Fișă cu date de securitate conform Regulamentului (CE) Nr. 1907/2006 (REACH) cu modificarea Regulamentului (UE) 2020/878
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Pictograme de pericol (CLP): GHS07
Cuvânt de avertizare (CLP): Warning
Conține: Linalyl acetate; Linalool; 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone; Citronellol Pure; Citrus medica limonum (Lemon) peel oil ; (R)-p-mentha-1,8-diene; d-limonene; CUPRESSUS FUNEBRIS WOOD OIL
Fraze de pericol (CLP): H317 - May cause an allergic skin reaction. / H412 - Harmful to aquatic life with long lasting effects.
Fraze de precauție (CLP):
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P321 - Specific treatment (see supplemental first aid instruction on this label).
Fraze suplimentare: For professional users only.
Not applicable
| Nume | Identificator produs | % | Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP] |
|---|---|---|---|
| benzyl benzoate | CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33 |
2.01 – 4.01 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Linalyl acetate | CAS-No.: 115-95-7 EC-No.: 204-116-4 REACH-no: 01-2119454789-19 |
0.58098256 – 1.16325606 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Linalool | CAS-No.: 78-70-6 EC-No.: 201-134-4 EC Index-No.: 603-235-00-2 REACH-no: 01-2119474016-42 |
0.49147548 – 0.973429105 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone | CAS-No.: 54464-57-2 EC-No.: 259-174-3 REACH-no: 01-2119489989-04 |
0.31 – 0.62 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 1, H410 |
| Citronellol Pure | CAS-No.: 106-22-9 EC-No.: 203-375-0 REACH-no: 01-2119453995-23 |
0.25 – 0.5 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| (R)-p-mentha-1,8-diene; d-limonene substance with national workplace exposure limit(s) (DE, ES, FI, SI, NO, CH) |
CAS-No.: 5989-27-5 EC-No.: 205-341-0 EC Index-No.: 601-096-00-2 REACH-no: 01-2119493353-35 |
0.1507368 – 0.3077543 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 |
| Citrus medica limonum (Lemon) peel oil | CAS-No.: 8008-56-8 EC-No.: 284-515-8 |
0.125 – 0.255625 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Repr. 2, H361 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| CUPRESSUS FUNEBRIS WOOD OIL | CAS-No.: 85085-29-6 EC-No.: 285-360-9 |
0.08 – 0.155 | Skin Corr. 1, H314 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| ACETYL HEXAMETHYL TETRALIN | CAS-No.: 21145-77-7 EC-No.: 244-240-6 |
0.06 – 0.125 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| .beta.-Pinene substance with national workplace exposure limit(s) (BE, EE, ES, LT, PT, SE, NO) |
CAS-No.: 127-91-3 EC-No.: 204-872-5 |
0.0045906 – 0.009372475 | Flam. Liq. 3, H226 |
| Toluene substance with national workplace exposure limit(s) (AT, BE, BG, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GI, GR, HR, HU, IE, IT, LT, LU, LV, MT, NL, PL, PT, RO, SE, SI, SK, NO, CH, TR); substance with a Community workplace exposure limit |
CAS-No.: 108-88-3 EC-No.: 203-625-9 EC Index-No.: 601-021-00-3 |
0.00000048 – 0.00000098 | Flam. Liq. 2, H225 Skin Irrit. 2, H315 Repr. 2, H361d STOT SE 3, H336 STOT RE 2, H373 Asp. Tox. 1, H304 |
Full text of H- and EUH-statements: see section 16
First-aid measures general: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation: Allow affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
First-aid measures after eye contact: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
First-aid measures after ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
No additional information available
Suitable extinguishing media: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media: Do not use a heavy water stream.
No additional information available
Firefighting instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1. Pentru personalul care nu face parte din serviciile de urgență
Emergency procedures: Evacuate unnecessary personnel.
6.1.2. Pentru respondenții la urgențe
Protective equipment: Equip cleanup crew with proper protection.
Emergency procedures: Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Methods for cleaning up: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Section 8. Exposure controls and personal protection.
Precautions for safe handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
Storage conditions: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Incompatible products: Strong bases. Strong acids.
Incompatible materials: Sources of ignition. Direct sunlight.
