1.2.1. Utilizări relevante identificate
Specificaţie utilizare industrială/profesională: Industrial
Doar pentru uz profesional
Utilizarea substanţei/amestecului: Perfumes, fragrances
Funcţie sau categorie de utilizare: Odour agents
1.2.2. Utilizări contraindicate
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Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Hazardous to the aquatic environment – Chronic Hazard, Category 3 H412
Efecte fizico-chimice, asupra sănătăţii umane şi asupra mediului
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Etichetare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Cuvânt de avertizare (CLP): -
Fraze de pericol (CLP): H412 - Harmful to aquatic life with long lasting effects.
Fraze de precauţie (CLP): P273 - Avoid release to the environment.
P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Fraze EUH: EUH208 - Contains Lemon oil, Bergamot oil, Linalool, Iso E Super, Linalyl acetate, Citronellol Pure, Anise oil (Spanish). May produce an allergic reaction.
Fraze suplimentare: For professional users only.
Conţine no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
Nu se aplică
| Nume | Identificator produs | % | Clasificare conform Regulamentului (EC) No. 1272/2008 [CLP] |
|---|---|---|---|
| Benzyl benzoate | CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33 | 2.75 – 5.5 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Lemon oil | CAS-No.: 8008-56-8 EC-No.: 284-515-8 | 0.23 – 0.45 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Repr. 2, H361 Aquatic Chronic 2, H411 |
| Bergamot oil | CAS-No.: 8007-75-8 EC-No.: 289-612-9 | 0.2 – 0.4 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 3, H412 |
| ACETYL HEXAMETHYL TETRALIN | CAS-No.: 21145-77-7 EC-No.: 244-240-6 | 0.15 – 0.3 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Linalool | CAS-No.: 78-70-6 EC-No.: 201-134-4 EC Index-No.: 603-235-00-2 REACH-no: 01-2119474016-42 | 0.13 – 0.25 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Iso E Super | CAS-No.: 54464-57-2 EC-No.: 259-174-3 REACH-no: 01-2119489989-04 | 0.09 – 0.175 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 1, H410 |
| Linalyl acetate | CAS-No.: 115-95-7 EC-No.: 204-116-4 REACH-no: 01-2119454789-19 | 0.08 – 0.15 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Citronellol Pure | CAS-No.: 106-22-9 EC-No.: 203-375-0 REACH-no: 01-2119453995-23 | 0.05 – 0.1 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Anise oil (Spanish) | CAS-No.: 8007-70-3 EC-No.: 616-914-3 | 0.05 – 0.1 | Skin Sens. 1, H317 Muta. 2, H341 Carc. 2, H351 Aquatic Chronic 3, H412 |
| Carbitol | substance with national workplace exposure limit(s) (AT, DE, EE, SE, SI, CH) CAS-No.: 111-90-0 EC-No.: 203-919-7 REACH-no: 01-2119475105-42 | 0.043398 – 0.086796 | Not classified |
Full text of H- and EUH-statements: see section 16
Măsuri generale de prim ajutor: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
După inhalare: Allow affected person to breathe fresh air. Allow the victim to rest.
După contactul cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
După contactul cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
După înghiţire: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
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Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
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Instrucţiuni de stingere: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protecţie în timpul stingerii incendiului: Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1. Pentru personalul care nu face parte din serviciile de urgenţă
Emergency procedures: Evacuate unnecessary personnel.
6.1.2. Pentru echipele de intervenţie
Protective equipment: Equip cleanup crew with proper protection.
Emergency procedures: Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Methods for cleaning up: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Section 8. Exposure controls and personal protection.
Precautions for safe handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
Storage conditions: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Incompatible products: Strong bases. Strong acids.
Incompatible materials: Sources of ignition. Direct sunlight.
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8.1.1. Valori limită naţionale de expunere profesională şi biologice
| Carbitol (111-90-0) | |
|---|---|
| Austria - Occupational Exposure Limits MAK (OEL TWA) MAK (OEL TWA) [ppm] MAK (OEL STEL) MAK (OEL STEL) [ppm] | 35 mg/m³ 6 ppm 140 mg/m³ 24 ppm |
| Estonia - Occupational Exposure Limits OEL TWA OEL TWA [ppm] OEL chemical category | 50.1 mg/m³ 10 ppm Skin notation |
| Germany - Occupational Exposure Limits (TRGS 900) AGW (OEL TWA) [1] AGW (OEL TWA) [2] | 35 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 6 ppm (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) |
| Slovenia - Occupational Exposure Limits OEL TWA OEL TWA [ppm] OEL STEL OEL STEL [ppm] | 35 mg/m³ 6 ppm 70 mg/m³ 12 ppm |
| Sweden - Occupational Exposure Limits NGV (OEL TWA) NGV (OEL TWA) [ppm] KTV (OEL STEL) KTV (OEL STEL) [ppm] | 80 mg/m³ 15 ppm 170 mg/m³ 30 ppm |
| Switzerland - Occupational Exposure Limits MAK (OEL TWA) [1] KZGW (OEL STEL) | 50 mg/m³ (aerosol, inhalable dust, vapour) 100 mg/m³ (aerosol, inhalable dust, vapour) |
8.1.2. Recommended monitoring procedures: No additional information available
8.1.3. Air contaminants formed: No additional information available
8.1.4. DNEL and PNEC: No additional information available
8.1.5. Control banding: No additional information available
8.2.1. Controale inginereşti corespunzătoare
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8.2.2. Echipament individual de protecţie
Personal protective equipment: Avoid all unnecessary exposure.
