Numai pentru uz profesional
No additional information available
No additional information available
Fișă cu date de securitate
conform Regulamentului (CE) Nr. 1907/2006 (REACH), cu modificarea prin Regulamentul (UE) 2020/878
No additional information available
No additional information available
Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Sensibilizare cutanată, Categoria 1 — H317
Periculos pentru mediul acvatic – Pericol cronic, Categoria 3 — H412
Textul complet al declarațiilor H și EUH: vezi secțiunea 16
Efecte adverse fizico-chimice, pentru sănătatea umană și pentru mediu: No additional information available
Etichetare conform Regulamentului (CE) Nr. 1272/2008 [CLP]
Pictograme de pericol (CLP): GHS07
Cuvânt de avertizare (CLP): Warning
Conține: 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone; Hexyl cinnamic aldehyde
Fraze de pericol (CLP): H317 - May cause an allergic skin reaction.
H412 - Harmful to aquatic life with long lasting effects.
Fraze de precauție (CLP):
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P321 - Specific treatment (see supplemental first aid instruction on this label).
Contine no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
Amestecul nu conține substanțe incluse în lista stabilită în conformitate cu articolul 59 alineatul (1) din REACH pentru proprietăți de perturbare endocrină, sau substanțele nu sunt identificate ca având proprietăți de perturbare endocrină în conformitate cu criteriile stabilite în Regulamentul delegat (UE) 2017/2100 al Comisiei sau în Regulamentul (UE) 2018/605 al Comisiei, la o concentrație egală sau mai mare de 0,1 %
| Nume | Identificator produs | % | Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP] |
|---|---|---|---|
| 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone | CAS-No.: 54464-57-2 EC-No.: 259-174-3 REACH-no: 01-2119489989-04 |
0.72 – 1.449 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 1, H410 |
| Hexyl cinnamic aldehyde | CAS-No.: 101-86-0 EC-No.: 202-983-3 REACH-no: 01-2119533092-50 |
0.55 – 1.099 | Skin Sens. 1, H317 Aquatic Chronic 2, H411 |
| tetrahydro-2-isobutyl-4-methylpyran-4-ol, mixed isomers (cis and trans) | CAS-No.: 63500-71-0 EC-No.: 405-040-6 EC Index-No.: 603-101-00-3 REACH-no: 01-000015458-64 |
0.5 – 1.00141 | Eye Irrit. 2, H319 |
| 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) | CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29 |
0.2 – 0.39 | Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| citral | substance with national workplace exposure limit(s) (BE, ES, IE, PL, PT) CAS-No.: 5392-40-5 EC-No.: 226-394-6 EC Index-No.: 605-019-00-3 REACH-no: 01-2119462829-23 |
0.0003 – 0.00174 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Alcohol C-10 | substance with national workplace exposure limit(s) (BG, DE, LT, LV, RO, CH) CAS-No.: 112-30-1 EC-No.: 203-956-9 |
0 – 0.00016 | Aquatic Chronic 3, H412 |
| Aldehyde C-6 | substance with national workplace exposure limit(s) (FI, PL) CAS-No.: 66-25-1 EC-No.: 200-624-5 |
0 – 0.00004 | Flam. Liq. 3, H226 |
Textul complet al declarațiilor H și EUH: vezi secțiunea 16
Simptome/efecte: Not expected to present a significant hazard under anticipated conditions of normal use.
No additional information available
Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
No additional information available
Instrucțiuni de stingere: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protecție în timpul stingerii: Do not enter fire area without proper protective equipment, including respiratory protection.
Pentru personalul care nu intervine în situații de urgență
Proceduri de urgență: Evacuate unnecessary personnel.
Pentru echipele de intervenție
Echipament de protecție: Equip cleanup crew with proper protection.
Proceduri de urgență: Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Methods for cleaning up: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Section 8. Exposure controls and personal protection.
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
Condiții de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Produse incompatibile: Strong bases. Strong acids.
Materiale incompatibile: Sources of ignition. Direct sunlight.