No additional information available
| Țară / Substanță | Valori |
|---|---|
| Toluene (108-88-3) |
EU - Indicative Occupational Exposure Limit (IOEL) IOEL TWA 192 mg/m³ 50 ppm IOEL STEL 384 mg/m³ 100 ppm Remark Possibility of significant uptake through the skin |
| Austria | MAK (OEL TWA) 190 mg/m³ 50 ppm MAK (OEL STEL) 380 mg/m³ 100 ppm OEL chemical category Skin notation |
| Belgium | OEL TWA 77 mg/m³ 20 ppm OEL STEL 384 mg/m³ 100 ppm OEL chemical category Skin, Skin notation |
| Bulgaria | OEL TWA 192 mg/m³ 50 ppm OEL STEL 384 mg/m³ 100 ppm BLV 1.6 mmol/mmol Creatinine Parameter: Hippuric acid - Medium: urine - Sampling time: at the end of exposure or end of work shift |
| Croatia | GVI (OEL TWA) 192 mg/m³ 50 ppm KGVI (OEL STEL) 384 mg/m³ 100 ppm OEL chemical category Skin notation BLV 1 mg/l Parameter: Toluene - Medium: blood - Sampling time: at the end of the work shift 20 ppm Parameter: Toluene - Medium: final exhaled air - Sampling time: during exposure 2.5 g/g creatinine Parameter: Hippuric acid - Medium: urine - Sampling time: at the end of the work shift (calculated on the average Creatinine value of 1.2 g/L urine) |
| Cyprus | OEL TWA 192 mg/m³ 50 ppm OEL STEL 384 mg/m³ 100 ppm OEL chemical category Skin-potential for cutaneous absorption |
| Czech Republic | PEL (OEL TWA) 200 mg/m³ OEL chemical category Potential for cutaneous absorption BLV 1.6 µmol/mmol Creatinine Parameter: o-Cresol - Medium: urine - Sampling time: end of shift (after hydrolysis) 1000 µmol/mmol Creatinine Parameter: Hippuric acid - Medium: urine - Sampling time: end of shift (exposure testing using the o-Cresol parameter to precisely measure Toluene exposure is needed if the value of Hippuric acid is between 1600 and 2500 mg/g of Creatinine, no additional testing is needed if the Hippuric acid value is >2500 mg/g of Creatinine as work exposure to Toluene will have highly exceeded the PEL value.) 1.5 mg/g creatinine Parameter: o-Cresol - Medium: urine - Sampling time: end of shift (after hydrolysis) 1600 mg/g creatinine Parameter: Hippuric acid - Medium: urine - Sampling time: end of shift (exposure testing using the o-Cresol parameter to precisely measure Toluene exposure is needed if the value of Hippuric acid is between 1600 and 2500 mg/g of Creatinine, no additional testing is needed if the Hippuric acid value is >2500 mg/g of Creatinine as work exposure to Toluene will have highly exceeded the PEL value.) |
Lista continuă în documentul original pentru alte țări și substanțe.
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Personal protective equipment: Avoid all unnecessary exposure.
Personal protective equipment symbol(s):
Eye protection: Chemical goggles or safety glasses
Hand protection: Wear protective gloves.
Respiratory protection: Wear appropriate mask
No additional information available
Other information: Do not eat, drink or smoke during use.
| Physical state | Liquid |
|---|---|
| Colour | Conforms to standard. |
| Odour | characteristic. |
| Odour threshold | Not available |
| Melting point | Not available |
| Freezing point | Not available |
| Boiling point | Not available |
| Flammability | Non flammable. |
| Lower explosion limit | Not available |
| Upper explosion limit | Not available |
| Flash point | > 93 °C |
| Auto-ignition temperature | Not available |
| Decomposition temperature | Not available |
| pH | Not available |
| Viscosity, kinematic | Not available |
| Solubility | Not available |
| Partition coefficient n-octanol/water (Log Kow) | Not available |
| Vapour pressure | Not available |
| Vapour pressure at 50°C | Not available |
| Density | Not available |
| Relative density | Not available |
| Relative vapour density at 20°C | Not available |
| Particle characteristics | Not applicable |
9.2.1. Informații privind clasele de pericol fizic
No additional information available
9.2.2. Alte caracteristici de siguranță
No additional information available
No additional information available
Not established.
Not established.
Direct sunlight. Extremely high or low temperatures.
Strong acids. Strong bases.
fume. Carbon monoxide. Carbon dioxide.
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
Substanțe și date toxilogice:
| benzyl benzoate (120-51-4) | LD50 oral rat > 2000 mg/kg (Source: ECHA_API) |
|---|---|
| benzyl benzoate (120-51-4) | LD50 oral 1160 mg/kg bodyweight LD50 dermal rabbit 4000 mg/kg (Source: NLM_CIP) |
| Linalyl acetate (115-95-7) | LD50 oral rat 14550 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: ECHA) LC50 Inhalation - Rat > 18.94 mg/l (Exposure time: 8 h Source: ECHA) |
| Linalool (78-70-6) | LD50 oral 2790 mg/kg |
| Citronellol Pure (106-22-9) | LD50 oral rat 3450 mg/kg (Source: NLM_CIP) LD50 oral 3450 mg/kg bodyweight LD50 dermal rabbit 2650 mg/kg (Source: EPA_HPV) LD50 dermal 2650 mg/kg bodyweight |
| Toluene (108-88-3) | LD50 oral rat 2600 mg/kg (Source: JAPAN_GHS) LD50 dermal rabbit 12000 mg/kg (Source: JAPAN_GHS) LC50 Inhalation - Rat 12.5 mg/l/4h |
| Citrus medica limonum (Lemon) peel oil (8008-56-8) | LD50 oral rat 2840 mg/kg (Source: NLM_CIP) |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | LD50 oral rat 4400 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 5 g/kg (Source: CHEMVIEW) |
| .beta.-Pinene (127-91-3) | LD50 oral rat > 5000 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: CHEMVIEW) |
| ACETYL HEXAMETHYL TETRALIN (21145-77-7) | LD50 oral rat 570 mg/kg (Source: NLM_CIP) LD50 oral 1000 mg/kg bodyweight LD50 dermal rabbit > 5 g/kg (Source: NLM_HSDB) |
Skin corrosion/irritation : Not classified
Additional information : Based on available data, the classification criteria are not met
Serious eye damage/irritation : Not classified
Additional information : Based on available data, the classification criteria are not met
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Toluene (108-88-3)
IARC group 3 - Not classifiable
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)
IARC group 3 - Not classifiable
Reproductive toxicity : Not classified
Additional information : Based on available data, the classification criteria are not met
STOT-single exposure : Not classified
Additional information : Based on available data, the classification criteria are not met
Toluene (108-88-3)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Not classified
Additional information : Based on available data, the classification criteria are not met
Toluene (108-88-3)
STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Additional information : Based on available data, the classification criteria are not met
benzyl benzoate (120-51-4)
Viscosity, kinematic 7.456 mm²/s
Toluene (108-88-3)
Hydrocarbon Yes
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)
Hydrocarbon Yes
.beta.-Pinene (127-91-3)
Hydrocarbon Yes
11.2.1. Proprietăți perturbatoare endocrine
No additional information available
11.2.2. Alte informații
Potential adverse human health effects and symptoms : Based on available data, the classification criteria are not met
Hazardous to the aquatic environment, short–term (acute) : Not classified
Hazardous to the aquatic environment, long–term (chronic) : Harmful to aquatic life with long lasting effects.