Personal protective equipment symbol(s):
8.2.2.1. Protecţia ochilor şi a feţei
Eye protection: Chemical goggles or safety glasses
8.2.2.2. Protecţia pielii
Hand protection: Wear protective gloves.
8.2.2.3. Protecţia căilor respiratorii
Respiratory protection: Wear appropriate mask
8.2.2.4. Pericole termice
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8.2.3. Controlul expunerii mediului
Other information: Do not eat, drink or smoke during use.
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Not established.
Not established.
Direct sunlight. Extremely high or low temperatures.
Strong acids. Strong bases.
fume. Carbon monoxide. Carbon dioxide.
Acute toxicity (oral): Not classified
Acute toxicity (dermal): Not classified
Acute toxicity (inhalation): Not classified
| Substanţă | Date toxicologice |
|---|---|
| Benzyl benzoate (120-51-4) | LD50 oral rat 500 mg/kg (Source: NLM_CIP) LD50 oral 1160 mg/kg bodyweight LD50 dermal rabbit 4000 mg/kg (Source: NLM_CIP) |
| Lemon oil (8008-56-8) | LD50 oral rat 2840 mg/kg (Source: NLM_CIP) |
| Bergamot oil (8007-75-8) | LD50 oral rat 11520 mg/kg (Source: NLM_CIP) |
| ACETYL HEXAMETHYL TETRALIN (21145-77-7) | LD50 oral rat 570 mg/kg (Source: NLM_CIP) LD50 oral 1000 mg/kg bodyweight LD50 dermal rabbit > 5 g/kg (Source: NLM_HSDB) |
| Linalool (78-70-6) | LD50 oral 2790 mg/kg bodyweight |
| Linalyl acetate (115-95-7) | LD50 oral rat 14550 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: EPA_HPV) |
| Carbitol (111-90-0) | LD50 oral rat 10502 mg/kg (Source: OECD_SIDS) LD50 dermal rabbit 9143 mg/kg (Source: OECD_SIDS) LC50 Inhalation - Rat > 5240 mg/m³ (Exposure time: 4 h Source: NLM_CIP) |
| Citronellol Pure (106-22-9) | LD50 oral rat 3450 mg/kg (Source: NLM_CIP) LD50 oral 3450 mg/kg bodyweight LD50 dermal rabbit 2650 mg/kg (Source: EPA_HPV) LD50 dermal 2650 mg/kg bodyweight |
| Anise oil (Spanish) (8007-70-3) | LD50 oral rat 2250 mg/kg (Source: NLM_CIP) LD50 oral 2200 mg/kg bodyweight |
Skin corrosion/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Serious eye damage/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Respiratory or skin sensitisation: Not classified
Additional information: Based on available data, the classification criteria are not met
Germ cell mutagenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Carcinogenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Reproductive toxicity: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-single exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-repeated exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
Aspiration hazard: Not classified
Additional information: Based on available data, the classification criteria are not met
Hazardous to the aquatic environment, short-term (acute): Not classified
Hazardous to the aquatic environment, long-term (chronic): Harmful to aquatic life with long lasting effects.
| Substanţă | Date ecologice |
|---|---|
| Benzyl benzoate (120-51-4) | LC50 - Fish [1] 2.32 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) NOEC (chronic) 0.168 mg/l |
| Linalool (78-70-6) | EC50 96h - Algae [1] 88.3 mg/l (Species: Desmodesmus subspicatus) |
| Linalyl acetate (115-95-7) | LC50 - Fish [1] 11 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [flow-through] Source: ECHA) |
| Carbitol (111-90-0) | LC50 - Fish [1] 10000 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static] Source: EPA) LC50 - Fish [2] 19100 – 23900 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [flow-through] Source: EPA) EC50 - Crustacea [1] 3940 – 4670 mg/l (Exposure time: 48 h - Species: Daphnia magna) |
BAMBOO & GREEN TEA #EU32908F 10%: Persistence and degradability Not established.
Benzyl benzoate (120-51-4): Persistence and degradability May cause long-term adverse effects in the environment.
