ECO REACH Honeydew Liquid Dye #D23207

Restricții de utilizare: Nu pentru: Food/feedstuff additives, Cosmetics, personal care products

FRENCH COLOR & FRAGRANCE CO., INC.
488 GRAND AVENUE
07631 ENGLEWOOD, NEW JERSEY
USA
T +001-201-567-6883 - F +001-201-567-5749
Regulatory@frenchcolor.com - www.frenchcolor.com

Număr de urgență: 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086

Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]

• Skin sensitisation, Category 1 — H317
• Hazardous to the aquatic environment – Chronic Hazard, Category 4 — H413

Efecte adverse fizico-chimice, asupra sănătății umane și asupra mediului: Poate cauza efecte nocive de lungă durată asupra organismelor acvatice. Poate provoca o reacție alergică a pielii.

Etichetare conform Regulamentului (CE) nr. 1272/2008 [CLP]

Pictograme de pericol (CLP): GHS07

Cuvânt de avertizare (CLP): Warning

Conține: 3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives

Fraze de pericol (CLP):

• H317 - May cause an allergic skin reaction.
• H413 - May cause long lasting harmful effects to aquatic life.

Fraze de precauție (CLP):

• P261 - Evitați să inspirați dust/fume/gas/mist/vapours/spray.
• P272 - Contaminated work clothing should not be allowed out of the workplace.
• P273 - Evitați eliberarea în mediu.
• P280 - Purtați protective gloves/protective clothing/eye protection/face protection/hearing protection.
• P302+P352 - ÎN CAZ DE CONTACT CU PIELEA: Spălați cu multă apă.
• P321 - Specific treatment (see supplemental first aid instruction on this label).

Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

Amestecul nu conține substanțe incluse în lista stabilită în conformitate cu Article 59(1) of REACH pentru proprietăți de perturbare endocrină sau nu este identificat ca având astfel de proprietăți în conformitate cu criteriile stabilite în Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 la o concentrație egală sau mai mare de 0,1 %

Not applicable

Full text of H- and EUH-statements: see section 16

Măsuri generale de prim ajutor: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

După inhalare: Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest.

După contactul cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention.

După contactul cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. Rinse eyes with water as a precaution.

După ingerare: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center or a doctor if you feel unwell.

Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.

Symptoms/effects after skin contact: May cause an allergic skin reaction.

Treat symptomatically.

Mijloace de stingere adecvate: Sand. Water spray. Dry powder. Foam. Carbon dioxide.

Mijloace de stingere neadecvate: Do not use a heavy water stream.

Produse periculoase de descompunere în caz de incendiu: Toxic fumes may be released.

Instrucțiuni de stingere a incendiilor: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.

Protecție în timpul stingerii incendiilor: Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.

6.1.1. Pentru personalul care nu participă la situații de urgență

Proceduri de urgență: Ventilate spillage area. Evacuate unnecessary personnel. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.

6.1.2. Pentru respondenții la situații de urgență

Echipament de protecție: Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection".

Proceduri de urgență: Ventilate area.

Evitați eliberarea în mediu. Preveniți pătrunderea în canalizări și ape publice. Notificați autoritățile dacă lichidul pătrunde în canalizări sau ape publice.

Metode de curățare: Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.

Alte informații: Dispose of materials or solid residues at an authorized site.

See Section 8. Exposure controls and personal protection. For further information refer to section 13.

Precauții pentru manipularea în siguranță: Ensure good ventilation of the work station. Wear personal protective equipment. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray.

Măsuri de igienă: Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.

Condiții de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container closed when not in use. Store in a well-ventilated place. Keep cool.

Produse incompatibile: Strong bases. Strong acids.

Materiale incompatibile: Sources of ignition. Direct sunlight.

Perioada maximă de depozitare: 1 year

Temperatura de depozitare: 4 – 37 °C

Zona de depozitare: Store in a well-ventilated place. Store away from heat.

Reguli speciale privind ambalarea: Store in a closed container.

Materiale de ambalare: Do not store in corrodable metal.

No additional information available

8.1.1. Valori limită naționale de expunere ocupațională și biologice

8.1.2. Proceduri recomandate de monitorizare: No additional information available

8.1.3. Contaminanți aerieni formați: No additional information available

8.1.4. DNEL și PNEC: No additional information available

8.1.5. Control banding: No additional information available

8.2.1. Controale tehnice corespunzătoare

Ensure good ventilation of the work station.

8.2.2. Echipament individual de protecție

Avoid all unnecessary exposure.

8.2.2.1. Protecția ochilor și a feței

Protecția ochilor: Chemical goggles or safety glasses. Safety glasses

8.2.2.2. Protecția pielii

Protecția pielii și a corpului: Wear suitable protective clothing

Protecția mâinilor: Wear protective gloves.

