Fișă cu date de securitate — SHADES OF LEATHER #EU55799F 25% in DPG

SECȚIUNEA 1: Identificarea substanței/amestecului și a societății/întreprinderii

1.1. Identificatorul produsului

Forma produsului: Mixture

Numele produsului: SHADES OF LEATHER #EU55799F 25% in DPG

Cod produs: EU55799F_25%

Tip produs: Perfumes, Fragrances

Grup produs: Trade product

1.2. Utilizări identificate relevante ale substanței sau amestecului și utilizări contraindicate

Categoria principală de utilizare: Professional use, Industrial use

Specificație de utilizare industrială/profesională: Industrial

Numai pentru uz profesional

Utilizarea substanței/amestecului: Perfumes, Fragrances

Categoria funcției sau utilizării: Odor agents

1.3. Detalii privind furnizorul fișei cu date de securitate

FRENCH COLOR & FRAGRANCE INTERNATIONAL GmbH

Mittlerer Weg 35

DE 79424 Auggen

Germany

T 49-7631-931-8900

SDS@frenchcolor.com, www.frenchcolor.com

1.4. Număr de telefon de urgență

Emergency number: 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086

SECȚIUNEA 2: Identificarea pericolelor

2.1. Clasificarea substanței sau amestecului

Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]

Skin sensitization, Category 1 H317

Hazardous to the aquatic environment – Chronic Hazard Category 2 H411

Efecte fizico-chimice, asupra sănătății umane și asupra mediului:

Toxic to aquatic life with long lasting effects. May cause an allergic skin reaction.

2.2. Elemente pentru etichetă

Pictograme de pericol (CLP): GHS07, GHS09

Cuvânt de avertizare (CLP): Warning

Conține: 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone; Hexyl cinnamic aldehyde; Geraniol

Fraze de pericol (CLP): H317 - May cause an allergic skin reaction. H411 - Toxic to aquatic life with long lasting effects.

Fraze de precauție (CLP): P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P321 - Specific treatment (see supplemental first aid instruction on this label).

2.3. Alte pericole

Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

SECȚIUNEA 3: Compoziție/Informații privind ingredientele

3.2. Amestecuri

Name	Product identifier	%	Classification according to Regulation (EC) No. 1272/2008 [CLP]
1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone	CAS-No.: 54464-57-2 EC-No.: 259-174-3 REACH-no: 01-2119489989-04	1.8 – 3.6225	Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 1, H410
Hexyl cinnamic aldehyde	CAS-No.: 101-86-0 EC-No.: 202-983-3 REACH-no: 01-2119533092-50	1.375 – 2.7475	Skin Sens. 1, H317 Aquatic Chronic 2, H411
tetrahydro-2-isobutyl-4-methylpyran-4-ol, mixed isomers (cis and trans)	CAS-No.: 63500-71-0 EC-No.: 405-040-6 EC Index-No.: 603-101-00-3 REACH-no: 01-000015458-64	1.25 – 2.503525	Eye Irrit. 2, H319
Patchouli oil	CAS-No.: 8014-09-3 EC-No.: 616-944-7 EC Index-No.: 616-944-7	0.575 – 1.125	Asp. Tox. 1, H304 Aquatic Chronic 2, H411
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB)	CAS-No.: 1222-05-5 EC-No.: 214-946-9 EC Index-No.: 603-212-00-7 REACH-no: 01-2119488227-29	0.5 – 0.975	Aquatic Acute 1, H400 Aquatic Chronic 1, H410
Geraniol	CAS-No.: 106-24-1 EC-No.: 203-377-1 EC Index-No.: 603-241-00-5 REACH-no: 01-2119552430-49	0.0375 – 0.1015	Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317
citral substance with national workplace exposure limit(s) (BE, ES, IE, PL, PT)	CAS-No.: 5392-40-5 EC-No.: 226-394-6 EC Index-No.: 605-019-00-3 REACH-no: 01-2119462829-23	0.00075 – 0.00435	Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317
Alcohol C-10 substance with national workplace exposure limit(s) (BG, DE, LT, LV, RO, CH)	CAS-No.: 112-30-1 EC-No.: 203-956-9	0 – 0.0004	Aquatic Chronic 3, H412
Aldehyde C-6 substance with national workplace exposure limit(s) (FI, PL)	CAS-No.: 66-25-1 EC-No.: 200-624-5	0 – 0.0001	Flam. Liq. 3, H226