Germania
Clasa de depozitare (LGK, TRGS 510): LGK 12 - Non-combustible liquids
Tabel de depozitare comună:
Joint storage not permitted for : LGK 1, LGK 6.2, LGK 7
Joint storage with restrictions permitted for : LGK 4.1A, LGK 4.3, LGK 5.1C
Joint storage permitted for : LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13
Elveția
Storage class (LK): LK 10/12 - Liquids
No additional information available
Valori limită naționale de expunere profesională și valori biologice limită
| Substanță | Țară / referință | Valori limită |
|---|---|---|
| citral (5392-40-5) | Belgium - Occupational Exposure Limits | OEL TWA 32 mg/m³ (vapor and aerosol) 5 ppm (vapor and aerosol) OEL chemical category Skin |
| Ireland - Occupational Exposure Limits | OEL TWA 5 ppm OEL STEL 15 ppm (calculated) |
|
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 27 mg/m³ NDSCh (OEL STEL) 54 mg/m³ |
|
| Portugal - Occupational Exposure Limits | OEL TWA 5 ppm (inhalable fraction; vapor) OEL chemical category Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen, skin - potential for cutaneous exposure |
|
| Spain - Occupational Exposure Limits | VLA-ED (OEL TWA) 5 ppm (inhalable fraction and vapor) OEL chemical category Sensitizer, skin - potential for cutaneous absorption |
|
| USA - ACGIH - Occupational Exposure Limits | ACGIH® TLV® TWA 5 ppm (inhalable fraction and vapor) ACGIH® chemical category Not Classifiable as a Human Carcinogen, Skin - potential significant contribution to overall exposure by the cutaneous route, dermal sensitizer |
|
| Alcohol C-10 (112-30-1) | Bulgaria - Occupational Exposure Limits | OEL TWA 10 mg/m³ |
| Germany - Occupational Exposure Limits (TRGS 900) | AGW (OEL TWA) 66 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 10 ppm (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) |
|
| Latvia - Occupational Exposure Limits | OEL TWA 10 mg/m³ | |
| Lithuania - Occupational Exposure Limits | IPRV (OEL TWA) 10 mg/m³ | |
| Romania - Occupational Exposure Limits | OEL TWA 100 mg/m³ 15 ppm OEL STEL 200 mg/m³ 30 ppm |
|
| Switzerland - Occupational Exposure Limits | MAK (OEL TWA) 66 mg/m³ (aerosol, vapour) 10 ppm (aerosol, vapour) KZGW (OEL STEL) 66 mg/m³ (aerosol, vapour) 10 ppm (aerosol, vapour) |
|
| Aldehyde C-6 (66-25-1) | Finland - Occupational Exposure Limits | HTP (OEL STEL) 42 mg/m³ 10 ppm |
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 40 mg/m³ NDSCh (OEL STEL) 80 mg/m³ |
Echipament individual de protecție
Personal protective equipment: Avoid all unnecessary exposure.
Personal protective equipment symbol(s):
Protecția ochilor și a feței
Eye protection: Chemical goggles or safety glasses
Protecția pielii
Hand protection: Wear protective gloves.
Protecția respiratorie
Respiratory protection: Wear appropriate mask
Controale ale expunerii mediului
Other information: Do not eat, drink or smoke during use.
No additional information available
No additional information available
Not established.
Not established.
Direct sunlight. Extremely high or low temperatures.
Strong acids. Strong bases.
fume. Carbon monoxide. Carbon dioxide.
