Forma produsului: Mixture
Denumirea produsului: LIME #EU40565F 5% in DPG
Cod produs: EU40565F_5%
Tipul produsului: Perfumes, fragrances
1.2.1. Utilizări relevante identificate
Industrial/Professional use spec: Industrial
For professional use only
Use of the substance/mixture: Perfumes, fragrances
Function or use category: Odour agents
1.2.2. Utilizări contraindicate
No additional information available
Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Hazardous to the aquatic environment – Chronic Hazard, Category 3
H412
Textul integral al frazelor H și EUH: vedeți secțiunea 16
Efecte fizico-chimice, pentru sănătatea umană și asupra mediului
No additional information available
Etichetare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Cuvânt de avertizare (CLP): -
Fraze de pericol (CLP): H412 - Harmful to aquatic life with long lasting effects.
Fraze de precauție (CLP): P273 - Avoid release to the environment.
P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Fraze EUH: EUH208 - Contains Lemon terpenes, citral. May produce an allergic reaction.
Fraze suplimentare: For professional users only.
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
| Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
|---|---|---|---|
| benzyl benzoate | CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33 |
1.83 – 3.6597 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Lemon terpenes | CAS-No.: 68917-33-9 EC-No.: 284-515-8 |
0.42 – 0.84 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| citral | substance with national workplace exposure limit(s) (BE, ES, IE, PL, PT) CAS-No.: 5392-40-5 EC-No.: 226-394-6 EC Index-No.: 605-019-00-3 REACH-no: 01-2119462829-23 |
0.075 – 0.15 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| (R)-p-mentha-1,8-diene; d-limonene | substance with national workplace exposure limit(s) (DE, ES, FI, SI, NO, CH) CAS-No.: 5989-27-5 EC-No.: 205-341-0 EC Index-No.: 601-096-00-2 REACH-no: 01-2119493353-35 |
0.0012807 – 0.0012807 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 |
| .beta.-Pinene | substance with national workplace exposure limit(s) (BE, EE, ES, LT, PT, SE, NO) CAS-No.: 127-91-3 EC-No.: 204-872-5 |
0.000191275 – 0.000191275 | Flam. Liq. 3, H226 |
| Alcohol C-10 | substance with national workplace exposure limit(s) (BG, DE, LT, LV, RO, CH) CAS-No.: 112-30-1 EC-No.: 203-956-9 |
0 – 0.00014 | Aquatic Chronic 3, H412 |
| Aldehyde C-6 | substance with national workplace exposure limit(s) (FI, PL) CAS-No.: 66-25-1 EC-No.: 200-624-5 |
0 – 0.000035 | Flam. Liq. 3, H226 |
Full text of H- and EUH-statements: see section 16
| First-aid measures general | Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). |
|---|---|
| First-aid measures after inhalation | Allow affected person to breathe fresh air. Allow the victim to rest. |
| First-aid measures after skin contact | Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. |
| First-aid measures after eye contact | Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. |
| First-aid measures after ingestion | Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. |
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
Suitable extinguishing media: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media: Do not use a heavy water stream.
Firefighting instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1. Pentru personalul care nu face parte din serviciile de urgență
Emergency procedures: Evacuate unnecessary personnel.
6.1.2. Pentru echipele de intervenție
Protective equipment: Equip cleanup crew with proper protection.
Emergency procedures: Ventilate area.
Methods for cleaning up: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Precautions for safe handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
Storage conditions: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Incompatible products: Strong bases. Strong acids.
Incompatible materials: Sources of ignition. Direct sunlight.
