GRAPEFRUIT #EU37497F 10% in DPG - Fișă cu date de securitate

SECȚIUNEA 1: Identificarea substanței/amestecului și a societății/întreprinderii

1.1. Identificatorul produsului

Formă produs

Amestec

Nume produs

GRAPEFRUIT #EU37497F 10% in DPG

Cod produs

EU37497F_10%

Tip produs

Perfumuri, fragranțe

1.2. Utilizări relevante identificate ale substanței sau amestecului și utilizări contraindicate

Specificare utilizare industrială/profesională

Industrial

Doar pentru uz profesional

Utilizarea substanței/amestecului

Perfumuri, fragranțe

Categorie funcție sau utilizare

Agenți de miros

1.2.2. Utilizări contraindicate

No additional information available

1.3. Detalii privind furnizorul fișei cu date de securitate

No additional information available

1.4. Număr de telefon pentru urgențe

No additional information available

SECȚIUNEA 2: Identificarea pericolelor

2.1. Clasificarea substanței sau amestecului

Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP]: Nu este clasificat

Efecte fizico-chimice, asupra sănătății umane și asupra mediului: No additional information available

2.2. Elemente de etichetare

Etichetare conform Regulamentului (CE) Nr. 1272/2008 [CLP]

EUH-statements : EUH208 - Contains Grapefruit oil terpenes, Grapefruit oil, (R)-p-mentha-1,8-diene; d-limonene, Geraniol, Nerol, Citronellol Pure. May produce an allergic reaction.

EUH210 - Safety data sheet available on request.

Fraze suplimentare : For professional users only.

2.3. Alte pericole

Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

SECȚIUNEA 3: Compoziție/informații privind componenții

3.1. Substanțe

Not applicable

3.2. Amestecuri

Name	Product identifier	%	Classification according to Regulation (EC) No. 1272/2008 [CLP]
Bis(2-ethylhexyl) adipate substance with national workplace exposure limit(s) (PL)	CAS-No.: 103-23-1 EC-No.: 203-090-1 REACH-no: 01-2119439699-19	3.66 – 7.325	Aquatic Acute 1, H400
Grapefruit oil terpenes	CAS-No.: 68917-32-8 EC-No.: 289-904-6	0.49 – 0.98	Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411
Grapefruit oil	CAS-No.: 8016-20-4 EC-No.: 600-007-4	0.028 – 0.21	Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411
Geraniol	CAS-No.: 106-24-1 EC-No.: 203-377-1 EC Index-No.: 603-241-00-5 REACH-no: 01-2119552430-49	0.07 – 0.196	Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317
(R)-p-mentha-1,8-diene; d-limonene substance with national workplace exposure limit(s) (DE, ES, FI, SI, NO, CH)	CAS-No.: 5989-27-5 EC-No.: 205-341-0 EC Index-No.: 601-096-00-2 REACH-no: 01-2119493353-35	0.035 – 0.14	Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 3, H412
Nerol	CAS-No.: 106-25-2 EC-No.: 203-378-7	0.042 – 0.14	Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317
Citronellol Pure	CAS-No.: 106-22-9 EC-No.: 203-375-0 REACH-no: 01-2119453995-23	0.0542 – 0.119	Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317

Full text of H- and EUH-statements: see section 16

SECȚIUNEA 4: Măsuri de prim ajutor

4.1. Descrierea măsurilor de prim ajutor

Măsuri generale de prim ajutor

Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

După inhalare

Allow affected person to breathe fresh air. Allow the victim to rest.

După contactul cu pielea

Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.

După contactul cu ochii

Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.

După ingerare

Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Cele mai importante simptome și efecte, atât acute cât și întârziate

Symptoms/effects : Not expected to present a significant hazard under anticipated conditions of normal use.

4.3. Indicații privind orice asistență medicală imediată și tratamente speciale necesare

No additional information available

SECȚIUNEA 5: Măsuri de combatere a incendiilor

5.1. Mijloace de stingere

Mijloace de stingere adecvate

Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Mijloace de stingere neadecvate

Do not use a heavy water stream.

5.2. Pericole speciale cauzate de substanță sau amestec

No additional information available

5.3. Recomandări pentru pompieri

Instrucțiuni de stingere a incendiilor

Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.

Protecție în timpul stingerii incendiului

Do not enter fire area without proper protective equipment, including respiratory protection.

SECȚIUNEA 6: Măsuri în caz de eliberare accidentală

6.1. Precauții personale, echipament de protecție și proceduri de urgență

Pentru personalul care nu face parte din echipa de intervenție

Evacuate unnecessary personnel.

Pentru persoanele care răspund la situații de urgență

Equip cleanup crew with proper protection. Ventilate area.

6.2. Precauții pentru mediu

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Metode și material pentru izolarea incendiului și pentru curățenie

Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.