Full text of H- and EUH-statements: see section 16

SECȚIUNEA 4: Măsuri de prim ajutor

4.1. Descrierea măsurilor de prim ajutor

Măsuri generale de prim ajutor: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

După inhalare: Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest.

După contactul cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention.

După contactul cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. Rinse eyes with water as a precaution.

După ingerare: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center/doctor/physician if you feel unwell.

4.2. Cele mai importante simptome și efecte, atât acute, cât și întârziate

Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.

Symptoms/effects after skin contact: May cause an allergic skin reaction.

4.3. Indicații privind orice îngrijire medicală imediată și tratamente speciale necesare

Treat symptomatically.

SECȚIUNEA 5: Măsuri de combatere a incendiilor

5.1. Mijloace de stingere

Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Mijloace de stingere neadecvate: Do not use a heavy water stream.

5.2. Pericole speciale generate de substanță sau amestec

Produse periculoase de descompunere în caz de incendiu: Toxic fumes may be released.

5.3. Recomandări pentru pompieri

Instrucțiuni de intervenție: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.

Protecție în timpul intervenției: Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.

SECȚIUNEA 6: Măsuri de eliberare accidentală

6.1. Precauții personale, echipament de protecție și proceduri de urgență

Pentru personalul care nu face parte din serviciile de urgență: Ventilate spillage area. Evacuate unnecessary personnel. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapors/spray.

Pentru persoanele care intervin în situații de urgență: Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection".

Proceduri de urgență: Ventilate area.

6.2. Precauții pentru mediu

Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Metode și material pentru izolare și curățare

Pentru izolare: Collect spillage.

Metode de curățare: Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.

Alte informații: Dispose of materials or solid residues at an authorized site.

6.4. Trimitere la alte secțiuni

See Heading 8. Exposure controls and personal protection. For further information refer to section 13.

SECȚIUNEA 7: Manipulare și depozitare

7.1. Precauții pentru manipulare în condiții de securitate

Precauții pentru manipulare în condiții de securitate: Ensure good ventilation of the work station. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear personal protective equipment.

Măsuri de igienă: Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product.

7.2. Condiții pentru depozitare în siguranță, inclusiv incompatibilități

Condiții de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Store in a well-ventilated place. Keep cool.

Produse incompatibile: Strong bases. Strong acids.

Materiale incompatibile: Sources of ignition. Direct sunlight.

Temperatura de depozitare: 25 °C

Zona de depozitare: Store in a well-ventilated place. Store away from heat.

Reguli speciale privind ambalarea: Store in a closed container.

Materiale de ambalare: Do not store in corrodable metal.

Germany

Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids

Joint storage table:

Joint storage not permitted for: LGK 1, LGK 6.2, LGK 7

Joint storage with restrictions permitted for: LGK 4.1A, LGK 4.3, LGK 5.1C

Joint storage permitted for: LGK 2A, LGK 2B, LGK 3, LGK 4.1B, LGK 4.2, LGK 5.1A, LGK 5.1B, LGK 5.2, LGK 6.1A, LGK 6.1B, LGK 6.1C, LGK 6.1D, LGK 8A, LGK 8B, LGK 10, LGK 11, LGK 12, LGK 13, LGK 10-13

