Forma produsului: Mixture
Numele produsului: SWEET ORANGE #EU37824F 5% in DPG
Codul produsului: EU37824F_5%
Tipul produsului: Perfumes, fragrances
Forma produsului: Mixture
Numele produsului: SWEET ORANGE #EU37824F 5% in DPG
Codul produsului: EU37824F_5%
Tipul produsului: Perfumes, fragrances
1.2.1. Utilizări identificate relevante
Industrial/Professional use spec: Industrial
For professional use only
Use of the substance/mixture: Perfumes, fragrances
Function or use category: Odour agents
1.2.2. Utilizări contraindicate
No additional information available
No additional information available
No additional information available
Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Hazardous to the aquatic environment – Chronic Hazard, Category 3 H412
Full text of H- and EUH-statements: see section 16
Efecte adverse fizico-chimice, asupra sănătății umane și asupra mediului
No additional information available
Etichetare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Cuvânt de avertizare (CLP): -
Fraze de pericol (CLP): H412 - Harmful to aquatic life with long lasting effects.
Fraze de precauție (CLP): P273 - Avoid release to the environment.
P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
EUH-statements: EUH208 - Contains (R)-p-mentha-1,8-diene; d-limonene, Tangerine oil. May produce an allergic reaction.
Fraze suplimentare: For professional users only.
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
Not applicable
| Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
|---|---|---|---|
| benzyl benzoate |
CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33 |
1.845 – 3.6875 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| (R)-p-mentha-1,8-diene; d-limonene |
substance with national workplace exposure limit(s) (DE, ES, FI, SI, NO, CH) CAS-No.: 5989-27-5 EC-No.: 205-341-0 EC Index-No.: 601-096-00-2 REACH-no: 01-2119493353-35 |
0.395 – 0.7875 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) |
CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 |
0.055 – 0.105 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Tangerine oil |
CAS-No.: 8016-85-1 EC-No.: 297-672-2 |
0.055 – 0.105 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
Full text of H- and EUH-statements: see section 16
First-aid measures general: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation: Allow affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
First-aid measures after eye contact: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
First-aid measures after ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
No additional information available
Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
No additional information available
Firefighting instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1. Pentru personalul care nu face parte din serviciile de urgență
Emergency procedures: Evacuate unnecessary personnel.
6.1.2. Pentru personalul de intervenție
Protective equipment: Equip cleanup crew with proper protection.
Emergency procedures: Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Methods for cleaning up: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Section 8. Exposure controls and personal protection.
Precautions for safe handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
Storage conditions: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Incompatible products: Strong bases. Strong acids.
Incompatible materials: Sources of ignition. Direct sunlight.
No additional information available
8.1.1. Valori limită naționale de expunere profesională și biologice
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | |
|---|---|
| Finland - Occupational Exposure Limits | |
| HTP (OEL TWA) [1] | 140 mg/m³ |
| HTP (OEL TWA) [2] | 25 ppm |
| HTP (OEL STEL) | 280 mg/m³ |
| HTP (OEL STEL) [ppm] | 50 ppm |
| Germany - Occupational Exposure Limits (TRGS 900) | |
| AGW (OEL TWA) [1] | 28 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) |
| AGW (OEL TWA) [2] | 5 ppm (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) |
| Chemical category | Skin notation, Skin sensitization |
| Slovenia - Occupational Exposure Limits | |
| OEL TWA | 28 mg/m³ |
| OEL TWA | 5 ppm |
| OEL STEL | 112 mg/m³ |
| OEL STEL | 20 ppm |
| OEL chemical category | Potential for cutaneous absorption |
| Spain - Occupational Exposure Limits | |
| VLA-ED (OEL TWA) [1] | 168 mg/m³ |
| VLA-ED (OEL TWA) [2] | 30 ppm |
| OEL chemical category | Sensitizer, skin - potential for cutaneous absorption |
| Norway - Occupational Exposure Limits | |
| Grenseverdi (OEL TWA) [1] | 140 mg/m³ |
| Grenseverdi (OEL TWA) [2] | 25 ppm |
| Korttidsverdi (OEL STEL) | 175 mg/m³ (value calculated) |
| Korttidsverdi (OEL STEL) [ppm] | 37.5 ppm (value calculated) |
| OEL chemical category | Allergenic substance |
| Switzerland - Occupational Exposure Limits | |
| MAK (OEL TWA) [1] | 40 mg/m³ |
| MAK (OEL TWA) [2] | 7 ppm |
| KZGW (OEL STEL) | 80 mg/m³ |
| KZGW (OEL STEL) [ppm] | 14 ppm |
| OEL chemical category | Sensitizer |
8.1.2. Proceduri de monitorizare recomandate
No additional information available
8.1.3. Contaminanți aerieni formați
No additional information available
8.1.4. DNEL și PNEC
No additional information available
8.1.5. Control banding
No additional information available
8.2.1. Controale tehnice corespunzătoare
No additional information available
8.2.2. Echipament individual de protecție
Personal protective equipment:
Avoid all unnecessary exposure.