6.4. Trimitere la alte secțiuni

See Section 8. Exposure controls and personal protection.

SECȚIUNEA 7: Manipulare și depozitare

7.1. Precauții pentru manipulare în condiții de securitate

Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.

7.2. Condiții pentru depozitare în condiții de securitate, inclusiv eventuale incompatibilități

Condiții de depozitare

Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.

Produse incompatibile

Strong bases. Strong acids.

Materiale incompatibile

Sources of ignition. Direct sunlight.

Germany

Storage class (LGK, TRGS 510)

LGK 12 - Non-combustible liquids

Joint storage not permitted for	LGK 1, LGK 6.2, LGK 7
Joint storage with restrictions permitted for	LGK 4.1A, LGK 4.3, LGK 5.1C
Joint storage permitted for	LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13

Switzerland

Storage class (LK)

LK 10/12 - Liquids

7.3. Utilizare finală specifică

No additional information available

SECȚIUNEA 8: Controale ale expunerii/protecție personală

8.1. Parametri de control

8.1.1. Valori limită naționale de expunere profesională și biologice

Substanță	Țară / referință	Valori limită
Bis(2-ethylhexyl) adipate (103-23-1)	Poland - Occupational Exposure Limits	NDS (OEL TWA) 400 mg/m³
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)	Finland - Occupational Exposure Limits	HTP (OEL TWA) 140 mg/m³ 25 ppm HTP (OEL STEL) 280 mg/m³ 50 ppm
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)	Germany - Occupational Exposure Limits (TRGS 900)	AGW (OEL TWA) 28 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 5 ppm (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Chemical category: Skin notation, Skin sensitization
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)	Slovenia - Occupational Exposure Limits	OEL TWA 28 mg/m³ 5 ppm OEL STEL 112 mg/m³ 20 ppm OEL chemical category Potential for cutaneous absorption
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)	Spain - Occupational Exposure Limits	VLA-ED (OEL TWA) 168 mg/m³ 30 ppm OEL chemical category Sensitizer, skin - potential for cutaneous absorption
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)	Norway - Occupational Exposure Limits	Grenseverdi (OEL TWA) 140 mg/m³ 25 ppm Korttidsverdi (OEL STEL) 175 mg/m³ (value calculated) 37.5 ppm (value calculated) OEL chemical category Allergenic substance
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)	Switzerland - Occupational Exposure Limits	MAK (OEL TWA) 40 mg/m³ 7 ppm KZGW (OEL STEL) 80 mg/m³ 14 ppm OEL chemical category Sensitizer

8.1.2. Proceduri recomandate de monitorizare

No additional information available

8.1.3. Contaminanți atmosferici formați

No additional information available

8.1.4. DNEL și PNEC

No additional information available

8.1.5. Control banding

No additional information available

8.2. Controale ale expunerii

8.2.1. Controale tehnice adecvate

No additional information available

8.2.2. Echipament individual de protecție

Personal protective equipment: Avoid all unnecessary exposure.

Protecția ochilor și a feței

Chemical goggles or safety glasses

Protecția pielii

Wear protective gloves.

Protecția respirației

Wear appropriate mask

Pericole termice

No additional information available

8.2.3. Controale ale expunerii mediului

Do not eat, drink or smoke during use.

SECȚIUNEA 9: Proprietăți fizice și chimice

9.1. Informații privind proprietățile fizice și chimice de bază

Stare fizică

Lichid

Culoare

Conforms to standard.

Miros

characteristic.

Prag de miros

Not available

Punct de topire

Not available

Punct de congelare

Not available

Punct de fierbere

Not available

Inflamabilitate

Non flammable.

Limită inferioară de explozie

Not available

Limită superioară de explozie

Not available

Punct de aprindere

> 93 °C

Temperatura de autoaprindere

Not available

Temperatura de descompunere

Not available

pH

Not available

Vâscozitate, cinematică

Not available

Solubilitate

Not available

Coeficient de partiție n-octanol/apă (Log Kow)

Not available

Presiune de vapori

Not available

Presiune de vapori la 50°C

Not available

Densitate

Not available

Densitate relativă

Not available

Densitate relativă a vaporilor la 20°C

Not available

Caracteristici ale particulelor

Not applicable

9.2. Alte informații

9.2.1. Informații privind clasele de pericol fizic

No additional information available

9.2.2. Alte caracteristici de securitate

No additional information available

SECȚIUNEA 10: Stabilitate și reactivitate

10.1. Reactivitate

No additional information available

10.2. Stabilitate chimică

Not established.

10.3. Posibilitatea reacțiilor periculoase

Not established.

10.4. Condiții de evitat

Direct sunlight. Extremely high or low temperatures.

