Fișă cu date de securitate conform Regulamentului (CE) nr. 1907/2006 (REACH), cu modificarea Regulamentului (UE) 2020/878 · EN (English) 1/24
1.2.1. Utilizări relevante identificate
1.2.2. Utilizări nerecomandate
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Efecte fizico-chimice, asupra sănătății umane și asupra mediului
Nu sunt disponibile informații suplimentare
Etichetare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Nu conține substanțe PBT și/sau vPvB ≥ 0,1% evaluate în conformitate cu REACH Anexa XIII
Amestecul nu conține substanțe incluse în lista stabilită în conformitate cu Articolul 59(1) din REACH pentru proprietăți de perturbare endocrină sau substanțe care nu sunt identificate ca având proprietăți de perturbare endocrină conform criteriilor stabilite în Regulamentul delegat (UE) 2017/2100 al Comisiei sau în Regulamentul (UE) 2018/605 al Comisiei la o concentrație egală sau mai mare de 0,1%
Nu se aplică
| Denumire | Identificator produs | % | Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP] |
|---|---|---|---|
| Bis(2-ethylhexyl) adipate | CAS-No.: 103-23-1 EC-No.: 203-090-1 REACH-no: 01-2119439699-19 | 7.25 – 14.5125 | Aquatic Acute 1, H400 |
| Ethylene brassylate | CAS-No.: 105-95-3 EC-No.: 203-347-8 REACH-no: 01-2119976314-33 | 2.3 – 4.6125 | Aquatic Chronic 2, H411 |
| Phenylethyl alcohol | CAS-No.: 60-12-8 EC-No.: 200-456-2 REACH-no: 01-2119963921-31 | 0.975 – 1.9375 | Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 |
| 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone | CAS-No.: 54464-57-2 EC-No.: 259-174-3 REACH-no: 01-2119489989-04 | 0.45 – 0.9 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 1, H410 |
| Citronellol Pure | CAS-No.: 106-22-9 EC-No.: 203-375-0 REACH-no: 01-2119453995-23 | 0.125 – 0.225 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| CUPRESSUS FUNEBRIS WOOD OIL | CAS-No.: 85085-29-6 EC-No.: 285-360-9 | 0.1 – 0.2125 | Skin Corr. 1, H314 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| Vertofix | CAS-No.: 32388-55-9 EC-No.: 251-020-3 REACH-no: 01-2119969651-28 | 0.1 – 0.2 | Skin Sens. 1B, H317 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Benzyl salicylate | CAS-No.: 118-58-1 EC-No.: 204-262-9 EC Index-No.: 607-754-00-5 REACH-no: 01-2119969442-31 | 0.075 – 0.1375 | Eye Irrit. 2, H319 Skin Sens. 1B, H317 Aquatic Chronic 3, H412 |
| Patchouli oil | CAS-No.: 8014-09-3 EC-No.: 616-944-7 EC Index-No.: 616-944-7 | 0.075 – 0.1375 | Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| Linalyl acetate | CAS-No.: 115-95-7 EC-No.: 204-116-4 REACH-no: 01-2119454789-19 | 0.0629094 – 0.1193641 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Benzyl acetate | CAS-No.: 140-11-4 EC-No.: 205-399-7 REACH-no: 01-2119638272-42 | 0.025 – 0.05 | Aquatic Chronic 3, H412 |
| (R)-p-mentha-1,8-diene; d-limonene | CAS-No.: 5989-27-5 EC-No.: 205-341-0 EC Index-No.: 601-096-00-2 REACH-no: 01-2119493353-35 | 0.012807 – 0.0192105 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 |
| .beta.-Pinene | CAS-No.: 127-91-3 EC-No.: 204-872-5 | 0.00191275 – 0.002869125 | Flam. Liq. 3, H226 |
| Toluene | CAS-No.: 108-88-3 EC-No.: 203-625-9 EC Index-No.: 601-021-00-3 | 0.0000002 – 0.0000003 | Flam. Liq. 2, H225 Skin Irrit. 2, H315 Repr. 2, H361d STOT SE 3, H336 STOT RE 2, H373 Asp. Tox. 1, H304 |
Măsuri generale de prim ajutor: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
După inhalare: Allow affected person to breathe fresh air. Allow the victim to rest.
După contactul cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
După contactul cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
După ingerare: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Symptoms/effects : Not expected to present a significant hazard under anticipated conditions of normal use.