Personal protective equipment symbol(s):
8.2.2.1. Protecția ochilor și a feței
Eye protection: Chemical goggles or safety glasses
8.2.2.2. Protecția pielii
Hand protection: Wear protective gloves.
8.2.2.3. Protecția respiratorie
Respiratory protection: Wear appropriate mask
8.2.2.4. Pericole termice
No additional information available
8.2.3. Controale ale expunerii asupra mediului
Other information: Do not eat, drink or smoke during use.
| Physical state | Liquid |
| Colour | Standard. |
| Odour | characteristic. |
| Odour threshold | No data available |
| pH | No data available |
| Relative evaporation rate (butylacetate=1) | No data available |
| Melting point | No data available |
| Freezing point | No data available |
| Boiling point | No data available |
| Flash point | > 93 °C |
| Auto-ignition temperature | No data available |
| Decomposition temperature | No data available |
| Flammability (solid, gas) | Non flammable. |
| Vapour pressure | No data available |
| Relative vapour density at 20°C | No data available |
| Relative density | No data available |
| Solubility | No data available |
| Partition coefficient n-octanol/water (Log Pow) | No data available |
| Viscosity, kinematic | No data available |
| Viscosity, dynamic | No data available |
| Explosive properties | No data available |
| Oxidising properties | No data available |
| Explosive limits | No data available |
No additional information available
10.1. Reactivitate
No additional information available
10.2. Stabilitate chimică
Not established.
10.3. Posibilitatea reacțiilor periculoase
Not established.
10.4. Condiții de evitat
Direct sunlight. Extremely high or low temperatures.
10.5. Materiale incompatibile
Strong acids. Strong bases.
10.6. Produși de descompunere periculoși
fume. Carbon monoxide. Carbon dioxide.
Acute toxicity (oral): Not classified
Acute toxicity (dermal): Not classified
Acute toxicity (inhalation): Not classified
benzyl benzoate (120-51-4)
LD50 oral rat 500 mg/kg (Source: NLM_CIP)
LD50 oral 1160 mg/kg bodyweight
LD50 dermal rabbit 4000 mg/kg (Source: NLM_CIP)
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)
LD50 oral rat 4400 mg/kg (Source: CHEMVIEW)
LD50 dermal rabbit > 5 g/kg (Source: CHEMVIEW)
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5)
LD50 oral rat > 3250 mg/kg (Source: CHEMVIEW)
LD50 dermal rabbit > 3250 mg/kg (Source: CHEMVIEW)
Skin corrosion/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Serious eye damage/irritation: Not classified
Additional information: Based on available data, the classification criteria are not met
Respiratory or skin sensitisation: Not classified
Additional information: Based on available data, the classification criteria are not met
Germ cell mutagenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
Carcinogenicity: Not classified
Additional information: Based on available data, the classification criteria are not met
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)
IARC group 3 - Not classifiable
Reproductive toxicity: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-single exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-repeated exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
Aspiration hazard: Not classified
Additional information: Based on available data, the classification criteria are not met
benzyl benzoate (120-51-4)
Viscosity, kinematic 7.456 mm²/s
Potential adverse human health effects and symptoms
Based on available data, the classification criteria are not met
Hazardous to the aquatic environment, short–term (acute): Not classified
Hazardous to the aquatic environment, long–term (chronic): Harmful to aquatic life with long lasting effects.
benzyl benzoate (120-51-4)
LC50 - Fish [1] 2.32 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA)
NOEC (chronic) 0.168 mg/l
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)
LC50 - Fish [1] 0.619 – 0.796 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA)
LC50 - Fish [2] 35 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss Source: EPA)
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5)
LC50 - Fish [1] 0.452 mg/l Wolf, 1996d-27682
LC50 - Other aquatic organisms [1] > 0.14 mg/l REACH DOSSIER Pimephales promelas
EC50 - Crustacea [2] 260 μg/l REACH Dossier
EC50 - Other aquatic organisms [1] 0.131 mg/l REACH Dossier
SWEET ORANGE #EU37824F 5% in DPG
Persistence and degradability Not established.
benzyl benzoate (120-51-4)
Persistence and degradability May cause long-term adverse effects in the environment.
