Pictograme de pericol (CLP): GHS07, GHS09
Declarații de pericol:
H317 - May cause an allergic skin reaction.
H411 - Toxic to aquatic life with long lasting effects.
Declarații de precauție:
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P321 - Specific treatment (see supplemental first aid instruction on this label).
| Nume | Identificator produs | % | Clasificare conform Regulamentului (CE) Nr. 1272/2008 [CLP] |
|---|---|---|---|
| Hexyl cinnamic aldehyde | CAS-No.: 101-86-0 EC-No.: 202-983-3 REACH-no: 01-2119533092-50 | 1.425 – 2.832725 | Skin Sens. 1, H317 Aquatic Chronic 2, H411 |
| Hexyl salicylate | CAS-No.: 6259-76-3 EC-No.: 228-408-6 EC Index-No.: 607-772-00-3 | 1.1015 – 2.2520675 | Skin Sens. 1B, H317 Repr. 2, H361d Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Benzyl salicylate | CAS-No.: 118-58-1 EC-No.: 204-262-9 EC Index-No.: 607-754-00-5 REACH-no: 01-2119969442-31 | 0.95 – 1.90555 | Eye Irrit. 2, H319 Skin Sens. 1B, H317 Aquatic Chronic 3, H412 |
| 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone | CAS-No.: 54464-57-2 EC-No.: 259-174-3 REACH-no: 01-2119489989-04 | 0.85 – 1.7137 | Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 1, H410 |
| Ethylene brassylate | CAS-No.: 105-95-3 EC-No.: 203-347-8 REACH-no: 01-2119976314-33 | 0.75 – 1.5222 | Aquatic Chronic 2, H411 |
| Linalool | CAS-No.: 78-70-6 EC-No.: 201-134-4 EC Index-No.: 603-235-00-2 REACH-no: 01-2119474016-42 | 0.65 – 1.320075 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1B, H317 |
| Vertenex | CAS-No.: 32210-23-4 EC-No.: 250-954-9 REACH-no: 01-2119976286-24 | 0.575 – 1.149225 | Skin Sens. 1B, H317 |
| Linalyl acetate | CAS-No.: 115-95-7 EC-No.: 204-116-4 REACH-no: 01-2119454789-19 | 0.325 – 0.6375 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Sandela | CAS-No.: 66068-84-6 EC-No.: 266-100-3 | 0.175 – 0.3629 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 |
| 2-methylpentane-2,4-diol | substance with national workplace exposure limit(s) (AT, BE, DK, ES, FI, FR, GB, GR, HR, IE, LT, PL, PT, SE, NO, CH) CAS-No.: 107-41-5 EC-No.: 203-489-0 | 0.175 – 0.36145 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 |
| Helional | CAS-No.: 1205-17-0 EC-No.: 214-881-6 EC Index-No.: 605-042-00-9 REACH-no: 01-2120740119-58 | 0.1 – 0.201625 | Skin Sens. 1B, H317 Repr. 2, H361 Aquatic Chronic 2, H411 |
| Sandal Mysore Core | CAS-No.: 28219-60-5 EC-No.: 248-907-2 | 0.1 – 0.2016 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| Cyclamal | CAS-No.: 103-95-7 EC-No.: 203-161-7 REACH-no: 01-2119970582-32 | 0.075 – 0.141125 | Skin Irrit. 2, H315 Skin Sens. 1B, H317 Aquatic Chronic 2, H411 |
| Benzyl acetate | substance with national workplace exposure limit(s) (BE, DK, ES, IE, LT, LV, PT, RO) CAS-No.: 140-11-4 EC-No.: 205-399-7 REACH-no: 01-2119638272-42 | 0.025 – 0.060475 | Aquatic Chronic 3, H412 |
| (R)-p-mentha-1,8-diene; d-limonene | substance with national workplace exposure limit(s) (DE, ES, FI, SI, NO, CH) CAS-No.: 5989-27-5 EC-No.: 205-341-0 EC Index-No.: 601-096-00-2 REACH-no: 01-2119493353-35 | 0.025 – 0.0479 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 |
| dipentene; limonene | substance with national workplace exposure limit(s) (EE, LT, SE, NO) CAS-No.: 138-86-3 EC-No.: 205-341-0 | 0 – 0.005175 | Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| .alpha.-Pinene | substance with national workplace exposure limit(s) (BE, EE, ES, LT, PT, SE, NO) CAS-No.: 80-56-8 EC-No.: 201-291-9 | 0 – 0.0019 | Flam. Liq. 3, H226 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
