1.2.1. Utilizări identificate relevante
1.2.2. Utilizări contraindicate
Nu sunt disponibile informații suplimentare.
FRENCH COLOR & FRAGRANCE International GmbH
Mittlerer Weg 35
DE– 79424 Auggen
Germany
T 49-7631-931-8900
SDS@frenchcolor.com - www.frenchcolor.com
Emergency number : 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086
Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Efecte fizico-chimice, asupra sănătății umane și asupra mediului
Toxic to aquatic life with long lasting effects. Harmful if swallowed. Causes skin irritation. Very toxic to aquatic life with long lasting effects. May cause an allergic skin reaction.
Etichetare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Conține Benzyl benzoate; Iso E Super; FORMALDEHYDE CYCLODECYL ETHYL ACETAL ; Patchouli oil; Phenylethyl alcohol; Cinnamic alcohol; beta-Caryophyllene; Cinnamic aldehyde
Fraze de pericol (CLP)
Fraze de precauție (CLP)
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Nu se aplică
| Denumire | Identificator produs | % | Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP] |
|---|---|---|---|
| benzyl benzoate | CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33 | 19.95 – 39.9 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Iso E Super | CAS-No.: 54464-57-2 EC-No.: 259-174-3 REACH-no: 01-2119489989-04 | 9.675 – 19.35 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 1, H410 |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) | CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 | 3.425 – 6.85 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Methyl ionone (mixture of isomers) | CAS-No.: 1335-46-2 EC-No.: 215-635-0 | 1.575 – 3.15 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Aquatic Chronic 2, H411 |
| FORMALDEHYDE CYCLODECYL ETHYL ACETAL | CAS-No.: 58567-11-6 EC-No.: 261-332-1 | 1.275 – 2.55 | Skin Irrit. 2, H315 Skin Sens. 1B, H317 Aquatic Chronic 2, H411 |
| Patchouli oil | CAS-No.: 8014-09-3 EC Index-No.: 616-944-7 | 1.25 – 2.5 | Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| Phenylethyl alcohol | CAS-No.: 60-12-8 EC-No.: 200-456-2 REACH-no: 01-2119963921-31 | 1 – 2 | Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 |
| Bacdanol | CAS-No.: 28219-61-6 EC-No.: 248-908-8 REACH-no: 01-2119529224-45 | 0.925 – 1.85 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Aquatic Chronic 1, H410 |
| Ethyl vanillin | CAS-No.: 121-32-4 EC-No.: 204-464-7 REACH-no: 01-211958961-24 | 0.75 – 1.5 | Eye Irrit. 2, H319 |
| Cinnamic alcohol | CAS-No.: 104-54-1 EC-No.: 203-212-3 REACH-no: 01-2119934496-29 | 0.75 – 1.5 | Acute Tox. 4 (Oral), H302 Skin Sens. 1B, H317 |
| 1-[(2-tert-butyl)cyclohexyloxy]-2-butanol | CAS-No.: 139504-68-0 EC-No.: 412-300-2 EC Index-No.: 603-154-00-2 REACH-no: 01-0000015959-52 | 0.75 – 1.5 | Aquatic Chronic 2, H411 |
| beta-Caryophyllene | CAS-No.: 87-44-5 EC-No.: 201-746-1 REACH-no: 01-2120745237-53 | 0.125 – 0.25 | Skin Sens. 1B, H317 Asp. Tox. 1, H304 |
| Isopropyl quinoline | CAS-No.: 135-79-5 EC-No.: 205-220-2 | 0.05 – 0.1 | Acute Tox. 2 (Dermal), H310 Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Skin Irrit. 2, H315 |
| Cinnamic aldehyde | CAS-No.: 104-55-2 EC-No.: 203-213-9 REACH-no: 01-2119935242-45 | 0 – 0.05 | Acute Tox. 4 (Dermal), H312 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1A, H317 Aquatic Chronic 3, H412 |
| benzaldehyde substance with national workplace exposure limit(s) (BG, FI, HU, LT, LV, PL) | CAS-No.: 100-52-7 EC-No.: 202-860-4 EC Index-No.: 605-012-00-5 REACH-no: 01-2119455540-44 | 0 – 0.05 | Acute Tox. 4 (Oral), H302 |
Full text of H- and EUH-statements: see section 16
Măsuri generale de prim ajutor: Call a poison center or a doctor if you feel unwell.
