Fișă cu date de securitate, conform Regulamentului (CE) nr. 1907/2006 (REACH), cu modificarea Regulamentului (UE) 2020/878
Forma produsului: Amestec
Numele produsului: GRAPEFRUIT #EU37497F 25% in DPG
Cod produs: EU37497F_25%
Tipul produsului: Parfumuri, fragranțe
Specificație utilizare industrială/profesională: Industrial
Numai pentru uz profesional
Utilizarea substanței/amestecului: Parfumuri, fragranțe
Categoria funcției sau utilizării: Agenți odorizanți
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Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Skin Sens. 1 — H317
Hazardous to the aquatic environment – Chronic Hazard, Category 3 — H412
Textul complet al frazelor H și EUH: vezi secțiunea 16
Efecte fizico-chimice, asupra sănătății umane și asupra mediului: Nu sunt disponibile informații suplimentare
Etichetare conform Regulamentului (CE) nr. 1272/2008 [CLP]
Pictograme de pericol (CLP): GHS07
Cuvânt de avertizare (CLP): Warning
Conține: Grapefruit oil terpenes; Grapefruit oil; (R)-p-mentha-1,8-diene; d-limonene; Geraniol; Nerol; Citronellol Pure
Fraze de pericol (CLP):
H317 - May cause an allergic skin reaction.
H412 - Harmful to aquatic life with long lasting effects.
Fraze de precauție (CLP):
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P321 - Specific treatment (see supplemental first aid instruction on this label).
Fraze suplimentare: For professional users only.
Nu conține substanțe PBT și/sau vPvB ≥ 0.1% evaluate în conformitate cu Anexa XIII REACH
Amestecul nu conține substanțe incluse în lista stabilită în conformitate cu articolul 59(1) din REACH pentru proprietăți de perturbare endocrină, sau substanțele nu sunt identificate ca având proprietăți de perturbare endocrină în conformitate cu criteriile stabilite în Regulamentul delegat al Comisiei (UE) 2017/2100 sau Regulamentul Comisiei (UE) 2018/605 la o concentrație egală sau mai mare de 0,1 %
Nu se aplică
| Nume | Identificator produs | % | Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP] |
|---|---|---|---|
| Bis(2-ethylhexyl) adipate | CAS-No.: 103-23-1 EC-No.: 203-090-1 REACH-no: 01-2119439699-19 |
9.15 – 18.3125 | Aquatic Acute 1, H400 |
| Grapefruit oil terpenes | CAS-No.: 68917-32-8 EC-No.: 289-904-6 |
1.225 – 2.45 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| Grapefruit oil | CAS-No.: 8016-20-4 EC-No.: 600-007-4 |
0.07 – 0.525 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| Geraniol | CAS-No.: 106-24-1 EC-No.: 203-377-1 EC Index-No.: 603-241-00-5 REACH-no: 01-2119552430-49 |
0.175 – 0.49 | Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317 |
| (R)-p-mentha-1,8-diene; d-limonene | CAS-No.: 5989-27-5 EC-No.: 205-341-0 EC Index-No.: 601-096-00-2 REACH-no: 01-2119493353-35 |
0.0875 – 0.35 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 |
| Nerol | CAS-No.: 106-25-2 EC-No.: 203-378-7 |
0.105 – 0.35 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Citronellol Pure | CAS-No.: 106-22-9 EC-No.: 203-375-0 REACH-no: 01-2119453995-23 |
0.1355 – 0.2975 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) | CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 |
0.125 – 0.2625 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| citral | CAS-No.: 5392-40-5 EC-No.: 226-394-6 EC Index-No.: 605-019-00-3 REACH-no: 01-2119462829-23 |
0.0035 – 0.021 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| .alpha.-Pinene | CAS-No.: 80-56-8 EC-No.: 201-291-9 |
< 0.007 | Flam. Liq. 3, H226 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
Textul complet al frazelor H și EUH: vezi secțiunea 16
Măsuri generale de prim ajutor: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
Măsuri de prim ajutor după inhalare: Allow affected person to breathe fresh air. Allow the victim to rest.
Măsuri de prim ajutor după contactul cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
Măsuri de prim ajutor după contactul cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
Măsuri de prim ajutor după înghițire: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Simptome/efecte: Not expected to present a significant hazard under anticipated conditions of normal use.