8.2.2.3. Protecția respirației

Protecția respirației: Wear appropriate mask

8.2.2.4. Pericole termice

No additional information available

8.2.3. Controlul expunerii mediului

Evitați eliberarea în mediu.

Alte informații: Do not eat, drink or smoke during use.

9.2.1. Informații privind clasele de pericol fizic

No additional information available

9.2.2. Alte caracteristici de siguranță

No additional information available

The product is non-reactive under normal conditions of use, storage and transport.

Not established.

Not established.

Direct sunlight. Extremely high or low temperatures.

Strong acids. Strong bases.

fume. Carbon monoxide. Carbon dioxide.

11.2.1. Proprietăți de perturbare endocrină

No additional information available

11.2.2. Alte informații

Potential adverse human health effects and symptoms: Based on available data, the classification criteria are not met

Ecology - general: May cause long lasting harmful effects to aquatic life.

Hazardous to the aquatic environment, short–term (acute): Not classified

Hazardous to the aquatic environment, long–term (chronic): May cause long lasting harmful effects to aquatic life.

ECO REACH Honeydew Liquid Dye #D23207

Persistence and degradability: Not established.

3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives (97660-72-5)

Persistence and degradability: Not established.

ECO REACH Honeydew Liquid Dye #D23207

Bioaccumulative potential: Not established.

3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives (97660-72-5)

Partition coefficient n-octanol/water (Log Pow): > 6.5 (at 30 °C (at pH 6.92)

Bioaccumulative potential: Not established.

No additional information available

No additional information available

No additional information available

Additional information: Avoid release to the environment.

Waste treatment methods: Dispose of contents/container in accordance with licensed collector’s sorting instructions.

Recomandări privind eliminarea produsului/ambalajului: Dispose in a safe manner in accordance with local/national regulations.

Ecology - waste materials: Avoid release to the environment.

HP Code: HP13 - “Sensitising:” waste which contains one or more substances known to cause sensitising effects to the skin or the respiratory organs.

HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment

In accordance with ADR / IMDG / IATA / ADN / RID

No supplementary information available

14.6. Precauții speciale pentru utilizator

Overland transport: No data available

Transport by sea: No data available

Air transport: No data available

Inland waterway transport: No data available

Rail transport: No data available

14.7. Maritime transport in bulk according to IMO instruments

Not applicable

15.1.1. EU-Regulations

REACH Annex XVII (Restriction List)

EU restriction list (REACH Annex XVII)

REACH Annex XIV (Authorisation List): Contains no substance(s) listed on REACH Annex XIV (Authorisation List)

REACH Candidate List (SVHC): Contains no substance(s) listed on the REACH Candidate List

PIC Regulation (Prior Informed Consent): Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)

POP Regulation (Persistent Organic Pollutants): Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)

Ozone Regulation (1005/2009): Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)

Explosives Precursors Regulation (2019/1148): Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)

Drug Precursors Regulation (273/2004): Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)

Germany

Water hazard class (WGK): WGK 3, Highly hazardous to water (Classification according to AwSV, Annex 1).

Hazardous Incident Ordinance (12. BImSchV): Is not subject of the Hazardous Incident Ordinance (12. BImSchV)

Netherlands

ABM category: A(3) - hazardous for aquatic organisms, may have longterm hazardous effects in aquatic environment

SZW-lijst van kankerverwekkende stoffen: Refined Soybean oil,3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives are listed

SZW-lijst van mutagene stoffen: Refined Soybean oil,3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-phenyl-, 4-[(4-C7-17-branched alkylphenyl)azo] derivatives are listed

SZW-lijst van reprotoxische stoffen – Borstvoeding: None of the components are listed

SZW-lijst van reprotoxische stoffen – Vruchtbaarheid: None of the components are listed

SZW-lijst van reprotoxische stoffen – Ontwikkeling: None of the components are listed

Denmark

Classification remarks: Emergency management guidelines for the storage of flammable liquids must be followed

Danish National Regulations: Young people below the age of 18 years are not allowed to use the product

No chemical safety assessment has been carried out

Data sources: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.

Other information: None.

Full text of H- and EUH-statements:

Aquatic Chronic 4 Hazardous to the aquatic environment – Chronic Hazard, Category 4

H317 May cause an allergic skin reaction.

H413 May cause long lasting harmful effects to aquatic life.

Skin Sens. 1 Skin sensitisation, Category 1

Classification complies with: ATP 12

Safety Data Sheet (SDS), EU

Data contained in this Safety Data Sheet is accurate to the best knowledge of French Color & Fragrance Co., applies to the product as supplied by French Color & Fragrance Co. and does not relate to use in combination with any other material or in any process. Data and information is furnished without warranty expressed or implied, nor does French Color & Fragrance Co. assume responsibility for use or reliance upon this data. This SDS is current to the date listed above. However, the GHS classifications may change due to hazard communication updates by the overseeing governing body. For the most current SDS information please contact SDS@frenchcolor.com