| benzyl benzoate (120-51-4) | LC50 - Fish [1] 2.32 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) NOEC (chronic) 0.168 mg/l |
|---|---|
| Linalyl acetate (115-95-7) | LC50 - Fish [1] 11 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [flow-through] Source: ECHA) |
| Linalool (78-70-6) | EC50 96h - Algae [1] 88.3 mg/l (Species: Desmodesmus subspicatus) |
| Toluene (108-88-3) | LC50 - Fish [1] 15.22 – 19.05 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) LC50 - Fish [2] 12.6 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static] Source: EPA) EC50 - Crustacea [1] 5.46 – 9.83 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) EC50 - Crustacea [2] 11.5 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 72h - Algae [1] 12.5 mg/l (Species: Pseudokirchneriella subcapitata [static]) EC50 96h - Algae [1] > 433 mg/l (Species: Pseudokirchneriella subcapitata) |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | LC50 - Fish [1] 0.619 – 0.796 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) LC50 - Fish [2] 35 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss Source: EPA) |
BERGAMOT #EU35643F 10% in DPG: Persistence and degradability Not established.
benzyl benzoate (120-51-4): May cause long-term adverse effects in the environment.
Linalyl acetate (115-95-7): Rapidly degradable
Linalool (78-70-6): Rapidly degradable
1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone (54464-57-2): Rapidly degradable
Citronellol Pure (106-22-9): Rapidly degradable
Toluene (108-88-3): Rapidly degradable
Citrus medica limonum (Lemon) peel oil (8008-56-8): Rapidly degradable
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5): Rapidly degradable
.beta.-Pinene (127-91-3): Rapidly degradable
CUPRESSUS FUNEBRIS WOOD OIL (85085-29-6): Rapidly degradable
ACETYL HEXAMETHYL TETRALIN (21145-77-7): Rapidly degradable
BERGAMOT #EU35643F 10% in DPG: Bioaccumulative potential Not established.
benzyl benzoate (120-51-4): Partition coefficient n-octanol/water (Log Pow) 3.97 (at 25 °C)
Linalyl acetate (115-95-7): Partition coefficient n-octanol/water (Log Pow) 3.9 (at 25 °C)
Citronellol Pure (106-22-9): Partition coefficient n-octanol/water (Log Pow) 3.41 (at 25 °C)
Toluene (108-88-3): Partition coefficient n-octanol/water (Log Pow) 2.73 (at 20 °C (at pH 7)
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5): Partition coefficient n-octanol/water (Log Pow) 4.38 (at 37 °C (at pH 7.2)
ACETYL HEXAMETHYL TETRALIN (21145-77-7): Partition coefficient n-octanol/water (Log Pow) 5.7 (at 24 °C)
No additional information available
No additional information available
No additional information available
Additional information: Avoid release to the environment.
Product/Packaging disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.
Ecological information: Avoid release to the environment.
HP Code: HP4 - “Irritant – skin irritation and eye damage:” waste which on application can cause skin irritation or damage to the eye.
HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID | |
|---|---|---|---|---|---|
| 14.1. UN number or ID number | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.2. UN proper shipping name | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.3. Transport hazard class(es) | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.4. Packing group | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.5. Environmental hazards | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
No supplementary information available
Overland transport: Not applicable
Transport by sea: Not applicable
Air transport: Not applicable
Inland waterway transport: Not applicable
Rail transport: Not applicable
Not applicable
15.1.1. EU-Regulations
REACH Annex XVII (Restriction List)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(a) | Toluene ; Citrus medica limonum (Lemon) peel oil ; (R)-p-mentha-1,8-diene; d-limonene ; .beta |