Nu sunt disponibile informații suplimentare
Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
Nu sunt disponibile informații suplimentare
Instrucțiuni de stingere: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protecție în timpul stingerii incendiului: Do not enter fire area without proper protective equipment, including respiratory protection.
Proceduri de urgență: Evacuate unnecessary personnel.
Echipament de protecție: Equip cleanup crew with proper protection.
Proceduri de urgență: Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Metode de curățare: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Vezi Secțiunea 8. Controlul expunerii și protecția personală.
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
Condiții de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Produse incompatibile: Strong bases. Strong acids.
Materiale incompatibile: Sources of ignition. Direct sunlight.
Germany
Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids
Joint storage table:
Joint storage not permitted for : LGK 1, LGK 6.2, LGK 7
Joint storage with restrictions permitted for : LGK 4.1A, LGK 4.3, LGK 5.1C
Joint storage permitted for : LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13
Switzerland
Storage class (LK): LK 10/12 - Liquids
Nu sunt disponibile informații suplimentare
| Substanță | Țară / referință | Valoare limită |
|---|---|---|
| Bis(2-ethylhexyl) adipate (103-23-1) | Poland - Occupational Exposure Limits | NDS (OEL TWA) 400 mg/m³ |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | Finland - Occupational Exposure Limits | HTP (OEL TWA) 140 mg/m³; 25 ppm HTP (OEL STEL) 280 mg/m³; 50 ppm |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | Germany - Occupational Exposure Limits (TRGS 900) | AGW (OEL TWA) 28 mg/m³; 5 ppm Chemical category: Skin notation, Skin sensitization |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | Slovenia - Occupational Exposure Limits | OEL TWA 28 mg/m³; 5 ppm OEL STEL 112 mg/m³; 20 ppm Chemical category: Potential for cutaneous absorption |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | Spain - Occupational Exposure Limits | VLA-ED (OEL TWA) 168 mg/m³; 30 ppm Chemical category: Sensitizer, skin - potential for cutaneous absorption |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | Norway - Occupational Exposure Limits | Grenseverdi (OEL TWA) 140 mg/m³; 25 ppm Korttidsverdi (OEL STEL) 175 mg/m³ (value calculated); 37.5 ppm (value calculated) Chemical category: Allergenic substance |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | Switzerland - Occupational Exposure Limits | MAK (OEL TWA) 40 mg/m³; 7 ppm KZGW (OEL STEL) 80 mg/m³; 14 ppm Chemical category: Sensitizer |
| .alpha.-Pinene (80-56-8) | Belgium - Occupational Exposure Limits | OEL TWA 20 ppm |
| .alpha.-Pinene (80-56-8) | Estonia - Occupational Exposure Limits | OEL TWA 150 mg/m³ ... 25 ppm ... OEL STEL 300 mg/m³ ... 50 ppm ... |
| citral (5392-40-5) | Belgium - Occupational Exposure Limits | OEL TWA 32 mg/m³ (vapor and aerosol); 5 ppm (vapor and aerosol) Chemical category: Skin |
| citral (5392-40-5) | Ireland - Occupational Exposure Limits | OEL TWA 5 ppm OEL STEL 15 ppm (calculated) |
| citral (5392-40-5) | Poland - Occupational Exposure Limits | NDS (OEL TWA) 27 mg/m³ NDSCh (OEL STEL) 54 mg/m³ |
| citral (5392-40-5) | Portugal - Occupational Exposure Limits | OEL TWA 5 ppm (inhalable fraction; vapor) Chemical category: Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen, skin - potential for cutaneous exposure |
| citral (5392-40-5) | Spain - Occupational Exposure Limits | VLA-ED (OEL TWA) 5 ppm (inhalable fraction and vapor) Chemical category: Sensitizer, skin - potential for cutaneous absorption |
| citral (5392-40-5) | USA - ACGIH - Occupational Exposure Limits | ACGIH OEL TWA 5 ppm (inhalable fraction and vapor) ACGIH chemical category: Not Classifiable as a Human Carcinogen, Skin - potential significant contribution to overall exposure by the cutaneous route, dermal sensitizer |
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Echipament individual de protecție: Evitați orice expunere inutilă.