Nu sunt disponibile informații suplimentare
Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
Nu sunt disponibile informații suplimentare
Instrucțiuni de stingere: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protecție în timpul intervenției: Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1. Pentru personalul care nu face parte din echipele de intervenție
Evacuate unnecessary personnel.
6.1.2. Pentru echipele de intervenție
Protective equipment: Equip cleanup crew with proper protection.
Emergency procedures: Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Vezi Secțiunea 8. Controlul expunerii/protecția personală.
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
Condiții de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Produse incompatibile: Strong bases. Strong acids.
Materiale incompatibile: Sources of ignition. Direct sunlight.
Germany
Storage class (LGK, TRGS 510) : LGK 12 - Non-combustible liquids
Table de depozitare comună:
Depozitare comună nu este permisă pentru: LGK 1, LGK 6.2, LGK 7
Depozitare comună cu restricții permisă pentru: LGK 4.1A, LGK 4.3, LGK 5.1C
Depozitare comună permisă pentru: LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13
Switzerland
Storage class (LK) : LK 10/12 - Liquids
Nu sunt disponibile informații suplimentare
8.1.1. Valori limită naționale de expunere profesională și valori biologice limită
| Substanță | Țară / limită | Valoare | Observații |
|---|---|---|---|
| Bis(2-ethylhexyl) adipate (103-23-1) | Poland - Occupational Exposure Limits NDS (OEL TWA) | 400 mg/m³ | |
| Toluene (108-88-3) | EU - Indicative Occupational Exposure Limit (IOEL) IOEL TWA | 192 mg/m³ 50 ppm | |
| IOEL STEL | 384 mg/m³ 100 ppm | Possibility of significant uptake through the skin | |
| Austria - Occupational Exposure Limits MAK (OEL TWA) | 190 mg/m³ 50 ppm | Skin notation | |
| Belgium - Occupational Exposure Limits OEL TWA / OEL STEL | 77 mg/m³ 20 ppm / 384 mg/m³ 100 ppm | Skin, Skin notation | |
| Bulgaria - Occupational Exposure Limits OEL TWA / OEL STEL | 192 mg/m³ 50 ppm / 384 mg/m³ 100 ppm |
A se vedea documentul original pentru lista completă de valori pe țări.
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Echipament individual de protecție: Avoid all unnecessary exposure.
Simbol(uri) pentru echipamentul individual de protecție:
8.2.2.1. Protecția ochilor și a feței
Eye protection: Chemical goggles or safety glasses
8.2.2.2. Protecția pielii
Hand protection: Wear protective gloves.
8.2.2.3. Protecția respirației
Respiratory protection: Wear appropriate mask
8.2.2.4. Pericole termice
Nu sunt disponibile informații suplimentare
Other information: Do not eat, drink or smoke during use.
| Stare fizică | Liquid |
|---|---|
| Culoare | Conforms to standard. |
| Miros | characteristic. |
| Pragul de miros | Not available |
| Punct de topire | Not available |
| Punct de îngheț | Not available |
| Punct de fierbere | Not available |
| Inflamabilitate | Non flammable. |
| Limita inferioară de explozie | Not available |
| Limita superioară de explozie | Not available |
| Punct de aprindere | > 93 °C |
| Temperatura de autoaprindere | Not available |
9.2. Alte informații
9.2.1. Informații privind clasele de pericol fizic
Nu sunt disponibile informații suplimentare
9.2.2. Alte caracteristici de siguranță
Nu sunt disponibile informații suplimentare
10.1. Reactivitate
Nu sunt disponibile informații suplimentare
10.2. Stabilitate chimică
Not established.
10.3. Posibilitatea de reacții periculoase
Not established.
10.4. Condiții de evitat
Direct sunlight. Extremely high or low temperatures.
10.5. Materiale incompatibile
Strong acids. Strong bases.
10.6. Produse de descompunere periculoase
fume. Carbon monoxide. Carbon dioxide.