Germany
Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids
Joint storage table:
Joint storage not permitted for: LGK 1, LGK 6.2, LGK 7
Joint storage with restrictions permitted for: LGK 4.1A, LGK 4.3, LGK 5.1C
Joint storage permitted for: LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13
Switzerland
Storage class (LK): LK 10/12 - Liquids
8.1.1 National occupational exposure and biological limit values
| citral (5392-40-5) | |
|---|---|
| Belgium - Occupational Exposure Limits | OEL TWA 32 mg/m³ (vapor and aerosol) 5 ppm (vapor and aerosol) OEL chemical category Skin |
| Ireland - Occupational Exposure Limits | OEL TWA 5 ppm OEL STEL 15 ppm (calculated) |
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 27 mg/m³ NDSCh (OEL STEL) 54 mg/m³ |
| Portugal - Occupational Exposure Limits | OEL TWA 5 ppm (inhalable fraction; vapor) OEL chemical category Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen, skin - potential for cutaneous exposure |
| Spain - Occupational Exposure Limits | VLA-ED (OEL TWA) 5 ppm (inhalable fraction and vapor) OEL chemical category Sensitizer, skin - potential for cutaneous absorption |
| USA - ACGIH - Occupational Exposure Limits | ACGIH OEL TWA 5 ppm (inhalable fraction and vapor) ACGIH chemical category Not Classifiable as a Human Carcinogen, Skin - potential significant contribution to overall exposure by the cutaneous route, dermal sensitizer |
| Alcohol C-10 (112-30-1) | |
|---|---|
| Bulgaria - Occupational Exposure Limits | OEL TWA 10 mg/m³ |
| Germany - Occupational Exposure Limits (TRGS 900) | AGW (OEL TWA) 66 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 10 ppm (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) |
| Latvia - Occupational Exposure Limits | OEL TWA 10 mg/m³ |
| Lithuania - Occupational Exposure Limits | IPRV (OEL TWA) 10 mg/m³ |
| Romania - Occupational Exposure Limits | OEL TWA 100 mg/m³ 15 ppm OEL STEL 200 mg/m³ 30 ppm |
| Switzerland - Occupational Exposure Limits | MAK (OEL TWA) 66 mg/m³ (aerosol, vapour) 10 ppm (aerosol, vapour) KZGW (OEL STEL) 66 mg/m³ (aerosol, vapour) 10 ppm (aerosol, vapour) |
| Aldehyde C-6 (66-25-1) | |
|---|---|
| Finland - Occupational Exposure Limits | HTP (OEL STEL) 42 mg/m³ 10 ppm |
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 40 mg/m³ NDSCh (OEL STEL) 80 mg/m³ |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | |
|---|---|
| Finland - Occupational Exposure Limits | HTP (OEL TWA) 140 mg/m³ 25 ppm HTP (OEL STEL) 280 mg/m³ 50 ppm |
| Germany - Occupational Exposure Limits (TRGS 900) | AGW (OEL TWA) 28 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 5 ppm (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Chemical category Skin notation, Skin sensitization |
| Slovenia - Occupational Exposure Limits | OEL TWA 28 mg/m³ 5 ppm OEL STEL 112 mg/m³ 20 ppm OEL chemical category Potential for cutaneous absorption |
| Spain - Occupational Exposure Limits | VLA-ED (OEL TWA) 168 mg/m³ 30 ppm OEL chemical category Sensitizer, skin - potential for cutaneous absorption |
| Norway - Occupational Exposure Limits | Grenseverdi (OEL TWA) 140 mg/m³ 25 ppm Korttidsverdi (OEL STEL) 175 mg/m³ (value calculated) 37.5 ppm (value calculated) OEL chemical category Allergenic substance |
| Switzerland - Occupational Exposure Limits | MAK (OEL TWA) 40 mg/m³ 7 ppm KZGW (OEL STEL) 80 mg/m³ 14 ppm OEL chemical category Sensitizer |
| .beta.-Pinene (127-91-3) | |
|---|---|
| Belgium - Occupational Exposure Limits | OEL TWA 20 ppm |
| Estonia - Occupational Exposure Limits | OEL TWA 150 mg/m³ (Turpentine produced from Nordic conifers has an irritating effect on the skin, monoterpenes, with the exception of 3-Carene, have a lesser effect) 25 ppm (Turpentine produced from Nordic conifers has an irritating effect on the skin, monoterpenes, with the exception of 3-Carene, have a lesser effect) OEL STEL 300 mg/m³ (Turpentine produced from Nordic conifers has an irritating effect on the skin, monoterpenes, with the exception of 3-Carene, have a lesser effect) 50 ppm (Turpentine produced from Nordic conifers has an irritating effect on the skin, monoterpenes, with the exception of 3-Carene, have a lesser effect) |
| Lithuania - Occupational Exposure Limits | IPRV (OEL TWA) 150 mg/m³ 25 ppm TPRV (OEL STEL) 300 mg/m³ 50 ppm |
| Portugal - Occupational Exposure Limits | OEL TWA 20 ppm (Turpentine and selected Monoterpenes) OEL chemical category Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen |
| Spain - Occupational Exposure Limits | VLA-ED (OEL TWA) 113 mg/m³ 20 ppm OEL chemical category Sensitizer |
| Sweden - Occupational Exposure Limits | NGV (OEL TWA) 150 mg/m³ 25 ppm KGV (OEL STEL) 300 mg/m³ 50 ppm OEL chemical category Sensitizer |
| Norway - Occupational Exposure Limits | Grenseverdi (OEL TWA) 140 mg/m³ 25 ppm Korttidsverdi (OEL STEL) 175 mg/m³ (value calculated) 37.5 ppm (value calculated) |
| USA - ACGIH - Occupational Exposure Limits | ACGIH OEL TWA 20 ppm (Turpentine and selected Monoterpenes) ACGIH chemical category Not Classifiable as a Human Carcinogen, dermal sensitizer |
8.2.1. Măsuri tehnice corespunzătoare
No additional information available
8.2.2. Echipament individual de protecție
Personal protective equipment: Avoid all unnecessary exposure.
Personal protective equipment symbol(s):
8.2.2.1. Protecția ochilor și a feței
Eye protection: Chemical goggles or safety glasses
8.2.2.2. Protecția pielii
Hand protection: Wear protective gloves.
8.2.2.3. Protecția respirației
Respiratory protection: Wear appropriate mask
8.2.2.4. Pericole termice
No additional information available
8.2.3. Controale ale expunerii asupra mediului
Other information: Do not eat, drink or smoke during use.
Physical state: Liquid
Colour: Standard.
Odour: characteristic.
Odour threshold: Not available
Melting point: Not available
Freezing point: Not available
Boiling point: Not available
Flammability: Non flammable.
Lower explosion limit: Not available
Upper explosion limit: Not available
Flash point: > 93 °C
Auto-ignition temperature: Not available
Decomposition temperature: Not available
pH: Not available
Viscosity, kinematic: Not available
Solubility: Not available
Partition coefficient n-octanol/water (Log Kow): Not available
Vapour pressure: Not available
Vapour pressure at 50°C: Not available
Density: Not available
Relative density: Not available
Relative vapour density at 20°C: Not available
Particle characteristics: Not applicable
9.2.1. Informații privind clasele de pericol fizic
No additional information available
9.2.2. Alte caracteristici de siguranță
No additional information available
Acute toxicity (oral): Not classified
Acute toxicity (dermal): Not classified
Acute toxicity (inhalation): Not classified
| benzyl benzoate (120-51-4) | |
|---|---|
| LD50 oral rat | 500 mg/kg (Source: NLM_CIP) |
| LD50 oral | 1160 mg/kg bodyweight |
| LD50 dermal rabbit | 4000 mg/kg (Source: NLM_CIP) |
| citral (5392-40-5) | |
| LD50 oral rat | 4960 mg/kg (Source: NLM_CIP) |
| LD50 dermal rabbit | 2250 mg/kg (Source: NLM_CIP) |
| Alcohol C-10 (112-30-1) | |
| LD50 oral rat | 4720 mg/kg (Source: NZ_CCID) |
| LD50 dermal rabbit | 3560 mg/kg (Source: NLM_CIP) |
| Aldehyde C-6 (66-25-1) | |
| LD50 oral rat | 4890 mg/kg (Source: NLM_CIP) |
| LD50 dermal rabbit | > 8100 mg/kg (Source: ECHA_API) |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | |
| LD50 oral rat | 4400 mg/kg (Source: CHEMVIEW) |
| LD50 dermal rabbit | > 5 g/kg (Source: CHEMVIEW) |
| .beta.-Pinene (127-91-3) | |
| LD50 oral rat | > 5000 mg/kg (Source: EPA_HPV) |
| LD50 dermal rabbit | > 5000 mg/kg (Source: CHEMVIEW) |
Skin corrosion/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Serious eye damage/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Respiratory or skin sensitisation: Not classified
Additional information: Based on available data, the classification criteria are not met
Germ cell mutagenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Carcinogenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)
IARC group 3 - Not classifiable
Reproductive toxicity: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-single exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-repeated exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
Aspiration hazard: Not classified
Additional information: Based on available data, the classification criteria are not met
benzyl benzoate (120-51-4)
Viscosity, kinematic 7.456 mm²/s
11.2.1. Proprietăți de perturbare endocrină
No additional information available
11.2.2. Alte informații
Potential adverse human health effects and symptoms: Based on available data, the classification criteria are not met
Hazardous to the aquatic environment, short–term (acute): Not classified
Hazardous to the aquatic environment, long–term (chronic): Harmful to aquatic life with long lasting effects.