Simboluri pentru echipamentul individual de protecție:
Protecție oculară
Protecția ochilor: Ochelari de protecție chimică sau ochelari de siguranță
Protecția mâinilor: Purtați mănuși de protecție.
Protecția respiratorie: Purtați o mască adecvată
Nu sunt disponibile informații suplimentare
Alte informații: Nu mâncați, nu beți și nu fumați în timpul utilizării.
| Stare fizică | Liquid |
|---|---|
| Culoare | Conforms to standard. |
| Miros | characteristic. |
| Prag de miros | Not available |
| Punct de topire | Not available |
| Punct de îngheț | Not available |
| Punct de fierbere | Not available |
| Inflamabilitate | Non flammable. |
| Limită inferioară de explozie | Not available |
| Limită superioară de explozie | Not available |
| Punct de aprindere | > 93 °C |
| Temperatura de autoaprindere | Not available |
| Temperatura de descompunere | Not available |
| pH | Not available |
| Vâscozitate, cinematică | Not available |
| Solubilitate | Not available |
| Coeficient de partiție n-octanol/apă (Log Kow) | Not available |
| Presiune de vapori | Not available |
| Presiune de vapori la 50°C | Not available |
| Densitate | Not available |
| Densitate relativă | Not available |
| Densitatea relativă a vaporilor la 20°C | Not available |
| Caracteristici ale particulelor | Not applicable |
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Not established.
Not established.
Direct sunlight. Extremely high or low temperatures.
Strong acids. Strong bases.
fume. Carbon monoxide. Carbon dioxide.
Toxicitate acută (oral): Not classified
Toxicitate acută (dermal): Not classified
Toxicitate acută (inhalare): Not classified
| Substanță | Date toxicologice |
|---|---|
| Bis(2-ethylhexyl) adipate (103-23-1) | LD50 oral rat 5600 mg/kg (Source: NLM_CIP) LD50 dermal rabbit 8410 mg/kg (Source: NLM_CIP) LC50 Inhalation - Rat > 5.7 mg/l/4h |
| Grapefruit oil (8016-20-4) | LD50 oral rat > 5 g/kg (Source: ECHA) |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | LD50 oral rat 4400 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 5 g/kg (Source: CHEMVIEW) |
| .alpha.-Pinene (80-56-8) | LD50 oral rat 3700 mg/kg (Source: NLM_CIP) LD50 dermal rat > 5000 mg/kg (Source: CHEMVIEW) |
| Geraniol (106-24-1) | LD50 oral rat 3600 mg/kg (Source: NLM_CIP) LD50 oral 3600 mg/kg bodyweight LD50 dermal rabbit > 5 g/kg (Source: NLM_CIP) |
| Nerol (106-25-2) | LD50 oral rat 4500 mg/kg (Source: NLM_CIP) LD50 oral 4500 mg/kg bodyweight LD50 dermal rabbit > 5 g/kg (Source: NLM_CIP) |
| Citronellol Pure (106-22-9) | LD50 oral rat 3450 mg/kg (Source: NLM_CIP) LD50 oral 3450 mg/kg bodyweight LD50 dermal rabbit 2650 mg/kg (Source: EPA_HPV) LD50 dermal 2650 mg/kg bodyweight |
| citral (5392-40-5) | LD50 oral rat 4960 mg/kg (Source: NLM_CIP) LD50 dermal rabbit 2250 mg/kg (Source: NLM_CIP) |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5) | LD50 oral rat > 3250 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 3250 mg/kg (Source: CHEMVIEW) LC50 Inhalation - Rat > 5.04 mg/l/4h |
Corodare/iritare a pielii: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Deteriorare/iritare gravă a ochilor: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Sensibilizare respiratorie sau cutanată: May cause an allergic skin reaction.