Switzerland

Storage class (LK): LK 10/12 - Liquids

7.3. Utilizare finală specifică

No additional information available

SECȚIUNEA 8: Controale ale expunerii/Protecția personală

8.1. Parametri de control

National occupational exposure and biological limit values

Substanță	Țară / limită	Valoare
citral (5392-40-5)	Belgium - Occupational Exposure Limits	OEL TWA 32 mg/m³ (vapor and aerosol) 5 ppm (vapor and aerosol) OEL chemical category Skin
citral (5392-40-5)	Ireland - Occupational Exposure Limits	OEL TWA 5 ppm OEL STEL 15 ppm (calculated)
citral (5392-40-5)	Poland - Occupational Exposure Limits	NDS (OEL TWA) 27 mg/m³ NDSCh (OEL STEL) 54 mg/m³
citral (5392-40-5)	Portugal - Occupational Exposure Limits	OEL TWA 5 ppm (inhalable fraction; vapor) OEL chemical category Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen, skin - potential for cutaneous exposure
citral (5392-40-5)	Spain - Occupational Exposure Limits	VLA-ED (OEL TWA) 5 ppm (inhalable fraction and vapor) OEL chemical category Sensitizer, skin - potential for cutaneous absorption
citral (5392-40-5)	USA - ACGIH - Occupational Exposure Limits	ACGIH® TLV® TWA 5 ppm (inhalable fraction and vapor) ACGIH® chemical category Not Classifiable as a Human Carcinogen, Skin - potential significant contribution to overall exposure by the cutaneous route, dermal sensitizer
Alcohol C-10 (112-30-1)	Bulgaria - Occupational Exposure Limits	OEL TWA 10 mg/m³
Alcohol C-10 (112-30-1)	Germany - Occupational Exposure Limits (TRGS 900)	AGW (OEL TWA) 66 mg/m³ (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 10 ppm (the risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed)
Alcohol C-10 (112-30-1)	Latvia - Occupational Exposure Limits	OEL TWA 10 mg/m³
Alcohol C-10 (112-30-1)	Lithuania - Occupational Exposure Limits	IPRV (OEL TWA) 10 mg/m³
Alcohol C-10 (112-30-1)	Romania - Occupational Exposure Limits	OEL TWA 100 mg/m³ 15 ppm OEL STEL 200 mg/m³ 30 ppm
Alcohol C-10 (112-30-1)	Switzerland - Occupational Exposure Limits	MAK (OEL TWA) 66 mg/m³ (aerosol, vapour) 10 ppm (aerosol, vapour) KZGW (OEL STEL) 66 mg/m³ (aerosol, vapour) 10 ppm (aerosol, vapour)
Aldehyde C-6 (66-25-1)	Finland - Occupational Exposure Limits	HTP (OEL STEL) 42 mg/m³ 10 ppm
Aldehyde C-6 (66-25-1)	Poland - Occupational Exposure Limits	NDS (OEL TWA) 40 mg/m³ NDSCh (OEL STEL) 80 mg/m³

8.2. Controale ale expunerii

Controale inginerești adecvate: Ensure good ventilation of the work station.

Echipament individual de protecție: Avoid all unnecessary exposure.

Protecția ochilor și a feței: Chemical goggles or safety glasses. Safety glasses

Protecția pielii și a corpului: Wear suitable protective clothing

Protecția mâinilor: Wear protective gloves.

Protecția respirației: Wear appropriate mask

Controale ale expunerii asupra mediului: Avoid release to the environment.

Alte informații: Do not eat, drink or smoke during use.

SECȚIUNEA 9: Proprietăți fizice și chimice

9.1. Informații privind proprietățile fizice și chimice de bază

Stare fizică: Liquid

Culoare: Conforms to standard.

Miros: characteristic.

Pragul de miros: Not available

Punct de topire: Not applicable

Punct de îngheț: Not available

Punct de fierbere: Not available

Inflamabilitate: Non flammable.