| benzyl benzoate (120-51-4) | |
|---|---|
| LC50 - Fish [1] | 2.32 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) |
| NOEC (chronic) | 0.168 mg/l |
| citral (5392-40-5) | |
| EC50 - Crustacea [1] | 7 mg/l (Exposure time: 48 h - Species: Daphnia magna) |
| EC50 72h - Algae [1] | 16 mg/l (Species: Desmodesmus subspicatus) |
| EC50 96h - Algae [1] | 19 mg/l (Species: Desmodesmus subspicatus) |
| Alcohol C-10 (112-30-1) | |
| LC50 - Fish [1] | 2.2 – 2.5 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) |
| LC50 - Fish [2] | 4.12 – 6.2 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static] Source: EPA) |
| EC50 - Crustacea [1] | 3 mg/l (Exposure time: 48 h - Species: Daphnia magna) |
| Aldehyde C-6 (66-25-1) | |
| LC50 - Fish [1] | 12 – 16.5 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | |
| LC50 - Fish [1] | 0.619 – 0.796 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) |
| LC50 - Fish [2] | 35 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss Source: EPA) |
LIME #EU40565F 5% in DPG: Persistence and degradability Not established.
benzyl benzoate (120-51-4): May cause long-term adverse effects in the environment.
Lemon terpenes (68917-33-9): Rapidly degradable
citral (5392-40-5): Rapidly degradable
Alcohol C-10 (112-30-1): Rapidly degradable
Aldehyde C-6 (66-25-1): Rapidly degradable
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5): Rapidly degradable
.beta.-Pinene (127-91-3): Rapidly degradable
LIME #EU40565F 5% in DPG: Bioaccumulative potential Not established.
benzyl benzoate (120-51-4): Partition coefficient n-octanol/water (Log Pow) 3.97 (at 25 °C) / Bioaccumulative potential Not established.
citral (5392-40-5): Partition coefficient n-octanol/water (Log Pow) 2.76 (at 25 °C)
Alcohol C-10 (112-30-1): Partition coefficient n-octanol/water (Log Pow) 4.5 (at 25 °C (at pH 6)
Aldehyde C-6 (66-25-1): Partition coefficient n-octanol/water (Log Pow) 2.3 (at 25 °C (at pH 5)
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5): Partition coefficient n-octanol/water (Log Pow) 4.38 (at 37 °C (at pH 7.2)
Product/Packaging disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.
Ecological information: Avoid release to the environment.
HP Code: HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID | |
|---|---|---|---|---|---|
| 14.1. UN number or ID number | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.2. UN proper shipping name | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.3. Transport hazard class(es) | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.4. Packing group | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.5. Environmental hazards | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
Overland transport
Not applicable
Transport by sea
Not applicable
Air transport
Not applicable
Inland waterway transport
Not applicable
Rail transport
Not applicable
15.1.1. EU-Regulations
REACH Annex XVII (Restriction List)
EU restriction list (REACH Annex XVII)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(a) | Lemon terpenes ; Aldehyde C-6 ; (R)-p-mentha-1,8-diene; d-limonene ; .beta.-Pinene | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F |
| 3(b) | benzyl benzoate ; Lemon terpenes ; citral ; (R)-p-mentha-1,8-diene; d-limonene |