SWEET ORANGE #EU37824F 5% in DPG
Bioaccumulative potential Not established.
benzyl benzoate (120-51-4)
Partition coefficient n-octanol/water (Log Pow) 3.97 (at 25 °C)
Bioaccumulative potential Not established.
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)
Partition coefficient n-octanol/water (Log Pow) 4.38 (at 37 °C (at pH 7.2)
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5)
BCF - Fish [1] (1618 dimensionless (whole body w.w.)
Partition coefficient n-octanol/water (Log Pow) 5.3 (at 25 °C (at pH 7)
No additional information available
No additional information available
Additional information: Avoid release to the environment.
Product/Packaging disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials: Avoid release to the environment.
HP Code: HP3 - “Flammable:”
– flammable liquid waste: liquid waste having a flash point below 60 °C or waste gas oil, diesel and light heating oils having a flash point > 55 °C and ≤ 75 °C;
– flammable pyrophoric liquid and solid waste: solid or liquid waste which, even in small quantities, is liable to ignite within five minutes after coming into contact with air;
– flammable solid waste: solid waste which is readily combustible or may cause or contribute to fire through friction;
– flammable gaseous waste: gaseous waste which is flammable in air at 20 °C and a standard pressure of 101.3 kPa;
– water reactive waste: waste which, in contact with water, emits flammable gases in dangerous quantities;
– other flammable waste: flammable aerosols, flammable self-heating waste, flammable organic peroxides and flammable self-reactive waste.
HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID | |
|---|---|---|---|---|---|
| 14.1. UN number | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.2. UN proper shipping name | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.3. Transport hazard class(es) | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.4. Packing group | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.5. Environmental hazards | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
No supplementary information available
14.6. Special precautions for user
Overland transport
Not applicable
Transport by sea
Not applicable
Air transport
Not applicable
Inland waterway transport
Not applicable
Rail transport
Not applicable
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
15.1.1. Reglementări UE
REACH Annex XVII (Restriction List)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(a) | (R)-p-mentha-1,8-diene; d-limonene ; Tangerine oil | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F |
| 3(b) | benzyl benzoate ; (R)-pmentha-1,8-diene; dlimonene ; Tangerine oil | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | SWEET ORANGE #EU37824F 5% in DPG ; benzyl benzoate ; (R)-pmentha-1,8-diene; dlimonene ; 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) ; Tangerine oil | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 |
| 40. | (R)-p-mentha-1,8-diene; d-limonene ; Tangerine oil | Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. |
REACH Annex XIV (Authorisation List)
Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC)
Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent)
Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants)
Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009)
Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Explosives Precursors Regulation (2019/1148)
Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004)
Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
15.1.2. Reglementări naționale
Germany
Water hazard class (WGK): WGK 1, Slightly hazardous to water (Classification according to AwSV, Annex 1).
Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids.
Joint storage table:
Joint storage not permitted for : LGK 1, LGK 6.2, LGK 7.
Joint storage with restrictions permitted for : LGK 4.1A, LGK 4.3, LGK 5.1C.
Joint storage permitted for : LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13.
Hazardous Incident Ordinance (12. BImSchV): Is not subject of the Hazardous Incident Ordinance (12. BImSchV)
Netherlands
ABM category: A(2) - toxic for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen: Tangerine oil is listed
SZW-lijst van mutagene stoffen: None of the components are listed
SZW-lijst van reprotoxische stoffen – Borstvoeding: None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid: None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling: None of the components are listed
Denmark
Classification remarks: Emergency management guidelines for the storage of flammable liquids must be followed
Switzerland
Storage class (LK): LK 10/12 - Liquids
No chemical safety assessment has been carried out
Data sources: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information: None.
Full text of H- and EUH-statements:
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard, Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment – Chronic Hazard, Category 1
Aquatic Chronic 2 Hazardous to the aquatic environment – Chronic Hazard, Category 2
Aquatic Chronic 3 Hazardous to the aquatic environment – Chronic Hazard, Category 3
Asp. Tox. 1 Aspiration hazard, Category 1
EUH208 Contains (R)-p-mentha-1,8-diene; d-limonene, Tangerine oil. May produce an allergic reaction.
Flam. Liq. 3 Flammable liquids, Category 3
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Skin Irrit. 2 Skin corrosion/irritation, Category 2
Skin Sens. 1 Skin sensitisation, Category 1
Skin Sens. 1B Skin sensitisation, category 1B
The classification complies with: ATP 12
Safety Data Sheet (SDS), EU
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.