După inhalare: Remove person to fresh air and keep comfortable for breathing.
După contactul cu pielea: Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention.
După contactul cu ochii: Rinse eyes with water as a precaution.
După ingerare: Rinse mouth. Call a poison center or a doctor if you feel unwell.
Simptome/efecte după contactul cu pielea: Irritation. May cause an allergic skin reaction.
Treat symptomatically.
Mijloace de stingere adecvate: Water spray. Dry powder. Foam. Carbon dioxide.
Produse periculoase de descompunere în caz de incendiu: Toxic fumes may be released.
Protecție în timpul combaterii incendiului: Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.
6.1.1. Pentru personalul care nu face parte din serviciile de urgență
Proceduri de urgență: Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.
6.1.2. Pentru echipele de intervenție
Echipament de protecție: Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".
Avoid release to the environment.
Pentru izolare: Collect spillage.
Metode de curățare: Take up liquid spill into absorbent material.
Alte informații: Dispose of materials or solid residues at an authorized site.
Pentru informații suplimentare, consultați secțiunea 13.
Precauții pentru manipulare în condiții de siguranță: Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. Avoid breathing dust/fume/gas/mist/vapours/spray.
Măsuri de igienă: Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product.
Condiții de depozitare: Store in a well-ventilated place. Keep cool.
Temperatura de depozitare: 25 °C
Zona de depozitare: Store in a well-ventilated place. Store away from heat.
Reguli speciale privind ambalajul: Store in a closed container.
Materiale de ambalare: Do not store in corrodable metal.
Nu sunt disponibile informații suplimentare.
| Substanță | Țară | Valori limită |
|---|---|---|
| benzaldehyde (100-52-7) | Bulgaria - Occupational Exposure Limits | OEL TWA 5 mg/m³ |
| Finland - Occupational Exposure Limits | HTP (OEL TWA) [1] 4.4 mg/m³ HTP (OEL TWA) [2] 1 ppm HTP (OEL C) 17.4 mg/m³ HTP (OEL C) [ppm]] 4 ppm | |
| Hungary - Occupational Exposure Limits | AK (OEL TWA) 5 mg/m³ CK (OEL STEL) 10 mg/m³ | |
| Latvia - Occupational Exposure Limits | OEL TWA 5 mg/m³ | |
| Lithuania - Occupational Exposure Limits | IPRV (OEL TWA) 5 mg/m³ | |
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 10 mg/m³ NDSCh (OEL STEL) 40 mg/m³ |
8.1.2. Proceduri recomandate de monitorizare
Nu sunt disponibile informații suplimentare.
8.1.3. Contaminanți din aer formați
Nu sunt disponibile informații suplimentare.
8.1.4. DNEL și PNEC
Nu sunt disponibile informații suplimentare.
8.1.5. Control banding
Nu sunt disponibile informații suplimentare.
Appropriate engineering controls: Ensure good ventilation of the work station.
Personal protective equipment symbol(s):
8.2.2.1. Protecția ochilor și a feței
Protecția ochilor: Safety glasses
8.2.2.2. Protecția pielii
Protecția pielii și a corpului: Wear suitable protective clothing
Protecția mâinilor: Protective gloves
8.2.2.3. Protecția respirației
Protecția respirației: In case of insufficient ventilation, wear suitable respiratory equipment
8.2.2.4. Pericole termice
Nu sunt disponibile informații suplimentare.
Avoid release to the environment.
| Stare fizică | Liquid |
| Culoare | light yellow. amber. Conforms to standard. |
| Miros | characteristic. characteristic. |
| Prag de miros | Not available |
| Punct de topire | Not applicable |
| Punct de îngheț | Not available |
| Punct de fierbere | Not available |
| Inflamabilitate | Not applicable |
| Limite explozive | Not available |
| Limită inferioară de explozie | Not available |
| Limită superioară de explozie | Not available |
| Punct de inflamabilitate | > 93 °C (closed cup) ASTM D7094 |
| Temperatură de autoaprindere | Not available |
| Temperatură de descompunere | Not available |
| pH | Not available |
| Vâscozitate, cinematică | Not available |
| Solubilitate | Not available |
| Coeficient de partiție n-octanol/apă (Log Kow) | Not available |
| Presiune de vapori | Not available |
| Presiune de vapori la 50°C | Not available |
| Densitate | Not available |
| Densitate relativă | ≈ 1.03 |
| Densitate relativă a vaporilor la 20°C | Not available |
| Caracteristicile particulelor | Not applicable |
9.2.1. Informații privind clasele de pericol fizic
Nu sunt disponibile informații suplimentare.