BAMBOO & GREEN TEA #EU32908F 10%: Bioaccumulative potential Not established.
Benzyl benzoate (120-51-4): Partition coefficient n-octanol/water (Log Pow) 3.97 (at 25 °C)
Bioaccumulative potential Not established.
ACETYL HEXAMETHYL TETRALIN (21145-77-7): Partition coefficient n-octanol/water (Log Pow) 5.7 (at 24 °C)
Linalyl acetate (115-95-7): Partition coefficient n-octanol/water (Log Pow) 3.9 (at 25 °C)
Carbitol (111-90-0): Partition coefficient n-octanol/water (Log Pow) -0.8
Citronellol Pure (106-22-9): Partition coefficient n-octanol/water (Log Pow) 3.41 (at 25 °C)
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Additional information: Avoid release to the environment.
Product/Packaging disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials: Avoid release to the environment.
HP Code: HP3 - “Flammable:”
– flammable liquid waste: liquid waste having a flash point below 60 °C or waste gas oil, diesel and light heating oils having a flash point > 55 °C and ≤ 75 °C;
– flammable pyrophoric liquid and solid waste: solid or liquid waste which, even in small quantities, is liable to ignite within five minutes after coming into contact with air;
– flammable solid waste: solid waste which is readily combustible or may cause or contribute to fire through friction;
– flammable gaseous waste: gaseous waste which is flammable in air at 20 °C and a standard pressure of 101.3 kPa;
– water reactive waste: waste which, in contact with water, emits flammable gases in dangerous quantities;
– other flammable waste: flammable aerosols, flammable self-heating waste, flammable organic peroxides and flammable self-reactive waste.
HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|
| 14.1. UN number Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.2. UN proper shipping name Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.3. Transport hazard class(es) Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.4. Packing group Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.5. Environmental hazards Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
No supplementary information available
Overland transport: Not applicable
Transport by sea: Not applicable
Air transport: Not applicable
Inland waterway transport: Not applicable
Rail transport: Not applicable
Not applicable
15.1.1. Reglementări UE
REACH Annex XVII (Restriction List)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(a) | Lemon oil ; Bergamot oil | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F |
| 3(b) | Benzyl benzoate ; Lemon oil ; Bergamot oil ; Linalool ; Iso E Super ; Linalyl acetate ; Citronellol Pure ; Anise oil (Spanish) | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | BAMBOO & GREEN TEA #EU32908F 10% ; Benzyl benzoate ; Lemon oil ; Bergamot oil ; Iso E Super ; Anise oil (Spanish) | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 |
| 40. | Lemon oil ; Bergamot oil | Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. |
REACH Annex XIV (Authorisation List): Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC): Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent): Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants): Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009): Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Explosives Precursors Regulation (2019/1148): Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004): Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
Germany
Water hazard class (WGK): WGK 2, Significantly hazardous to water (Classification according to AwSV, Annex 1).
Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids.
Joint storage table:
Joint storage not permitted for: LGK 1, LGK 6.2, LGK 7.
Joint storage with restrictions permitted for: LGK 4.1A, LGK 4.3, LGK 5.1C.
Joint storage permitted for: LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13.
Hazardous Incident Ordinance (12. BImSchV): Is not subject of the Hazardous Incident Ordinance (12. BImSchV)
Netherlands
ABM category: A(2) - toxic for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen: Lemon oil ,Bergamot oil are listed
SZW-lijst van mutagene stoffen: Lemon oil ,Bergamot oil are listed
SZW-lijst van reprotoxische stoffen – Borstvoeding: None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid: None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling: None of the components are listed
Denmark
Classification remarks: Emergency management guidelines for the storage of flammable liquids must be followed
Switzerland
Storage class (LK): LK 10/12 - Liquids
No chemical safety assessment has been carried out
Surse de date: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Alte informaţii: None.
| Text complet al frazelor H şi EUH | Traducere |
|---|---|
| Acute Tox. 4 (Oral) | Acute toxicity (oral), Category 4 |
| Aquatic Acute 1 | Hazardous to the aquatic environment – Acute Hazard, Category 1 |
| Aquatic Chronic 1 | Hazardous to the aquatic environment – Chronic Hazard, Category 1 |
| Aquatic Chronic 2 | Hazardous to the aquatic environment – Chronic Hazard, Category 2 |
| Aquatic Chronic 3 | Hazardous to the aquatic environment – Chronic Hazard, Category 3 |
| Asp. Tox. 1 | Aspiration hazard, Category 1 |
| Carc. 2 | Carcinogenicity, Category 2 |
| EUH208 | Contains Lemon oil, Bergamot oil, Linalool, Iso E Super, Linalyl acetate, Citronellol Pure, Anise oil (Spanish). May produce an allergic reaction. |
| Eye Irrit. 2 | Serious eye damage/eye irritation, |