Toxicitate acută (oral): Not classified
Toxicitate acută (dermic): Not classified
Toxicitate acută (inhalare): Not classified
Hexyl cinnamic aldehyde (101-86-0)
LD50 oral rat 3100 mg/kg (Source: NLM_CIP)
LD50 oral 3100 mg/kg
LD50 dermal rabbit > 3000 mg/kg (Source: EPA_HPV)
LC50 Inhalation - Rat > 5 mg/l/4h
tetrahydro-2-isobutyl-4-methylpyran-4-ol, mixed isomers (cis and trans) (63500-71-0)
LD50 dermal rabbit > 2000 mg/kg (Source: ECHA_API)
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5)
LD50 oral rat > 3250 mg/kg (Source: CHEMVIEW)
LD50 dermal rabbit > 3250 mg/kg (Source: CHEMVIEW)
LC50 Inhalation - Rat > 5.04 mg/l/4h
citral (5392-40-5)
LD50 oral rat 4960 mg/kg (Source: NLM_CIP)
LD50 dermal rabbit 2250 mg/kg (Source: NLM_CIP)
Alcohol C-10 (112-30-1)
LD50 oral rat 4720 mg/kg (Source: NZ_CCID)
LD50 dermal rat > 5000 mg/kg (Source: ECHA_API)
LC50 Inhalation - Rat > 71 mg/l (Exposure time: 1 h Source: ECHA_API)
Aldehyde C-6 (66-25-1)
LD50 oral rat 4890 mg/kg (Source: NLM_CIP)
LD50 dermal rabbit > 8100 mg/kg (Source: ECHA_API)
Corodare/iritare cutanată: Not classified
Additional information: Based on available data, the classification criteria are not met
Leziuni/iritații oculare grave: Not classified
Additional information: Based on available data, the classification criteria are not met
Sensibilizare respiratorie sau cutanată: May cause an allergic skin reaction.
Additional information: Based on available data, the classification criteria are not met
Mutagenicitate asupra celulelor germinale: Not classified
Additional information: Based on available data, the classification criteria are not met
Carcinogenitate: Not classified
Additional information: Based on available data, the classification criteria are not met
Toxicitate pentru reproducere: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-single exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-repeated exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
Pericol de aspirație: Not classified
Additional information: Based on available data, the classification criteria are not met
Alte informații
Potential adverse human health effects and symptoms: Based on available data, the classification criteria are not met
Periculos pentru mediul acvatic, pe termen scurt (acut): Not classified
Periculos pentru mediul acvatic, pe termen lung (cronic): Harmful to aquatic life with long lasting effects.
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5)
LC50 - Fish [1] 0.452 mg/l Wolf, 1996d-27682
LC50 - Other aquatic organisms [1] > 0.14 mg/l REACH DOSSIER Pimephales promelas
EC50 - Crustacea [2] 260 μg/l REACH Dossier
EC50 - Other aquatic organisms [1] 0.131 mg/l REACH Dossier
citral (5392-40-5)
EC50 - Crustacea [1] 7 mg/l (Exposure time: 48 h - Species: Daphnia magna)
EC50 72h - Algae [1] 16 mg/l (Species: Desmodesmus subspicatus)
EC50 96h - Algae [1] 19 mg/l (Species: Desmodesmus subspicatus)
Alcohol C-10 (112-30-1)
LC50 - Fish [1] 2.2 – 2.5 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA)
LC50 - Fish [2] 4.12 – 6.2 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static] Source: EPA)
EC50 - Crustacea [1] 3 mg/l (Exposure time: 48 h - Species: Daphnia magna)
Aldehyde C-6 (66-25-1)
LC50 - Fish [1] 12 – 16.5 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA)
SHADES OF LEATHER #EU55799F 10% in DPG: Persistence and degradability Not established.
1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone (54464-57-2)
Persistence and degradability Rapidly degradable
Hexyl cinnamic aldehyde (101-86-0)
Persistence and degradability Rapidly degradable
tetrahydro-2-isobutyl-4-methylpyran-4-ol, mixed isomers (cis and trans) (63500-71-0)
Persistence and degradability Rapidly degradable
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5)
Persistence and degradability Rapidly degradable
citral (5392-40-5)
Persistence and degradability Rapidly degradable
Alcohol C-10 (112-30-1)
Persistence and degradability Rapidly degradable
Aldehyde C-6 (66-25-1)
Persistence and degradability Rapidly degradable
SHADES OF LEATHER #EU55799F 10% in DPG: Bioaccumulative potential Not established.