10.5. Materiale incompatibile

Strong acids. Strong bases.

10.6. Produși de descompunere periculoși

fume. Carbon monoxide. Carbon dioxide.

SECȚIUNEA 11: Informații toxicologice

11.1. Informații privind clasele de pericol definite în Regulamentul (CE) Nr. 1272/2008

Toxicitate acută (oral)

Not classified

Toxicitate acută (dermal)

Not classified

Toxicitate acută (inhalare)

Not classified

Bis(2-ethylhexyl) adipate (103-23-1)	LD50 oral rat 5600 mg/kg (Source: NLM_CIP) LD50 dermal rabbit 8410 mg/kg (Source: NLM_CIP) LC50 Inhalation - Rat > 5.7 mg/l/4h
Grapefruit oil (8016-20-4)	LD50 oral rat > 5 g/kg (Source: ECHA)
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)	LD50 oral rat 4400 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 5 g/kg (Source: CHEMVIEW)
Geraniol (106-24-1)	LD50 oral rat 3600 mg/kg (Source: NLM_CIP) LD50 oral 3600 mg/kg bodyweight LD50 dermal rabbit > 5 g/kg (Source: NLM_CIP)
Nerol (106-25-2)	LD50 oral rat 4500 mg/kg (Source: NLM_CIP) LD50 oral 4500 mg/kg bodyweight LD50 dermal rabbit > 5 g/kg (Source: NLM_CIP)
Citronellol Pure (106-22-9)	LD50 oral rat 3450 mg/kg (Source: NLM_CIP) LD50 oral 3450 mg/kg bodyweight LD50 dermal rabbit 2650 mg/kg (Source: EPA_HPV) LD50 dermal 2650 mg/kg bodyweight

Corodarea/iritarea pielii

Not classified

Informații suplimentare

Based on available data, the classification criteria are not met

Lezarea gravă/iritarea ochilor

Not classified

Informații suplimentare

Based on available data, the classification criteria are not met

Sensibilizarea căilor respiratorii sau a pielii

Not classified

Informații suplimentare

Based on available data, the classification criteria are not met

Mutagenitatea celulelor germinale

Not classified

Informații suplimentare

Based on available data, the classification criteria are not met

Carcinogenicitate

Not classified

Informații suplimentare

Based on available data, the classification criteria are not met

Bis(2-ethylhexyl) adipate (103-23-1)	IARC group 3 - Not classifiable
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)	IARC group 3 - Not classifiable

Toxicitate pentru reproducere

Not classified

Informații suplimentare

Based on available data, the classification criteria are not met

STOT - expunere unică

Not classified

Informații suplimentare

Based on available data, the classification criteria are not met

STOT - expunere repetată

Not classified

Informații suplimentare

Based on available data, the classification criteria are not met

Pericol de aspirație

Not classified

Informații suplimentare

Based on available data, the classification criteria are not met

(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)
Hydrocarbon Yes

11.2. Informații privind alte pericole

11.2.1. Proprietăți de perturbare endocrină

No additional information available

11.2.2. Alte informații

Potential adverse human health effects and symptoms : Based on available data, the classification criteria are not met

SECȚIUNEA 12: Informații ecologice

12.1. Toxicitate

Periculos pentru mediul acvatic, pe termen scurt (acut)

Not classified

Periculos pentru mediul acvatic, pe termen lung (cronic)

Not classified

Bis(2-ethylhexyl) adipate (103-23-1)	LC50 - Fish [1] 0.48 – 0.85 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static] Source: EPA) LC50 - Fish [2] 0.48 – 0.85 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static] Source: EPA) EC50 - Crustacea [1] > 1.6 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 72h - Algae [1] > 500 mg/l (Species: Desmodesmus subspicatus)
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)	LC50 - Fish [1] 0.619 – 0.796 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) LC50 - Fish [2] 35 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss Source: EPA)
Geraniol (106-24-1)	LC50 - Fish [1] 22 mg/l (Exposure time: 96 h - Species: Danio rerio [static] Source: ECHA)
Nerol (106-25-2)	LC50 - Fish [1] 20.3 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA)

12.2. Persistență și degradabilitate

GRAPEFRUIT #EU37497F 10% in DPG
Persistence and degradability Not established.

Bis(2-ethylhexyl) adipate (103-23-1)
Persistence and degradability Rapidly degradable

Grapefruit oil terpenes (68917-32-8)
Persistence and degradability Rapidly degradable

Grapefruit oil (8016-20-4)
Persistence and degradability Rapidly degradable

(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)
Persistence and degradability Rapidly degradable

Geraniol (106-24-1)
Persistence and degradability Rapidly degradable

Nerol (106-25-2)
Persistence and degradability Rapidly degradable

Citronellol Pure (106-22-9)
Persistence and degradability Rapidly degradable

12.3. Potențial de bioacumulare

GRAPEFRUIT #EU37497F 10% in DPG
Bioaccumulative potential Not established.

