Fișă cu date de securitate conform Regulamentului (CE) nr. 1907/2006 (REACH) cu modificarea Regulamentului (UE) 2020/878
Limba: RO (Română)
Document: Safety Data Sheet
Tip produs: Perfumes, fragrances
Utilizare: Industrial; For professional use only
Funcție / categorie de utilizare: Odour agents
Forma produsului: Mixture
Denumirea produsului: GUERLAIN SHALIMAR #EU36035F 10% in DPG
Cod produs: EU36035F_10%
Tip produs: Perfumes, fragrances
Specificație de utilizare industrială/profesională: Industrial
Utilizare a substanței/amestecului: Perfumes, fragrances
Funcție sau categorie de utilizare: Odour agents
Utilizări contraindicate: No additional information available
No additional information available
No additional information available
Clasificare conform Regulamentului (CE) nr. 1272/2008 [CLP]:
Full text of H- and EUH-statements: see section 16
Efecte adverse fizico-chimice, asupra sănătății umane și asupra mediului: No additional information available
Pictograme de pericol (CLP): GHS07
Cuvânt de avertizare (CLP): Warning
Conține: Citrus medica limonum (Lemon) peel oil ; Patchouli oil; Carrot seed oil; COUMARIN; Citronellol Pure; Linalyl acetate; Linalool
Fraze de pericol (CLP):
Fraze de precauție (CLP):
Fraze suplimentare: For professional users only.
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
Not applicable
| Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
|---|---|---|---|
| benzyl benzoate | CAS-No.: 120-51-4 EC-No.: 204-402-9 EC Index-No.: 607-085-00-9 REACH-no: 01-2119976371-33 |
1.51 – 3.015 | Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Citrus medica limonum (Lemon) peel oil | CAS-No.: 8008-56-8 EC-No.: 284-515-8 |
0.75 – 1.5 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Repr. 2, H361 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| Linalool | CAS-No.: 78-70-6 EC-No.: 201-134-4 EC Index-No.: 603-235-00-2 REACH-no: 01-2119474016-42 |
0.69 – 1.38 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Linalyl acetate | CAS-No.: 115-95-7 EC-No.: 204-116-4 REACH-no: 01-2119454789-19 |
0.68 – 1.35 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| COUMARIN | CAS-No.: 91-64-5 EC-No.: 202-086-7 REACH-no: 01-2119943756-26 |
0.54 – 1.08 | Acute Tox. 4 (Oral), H302 Skin Sens. 1B, H317 |
| Citronellol Pure | CAS-No.: 106-22-9 EC-No.: 203-375-0 REACH-no: 01-2119453995-23 |
0.1615 – 0.32475 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Patchouli oil | CAS-No.: 8014-09-3 EC-No.: 616-944-7 EC Index-No.: 616-944-7 |
0.15 – 0.3 | Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| Carrot seed oil | CAS-No.: 8015-88-1 EC-No.: 616-965-1 |
0.06 – 0.12 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 |
| citral | CAS-No.: 5392-40-5 EC-No.: 226-394-6 EC Index-No.: 605-019-00-3 REACH-no: 01-2119462829-23 |
0.0305 – 0.05785 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Benzyl acetate substance with national workplace exposure limit(s) (BE, DK, ES, IE, LT, LV, PT, RO) |
CAS-No.: 140-11-4 EC-No.: 205-399-7 REACH-no: 01-2119638272-42 |
0.01 – 0.01 | Aquatic Chronic 3, H412 |
Full text of H- and EUH-statements: see section 16
Măsuri generale de prim ajutor: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
După inhalare: Allow affected person to breathe fresh air. Allow the victim to rest.
După contactul cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
După contactul cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
După înghițire: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Symptoms/effects: Not expected to present a significant hazard under anticipated conditions of normal use.
No additional information available
Mijloace de stingere adecvate: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Mijloace de stingere neadecvate: Do not use a heavy water stream.
No additional information available
Instrucțiuni de stingere a incendiilor: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protecție în timpul stingerii incendiului: Do not enter fire area without proper protective equipment, including respiratory protection.
Pentru personalul care nu face parte din serviciile de urgență: Evacuate unnecessary personnel.