9.2.2. Alte caracteristici de siguranță
Nu sunt disponibile informații suplimentare.
10.1. Reactivitate
The product is non-reactive under normal conditions of use, storage and transport.
10.2. Stabilitate chimică
Stable under normal conditions.
10.3. Posibilitatea reacțiilor periculoase
No dangerous reactions known under normal conditions of use.
10.4. Condiții de evitat
None under recommended storage and handling conditions (see section 7).
10.5. Materiale incompatibile
Nu sunt disponibile informații suplimentare.
10.6. Produși de descompunere periculoși
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
11.1. Informații privind clasele de pericol definite în Regulamentul (CE) Nr. 1272/2008
| Bibliotheque Byredo #EU38209F ATE CLP (oral) | 1189.867 mg/kg bodyweight |
| benzyl benzoate (120-51-4) LD50 oral rat | 500 mg/kg (Source: NLM_CIP) |
| LD50 oral | 1160 mg/kg bodyweight |
| LD50 dermal rabbit | 4000 mg/kg (Source: NLM_CIP) |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5) LD50 oral rat | > 3250 mg/kg (Source: CHEMVIEW) |
| LD50 dermal rabbit | > 3250 mg/kg (Source: CHEMVIEW) |
| Methyl ionone (mixture of isomers) (1335-46-2) LD50 oral rat | > 5000 mg/kg |
| LD50 dermal rabbit | > 5000 mg/kg (Source: CHEMVIEW) |
| LD50 dermal | 2900 mg/kg bodyweight |
| FORMALDEHYDE CYCLODECYL ETHYL ACETAL (58567-11-6) LD50 oral rat | > 5 g/kg (Source: NLM_CIP) |
| LD50 dermal rabbit | > 5000 mg/kg (Source: ECHA_API) |
| Patchouli oil (8014-09-3) LD50 oral rat | > 5 g/kg (Source: NLM_CIP) |
| Phenylethyl alcohol (60-12-8) LD50 oral rat | 1609 mg/kg (Source: EPA_HPV) |
| LD50 oral | 1610 mg/kg bodyweight |
| LD50 dermal rabbit | 2535 mg/kg (Source: EPA_HPV) |
| LD50 dermal | 2500 mg/kg bodyweight |
| LC50 Inhalation - Rat | > 4.63 mg/l/4h |
| Ethyl vanillin (121-32-4) LD50 oral rat | 1590 mg/kg (Source: NLM_CIP) |
| LD50 oral | 3000 mg/kg bodyweight |
| LD50 dermal rat | > 2000 mg/kg (Source: ECHA_API) |
| Cinnamic alcohol (104-54-1) LD50 oral | 2000 mg/kg bodyweight |
| LD50 dermal rabbit | > 5000 mg/kg (Source: ECHA_API) |
| 1-[(2-tert-butyl)cyclohexyloxy]-2-butanol (139504-68-0) LD50 dermal rat | > 2000 mg/kg (Source: ECHA_API) |
| Isopropyl quinoline (135-79-5) LD50 oral | 1500 mg/kg bodyweight |
| LD50 dermal | 160 mg/kg bodyweight |
| Cinnamic aldehyde (104-55-2) LD50 oral rat | 2220 mg/kg (Source: NLM_CIP) |
| LD50 oral | 2200 mg/kg bodyweight |
| LD50 dermal rabbit | 1260 mg/kg (Source: EPA_HPV) |
| LD50 dermal | 1100 mg/kg bodyweight |
| benzaldehyde (100-52-7) LD50 oral rat | 1292 mg/kg (Source: JAPAN_GHS) |
| LD50 dermal rabbit | > 1250 mg/kg (Source: JAPAN_GHS) |
benzyl benzoate (120-51-4) Viscosity, kinematic 7.456 mm²/s
11.2. Informații privind alte pericole
Nu sunt disponibile informații suplimentare.