Bis(2-ethylhexyl) adipate (103-23-1)
BCF - Fish [1] (27 dimensionless)
Partition coefficient n-octanol/water (Log Pow) 8.94 (at 25 °C)

(R)-p-mentha-1,8-diene; d-limonene (5989-27-5)
Partition coefficient n-octanol/water (Log Pow) 4.38 (at 37 °C (at pH 7.2)

Geraniol (106-24-1)
Partition coefficient n-octanol/water (Log Pow) 2.6 (at 25 °C)

Nerol (106-25-2)
Partition coefficient n-octanol/water (Log Pow) 2.76 (at 30 °C (at pH 6.5)

Citronellol Pure (106-22-9)
Partition coefficient n-octanol/water (Log Pow) 3.41 (at 25 °C)

12.4. Mobilitate în sol

No additional information available

12.5. Rezultatele evaluării PBT și vPvB

No additional information available

12.6. Proprietăți de perturbare endocrină

No additional information available

12.7. Alte efecte adverse

Additional information : Avoid release to the environment.

SECȚIUNEA 13: Considerații privind eliminarea

13.1. Metode de tratare a deșeurilor

Recomandări pentru eliminarea produsului/ambalajului : Dispose in a safe manner in accordance with local/national regulations.

Informații ecologice : Avoid release to the environment.

SECȚIUNEA 14: Informații privind transportul

In accordance with ADR / IMDG / IATA / ADN / RID

	ADR	IMDG	IATA	ADN	RID
14.1. UN number or ID number	Not applicable	Not applicable	Not applicable	Not applicable	Not applicable
14.2. UN proper shipping name	Not applicable	Not applicable	Not applicable	Not applicable	Not applicable
14.3. Transport hazard class(es)	Not applicable	Not applicable	Not applicable	Not applicable	Not applicable
14.4. Packing group	Not applicable	Not applicable	Not applicable	Not applicable	Not applicable
14.5. Environmental hazards	Not applicable	Not applicable	Not applicable	Not applicable	Not applicable

No supplementary information available

14.6. Precauții speciale pentru utilizator

Overland transport: Not applicable
Transport by sea: Not applicable
Air transport: Not applicable
Inland waterway transport: Not applicable
Rail transport: Not applicable

14.7. Transport maritim în vrac conform instrumentelor IMO

Not applicable

SECȚIUNEA 15: Informații de reglementare

15.1. Reglementări/legislație privind securitatea, sănătatea și mediul, specifice pentru substanță sau amestec

15.1.1. Reglementări UE

REACH Annex XVII (Restriction List)

EU restriction list (REACH Annex XVII)

Reference code / Applicable on / Entry title or description

3(a) Grapefruit oil terpenes ; Grapefruit oil ; (R)-p-mentha-1,8-diene; d-limonene — Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F

3(b) Grapefruit oil terpenes ; Grapefruit oil ; (R)-p-mentha-1,8-diene; d-limonene ; Geraniol ; Nerol ; Citronellol Pure — Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10

3(c) Bis(2-ethylhexyl) adipate ; Grapefruit oil terpenes ; Grapefruit oil ; (R)-p-mentha-1,8-diene; d-limonene — Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1

40. Grapefruit oil terpenes ; Grapefruit oil ; (R)-p-mentha-1,8-diene; d-limonene — Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not.

REACH Annex XIV (Authorisation List)
Contains no substance(s) listed on REACH Annex XIV (Authorisation List)

REACH Candidate List (SVHC)
Contains no substance(s) listed on the REACH Candidate List

PIC Regulation (Prior Informed Consent)
Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)

POP Regulation (Persistent Organic Pollutants)
Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)

Ozone Regulation (1005/2009)
Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)

Council Regulation (EC) for the control of dual-use items
Contains no substance subject to the COUNCIL REGULATION (EC) for the control of dual-use items

Explosives Precursors Regulation (2019/1148)
Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)

Drug Precursors Regulation (273/2004)
Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)

15.1.2. Reglementări naționale

Germany
Water hazard class (WGK) : WGK 2, Significantly hazardous to water (Classification according to AwSV, Annex 1).
Hazardous Incident Ordinance (12. BImSchV) : Is not subject to the Hazardous Incident Ordinance (12. BImSchV)

Netherlands
ABM category : A(2) - toxic for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen : Grapefruit oil terpenes is listed
SZW-lijst van mutagene stoffen : Grapefruit oil terpenes is listed
SZW-lijst van reprotoxische stoffen – Borstvoeding : None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid : None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling : None of the components are listed

Denmark