.1C.
Joint storage permitted for : LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13.
Hazardous Incident Ordinance (12. BImSchV): Is not subject of the Hazardous Incident Ordinance (12. BImSchV)
Netherlands
ABM category: A(3) - hazardous for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
SZW-lijst van reprotoxische stoffen – Borstvoeding : None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid : None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling : None of the components are listed
Denmark
Classification remarks: Emergency management guidelines for the storage of flammable liquids must be followed
Danish National Regulations: Pregnant/breastfeeding women working with the product must not be in direct contact with the product
Switzerland
Storage class (LK): LK 10/12 - Liquids
No chemical safety assessment has been carried out
Surse de date: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Alte informaţii: None.
| Cod | Text |
|---|---|
| Acute Tox. 4 (Oral) | Acute toxicity (oral), Category 4 |
| Aquatic Acute 1 | Hazardous to the aquatic environment – Acute Hazard, Category 1 |
| Aquatic Chronic 1 | Hazardous to the aquatic environment – Chronic Hazard, Category 1 |
| Aquatic Chronic 2 | Hazardous to the aquatic environment – Chronic Hazard, Category 2 |
| Aquatic Chronic 3 | Hazardous to the aquatic environment – Chronic Hazard, Category 3 |
| EUH208 | Contains Hexyl cinnamic aldehyde, Linalyl acetate, Linalool, Vertenex, Geraniol, Benzyl salicylate, Iso E Super, Citronellol Pure. May produce an allergic reaction. |
| Eye Dam. 1 | Serious eye damage/eye irritation, Category 1 |
| Eye Irrit. 2 | Serious eye damage/eye irritation, Category 2 |
| Flam. Liq. 3 | Flammable liquids, Category 3 |
| H226 | Flammable liquid and vapour. |