1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone (54464-57-2)
Partition coefficient n-octanol/water (Log Pow) 5.65 (at 30°C)
tetrahydro-2-isobutyl-4-methylpyran-4-ol, mixed isomers (cis and trans) (63500-71-0)
Partition coefficient n-octanol/water (Log Pow) 1.65 (at 23 °C (at pH >6.09-<6.74)
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran; galaxolide; (HHCB) (1222-05-5)
BCF - Fish [1] (1618 dimensionless (whole body w.w.)
Partition coefficient n-octanol/water (Log Pow) 5.3 (at 25 °C (at pH 7)
citral (5392-40-5)
Partition coefficient n-octanol/water (Log Pow) 2.76 (at 25 °C)
Alcohol C-10 (112-30-1)
Partition coefficient n-octanol/water (Log Pow) 4.5 (at 25 °C (at pH 6)
Aldehyde C-6 (66-25-1)
Partition coefficient n-octanol/water (Log Pow) 2.3 (at 25 °C (at pH 5)
No additional information available
No additional information available
No additional information available
Other information: Avoid release to the environment.
Recomandări privind eliminarea produsului/ambalajului: Dispose in a safe manner in accordance with local/national regulations.
Informații ecologice privind deșeurile: Avoid release to the environment.
Cod HP: HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
În conformitate cu ADR / IMDG / IATA / ADN / RID
| Informație | ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|---|
| 14.1. Numărul ONU sau numărul de identificare | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.2. Denumirea corectă ONU pentru expediție | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.3. Clasa(clasele) de pericol pentru transport | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.4. Grup de ambalare | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
| 14.5. Pericole pentru mediu | Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
No supplementary information available
Overland transport
Not applicable
Transport by sea
Not applicable
Air transport
Not applicable
Inland waterway transport
Not applicable
Rail transport
Not applicable
Not applicable
Regulamente UE
REACH Annex XVII (Restriction List)
EU restriction list (REACH Annex XVII)
Reference code / Applicable on / Entry title or description
3(a) Aldehyde C-6 Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F
3(b) SHADES OF LEATHER #EU55799F 10% in DPG ; 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone ; Hexyl cinnamic aldehyde ; Florol ; Citral
Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10
3(c) SHADES OF LEATHER #EU55799F 10% in DPG ; 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone ; Hexyl cinnamic aldehyde ; Hexamethylindanopyran ; Alcohol C-10
Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1
REACH Annex XIV (Authorisation List) Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC) Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent) Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants) Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (2024/590) Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 2024/590 on substances that deplete the ozone layer)
Council Regulation (EC) for the control of dual-use items Contains no substance subject to the COUNCIL REGULATION (EC) for the control of dual-use items
Explosives Precursors Regulation (EU 2019/1148) Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (EC 273/2004) Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
National regulations
Austria
Toxic Substances Ordinance 2000 : Is not subject to the Toxic Substances Ordinance 2000.
Germany
VOC ordinance (ChemVOCFarbV) :
Water hazard class (WGK) : WGK 2, Significantly hazardous to water (Classification according to AwSV, Annex 1).
Major Accidents Ordinance (12. BImSchV) : Is not subject to the Major Accidents Ordinance (12. BImSchV)
Netherlands
ABM category : A(3) - hazardous for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
SZW-lijst van reprotoxische stoffen – Borstvoeding : None of the components are listed
SZW-lijst van reprotoxische stoffen – Vruchtbaarheid : None of the components are listed
SZW-lijst van reprotoxische stoffen – Ontwikkeling : None of the components are listed
Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed
Danish National Regulations : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct contact with the product
Poland
Polish National Regulations : Act of 25 February 2011 on chemical substances and their mixtures (J. o L. No. 63, item 322 as amended; consolidated text J. o L. 2019, item 1225).
Act of 14 December 2012 on waste (J. o L. 2013, item 322 as amended; consolidated text J. o L. 2020, item 797).
The announcement of Marshal of the Sejm of the Republic of Poland dated 19 October 2016 concerning the consolidated text announcement