Limita inferioară de explozie: Not available

Limita superioară de explozie: Not available

Punct de aprindere: > 93 °C

Temperatura de autoaprindere: Not available

Temperatura de descompunere: Not available

pH: Not available

Vâscozitate, cinematică: Not available

Solubilitate: Not available

Coeficient de partiție n-octanol/apă (Log Kow): Not available

Presiune de vapori: Not available

Presiune de vapori la 50°C: Not available

Densitate: Not available

Densitate relativă: Not available

Densitate relativă a vaporilor la 20°C: Not available

Caracteristici ale particulelor: Not applicable

9.2. Alte informații

No additional information available

SECȚIUNEA 10: Stabilitate și reactivitate

10.1. Reactivitate

The product is non-reactive under normal conditions of use, storage and transport.

10.2. Stabilitate chimică

Not established.

10.3. Posibilitatea de reacții periculoase

Not established.

10.4. Condiții de evitat

Direct sunlight. Extremely high or low temperatures.

10.5. Materiale incompatibile

Strong acids. Strong bases.

10.6. Produși de descompunere periculoși

fume. Carbon monoxide. Carbon dioxide.

SECȚIUNEA 11: Informații toxicologice

11.1. Informații privind clasele de pericol definite în Regulamentul (CE) nr. 1272/2008

Toxicitate acută (oral): Not classified

Toxicitate acută (dermal): Not classified

Toxicitate acută (inhalare): Not classified

Substanță	Date toxicologice
Hexyl cinnamic aldehyde (101-86-0)	LD50 oral rat 3100 mg/kg (Source: NLM_CIP) LD50 oral 3100 mg/kg LD50 dermal rabbit > 3000 mg/kg (Source: EPA_HPV) LC50 Inhalation - Rat > 5 mg/l/4h
tetrahydro-2-isobutyl-4-methylpyran-4-ol, mixed isomers (cis and trans) (63500-71-0)	LD50 dermal rabbit > 2000 mg/kg (Source: ECHA_API)
Patchouli oil (8014-09-3)	LD50 oral rat > 5 g/kg (Source: NLM_CIP)
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB) (1222-05-5)	LD50 oral rat > 3250 mg/kg (Source: CHEMVIEW) LD50 dermal rabbit > 3250 mg/kg (Source: CHEMVIEW) LC50 Inhalation - Rat > 5.04 mg/l/4h
Geraniol (106-24-1)	LD50 oral rat 3600 mg/kg (Source: NLM_CIP) LD50 oral 3600 mg/kg LD50 dermal rabbit > 5 g/kg (Source: NLM_CIP)
citral (5392-40-5)	LD50 oral rat 4960 mg/kg (Source: NLM_CIP) LD50 dermal rabbit 2250 mg/kg (Source: NLM_CIP)
Alcohol C-10 (112-30-1)	LD50 oral rat 4720 mg/kg (Source: NZ_CCID) LD50 dermal rat > 5000 mg/kg (Source: ECHA_API) LC50 Inhalation - Rat > 71 mg/l (Exposure time: 1 h Source: ECHA_API)
Aldehyde C-6 (66-25-1)	LD50 oral rat 4890 mg/kg (Source: NLM_CIP) LD50 dermal rabbit > 8100 mg/kg (Source: ECHA_API)

Corodare/iritație cutanată: Not classified

Informații suplimentare: Based on available data, the classification criteria are not met

Leziuni oculare grave/iritație oculară: Not classified

Informații suplimentare: Based on available data, the classification criteria are not met

Sensibilizare respiratorie sau cutanată: May cause an allergic skin reaction.

Informații suplimentare: Based on available data, the classification criteria are not met

Mutagenicitate la celulele germinale: Not classified

Carcinogenitate: Not classified

Toxicitate pentru reproducere: Not classified

STOT-single exposure: Not classified

STOT-repeated exposure: Not classified

Pericol prin aspirare: Not classified

11.2. Informații privind alte pericole

Other information

Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met

SECȚIUNEA 12: Informații ecologice

12.1. Toxicitate

Ecology - general: Toxic to aquatic life with long lasting effects.