Informații suplimentare: Based on available data, the classification criteria are not met
Mutagenicitatea celulelor germinale: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Carcinogenicitate: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Reproductivitate: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
STOT - expunere unică: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
STOT - expunere repetată: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
Pericol prin aspirare: Not classified
Informații suplimentare: Based on available data, the classification criteria are not met
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5) — Hydrocarbon: Yes
.alpha.-Pinene (80-56-8) — Hydrocarbon: Yes
Nu sunt disponibile informații suplimentare
Posibile efecte adverse asupra sănătății umane și simptome: Based on available data, the classification criteria are not met
Hazardous to the aquatic environment, short-term (acute): Not classified
Hazardous to the aquatic environment, long-term (chronic): Harmful to aquatic life with long lasting effects.
| Substanță | Date ecotoxicologice |
|---|---|
| Bis(2-ethylhexyl) adipate (103-23-1) | LC50 - Fish [1] 0.48 – 0.85 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static] Source: EPA) LC50 - Fish [2] 0.48 – 0.85 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static] Source: EPA) EC50 - Crustacea [1] > 1.6 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 72h - Algae [1] > 500 mg/l (Species: Desmodesmus subspicatus) |
| (R)-p-mentha-1,8-diene; d-limonene (5989-27-5) | LC50 - Fish [1] 0.619 – 0.796 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) LC50 - Fish [2] 35 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss Source: EPA) |
| .alpha.-Pinene (80-56-8) | LC50 - Fish [1] 0.28 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static] Source: IUCLID) EC50 - Crustacea [1] 41 mg/l (Exposure time: 48 h - Species: Daphnia magna) |
| Geraniol (106-24-1) | LC50 - Fish [1] 22 mg/l (Exposure time: 96 h - Species: Danio rerio [static] Source: ECHA) |
| Nerol (106-25-2) | LC50 - Fish [1] 20.3 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) |
| citral (5392-40-5) | EC50 - Crustacea [1] 7 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 72h - Algae [1] 16 mg/l (Species: Desmodesmus subspicatus) EC50 96h - Algae [1] 19 mg/l (Species: Desmodesmus subspicatus) |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5) | LC50 - Fish [1] 0.452 mg/l Wolf, 1996d-27682 LC50 - Other aquatic organisms [1] > 0.14 mg/l REACH DOSSIER Pimephales promelas EC50 - Crustacea [2] 260 μg/l REACH Dossier EC50 - Other aquatic organisms [1] 0.131 mg/l REACH Dossier |
GRAPEFRUIT #EU37497F 25% in DPG — Persistence and degradability Not established.
Bis(2-ethylhexyl) adipate (103-23-1) — Rapidly degradable
Grapefruit oil terpenes (68917-32-8) — Rapidly degradable
Grapefruit oil (8016-20-4) — Rapidly degradable
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5) — Rapidly degradable
.alpha.-Pinene (80-56-8) — Rapidly degradable
Geraniol (106-24-1) — Rapidly degradable
Nerol (106-25-2) — Rapidly degradable
Citronellol Pure (106-22-9) — Rapidly degradable
citral (5392-40-5) — Rapidly degradable
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5) — Rapidly degradable
GRAPEFRUIT #EU37497F 25% in DPG — Bioaccumulative potential Not established.
Bis(2-ethylhexyl) adipate (103-23-1) — BCF - Fish [1] (27 dimensionless); Partition coefficient n-octanol/water (Log Pow) 8.94 (at 25 °C)
(R)-p-mentha-1,8-diene; d-limonene (5989-27-5) — Partition coefficient n-octanol/water (Log Pow) 4.38 (at 37 °C (at pH 7.2)
.alpha.-Pinene (80-56-8) — Partition coefficient n-octanol/water (Log Pow) 4.1
Geraniol (106-24-1) — Partition coefficient n-octanol/water (Log Pow) 2.6 (at 25 °C)
Nerol (106-25-2) — Partition coefficient n-octanol/water (Log Pow) 2.76 (at 30 °C (at pH 6.5)
Citronellol Pure (106-22-9) — Partition coefficient n-octanol/water (Log Pow) 3.41 (at 25 °C)
citral (5392-40-5) — Partition coefficient n-octanol/water (Log Pow) 2.76 (at 25 °C)
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5) — BCF - Fish [1] (1618 dimensionless (whole body w.w.); Partition coefficient n-octanol/water (Log Pow) 5.3 (at 25 °C (at pH 7)
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Nu sunt disponibile informații suplimentare
Informații suplimentare: Avoid release to the environment.
Recomandări privind eliminarea produsului/ambalajului: Dispose in a safe manner in accordance with local/national regulations.
Informații ecologice: Avoid release to the environment.
Cod HP: HP4 - “Irritant – skin irritation and eye damage:” waste which on application can