| citral | substance with national workplace exposure limit(s) (BE, ES, IE, PL, PT) CAS-No.: 5392-40-5 EC-No.: 226-394-6 EC Index-No.: 605-019-00-3 REACH-no: 01-2119462829-23 | 0 – 0.000675 | Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 |
| Dipropylene glycol monomethyl ether | substance with national workplace exposure limit(s) (AT, BE, BG, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GI, GR, HR, HU, IE, IT, LT, LU, LV, MT, NL, PL, PT, RO, SE, SI, SK, NO, CH, TR); substance with a Community workplace exposure limit CAS-No.: 34590-94-8 EC-No.: 252-104-2 | 0.0000635 – 0.0001208405 | Not classified |
| Toluene | substance with national workplace exposure limit(s) (AT, BE, BG, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GI, GR, HR, HU, IE, IT, LT, LU, LV, MT, NL, PL, PT, RO, SE, SI, SK, NO, CH, TR); substance with a Community workplace exposure limit CAS-No.: 108-88-3 EC-No.: 203-625-9 EC Index-No.: 601-021-00-3 | ≤ 0.00000142725 | Not classified |
Măsuri generale: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
După inhalare: Allow affected person to breathe fresh air. Allow the victim to rest.
După contactul cu pielea: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.
După contactul cu ochii: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists.
După înghițire: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Instrucțiuni de stingere a incendiilor: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protecție în timpul stingerii incendiilor: Do not enter fire area without proper protective equipment, including respiratory protection.
Pentru personalul care nu intervine în urgență: Evacuate unnecessary personnel.
Pentru echipele de intervenție: Equip cleanup crew with proper protection. Ventilate area.
Condiții de depozitare: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.
Produse incompatibile: Strong bases. Strong acids.
Materiale incompatibile: Sources of ignition. Direct sunlight.
| Țara | Clasa de depozitare / indicații |
|---|---|
| Germany | Storage class (LGK, TRGS 510): LGK 12 - Non-combustible liquids Joint storage table: vezi tabelul din documentul original |
| Switzerland | Storage class (LK): LK 10/12 - Liquids |
| Substanță | Exemple de limite ocupaționale / biomonitorizare |
|---|---|
| 2-methylpentane-2,4-diol | Limite naționale în multiple state; valori TWA/STEL variabile; notare piele în unele țări. |
| Benzyl acetate | Limite naționale TWA/STEL; categorie A4 în Portugalia; fără clasificare ca carcinogen uman în ACGIH. |
| (R)-p-mentha-1,8-diene; d-limonene | Limite TWA/STEL în mai multe state; sensibilizant; posibilă absorbție cutanată. |
| Toluene | IOEL TWA 192 mg/m³, 50 ppm; IOEL STEL 384 mg/m³, 100 ppm; numeroase limite biologice și mențiuni privind absorbția cutanată. |
| Dipropylene glycol monomethyl ether | IOEL TWA 308 mg/m³, 50 ppm; mențiuni privind absorbția cutanată. |
| dipentene; limonene | Limite TWA/STEL în unele state; sensibilizant. |
| .alpha.-Pinene | Limite TWA/STEL în unele state; sensibilizant dermal. |
| citral | Limite TWA/STEL mici; sensibilizant dermal; posibilă absorbție cutanată. |
10.1. Reactivitate
No additional information available
10.2. Stabilitate chimică
Not established.
10.3. Posibilitatea de reacții periculoase
Not established.
10.4. Condiții de evitat
Direct sunlight. Extremely high or low temperatures.
10.5. Materiale incompatibile
Strong acids. Strong bases.