Ecologie - general: Toxic to aquatic life with long lasting effects. Very toxic to aquatic life with long lasting effects.
Periculos pentru mediul acvatic, pe termen scurt (acut): Very toxic to aquatic life.
Periculos pentru mediul acvatic, pe termen lung (cronic): Very toxic to aquatic life with long lasting effects.
| benzyl benzoate (120-51-4) LC50 - Fish [1] | 2.32 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) |
| NOEC (chronic) | 0.168 mg/l |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5) LC50 - Fish [1] | 0.452 mg/l Wolf, 1996d-27682 |
| LC50 - Other aquatic organisms [1] | > 0.14 mg/l REACH DOSSIER Pimephales promelas |
| EC50 - Crustacea [2] | 260 μg/l REACH Dossier |
| EC50 - Other aquatic organisms [1] | 0.131 mg/l REACH Dossier |
| Methyl ionone (mixture of isomers) (1335-46-2) LC50 - Fish [1] | 2.3 mg/l (Exposure time: 96 h - Species: Danio rerio [static] Source: ECHA) |
| Phenylethyl alcohol (60-12-8) EC50 - Crustacea [1] | 287.17 mg/l (Exposure time: 48 h - Species: Daphnia magna) |
| EC50 72h - Algae [1] | 490 mg/l (Species: Desmodesmus subspicatus) |
| Ethyl vanillin (121-32-4) LC50 - Fish [1] | 81.4 – 94.3 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) |
| benzaldehyde (100-52-7) LC50 - Fish [1] | 10.6 – 11.8 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through] Source: EPA) |
| LC50 - Fish [2] | 12.69 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static] Source: IUCLID) |
benzyl benzoate (120-51-4)
Persistence and degradability May cause long-term adverse effects in the environment.
FORMALDEHYDE CYCLODECYL ETHYL ACETAL (58567-11-6)
Persistence and degradability May cause long-term adverse effects in the environment. Not established.
| benzyl benzoate (120-51-4) Partition coefficient n-octanol/water (Log Pow) | 3.97 (at 25 °C) |
| Bioaccumulative potential | Not established. |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5) BCF - Fish [1] | (1618 dimensionless (whole body w.w.) |
| Partition coefficient n-octanol/water (Log Pow) | 5.3 (at 25 °C (at pH 7) |
| Methyl ionone (mixture of isomers) (1335-46-2) Partition coefficient n-octanol/water (Log Pow) | (>4.5 - <5 - at 23 °C (at pH 6.2) |
| FORMALDEHYDE CYCLODECYL ETHYL ACETAL (58567-11-6) BCF - Fish [1] | (530 dimensionless (whole body w.w.) |
| Partition coefficient n-octanol/water (Log Pow) | 5.4 (at 25 °C) |
| Bioaccumulative potential | Not established. |
| Phenylethyl alcohol (60-12-8) Partition coefficient n-octanol/water (Log Pow) | 1.36 (at 20 °C (at pH 7) |
| Ethyl vanillin (121-32-4) Partition coefficient n-octanol/water (Log Pow) | 1.61 (at 25 °C) |
| Cinnamic alcohol (104-54-1) Partition coefficient n-octanol/water (Log Pow) | 1.636 (at 27 °C (at pH 3.52) |
| 1-[(2-tert-butyl)cyclohexyloxy]-2-butanol (139504-68-0) BCF - Fish [1] | (173 dimensionless) |
| beta-Caryophyllene (87-44-5) Partition coefficient n-octanol/water (Log Pow) | 6.23 (at 25 °C (at pH 7) |
| Cinnamic aldehyde (104-55-2) Partition coefficient n-octanol/water (Log Pow) | 2.1065 (at 25 °C) |
| benzaldehyde (100-52-7) BCF - Fish [1] | (no significant bioaccumulation) |
| Partition coefficient n-octanol/water (Log Pow) | 1.4 (at 25 °C) |
Nu sunt disponibile informații suplimentare.
Nu sunt disponibile informații suplimentare.
Nu sunt disponibile informații suplimentare.
Nu sunt disponibile informații suplimentare.
Metode de tratare a deșeurilor: Dispose of contents/container in accordance with licensed collector’s sorting instructions.
HP Code: HP6 - “Acute Toxicity:” waste which can cause acute toxic effects following oral or dermal administration, or inhalation exposure.