Hazardous to the aquatic environment, short-term (acute): Not classified

Hazardous to the aquatic environment, long-term (chronic): Toxic to aquatic life with long lasting effects.

Substanță	Date ecotoxicologice
1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB) (1222-05-5)	LC50 - Fish [1] 0.452 mg/l Wolf, 1996d-27682 LC50 - Other aquatic organisms [1] > 0.14 mg/l REACH DOSSIER Pimephales promelas EC50 - Crustacea [2] 260 μg/l REACH Dossier EC50 - Other aquatic organisms [1] 0.131 mg/l REACH Dossier
Geraniol (106-24-1)	LC50 - Fish [1] 22 mg/l (Exposure time: 96 h - Species: Danio rerio [static] Source: ECHA)
citral (5392-40-5)	EC50 - Crustacea [1] 7 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 72h - Algae [1] 16 mg/l (Species: Desmodesmus subspicatus) EC50 96h - Algae [1] 19 mg/l (Species: Desmodesmus subspicatus)
Alcohol C-10 (112-30-1)	LC50 - Fish [1] 2.2 – 2.5 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) LC50 - Fish [2] 4.12 – 6.2 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static] Source: EPA) EC50 - Crustacea [1] 3 mg/l (Exposure time: 48 h - Species: Daphnia magna)
Aldehyde C-6 (66-25-1)	LC50 - Fish [1] 12 – 16.5 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA)

12.2. Persistență și degradabilitate

SHADES OF LEATHER #EU55799F 25% in DPG: Not established.

1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone: Rapidly degradable

Hexyl cinnamic aldehyde: Rapidly degradable

tetrahydro-2-isobutyl-4-methylpyran-4-ol, mixed isomers (cis and trans): Rapidly degradable

Patchouli oil: Rapidly degradable

1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB): Rapidly degradable

Geraniol: Rapidly degradable

citral: Rapidly degradable

Alcohol C-10: Rapidly degradable

Aldehyde C-6: Rapidly degradable

12.3. Potențial de bioacumulare

SHADES OF LEATHER #EU55799F 25% in DPG: Not established.

1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone: Partition coefficient n-octanol/water (Log Pow) 5.65 (at 30°C)

tetrahydro-2-isobutyl-4-methylpyran-4-ol, mixed isomers (cis and trans): Partition coefficient n-octanol/water (Log Pow) 1.65 (at 23 °C (at pH >6.09-<6.74)

Patchouli oil: Partition coefficient n-octanol/water (Log Pow) Not established

1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno[5,6-c]pyran, galaxolide, (HHCB): BCF - Fish [1] (1618 dimensionless (whole body w.w.) ; Log Pow 5.3 (at 25 °C (at pH 7)

Geraniol: Log Pow 2.6 (at 25 °C)

citral: Log Pow 2.76 (at 25 °C)

Alcohol C-10: Log Pow 4.5 (at 25 °C (at pH 6)

Aldehyde C-6: Log Pow 2.3 (at 25 °C (at pH 5)

12.4. Mobilitate în sol

No additional information available

12.5. Rezultatele evaluării PBT și vPvB

No additional information available

12.6. Proprietăți de perturbare endocrină

No additional information available

12.7. Alte efecte adverse

Other information: Avoid release to the environment.

SECȚIUNEA 13: Considerații privind eliminarea

13.1. Metode de tratare a deșeurilor

Metode de tratare a deșeurilor: Dispose of contents/container in accordance with licensed collector’s sorting instructions.

Recomandări pentru eliminarea produsului/ambalajului: Dispose in a safe manner in accordance with local/national regulations.

Informații ecologice privind deșeurile: Avoid release to the environment.

Cod HP: HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment

SECȚIUNEA 14: Informații privind transportul

In accordance with ADR / IMDG / IATA / ADN / RID

ADR	IMDG	IATA	ADN	RID
UN 3082	UN 3082	UN 3082	UN 3082	UN 3082
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone)	ENVIRONMENT