10.6. Produși de descompunere periculoși
fume. Carbon monoxide. Carbon dioxide.
| Ingredient | Date toxicologice reprezentative |
|---|---|
| Hexyl cinnamic aldehyde | LD50 oral rat 3100 mg/kg; LD50 dermal rabbit > 3000 mg/kg; LC50 Inhalation - Rat > 5 mg/l/4h |
| Hexyl salicylate | LD50 oral rat > 5 g/kg; LD50 dermal rabbit > 5000 mg/kg |
| Benzyl salicylate | LD50 oral rat 2227 mg/kg; LD50 dermal rabbit > 5000 mg/kg |
| Ethylene brassylate | LD50 oral rat > 5000 mg/kg; LD50 dermal rabbit > 5000 mg/kg |
| Linalool | LD50 oral rat 2790 mg/kg; LD50 dermal rabbit 5610 mg/kg |
| Vertenex | LD50 oral rat 5 g/kg; LD50 dermal rabbit > 5000 mg/kg |
| Linalyl acetate | LD50 oral rat 14550 mg/kg; LD50 dermal rabbit > 5000 mg/kg; LC50 Inhalation - Rat > 18.94 mg/l |
| Sandela | LD50 dermal rat > 2000 mg/kg; LC50 Inhalation - Rat > 5.27 mg/l/4h |
| 2-methylpentane-2,4-diol | LD50 oral rat 3700 mg/kg; LD50 dermal rabbit 12300 mg/kg; LC50 Inhalation - Rat > 310 mg/m³ |
| Helional | LD50 dermal rabbit > 2000 mg/kg |
| Cyclamal | LD50 oral rat 3810 mg/kg; LD50 dermal rat > 5000 mg/kg |
| Benzyl acetate | LD50 oral rat 2490 mg/kg; LD50 dermal rabbit > 5000 mg/kg |
| (R)-p-mentha-1,8-diene; d-limonene | LD50 oral rat 4400 mg/kg; LD50 dermal rabbit > 5 g/kg |
| Toluene | LD50 oral rat 2600 mg/kg; LD50 dermal rabbit 12000 mg/kg; LC50 Inhalation - Rat 12.5 mg/l/4h |
| Dipropylene glycol monomethyl ether | LD50 oral rat 5.35 g/kg; LD50 dermal rabbit 9500 mg/kg |
| dipentene; limonene | LD50 oral rat 5300 mg/kg |
| .alpha.-Pinene | LD50 oral rat 3700 mg/kg; LD50 dermal rat > 5000 mg/kg |
| citral | LD50 oral rat 4960 mg/kg; LD50 dermal rabbit 2250 mg/kg |
Corodarea/iritarea pielii: Not classified
Daune/iritare oculară severă: Not classified
Sensibilizare respiratorie sau cutanată: May cause an allergic skin reaction.
Mutagenicitatea celulelor germinale: Not classified
Carcinogenicitate: Not classified
Toxicitate pentru reproducere: Not classified
STOT - expunere unică: Not classified
STOT - expunere repetată: Not classified
Pericol prin aspirare: Not classified
Alte informații: Based on available data, the classification criteria are not met
Hazardous to the aquatic environment, short–term (acute): Not classified
Hazardous to the aquatic environment, long–term (chronic): Toxic to aquatic life with long lasting effects.
| Ingredient | Date ecotoxicologice reprezentative |
|---|---|
| Benzyl salicylate | LC50 - Fish [1] 1.03 mg/l (96 h, Danio rerio) |
| Linalool | LC50 - Fish [1] 27.8 mg/l (96 h, Oncorhynchus mykiss); EC50 - Crustacea [1] 20 mg/l; EC50 96h - Algae [1] 88.3 mg/l |
| Vertenex | LC50 - Fish [1] 8.6 mg/l (96 h, Cyprinus carpio) |
| Linalyl acetate | LC50 - Fish [1] 11 mg/l (96 h, Cyprinus carpio) |
| 2-methylpentane-2,4-diol | LC50 - Fish [1] 10.5 (10500–11000) mg/l; LC50 - Fish [2] 10000 mg/l; EC50 - Crustacea [1] 2.7 (2700–3700) mg/l |
| (R)-p-mentha-1,8-diene; d-limonene | LC50 - Fish [1] 0.619–0.796 mg/l; LC50 - Fish [2] 35 mg/l |
| Toluene | LC50 - Fish [1] 15.22–19.05 mg/l; LC50 - Fish [2] 12.6 mg/l; EC50 - Crustacea [1] 5.46–9.83 mg/l; EC50 - Crustacea [2] 11.5 mg/l; EC50 72h - Algae [1] 12.5 mg/l; EC50 96h - Algae [1] > 433 mg/l |
| Dipropylene glycol monomethyl ether | LC50 - Fish [1] > 10000 mg/l; EC50 - Crustacea [1] 1919 mg/l |
| .alpha.-Pinene | LC50 - Fish [1] 0.28 mg/l; EC50 - Crustacea [1] 41 mg/l |
| citral | EC50 - Crustacea [1] 7 mg/l; EC50 72h - Algae [1] 16 mg/l; EC50 96h - Algae [1] 19 mg/l |
YVES SAINT LAUREN OPIUM #EU46259F 25% in DPG: Persistence and degradability Not established.