11.1. Informații privind clasele de pericol definite în Regulamentul (CE) nr. 1272/2008
Următoarele intrări pentru substanțe individuale păstrează denumirile originale și datele numerice din documentul sursă.
| Substanță | Date toxicologice |
|---|---|
| Bis(2-ethylhexyl) adipate (103-23-1) | LD50 oral rat 5600 mg/kg (Source: NLM_CIP) LD50 dermal rabbit 8410 mg/kg (Source: NLM_CIP) LC50 Inhalation - Rat > 5.7 mg/l/4h |
| Ethylene brassylate (105-95-3) | LD50 oral rat > 5000 mg/kg (Source: ECHA) LD50 dermal rabbit > 5000 mg/kg (Source: ECHA) |
| Phenylethyl alcohol (60-12-8) | LD50 oral rat 1609 mg/kg (Source: EPA_HPV) LD50 oral 1610 mg/kg LD50 dermal rabbit 2535 mg/kg (Source: EPA_HPV) LC50 Inhalation - Rat > 4.63 mg/l/4h |
| Citronellol Pure (106-22-9) | LD50 oral rat 3450 mg/kg (Source: NLM_CIP) LD50 oral 3450 mg/kg bodyweight LD50 dermal rabbit 2650 mg/kg (Source: EPA_HPV) LD50 dermal 2650 mg/kg bodyweight |
| Vertofix (32388-55-9) | LD50 oral 4500 mg/kg bodyweight LD50 dermal rabbit > 5000 mg/kg (Source: ECHA_API) |
| Benzyl salicylate (118-58-1) | LD50 oral rat 2227 mg/kg (Source: NLM_CIP) LD50 oral 2200 mg/kg bodyweight LD50 dermal rabbit > 5000 mg/kg (Source: CHEMVIEW) |
| Patchouli oil (8014-09-3) | LD50 oral rat > 5 g/kg (Source: NLM_CIP) |
| Linalyl acetate (115-95-7) | LD50 oral rat 14550 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: ECHA) LC50 Inhalation - Rat > 18.94 mg/l (Exposure time: 8 h Source: ECHA) |
| Toluene (108-88-3) | LD50 oral rat 2600 mg/kg (Source: JAPAN_GHS) LD50 dermal rabbit 12000 mg/kg (Source: JAPAN_GHS) LC50 Inhalation - Rat 12.5 mg/l/4h |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | LD50 oral rat 4400 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 5 g/kg (Source: CHEMVIEW) |
| .beta.-Pinene (127-91-3) | LD50 oral rat > 5000 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: CHEMVIEW) |
| Benzyl acetate (140-11-4) | LD50 oral rat 2490 mg/kg (Source: JAPAN_GHS) LD50 oral 2490 mg/kg bodyweight LD50 dermal rabbit > 5000 mg/kg (Source: JAPAN_GHS) |
Corodarea/iritarea pielii: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Leziuni/iritare oculară grave: Not classified
Sensibilizare respiratorie sau cutanată: Not classified
Mutagenitatea celulelor germinale: Not classified
Carcinogenicitate: Not classified
Toxicitate pentru reproducere: Not classified
STOT - expunere unică: Not classified
Toluene (108-88-3) STOT-single exposure: May cause drowsiness or dizziness.
STOT - expunere repetată: Not classified
Toluene (108-88-3) STOT-repeated exposure: May cause damage to organs through prolonged or repeated exposure.
Pericol prin aspirație: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
12.1. Toxicitate
Hazardous to the aquatic environment, short-term (acute) : Not classified
Hazardous to the aquatic environment, long-term (chronic) : Harmful to aquatic life with long lasting effects.
12.2. Persistență și degradabilitate
CHAMPAGNE ROSE #EU30715F 25% in DPG: Not established.
12.3. Potențial de bioacumulare
CHAMPAGNE ROSE #EU30715F 25% in DPG: Not established.
12.4. Mobilitate în sol
Nu sunt disponibile informații suplimentare
12.5. Rezultatele evaluării PBT și vPvB
Nu sunt disponibile informații suplimentare
12.6. Proprietăți de perturbare endocrină
Nu sunt disponibile informații suplimentare
12.7. Alte efecte adverse
Additional information : Avoid release to the environment.
13.1. Metode de tratare a deșeurilor
Recomandări pentru eliminarea produsului/ambalajului: Dispose in a safe manner in accordance with local/national regulations.
Informații ecologice: Avoid release to the environment.
Cod HP: HP4 - “Irritant – skin irritation and eye damage:” waste which on application can cause skin irritation or damage to the eye.
HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
Conform ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|
| 14.1. UN number or ID number: Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.2. UN proper shipping name: Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.3. Transport hazard class(es): Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.4. Packing group: Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.5. Environmental hazards: Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
No supplementary information available
14.6. Precauții speciale pentru utilizator
Overland transport: Not applicable
Transport by sea: Not applicable
Air transport: Not applicable
Inland waterway transport: Not applicable
Rail transport: Not applicable
14.7. Transport maritim în vrac conform instrumentelor IMO
Not applicable
15.1.1. Reglementări UE
REACH Anexa XVII (Lista de restricții)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(a) | Toluene ; (R)-p-mentha-1,8-diene; d-limonene ; .beta.-Pinene | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F |
| 3(b) | Phenylethyl alcohol ; 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone ; Citronellol Pure ; CUPRESSUS FUNEBRIS WOOD OIL ; Vertofix ; Benzyl salicylate ; Patchouli oil ; Linalyl acetate ; Toluene ; (R)-p-mentha-1,8-diene; d-limonene | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | CHAMPAGNE ROSE #EU30715F 25% in DPG ; Bis(2-ethylhexyl) adipate ; Ethylene brassylate ; 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone ; CUPRESSUS FUNEBRIS WOOD OIL ; Vertofix ; Benzyl salicylate ; Patchouli oil ; (R)-p-mentha-1,8-diene; d-limonene ; Benzyl acetate | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 |
| 40. | Toluene ; (R)-p-mentha-1,8-diene; d-limonene ; .beta.-Pinene | Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. |
| 48. | Toluene | Toluene |
REACH Anexa XIV (Lista de autorizare)
Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC)
Contains no substance(s) listed on the REACH Candidate List
Regulamentul PIC (Prior Informed Consent)
Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
Regulamentul POP (Persistent Organic Pollutants)
Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Regulamentul Ozonului (1005/2009)
Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Regulamentul Consiliului (EC) pentru controlul articolelor cu dublă utilizare
Contains no substance subject to the COUNCIL REGULATION (EC) for the control of dual-use items
Regulamentul privind precursorii de explozivi (2019/1148)
Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Regulamentul privind precursorii de droguri (273/2004)
Contains substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
| Name | CN designation | CAS-No. | CN code | Category, Subcategory | Threshold | Annex |
|---|---|---|---|---|---|---|
| Toluene | 108-88-3 | 2902 30 00 | Category 3 | Annex I |
15.1.2. Reglementări naționale
France
| Cod | Descriere |
|---|---|
| RG 4 BIS | Gastrointestinal disorders caused by benzene, toluene, xylenes and all products containing them |
| RG 84 | Conditions caused by liquid organic solvents for professional use: saturated or unsaturated aliphatic or cyclic liquid hydrocarbons and mixtures thereof; liquid halogenated hydrocarbons; nitrated derivatives of aliphatic hydrocarbons; alcohols; glycols, glycol ethers; ketones; aldehydes; aliphatic and cyclic ethers, including tetrahydrofuran; esters; dimethylformamide and dimethylacetamine; acetonitrile and propionitrile; pyridine; dimethylsulfone and dimethylsulfoxide |
Germany
Water hazard class (WGK) : WGK 2, Significantly hazardous to water (Classification according to AwSV, Annex 1).
Hazardous Incident Ordinance (12. BImSchV) : Is not subject to the Hazardous Incident Ordinance (12. BImSchV)
Netherlands
ABM category : A(2) - toxic for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen : CUPRESSUS FUNEBRIS WOOD OIL is listed
SZW-lijst van mutagene stoffen : CUPRESSUS FUNEBRIS WOOD OIL is listed
SZW-lijst van reprotoxische stoffen – Borstvoeding : None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid : None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling : Toluene is listed
Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed
Danish National Regulations : Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2. Evaluare a securității chimice
No chemical safety assessment has been carried out
Date sursă: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Alte informații: None.
Păstrat conform documentului sursă:
| Acute Tox. 4 (Oral) | Acute toxicity (oral), Category 4 |
|---|---|
| Aquatic Acute 1 | Hazardous to the aquatic environment – Acute Hazard, Category 1 |
| Aquatic Chronic 1 | Hazardous to the aquatic environment – Chronic Hazard, Category 1 |
| Aquatic Chronic 2 | Hazardous to the aquatic environment – Chronic Hazard, Category 2 |
| Aquatic Chronic 3 | Hazardous to the aquatic environment – Chronic Hazard, Category 3 |
| Asp. Tox. 1 | Aspiration hazard, Category 1 |
| EUH208 | Contains 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone, Citronellol Pure, CUPRESSUS FUNEBRIS WOOD OIL, Vertofix, Benzyl salicylate, Patchouli oil, Linalyl acetate. May produce an |