Pentru echipele de intervenție: Equip cleanup crew with proper protection.
Proceduri de urgență: Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
See Section 8. Exposure controls and personal protection.
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
Condiții de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Produse incompatibile: Strong bases. Strong acids.
Materiale incompatibile: Sources of ignition. Direct sunlight.
Germany — Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids
Joint storage table:
Switzerland — Storage class (LK): LK 10/12 - Liquids
No additional information available
8.1.1. Valori-limită naționale de expunere profesională și valori-limită biologice
| Substanță | Țară / categorie | Limită |
|---|---|---|
| Benzyl acetate (140-11-4) | Belgium - Occupational Exposure Limits | OEL TWA 62 mg/m³ 10 ppm |
| Denmark - Occupational Exposure Limits | OEL TWA 61 mg/m³ 10 ppm OEL STEL 122 mg/m³ 20 ppm | |
| Ireland - Occupational Exposure Limits | OEL TWA 10 ppm OEL STEL 30 ppm (calculated) | |
| Latvia - Occupational Exposure Limits | OEL TWA 5 mg/m³ | |
| Lithuania - Occupational Exposure Limits | IPRV (OEL TWA) 5 mg/m³ | |
| Portugal - Occupational Exposure Limits | OEL TWA 10 ppm OEL chemical category A4 - Not Classifiable as a Human Carcinogen | |
| Romania - Occupational Exposure Limits | OEL TWA 50 mg/m³ 8 ppm OEL STEL 80 mg/m³ 13 ppm | |
| Spain - Occupational Exposure Limits USA - ACGIH - Occupational Exposure Limits | VLA-ED (OEL TWA) 62 mg/m³ 10 ppm ACGIH OEL TWA 10 ppm ACGIH chemical category Not Classifiable as a Human Carcinogen | |
| citral (5392-40-5) | Belgium - Occupational Exposure Limits | OEL TWA 32 mg/m³ (vapor and aerosol) 5 ppm (vapor and aerosol) OEL chemical category Skin |
| Ireland - Occupational Exposure Limits | OEL TWA 5 ppm OEL STEL 15 ppm (calculated) | |
| Poland - Occupational Exposure Limits | NDS (OEL TWA) 27 mg/m³ NDSCh (OEL STEL) 54 mg/m³ | |
| Portugal - Occupational Exposure Limits | OEL TWA 5 ppm (inhalable fraction; vapor) OEL chemical category Sensitizer dermal, A4 - Not Classifiable as a Human Carcinogen, skin - potential for cutaneous exposure | |
| Spain - Occupational Exposure Limits USA - ACGIH - Occupational Exposure Limits | VLA-ED (OEL TWA) 5 ppm (inhalable fraction and vapor) OEL chemical category Sensitizer, skin - potential for cutaneous absorption ACGIH OEL TWA 5 ppm (inhalable fraction and vapor) ACGIH chemical category Not Classifiable as a Human Carcinogen, Skin - potential significant contribution to overall exposure by the cutaneous route, dermal sensitizer |
8.1.2. Proceduri recomandate de monitorizare: No additional information available
8.1.3. Contaminanți aerieni formați: No additional information available
8.1.4. DNEL și PNEC: No additional information available
8.1.5. Control banding: No additional information available
8.2.1. Controale inginerești adecvate: No additional information available
Echipament individual de protecție: Avoid all unnecessary exposure.
8.2.2.1. Protecția ochilor și a feței
Eye protection: Chemical goggles or safety glasses
8.2.2.2. Protecția pielii
Hand protection: Wear protective gloves.
8.2.2.3. Protecția respiratorie
Respiratory protection: Wear appropriate mask
8.2.2.4. Pericole termice
No additional information available
Other information: Do not eat, drink or smoke during use.
| Physical state | Liquid |
|---|---|
| Colour | Conforms to standard. |
| Odour | characteristic. |
| Odour threshold | Not available |
| Melting point | Not available |
| Freezing point | Not available |
| Boiling point | Not available |
| Flammability | Non flammable. |
| Lower explosion limit | Not available |
| Upper explosion limit | Not available |
| Flash point | > 93 °C |
| Auto-ignition temperature | Not available |
| Decomposition temperature | Not available |
| pH | Not available |
| Viscosity, kinematic | Not available |
| Solubility | Not available |
| Partition coefficient n-octanol/water (Log Kow) | Not available |
| Vapour pressure | Not available |
| Vapour pressure at 50°C | Not available |
| Density | Not available |
| Relative density | Not available |
| Relative vapour density at 20°C | Not available |
| Particle characteristics | Not applicable |
9.2.1. Informații cu privire la clasele de pericol fizic: No additional information available
9.2.2. Alte caracteristici de siguranță: No additional information available
10.1. Reactivitate: No additional information available
10.2. Stabilitate chimică: Not established.
10.3. Posibilitatea de reacții periculoase: Not established.
10.4. Condiții de evitat: Direct sunlight. Extremely high or low temperatures.
10.5. Materiale incompatibile: Strong acids. Strong bases.
10.6. Produși de descompunere periculoși: fume. Carbon monoxide. Carbon dioxide.
Toxicitate acută (oral): Not classified
Toxicitate acută (dermal): Not classified
Toxicitate acută (inhalare): Not classified
| Substanță | Date toxicologice |
|---|---|
| Benzyl acetate (140-11-4) | LD50 oral rat 2490 mg/kg (Source: JAPAN_GHS) LD50 oral 2490 mg/kg bodyweight LD50 dermal rabbit > 5000 mg/kg (Source: JAPAN_GHS) |
| citral (5392-40-5) | LD50 oral rat 4960 mg/kg (Source: NLM_CIP) LD50 dermal rabbit 2250 mg/kg (Source: NLM_CIP) |
| Citrus medica limonum (Lemon) peel oil (8008-56-8) | LD50 oral rat 2840 mg/kg (Source: NLM_CIP) |
| Patchouli oil (8014-09-3) | LD50 oral rat > 5 g/kg (Source: NLM_CIP) |
| COUMARIN (91-64-5) | LD50 oral rat > 5000 mg/kg (Source: JAPAN_GHS) LD50 dermal rat 293 mg/kg (Source: ECHA_API) |
| Citronellol Pure (106-22-9) | LD50 oral rat 3450 mg/kg (Source: NLM_CIP) LD50 oral 3450 mg/kg bodyweight LD50 dermal rabbit 2650 mg/kg (Source: EPA_HPV) LD50 dermal 2650 mg/kg bodyweight |
| Linalyl acetate (115-95-7) | LD50 oral rat 14550 mg/kg (Source: EPA_HPV) LD50 dermal rabbit > 5000 mg/kg (Source: ECHA) LC50 Inhalation - Rat > 18.94 mg/l (Exposure time: 8 h Source: ECHA) |
| Linalool (78-70-6) | LD50 oral 2790 mg/kg |
| benzyl benzoate (120-51-4) | LD50 oral rat > 2000 mg/kg (Source: ECHA_API) LD50 oral 1160 mg/kg bodyweight LD50 dermal rabbit 4000 mg/kg (Source: NLM_CIP) |
Corodare/iritare a pielii: Not classified
Additional information: Based on available data, the classification criteria are not met
Leziune/iritare oculară gravă: Not classified
Additional information: Based on available data, the classification criteria are not met
Sensibilizare respiratorie sau cutanată: May cause an allergic skin reaction.
Additional information: Based on available data, the classification criteria are not met
Mutagenicitate asupra celulelor germinale: Not classified
Additional information: Based on available data, the classification criteria are not met
Carcinogenicitate: Not classified
Additional information: Based on available data, the classification criteria are not met
Benzyl acetate (140-11-4) — IARC group: 3 - Not classifiable
COUMARIN (91-64-5) — IARC group: 3 - Not classifiable
Toxicitate pentru reproducere: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-single exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
STOT-repeated exposure: Not classified
Additional information: Based on available data, the classification criteria are not met
Pericol prin aspirație: Not classified
Additional information: Based on available data, the classification criteria are not met
benzyl benzoate (120-51-4) — Viscosity, kinematic: 7.456 mm²/s
11.2.1. Proprietăți care perturbă sistemul endocrin: No additional information available
11.2.2. Alte informații: Potential adverse human health effects and symptoms: Based on available data, the classification criteria are not met
Hazardous to the aquatic environment, short–term (acute): Not classified
Hazardous to the aquatic environment, long–term (chronic): Harmful to aquatic life with long lasting effects.
| Substanță | Date ecotoxicologice |
|---|---|
| citral (5392-40-5) | EC50 - Crustacea [1] 7 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 72h - Algae [1] 16 mg/l (Species: Desmodesmus subspicatus) EC50 96h - Algae [1] 19 mg/l (Species: Desmodesmus subspicatus) |
| Linalyl acetate (115-95-7) | LC50 - Fish [1] 11 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [flow-through] Source: ECHA) |
| Linalool (78-70-6) | EC50 96h - Algae [1] 88.3 mg/l (Species: Desmodesmus subspicatus) |
| benzyl benzoate (120-51-4) | LC50 - Fish [1] 2.32 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static] Source: ECHA) NOEC (chronic) 0.168 mg/l |
GUERLAIN SHALIMAR #EU36035F 10% in DPG: Persistence and degradability Not established.
GUERLAIN SHALIMAR #EU36035F 10% in DPG: Bioaccumulative potential Not established.
12.4. Mobilitate în sol: No additional information available
12.5. Rezultatele evaluării PBT și vPvB: No additional information available
12.6. Proprietăți care perturbă sistemul endocrin: No additional information available
12.7. Alte efecte adverse: Avoid release to the environment.
Recomandări privind eliminarea produsului/ambalajului: Dispose in a safe manner in accordance with local/national regulations.
Informații ecologice: Avoid release to the environment.
Cod HP: HP4 - “Irritant – skin irritation and eye damage:” waste which on application can cause skin irritation or damage to the eye.
HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|
| Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
14.1. Număr ONU sau număr de identificare: Not applicable
14.2. Denumirea oficială ONU pentru transport: Not applicable
14.3. Clasa (clasele) de pericol pentru transport: Not applicable
14.4. Grupul de ambalare: Not applicable
14.5. Pericole pentru mediu: Not applicable
No supplementary information available
14.6. Precauții speciale pentru utilizatori:
Overland transport: Not applicable
Transport by sea: Not applicable
Air transport: Not applicable
Inland waterway transport: Not applicable
Rail transport: Not applicable
14.7. Transport maritim în vrac conform instrumentelor IMO: Not applicable
REACH Annex XVII (Restriction List)
EU restriction list (REACH Annex XVII)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(a) | Citrus medica limonum (Lemon) peel oil ; Carrot seed oil | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F |
| 3(b) | GUERLAIN SHALIMAR #EU36035F 10% in DPG ; citral ; Citrus medica limonum (Lemon) peel oil ; Patchouli oil ; Carrot seed oil ; Citronellol Pure ; Linalyl acetate ; Linalool ; benzyl benzoate | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | GUERLAIN SHALIMAR #EU36035F 10% in DPG ; Benzyl acetate ; Citrus medica limonum (Lemon) peel oil ; Patchouli oil ; Carrot seed oil ; benzyl benzoate | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 |
| 40. | Citrus medica limonum (Lemon) peel oil ; Carrot seed oil | Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. |
REACH Annex XIV (Authorisation List): Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC): Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent): Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants): Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009): Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Council Regulation (EC) for the control of dual-use items: Contains no substance subject to the COUNCIL REGULATION (EC) for the control of dual-use items
Explosives Precursors Regulation (2019/1148): Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004): Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
Germany
Water hazard class (WGK) : WGK 2, Significantly hazardous to water (Classification according to AwSV, Annex 1).
Major Accidents Ordinance (12. BImSchV) : Is not subject to the Major Accidents Ordinance (12. BImSchV)
Netherlands
ABM category : A(2) - toxic for aquatic organisms, may have longterm hazardous effects in aquatic environment
SZW-lijst van kankerverwekkende stoffen : Lemon oil is listed
SZW-lijst van mutagene stoffen : Lemon oil is listed
SZW-lijst van reprotoxische stoffen – Borstvoeding : None of the components