Majoritatea componentelor listate: Rapidly degradable
Ethylene brassylate: May cause long-term adverse effects in the environment.
YVES SAINT LAUREN OPIUM #EU46259F 25% in DPG: Bioaccumulative potential Not established.
| Ingredient | Coeficient de partiție n-octanol/apă (Log Pow) |
|---|---|
| Hexyl salicylate | 5.5 (at 30 °C (at pH 7) |
| Benzyl salicylate | 4 |
| 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone | 5.65 (at 30°C) |
| Ethylene brassylate | 4.3 (at 25 °C (at pH 6.4-7) |
| Linalool | 2.9 (at 20 °C (at pH 7) |
| Vertenex | 4.8 (at 25 °C) |
| Linalyl acetate | 3.9 (at 25 °C) |
| 2-methylpentane-2,4-diol | < 0.14 |
| Helional | 2.4 (at 25 °C) |
| Sandal Mysore Core | 3.8 |
| Cyclamal | 3.4 (at 35 °C) |
| Benzyl acetate | 1.96 (at 25 °C (at pH 7) |
| (R)-p-mentha-1,8-diene; d-limonene | 4.38 (at 37 °C (at pH 7.2) |
| Toluene | 2.73 (at 20 °C (at pH 7) |
| Dipropylene glycol monomethyl ether | 0.35 (at 25 °C (at pH 7) |
| .alpha.-Pinene | 4.1 |
| citral | 2.76 (at 25 °C) |
YVES SAINT LAUREN OPIUM #EU46259F 25% in DPG: Avoid release to the environment.
Ethylene brassylate (105-95-3): Avoid release to the environment.
Cyclamal (103-95-7): Avoid release to the environment.
Recomandări privind eliminarea produsului/ambalajului: Dispose in a safe manner in accordance with local/national regulations.
Informații ecologice privind deșeurile: Avoid release to the environment.
HP Code: HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one or more sectors of the environment
In accordance with ADR / IMDG / IATA / ADN / RID
| ADR | IMDG | IATA | ADN | RID |
|---|---|---|---|---|
| Not applicable | Not applicable | Not applicable | Not applicable | Not applicable |
14.1. Număr ONU sau număr de identificare: Not applicable
14.2. Denumirea corectă ONU pentru expediție: Not applicable
14.3. Clasa (clasele) de pericol pentru transport: Not applicable
14.4. Grupul de ambalare: Not applicable
14.5. Pericole pentru mediu: Not applicable
14.6. Precauții speciale pentru utilizatori: Not applicable
14.7. Transport maritim în vrac conform instrumentelor IMO: Not applicable
EU-Regulations
REACH Annex XVII (Restriction List)
| Reference code | Applicable on | Entry title or description |
|---|---|---|
| 3(a) | d-Limonene ; Dipentene ; .alpha.-Pinene | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F |
| 3(b) | YVES SAINT LAUREN OPIUM #EU46259F 25% in DPG ; Hexyl cinnamic aldehyde ; Hexyl salicylate ; Benzyl salicylate ; 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone ; Linalool ; Vertenex ; Linalyl acetate ; Sandela ; 2-Methyl-2,4-pentandiol ; Helional ; Sandal Mysore Core ; Cyclamal ; d-Limonene ; Dipentene ; .alpha.-Pinene ; Citral | Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 |
| 3(c) | YVES SAINT LAUREN OPIUM #EU46259F 25% in DPG ; Hexyl cinnamic aldehyde ; Hexyl salicylate ; Benzyl salicylate ; 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalen |